Abstract: Chlorous acid is generated from a chlorite salt precursor, a chlorate salt precursor, or a combination of both by ion exchange. The ion exchange material facilitates the generation of chlorous acid by simultaneously removing unwanted cations from solution and adding hydrogen ion to solution. Chlorine dioxide is generated in a controlled manner from chlorous acid by catalysis. Chlorine dioxide can be generated either subsequent to the generation of chlorous acid or simultaneously with the generation of chlorous acid. For catalysis of chlorous acid to chlorine dioxide, the chlorous acid may be generated by ion exchange or in a conventional manner. Ion exchange materials are also used to purify the chlorous acid and chlorine dioxide solutions, without causing degradation of said solutions, to exchange undesirable ions in the chlorous acid and chlorine dioxide solutions with desirable ions, such as stabilizing ions, and to adjust the pH of chlorous acid and chlorine dioxide solutions.

Abstract: Chlorous acid is generated from a chlorite salt precursor, a chlorate salt precursor, or a combination of both by ion exchange. The ion exchange material facilitates the generation of chlorous acid by simultaneously removing unwanted cations from solution and adding hydrogen ion to solution. Chlorine dioxide is generated in a controlled manner from chlorous acid by catalysis. Chlorine dioxide can be generated either subsequent to the generation of chlorous acid or simultaneously with the generation of chlorous acid. For catalysis of chlorous acid to chlorine dioxide, the chlorous acid may be generated by ion exchange or in a conventional manner. Ion exchange materials are also used to purify the chlorous acid and chlorine dioxide solutions, without causing degradation of said solutions, to exchange undesirable ions in the chlorous acid and chlorine dioxide solutions with desirable ions, such as stabilizing ions, and to adjust the pH of chlorous acid and Chlorine dioxide solutions.

Abstract: Chlorine dioxide solutions are stabilized and prepared for storage, transportation, and testing. Each solution is separated into two samples. Chlorine dioxide is removed from one sample and then each sample is stabilized and prepared such that each sample contains only oxidized and/or reduced forms of chlorine dioxide. The stable samples may be stored, transported, and tested for chlorine dioxide. The samples are tested for the oxidized and/or reduced forms of chlorine dioxide by known methods, and mass balance equations are used to determine the concentration of chlorine dioxide in the original sample before stabilization and preparation.

Abstract: A method for determining the concentration of chlorine dioxide in a chlorine dioxide solution having the following steps: (1) isolating two samples, Sample 1 and Sample 2, from the chlorine dioxide solution; (2) stripping the chlorine dioxide from Sample 1; (3) completely converting the chlorine dioxide in Sample 2 to other chlorine species; (4) transporting the chlorine dioxide samples either within the facility or outside the facility to a testing site; (5) separately determining the concentration of the chlorine containing species in each of Samples 1 and 2; and (6) calculating the concentration of chlorine dioxide in said chlorine dioxide solution based upon the information obtained in step (5).

Abstract: The halogen dioxide, chlorine dioxide is produced from its chlorite reactant using ion exchange media in a stable reactant form, and then passing a known concentration of counter ions through the ion exchange media in a moist environment so that there is an exchange of ions, and the reactants that are released form activated chlorine dioxide within the ion exchange material. The ion exchange media both contributes reactants to and extracts contaminants from the moist environment via its ion exchange mechanism. The counter ions may be derived from one or more stable precursor solutions which themselves may contain reactants and/or soluble catalysts. The reactants of the precursor solutions cannot act as the counter ion, or ions, in the ion exchange mechanism, but the soluble catalysts can. The ion exchange media can be mixed or layered with one or more insoluble catalysts, to enhance the formation of the activated halogen dioxide, chlorine dioxide within the ion exchange material.

Abstract: Chlorous acid is generated from a chlorite salt precursor, a chlorate salt precursor, or a combination of both by ion exchange. The ion exchange material facilitates the generation of chlorous acid by simultaneously removing unwanted cations from solution and adding hydrogen ion to solution. Chlorine dioxide is generated in a controlled manner from chlorous acid by catalysis. Chlorine dioxide can be generated either subsequent to the generation of chlorous acid or simultaneously with the generation of chlorous acid. For catalysis of chlorous acid to chlorine dioxide, the chlorous acid may be generated by ion exchange or in a conventional manner. Ion exchange materials are also used to purify the chlorous acid and chlorine dioxide solutions, without causing degradation of said solutions, to exchange undesirable ions in the chlorous acid and chlorine dioxide solutions with desirable ions, such as stabilizing ions, and to adjust the pH of chlorous acid and chlorine dioxide solutions.

