Patents by Inventor Richard J. Ambrose
Richard J. Ambrose has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
-
Patent number: 4551807Abstract: Curing of rubber in a mold is disclosed wherein a desired modulus or viscosity for the cured rubber product is obtained on the basis of an equation developed from a relaxation phenomenon. The cure process may be isothermal and non-isothermal and is controlled in a manner to compensate for acceleration of the cure reaction due to an increase in carbon black filler loading and the effect thereof which broadens the relaxation spectrum. Control of the curing process for the rubber material according to the equation permits response to the effect of the presence of a filler which reduces the activation energy of the viscous flow and that the presence of the filler produces a small effect on the activation energy of the cure reaction.Type: GrantFiled: August 17, 1983Date of Patent: November 5, 1985Assignee: Lord CorporationInventors: Henry S. Y. Hsich, Richard J. Ambrose
-
Patent number: 4508874Abstract: Polymeric compositions having resistance to impact comprising (a) from about 50 to about 90 percent by weight of a polyamide having a number average molecular weight of at least 10,000 and (b) from about 10 to about 50 percent by weight of a maleic anhydride adduct of a hydrogenated polymer of one or more conjugated dienes or a hydrogenated copolymer of a conjugated diene and a vinyl aromatic hydrocarbon, said hydrogenated polymer or copolymer having a residual unsaturation content of from about 0.5 to about 20% of its original unsaturation content prior to hydrogenation; wherein at least 5 percent by weight of components (a) and (b) are present in the form of a graft copolymer containing at least 20 percent of polyamide. The compositions exhibit especially advantageous properties, particularly high impact strength and are useful in a variety of molding applications such as molded bushings, gears, cams, valves and a variety of other products.Type: GrantFiled: November 4, 1983Date of Patent: April 2, 1985Assignee: The Firestone Tire & Rubber CompanyInventors: William L. Hergenrother, Mark G. Matlock, Richard J. Ambrose
-
Patent number: 4427828Abstract: Polymeric compositions having resistance to impact comprising (a) from about 50 to about 90 percent by weight of a polyamide having a number average molecular weight of at least 10,000 and (b) from about 10 to about 50 percent by weight of a maleic anhydride adduct of a hydrogenated polymer of one or more conjugated dienes or a hydrogenated copolymer of a conjugated diene and a vinyl aromatic hydrocarbon, said hydrogenated polymer or copolymer having a residual unsaturation content of from about 0.5 to about 20% of its original unsaturation content prior to hydrogenation; wherein at least 5 percent by weight of components (a) and (b) are present in the form of a graft copolymer containing at least 20 percent of polyamide. The compositions exhibit especially advantageous properties, particularly high impact strength and are useful in a variety of molding applications such as molded bushings, gears, cams, valves and a variety of other products.Type: GrantFiled: August 20, 1982Date of Patent: January 24, 1984Assignee: The Firestone Tire & Rubber CompanyInventors: William L. Hergenrother, Mark G. Matlock, Richard J. Ambrose
-
Patent number: 4316967Abstract: Polymers of anionically polymerized monomers such as mono-olefins, conjugated dienes, vinyl substituted aromatics, vinyl substituted pyridine, vinyl substituted quinolines, various aldehydes, various epoxides, various oxetanes, various oxygen-containing compounds, and the like are produced and end capped with a polyisocyanate or polyisothiocyanate having the formula R--N.dbd.C.dbd.X).sub.n wherein R is a hydrocarbon, n is 2 or 3, and X is oxygen or sulfur. Such end capped polymers, of course, contain one reacted or connected isocyanate or isothiocyanate group and at least one free isocyanate or isothiocyanate end group, which free end group(s) reacts with an amide to give an imide end group. The imide terminated polymer is then hydrolyzed to form a stable amine terminated polymer. The reaction of the amide compound with the isocyanate(s) or isothiocyanate(s), followed by hydrolysis, results in the replacement of the free isocyanate or isothiocyanate end group(s) with an amine group(s).Type: GrantFiled: March 5, 1979Date of Patent: February 23, 1982Assignee: The Firestone Tire & Rubber CompanyInventors: William L. Hergenrother, Richard A. Schwarz, Richard J. Ambrose, Robert A. Hayes
