Abstract: A method of manufacturing a preform, the method including positioning at least one glass tube in a glass outer cladding to form a preform precursor, the glass tube comprising a first open end and a second open end, forming a preform from the preform precursor, and thermally treating at least one of the preform precursor and the preform. The thermally treating including sealing the first open end and the second open end of the glass tube to form a closed tube and heating and/or cooling the glass tube to manipulate gas pressure within the closed glass tube.

Abstract: An aqueous treating medium may include water; an acid selected from the group consisting of: HCl, HBr, HNO3, H2SO4, H2SO3, H3PO4, H3PO2, HOAc, citric acid, tartaric acid, ascorbic acid, EDTA, methanesulfonic acid, toluenesulfonic acid, and combinations thereof, wherein a concentration of the acid in the aqueous treating medium is from 0.5 M to 1.5 M; a salt, wherein a concentration of the salt in the aqueous treating medium is from greater than 0 M to 2 M; a fluoride-containing compound selected from the group consisting of: HF, NaF, NH4HF2, and combinations thereof, wherein a concentration of the fluoride-containing compound in the aqueous treating medium is from 0.026 M to 0.26 M; and silica, wherein the aqueous treating medium is saturated with silica.

Abstract: The present disclosure is directed to various embodiments of methods for making an optical fiber. The methods may include drawing an optical fiber from a hollow-core preform. The hollow-core preform may include an annular support structure with an inner surface defining an interior cavity. The interior cavity may include a tube in direct contact with the inner surface of the annular support structure. The tube may include a wall defining an internal opening, the internal opening having a sealed end. The drawing may include regulating a pressure of the internal cavity to a predetermined pressure.

Abstract: The present invention relates to a method of forming an optical fiber precursor including: forming an alkali metal doped tube; inserting an optical fiber core rod within the alkali metal doped tube; forming a cladding jacket around the alkali metal doped tube; and diffusing an alkali metal from the alkali metal doped tube through a surface of the optical fiber core rod. The present invention further relates to an optical fiber preform having: an optical fiber core rod; an alkali metal doped tube surrounding the optical fiber core rod; and a cladding jacket surrounding the alkali metal doped tube.

Abstract: A coated glass article includes a glass article comprising a glass having a surface. The surface has an adhesion promoting region comprising a nanostructure formed at the surface of the glass. The adhesion promoting region is constructed of materials that are the same as one or more constituents of a glass composition of the glass. The coated glass article further includes a coating disposed on the adhesion promoting region formed at the surface of the glass. The coating incudes one or more polymer coating materials. The adhesion promoting region improves adhesion of the coating to the glass while also eliminating the use of titania or other adhesion promoting compounds that can adversely affect the optical properties of the coatings.

Abstract: An anti-resonant hollow core optical fiber preform that includes an outer cladding, a plurality of structural tubes, and a central support tube. The outer cladding has a length, a central longitudinal axis, and a hollow interior. The plurality of structural tubes are disposed within the hollow interior of the outer cladding, the plurality of structural tubes each having a length that extends the length of the outer cladding. And the central support tube is disposed within the hollow interior of the outer cladding such that the plurality of structural tubes are disposed radially outward of the central support tube, the central support tube having a length that extends along the central longitudinal axis of the outer cladding. Furthermore, the length of the central support tube is less than the length of the outer cladding.

Abstract: A method for forming an optical glass preform from a soot preform is provided. The method includes forming a soot preform, placing the soot preform in a furnace, and applying a vacuum through a centerline hole of the soot preform.

Abstract: An optical fiber can include a core comprising silica co-doped with nitrogen and chlorine and an outer cladding surrounding the core. In some aspects, the core can be characterized by an annealing temperature of less than or equal to about 1150° C. and/or the core can include a relative refractive index ?core in a range of from about 0.15% to about 0.45%.

Abstract: Glasses with compressive stress profiles that allow higher surface compression and deeper depth of layer (DOL) than is allowable in glasses with stress profiles that follow the complementary error function at a given level of stored tension. In some instances, a buried layer or local maximum of increased compression, which can alter the direction of cracking systems, is present within the depth of layer. Theses compressive stress profiles are achieved by a three step process that includes a first ion exchange step to create compressive stress and depth of layer that follows the complimentary error function, a heat treatment at a temperature below the strain point of the glass to partially relax the stresses in the glass and diffuse larger alkali ions to a greater depth, and a re-ion-exchange at short times to re-establish high compressive stress at the surface.

Abstract: Preparation of halogen-doped silica is described. The preparation includes doping silica with high halogen concentration, sintering halogen-doped silica to a closed-pore state, and subjecting the closed-pore silica body to a thermal treatment process and/or a pressure treatment process. The temperature of thermal treatment is sufficiently high to facilitate reaction of unreacted doping precursor trapped in voids or interstices of the glass structure, but is below temperatures conducive to foaming. Core canes or fibers drawn from halogen-doped silica subjected to the thermal treatment and/or pressure treatment show improved optical quality and possess fewer defects. The thermal treatment and/or pressure treatment is particularly advantageous when used for silica doped with high concentrations of halogen.

