Abstract: The invention relates to a method for improving the performance of coated nickel electrodes in chloralkali electrolysis by adding water-soluble platinum compounds to the catholyte during the electrolysis at low current density.

Abstract: The invention relates to a method for improving the performance of nickel electrodes in alkali chloride electrolysis by adding water-soluble platinum compounds to the catolyte.

Abstract: The invention relates to a method for improving the performance of nickel electrodes in alkali chloride electrolysis by adding water-soluble platinum compounds to the catolyte.

Abstract: A method is described for the electrolysis of an aqueous solution of hydrogen chloride or alkali metal chloride in an electrolysis cell. The cell includes at least of an anode half-element and an anode, a cathode half-element and a gas diffusion electrode as the cathode, and a cation exchange membrane for separating the anode half-element and the cathode half-element. A gas containing oxygen is supplied to the cathode half-element and excess gas containing oxygen is discharged from the cathode half-element. Excess gas containing oxygen discharged from the cathode half-element is subjected to catalytic oxidation of hydrogen.

Abstract: The invention relates to a method for improving the performance of nickel electrodes in alkali chloride electrolysis by adding water-soluble platinum compounds to the catolyte.

Abstract: The present invention relates to a process for absorbing chlorine from a gas containing chlorine and carbon dioxide, in particular to a process for washing small amounts of chlorine out of a waste gas stream containing a large excess of carbon dioxide, wherein the washed waste gas can be released directly into the atmosphere.

Abstract: A method is described for the electrolysis of an aqueous solution of hydrogen chloride or alkali metal chloride in an electrolysis cell. The cell includes at least of an anode half-element and an anode, a cathode half-element and a gas diffusion electrode as the cathode, and a cation exchange membrane for separating the anode half-element and the cathode half-element. A gas containing oxygen is supplied to the cathode half-element and excess gas containing oxygen is discharged from the cathode half-element. Excess gas containing oxygen discharged from the cathode half-element is subjected to catalytic oxidation of hydrogen.

Abstract: The present invention relates to an electrochemical cell suitable for a membrane electrolysis process, comprising (i) at least one anode compartment having a metal electrode, (ii) a cathode compartment having a gas diffusion electrode (iii) and an ion exchange membrane arranged between the anode compartment and the cathode compartment. The metal electrode that functions as an anode is capable of being dipped into an electrolyte during use and is provided with one or more orifices for the passage of gas formed during operation. The metal electrode can optionally be angled and/or curved, and the orifices preferably have guide structures that conduct the gas formed to a side of the metal electrode that faces away from the cathode. The present invention also relates to electrodes per se as well as methods for use of electrodes and electrochemical cells.

Abstract: The invention describes an electrochemical half-cell, in particular for the electrolysis of aqueous solutions of hydrogen chloride, at least comprising a gas space, the gas space having a gas feed and a gas discharge as well as a liquid outlet, and a gas diffusion electrode which rests on an electrically conductive current distributor and makes an electrically conductive contact with the current distributor, the current distributor having a free area in the range from 5 to 65%, preferably from 10 to 60%, particularly preferably from 15 to 50%, based on the total area of the current distributor, and a thickness of from 0.3 mm to 5 mm, preferably from 0.35 to 0.6 mm.