Abstract: An apparatus for producing a cleaning solution. Specifically, the apparatus of some embodiments includes a reservoir for containing sodium chlorite. A disposable ion exchange cartridge is placed in fluid communication with the sodium chlorite reservoir via a conduit. The ion exchange cartridge is selectively disconnectable from fluid communication with the sodium chlorite reservoir or from the conduit. Generally, the ion exchange cartridge will be disconnected and replaced when the ion exchange materials in the cartridge are depleted or exhausted. A catalyst can also be placed in fluid communication with the sodium chlorite reservoir. The catalyst can be contained in disposable or selectively disconnectable cartridge that can be easily replaced when depleted. In another aspect of the invention, a color comparison chart is positioned adjacent a conduit to allow one to compare the color of the solution to the chart and determine the concentration of the solution.

Abstract: The halogen dioxide, chlorine dioxide is produced from its chlorite reactant using ion exchange media in a stable reactant form, and then passing a known concentration of counter ions through the ion exchange media in a moist environment so that there is an exchange of ions, and the reactants that are released form activated chlorine dioxide within the ion exchange material. The ion exchange media both contributes reactants to and extracts contaminants from the moist environment via its ion exchange mechanism. The counter ions may be derived from one or more stable precursor solutions which themselves may contain reactants and/or soluble catalysts. The reactants of the precursor solutions cannot act as the counter ion, or ions, in the ion exchange mechanism, but the soluble catalysts can. The ion exchange media can be mixed or layered with one or more insoluble catalysts, to enhance the formation of the activated halogen dioxide, chlorine dioxide within the ion exchange material.

Abstract: Chlorous acid is generated from a chlorite salt precursor, a chlorate salt precursor, or a combination of both by ion exchange. The ion exchange material facilitates the generation of chlorous acid by simultaneously removing unwanted cations from solution and adding hydrogen ion to solution. Chlorine dioxide is generated in a controlled manner from chlorous acid by catalysis. Chlorine dioxide can be generated either subsequent to the generation of chlorous acid or simultaneously with the generation of chlorous acid. For catalysis of chlorous acid to chlorine dioxide, the chlorous acid may be generated by ion exchange or in a conventional manner. Ion exchange materials are also used to purify the chlorous acid and chlorine dioxide solutions, without causing degradation of said solutions, to exchange undesirable ions in the chlorous acid and chlorine dioxide solutions with desirable ions, such as stabilizing ions, and to adjust the pH of chlorous acid and chlorine dioxide solutions.

Abstract: Chlorous acid is generated from a chlorite salt precursor, a chlorate salt precursor, or a combination of both by ion exchange. The ion exchange material facilitates the generation of chlorous acid by simultaneously removing unwanted cations from solution and adding hydrogen ion to solution. Chlorine dioxide is generated in a controlled manner from chlorous acid by catalysis. Chlorine dioxide can be generated either subsequent to the generation of chlorous acid or simultaneously with the generation of chlorous acid. For catalysis of chlorous acid to chlorine dioxide, the chlorous acid may be generated by ion exchange or in a conventional manner. Ion exchange materials are also used to purify the chlorous acid and chlorine dioxide solutions, without causing degradation of said solutions, to exchange undesirable ions in the chlorous acid and chlorine dioxide solutions with desirable ions, such as stabilizing ions, and to adjust the pH of chlorous acid and chlorine dioxide solutions.

Abstract: An electrolytic process and apparatus is disclosed for oxidizing or reducing inorganic and organic species, especially in dilute aqueous solutions, and for water purification and treatment. The electrolytic reactor includes an anode, cathode and a packed bed of particulate ion exchange material which, preferably, is modified by converting a portion of the transfer sites to semiconductor junctions which act as mini anodes, or cathodes, to significantly increase the capacity of the reactor to oxidize or reduce the species to be treated, or split water. The ion exchange material may be a monobed of either modified anion exchange material or modified cation exchange material, or a mixed bed of both, and can be in direct contact with either the anode or cathode, or separated from both. Under the influence of direct current, free radical hydroxyl, free radical hydrogen, regenerant hydroxyl ion and/or regenerant hydrogen ion are generated.

Abstract: An electrolytic process and apparatus are disclosed for water purification and pH adjustment. The electrolytic reactor includes an anode, cathode and a bed of particulate ion exchange material modified by converting a portion of the transfer sites to semiconductor junctions. The ion exchange material may be a monobed of either modified anion exchange material or modified cation exchange material, or a mixed bed of both. Undesirable ions are exchanged onto the ion exchange material at the ion exchange sites. Regenerant ions, produced at the semiconductor junctions then exchange with the undesirable ions attached to the ion exchange material, and the undesirable ions migrate through the bed toward the respective anode or cathode and out of the aqueous solution. The pH of the aqueous solution can be adjusted by passing the solution through either a modified cation resin bed or through a modified anion resin bed to lower or increase the pH, respectively.