-
Patent number: 4299932Abstract: Polymers of anionically polymerized monomers such as mono-olefins, conjugated dienes, vinyl substituted aromatics, vinyl substituted pyridine, vinyl substituted quinolines, various aldehydes, various epoxides, various oxetanes, various oxygen-containing compounds, and the like are produced and end capped with a polyisocyanate or polyisothiocyanate having the formula R--N.dbd.C.dbd.X).sub.n wherein R is a hydrocarbon, n is 2 or 3, and X is oxygen or sulfur. Such end capped polymers, of course, contain one reacted or connected isocyanate or isothiocyanate group and at least one free isocyanate or isothiocyanate end group, which free end group(s) reacts with an amide to give an imide end group. The imide terminated polymer is then hydrolyzed to form a stable amine terminated polymer. The reaction of the amide compound with the isocyanate(s) or isothiocyanate(s), followed by hydrolysis, results in the replacement of the free isocyanate or isothiocyanate end group(s) with an amine group(s).Type: GrantFiled: March 5, 1979Date of Patent: November 10, 1981Assignee: The Firestone Tire & Rubber CompanyInventors: William L. Hergenrother, Richard A. Schwarz, Richard J. Ambrose, Robert A. Hayes
-
Patent number: 4298707Abstract: Polymers of anionically polymerized monomers such as mono-olefins, conjugated dienes, vinyl substituted aromatics, vinyl substituted pyridine, vinyl substituted quinolines, various aldehydes, various epoxides, various oxetanes, various oxygen-containing compounds, and the like are produced and end capped with a polyisocyanate or polyisothiocyanate having the formula R--N.dbd.C.dbd.X).sub.n wherein R is a hydrocarbon, n is 2 or 3, and X is oxygen or sulfur. Such end capped polymers, of course, contain one reacted or connected isocyanate or isothiocyanate group and at least one free isocyanate or isothiocyanate end group, which free end group(s) reacts with an amide to give an imide end group. The imide terminated polymer is then hydrolyzed to form a stable amine terminated polymer. The reaction of the amide compound with the isocyanate(s) or isothyiocyanate(s), followed by hydrolysis, results in the replacement of the free isocyanate or isothiocyanate end group(s) with an amine group(s).Type: GrantFiled: March 5, 1979Date of Patent: November 3, 1981Assignee: The Firestone Tire & Rubber CompanyInventors: William L. Hergenrother, Richard A. Schwarz, Richard J. Ambrose, Robert A. Hayes
-
Patent number: 4239860Abstract: Polymers of anionically polymerized monomers such as mono-olefins, conjugated dienes, vinyl substituted aromatics, vinyl substituted pyridiine, vinyl substituted quinolines, various aldehydes, various epoxides, various oxetanes, various oxgen-containing compounds, and the like are produced and end capped with a polyisocyanate or polyisothiocyanate having the formula R--N.dbd.C.dbd.X).sub.n wherein R is a hydrocarbon, n is 2 or 3, and X is oxygen or sulfur. Such end capped polymers, of course, contain one reacted or connected isocyanate or isothiocyanate group and at least one free isocyanate or isothiocyanate end group, which free end groups(s) reacts with an amide to give an imide end group. The imide terminated polymer is then hydrolyzed to form a stable amine terminated polymer. The reaction of the amide compound with the isocyanate(s) or isothiocyanate(s), followed by hydrolysis, results in the replacement of the free isocyanate or isothiocyanate end group(s) with an amine group(s).Type: GrantFiled: March 5, 1979Date of Patent: December 16, 1980Assignee: The Firestone Tire & Rubber CompanyInventors: William L. Hergenrother, Richard A. Schwarz, Richard J. Ambrose, Robert A. Hayes
-