Abstract: A high-density optical fiber ribbon is formed by two or more cladding-strengthened glass optical fibers each having an outer surface and that do not individually include a protective polymer coating. A common protective coating substantially surrounds the outer surfaces of the two or more cladding-strengthened glass optical fibers so that the common protective coating is common to the two or more cladding-strengthened glass optical fibers. A fiber ribbon cable is formed by adding a cover assembly to the fiber ribbon. A fiber ribbon interconnect is formed adding one or more optical connectors to the fiber ribbon or fiber ribbon cable. Optical data transmission systems that employ the fiber ribbon to optically connect to a photonic device are also disclosed. Methods of forming the cladding-strengthened glass optical fibers and the high-density optical fiber ribbons are also disclosed.

Abstract: Preparation of halogen-doped silica is described. The preparation includes doping silica with high halogen concentration and sintering halogen-doped silica to a closed-pore state in a gas-phase environment that has a low partial pressure of impermeable gases. Impermeable gases are difficult to remove from halogen-doped fiber preforms and lead to defects in optical fibers drawn from the preforms. A low partial pressure of impermeable gases in the sintering environment leads to a low concentration of impermeable gases and a low density of gas-phase voids in densified halogen-doped silica. Preforms with fewer defects result.

Abstract: An optical fiber can include a core comprising silica co-doped with nitrogen and chlorine and an outer cladding surrounding the core. In some aspects, the core can be characterized by an annealing temperature of less than or equal to about 1150° C. and/or the core can include a relative refractive index ?core in a range of from about 0.15% to about 0.45%.

Abstract: A method of preparing an optical preform, comprises the steps of: positioning an optical preform comprising silica within a cavity of a furnace; passing an etchant gas into the furnace and at least one of through an open channel defined in the optical preform and around the optical preform; and passing a neutralizing gas into the cavity of the furnace, the neutralizing gas configured to neutralize the etchant gas.

Abstract: Disclosed herein are methods for forming an optical fiber preform using organic silica and germania precursors. The method includes depositing soot composed of germanium dioxide and silica on a substrate, removing the substrate, conducting a dehydration step and one or more heating steps under an oxygen-containing atmosphere to form the preform. Also disclosed are optical fibers drawn from the preforms produced herein.

Abstract: Preparation of halogen-doped silica is described. The preparation includes doping silica with high halogen concentration and sintering halogen-doped silica to a closed-pore state. The sintering includes a high pressure sintering treatment and a low pressure sintering treatment. The high pressure sintering treatment is conducted in the presence of a high partial pressure of a gas-phase halogen doping precursor and densifies a silica soot body to a partially consolidated state. The low pressure sintering treatment is conducted in the presence of a low partial pressure of gas-phase halogen doping precursor and transforms a partially consolidated silica body to a closed-pore state. The product halogen-doped silica glass exhibits little foaming when heated to form fibers in a draw process or core canes in a redraw process.

Abstract: Methods of manufacturing multi-mode optical fiber, and multi-mode optical fiber produced thereby, are disclosed. According to embodiments, a method for forming an optical fiber may include heating a multi-mode optical fiber preform and applying a draw tension to a root of the multi-mode optical fiber preform on a long axis of the multi-mode optical fiber preform thereby drawing a multi-mode optical fiber from the root of the multi-mode optical fiber preform. The draw tension may be modulated while the multi-mode optical fiber is drawn from the root of the multi-mode optical fiber preform. Modulating the draw tension introduces stress perturbations in the multi-mode optical fiber and corresponding refractive index perturbations in a core of the multi-mode optical fiber.

Abstract: A method of making an antimicrobial glass article that includes the steps: submersing the article in a strengthening bath to exchange a portion of ion-exchangeable metal ions in the glass article with a portion of ion-exchanging metal ions in the strengthening bath to form a compressive stress layer extending from the first surface to a diffusion depth in the article; removing a portion of the compressive stress layer from the first surface of the article to a first depth above the diffusion depth in the article to define a new first surface and a remaining compressive stress layer; and submersing the article in an antimicrobial bath to exchange a portion of the ion-exchangeable and the ion-exchanging metal ions in the compressive stress layer with a portion of the silver metal ions in the antimicrobial bath to impart an antimicrobial property in the article.

Abstract: A high-density optical fiber ribbon is formed by two or more cladding-strengthened glass optical fibers each having an outer surface and that do not individually include a protective polymer coating. A common protective coating substantially surrounds the outer surfaces of the two or more cladding-strengthened glass optical fibers so that the common protective coating is common to the two or more cladding-strengthened glass optical fibers. A fiber ribbon cable is formed by adding a cover assembly to the fiber ribbon. A fiber ribbon interconnect is formed adding one or more optical connectors to the fiber ribbon or fiber ribbon cable. Optical data transmission systems that employ the fiber ribbon to optically connect to a photonic device are also disclosed. Methods of forming the cladding-strengthened glass optical fibers and the high-density optical fiber ribbons are also disclosed.

Abstract: Preparation of halogen-doped silica is described. The preparation includes doping silica with high halogen concentration and sintering halogen-doped silica to a closed-pore state in a gas-phase environment that has a low partial pressure of impermeable gases. Impermeable gases are difficult to remove from halogen-doped fiber preforms and lead to defects in optical fibers drawn from the preforms. A low partial pressure of impermeable gases in the sintering environment leads to a low concentration of impermeable gases and a low density of gas-phase voids in densified halogen-doped silica. Preforms with fewer defects result.