Abstract: Ion exchange materials, as particulate and membranes, are modified by permanently attaching counter ions to a portion of the ion exchange sites. The permanent attachment of the counter ions forms semiconductor junctions which act as mini anodes, or cathodes, to significantly increase the ability to oxidize or reduce a species to be treated, or split water, in an electrolytic reactor. The non-converted transfer sites in the ion exchange material also significantly increase the mobility of the ionic species in the electrolyte. The ion exchange material may be a monobed of either modified anion exchange material or modified cation exchange material, or a suitable mixed bed of both, depending upon the application. When the anode is in direct contact with a modified cation exchange material and under the influence of direct current, free radical hydroxyl and regenerant hydrogen are formed.

Abstract: Improvements on the electrolytic reactor and process of U.S. Pat. No. 5,419,816 and copending U.S. application Ser. No. 08/400,950, filed Mar. 9, 1995, now U.S. Pat. No. 5,609,742, are disclosed for the controlled oxidation and reduction of inorganic and organic species in dilute aqueous solutions. More specifically, other physical forms and additives for the modified ion exchange material can be used in the packed bed electrolytic reactor, including powdered ion exchange materials and solid membranes containing the modified ion exchange materials. Direct contact with only one electrode, the anode for oxidation, and the cathode for reduction, is required for the modified ion exchange resin, instead of with both electrodes. Superior performance is also demonstrated for bipolar operation of the electrolytic reactor in comparison to monopolar operation. Preferably, the polarity of the electrodes is reversed every 1 to 60 minutes.

Abstract: An electrolytic process and apparatus is disclosed for oxidizing or reducing inorganic and organic species, especially in dilute aqueous solutions. The electrolytic reactor includes an anode and cathode in contact with a packed bed of particulate ion exchange material which establishes an infinite number of transfer sites in the electrolyte to significantly increase the mobility of the ionic species to be oxidized or reduced toward the anode or cathode, respectively. The ion exchange material is cationic for oxidation and anionic for reduction, or a combination of both for special circumstances. Preferably, the ion exchange material is treated to convert a portion of the transfer sites to semiconductor junctions which act as mini anodes, or cathodes, to significantly increase the capacity of the reactor to oxidize or reduce the species to be treated. Exemplary applications for the disclosed electrolytic process and apparatus are the conversion of halides to halous acids in dilute solutions.

Abstract: An electrolytic process and apparatus is disclosed for oxidizing or reducing inorganic and organic species, especially in dilute aqueous solutions. The electrolytic reactor includes an anode and cathode in contract with a packed bed of particulate ion exchange material which establishes an infinite number of transfer sites in the electrolyte to significantly increase the mobility of the ionic species to be oxidized or reduced toward the anode or cathode, respectively. The ion exchange material is cationic for oxidation and anionic for reduction, or a combination of both for special circumstances. Preferably, the ion exchange material is treated to convert a portion of the transfer sites to semiconductor junctions which act as mini anodes, or cathodes, to significantly increase the capacity of the reactor to oxidize or reduce the species to be treated. Exemplary applications for the disclosed electrolytic process and apparatus are the conversion of halides to halous acids in dilute solutions.

Abstract: A method of regenerating an ion exchanger which is used to treat a solution introduced to the ion exchanger in a downward charging direction. The ion exchanger comprises a non-constrained bed of ion exchange material in the form of ion exchange granules and has a concentration profile through the ion exchange material after the solution has been introduced to the ion exchanger in the charging direction. The method in one embodiment comprises passing a regenerating solution upwardly through the non-constrained bed of ion exchange material in an intermittent pulsed flow comprising a pulse or up flow of regenerating solution, a subsequent non-flow pause time, followed by a down flow pulse in a direction opposite to the up flow.

Abstract: A method of regenerating an ion exchanger which is used to treat a solution introduced to the ion exchanger in a downward changing direction. The ion exchanger contains a non-constrained bed of ion exchange material in the form of ion exchange granules and has a concentration profile through the ion exchange material after solution has been introduced to the ion exchanger in the charging direction. The method of regenerating comprises passing a regenerating solution upwardly through the non-constrained bed of ion exchange material in an intermittent flow manner comprising an alternating up flow of regenerating solution followed by a down flow of liquid in a direction opposite to the up flow. The duration and velocity of the up flow of regenerating solution is sufficient to lift and generate a perceptible mixing of ion exchange materials in approximately the bottom portion of the ion exchange bed, with the down flow being sufficient to seat the bed very rapidly and terminate mixing.

Abstract: A low-cost solar air heater is disclosed which utilizes an array of jets to produce impingement of the air on the lower surface of the absorber plate which enhances heat transfer efficiency.