Patent number: 4235979Abstract: Polymers of anionically polymerized monomers such as mono-olefins, conjugated dienes, vinyl substituted aromatics, vinyl substituted pyridine, vinyl substituted quinolines, various aldehydes, various epoxides, various oxetanes, various oxygen-containing compounds, and the like are produced and end capped with a polyisocyanate or polyisothiocyanate having the formula R--N.dbd.C.dbd.X).sub.n wherein R is a hydrocarbon, n is 2 or 3, and X is oxygen or sulfur. Such end capped polymers, of course, contain one reacted or connected isocyanate or isothiocyanate group and at least one free isocyanate or isothiocyanate end group, which free end group(s) reacts with an amide to give an imide end group. The imide terminated polymer is then hydrolyzed to form a stable amine terminated polymer. The reaction of the amide compound with the isocyanate(s) or isothiocyanate(s), followed by hydrolysis, results in the replacement of the free isocyanate or isothiocyanate end group(s) with an amine group(s).Type: GrantFiled: March 5, 1979Date of Patent: November 25, 1980Assignee: The Firestone Tire & Rubber CompanyInventors: William L. Hergenrother, Richard A. Schwarz, Richard J. Ambrose, Robert A. Hayes
-
Patent number: 4157429Abstract: Polymers of anionically polymerized monomers such as conjugated dienes, vinyl substituted aromatics, olefinic type compounds, and heterocyclic nitrogen containing compounds, are produced and end capped with a polyisocyanate or polyisothiocyanate. Such end capped polymers are then reacted with compounds containing an amide such as lactam to give an imide type end group. The imide type terminated polymer is hydrolyzed to form a stable amine terminated polymer which may be utilized, as a composition of matter or stored for a short period of time to an extended period of time and reacted with other various polymers and monomers, or various combinations of monomers to form various block or graft polymers. That is the amine polymer may be subsequently reacted with any amine reactive compound such as with a polyisocyanate or polyisothiocyanate and a lactam in the presence of a known anionic Iactam polymerization catalysts to give a blocked nylon copolymer.Type: GrantFiled: April 29, 1977Date of Patent: June 5, 1979Assignee: The Firestone Tire & Rubber CompanyInventors: William L. Hergenrother, Richard A. Schwarz, Richard J. Ambrose, Robert A. Hayes
-
Patent number: 4157430Abstract: Polymers of anionically polymerized monomers such as conjugated dienes, vinyl substituted aromatics, olefinic type compounds, and heterocyclic nitrogen containing compounds, are produced and end capped with a polyisocyanate or polyisothiocyanate. Such end capped polymers are then reacted with compounds containing an amide such as lactam to give an imide type end group. The imide type terminated polymer is hydrolyzed to form a stable amine terminated polymer which may be utilized, as a composition of matter or stored for a short period of time to an extended period of time and reacted with other various polymers and monomers, or various combinations of monomers to form various block or graft polymers. That is the amine polymer may be subsequently reacted with any amine reactive compound such as with a polyisocyanate or polyisothiocyanate and a lactam in the presence of a known anionic Iactam polymerization catalysts to give a blocked nylon copolymer.Type: GrantFiled: April 29, 1977Date of Patent: June 5, 1979Assignee: The Firestone Tire & Rubber CompanyInventors: William L. Hergenrother, Richard A. Schwarz, Richard J. Ambrose, Robert A. Hayes
-
Patent number: 4155948Abstract: Polymers of anionically polymerized monomers such as conjugated dienes, vinyl substituted aromatics, olefinic type compounds, and heterocyclic nitrogen containing compounds, are produced and end capped with a polyisocyanate or polyisothiocyanate. Such end capped polymers are then reacted with compounds containing an amide such as lactam to give an imide type end group. The imide type terminated polymer is hydrolyzed to form a stable amine terminated polymer which may be utilized, as a composition of matter or stored for a short period of time to an extended period of time and reacted with other various polymers and monomers, or various combinations of monomers to form various block or graft polymers. That is the amine polymer may be subsequently reacted with any amine reactive compound such as with a polyisocyanate or polyisothiocyanate and a lactam in the presence of a known anionic lactam polymerization catalysts to give a blocked nylon copolymer.Type: GrantFiled: June 10, 1977Date of Patent: May 22, 1979Assignee: The Firestone Tire & Rubber CompanyInventors: William L. Hergenrother, Richard A. Schwartz, Richard J. Ambrose, Robert A. Hayes
-
Patent number: 4155947Abstract: Polymers of anionically polymerized monomers such as conjugated dienes, vinyl substituted aromatics, olefinic type compounds, and heterocyclic nitrogen containing compounds, are produced and end capped with a polyisocyanate or polyisothiocyanate. Such end capped polymers are then reacted with compounds containing an amide such as lactam to give an imide type end group. The imide type terminated polymer is hydrolyzed to form a stable amine terminated polymer which may be utilized, as a composition of matter or stored for a short period of time to an extended period of time and reacted with other various polymers and monomers, or various combinations of monomers to form various block or graft polymers. That is the amine polymer may be subsequently reacted with any amine reactive compound such as with a polyisocyanate or polyisothiocyanate and a lactam in the presence of a known anionic Iactam polymerization catalysts to give a blocked nylon copolymer.Type: GrantFiled: June 10, 1977Date of Patent: May 22, 1979Assignee: The Firestone Tire & Rubber CompanyInventors: William L. Hergenrother, Richard A. Schwarz, Richard J. Ambrose, Robert A. Hayes
-
Patent number: 4154913Abstract: Polymers of anionically polymerized monomers such as conjugated dienes, vinyl substituted aromatics, olefinic type compounds, and heterocyclic nitrogen containing compounds, are produced and end capped with a polyisocyanate or polyisothiocyanate. Such end capped polymers are then reacted with compounds containing an amide such as lactam to give an imide type end group. The imide type terminated polymer is hydrolyzed to form a stable amine terminated polymer which may be utilized, as a composition of matter or stored for a short period of time to an extended period of time and reacted with other various polymers and monomers, or various combinations of monomers to form various block or graft polymers. That is the amine polymer may be subsequently reacted with any amine reactive compound such as with a polyisocyanate or polyisothiocyanate and a lactam in the presence of a known anionic lactam polymerization catalysts to give a blocked nylon copolymer.Type: GrantFiled: June 10, 1977Date of Patent: May 15, 1979Assignee: The Firestone Tire & Rubber CompanyInventors: William L. Hergenrother, Richard A. Schwarz, Richard J. Ambrose, Robert A. Hayes
-
Patent number: 4154773Abstract: Polymers of anionically polymerized monomers such as conjugated dienes, vinyl substituted aromatics, olefinic type compounds, and heterocyclic nitrogen containing compounds, are produced and end capped with a polyisocyanate or polyisothiocyanate. Such end capped polymers are then reacted with compounds containing an amide such as lactam to give an imide type end group. The imide type terminated polymer is hydrolyzed to form a stable amine terminated polymer which may be utilized, as a composition of matter or stored for a short period of time to an extended period of time and reacted with other various polymers and monomers, or various combinations of monomers to form various block or graft polymers. That is the amine polymer may be subsequently reacted with any amine reactive compound such as with a polyisocyanate or polyisothiocyanate and a lactam in the presence of a known anionic Iactam polymerization catalysts to give a blocked nylon copolymer.Type: GrantFiled: June 10, 1977Date of Patent: May 15, 1979Assignee: The Firestone Tire & Rubber CompanyInventors: William L. Hergenrother, Richard A. Schwarz, Richard J. Ambrose, Robert A. Hayes
-
Patent number: 4154772Abstract: Polymers of anionically polymerized monomers such as conjugated dienes, vinyl substituted aromatics, olefinic type compounds, and heterocyclic nitrogen containing compounds, are produced and end capped with a polyisocyanate or polyisothiocyanate. Such end capped polymers are then reacted with compounds containing an amide such as lactam to give an imide type end group. The imide type terminated polymer is hydrolyzed to form a stable amine terminated polymer which may be utilized, as a composition of matter or stored for a short period of time to an extended period of time and reacted with other various polymers and monomers, or various combinations of monomers to form various block or graft polymers. That is the amine polymer may be subsequently reacted with any amine reactive compound such as with a polyisocyanate or polyisothiocyanate and a lactam in the presence of a known anionic Iactam polymerization catalysts to give a blocked nylon copolymer.Type: GrantFiled: June 10, 1977Date of Patent: May 15, 1979Assignee: The Firestone Tire & Rubber CompanyInventors: William L. Hergenrother, Richard A. Schwarz, Richard J. Ambrose, Robert A. Hayes
-
Patent number: 4151222Abstract: Polymers of anionically polymerized monomers such as mono-olefins, conjugated dienes, vinyl substituted aromatics, vinyl substituted pyridine, vinyl substituted quinolines, various aldehydes, various epoxides, various oxetanes, various oxygen-containing compounds, and the like are produced and end capped with a polyisocyanate or polyisothiocyanate having the formula R--(N.dbd.C.dbd.X).sub.n wherein R is a hydrocarbon, n is 2 or 3, and X is oxygen or sulfur. Such end capped polymers, of course, contain one reacted or connected isocyanate or isothiocyanate group and at least one free isocyanate or isothiocyanate end group, which free end group(s) reacts with an amide to give an imide end group. The imide terminated polymer is then hydrolyzed to form a stable amine terminated polymer. The reaction of the amide compound with the isocyanate(s) or isothiocyanate(s), followed by hydrolysis, results in the replacement of the free isocyanate or isothiocyanate end group(s) with an amine group(s).Type: GrantFiled: November 7, 1977Date of Patent: April 24, 1979Assignee: The Firestone Tire & Rubber CompanyInventors: William L. Hergenrother, Richard A. Schwarz, Richard J. Ambrose, Robert A. Hayes
-
Patent number: 4075186Abstract: A graft copolymer composition comprises a butadiene polymer grafted onto or pendent from a backbone consisting solely of a substituted polyacrylate. The substituted acrylate polymer is prepared from monomers having the formula: ##STR1## where R.sub.1 is a hydrocarbon radical of 1 through 30 carbon atoms selected from the group consisting of alkyl, cycloalkyl, aryl and aralkyl and where R.sub.2 is a hydrocarbon radical containing from 1 through 12 carbon atoms selected from the group consisting of alkyl, cycloalkyl, aryl, and aralkyl.Type: GrantFiled: January 21, 1976Date of Patent: February 21, 1978Assignee: The Firestone Tire & Rubber CompanyInventors: Richard J. Ambrose, Robert A. Hayes
-
Patent number: 4070344Abstract: Polymers of anionically polymerized monomers such as conjugated dienes, vinyl substituted aromatics, olefinic type compounds, and heterocyclic nitrogen containing compounds, are produced and end capped with a polyisocyanate or polyisothiocyanate. Such end capped polymers are then reacted with compounds containing an amide such as lactam to give an imide type end group. The imide type terminated polymer is hydrolyzed to form a stable amine terminated polymer which may be utilized, as a composition of matter or stored for a short period of time to an extended period of time and reacted with other various polymers and monomers, or various combinations of monomers to form various block or graft polymers. That is, the amine polymer may be subsequently reacted with any amine reactive compound such as with a polyisocyanate or polyisothiocyanate and a lactam in the presence of a known anionic lactam polymerizaton catalyst to give a blocked nylon copolymer.Type: GrantFiled: May 5, 1975Date of Patent: January 24, 1978Assignee: The Firestone Tire and Rubber CompanyInventors: William L. Hergenrother, Richard A. Schwarz, Richard J. Ambrose, Robert A. Hayes