Abstract: A luminescent polymer comprising a triarylene repeat unit which comprises a triarylene of general formula (I) which is substituted or unsubstituted and an arylene repeat unit -[-Ar-]- that is different from the triarylene repeat unit wherein X, Y, and Z are each independently O, S, CR2, SiR2 or NR and each R is independently alkyl, aryl or H.

Abstract: A polymer comprising a first repeat unit comprising ArhX2 wherein ArhX2 comprises a substituted or unsubstituted heteroaryl group and each X is the same or different and independently comprises a substituted or unsubstituted aryl or heteroaryl group and a second repeat unit that is adjacent to the first repeat unit wherein each X that is part of a main body of the polymer backbone is directly conjugated to the second repeat unit.

Abstract: A polymer comprising a first repeat unit comprising ArhX2 wherein ArhX2 comprises a substituted or unsubstituted heteroaryl group and each X is the same or different and independently comprises a substituted or unsubstituted aryl or heteroaryl group and a second repeat unit that is adjacent to the first repeat unit wherein each X that is part of a main body of the polymer backbone is directly conjugated to the second repeat unit.

Abstract: A polymer for use in an optical device comprising one or more regions, where each region comprises (i) a first structural unit having general formula I: where m=1 or 2 and which contains at least one substituent selected from the group consisting of alkyl, alkoxy, aryl, aryloxy, heteroaryl, and heteroaryloxy groups, each of which may be further substituted; and (ii) a second structural unit Ar selected from the group consisting of heteroaryl, triarylamine and 2,7-fluorenyl; such that where m=1 each region comprises a unit having general formula II: wherein, the substituent has a molecular weight of less than 300.

Abstract: The present invention relates to new semiconductive oligomers and polymers, a process for their manufacture and their use in thin film electronic and optical devices, such as organic light emitting diodes (OLED) and photovoltaic devices, eg. solar cells and photodetectors.

Abstract: A polymer for use in an optical device comprising a first, optionally substituted, repeat unit of formula and a second, optionally substituted, repeat unit of formula wherein each Ar and Ar? is the same or different and comprises an optionally substituted aryl or heteroaryl group and optionally a third, optionally substituted, repeat unit in a molar ratio of no greater than 5%, the third repeat unit having a formula —Ar—N(Ar)—Ar— and having a single nitrogen atom in its backbone.

Abstract: A soluble luminescent polymer comprising a first repeat unit [Ar1] and a second repeat unit comprising a unit of general formula (I) which is substituted or unsubstituted: wherein X is RC?CR, S, O or NR; Ar1, Ar2 and Ar3 are each independently an aromatic or heteroaromatic group; and each R independently is hydrogen or a substituent group.

Abstract: A polymer for use in an optical device comprising a hole transporting region, an electron transporting region, an emissive region, said polymer comprising an optionally substituted repeat unit of formula (I): wherein each Ar is the same or different and comprises an optionally substituted aryl group.

Abstract: A polymer having a first repeat unit comprising a group having general formula (I) which is substituted or unsubstituted: where at least one of R1 or R2 comprises at least two substituted or unsubstituted aryl or heteroaryl groups and excluding the group having general formula (I) where one or both of R1 and R2 comprises a triarylamine group.

Abstract: A method for making a polymer containing a first repeat unit having formula: —Ar—N(R)—Ar(N(R?)—Ar)x— which may be substituted or unsubstituted where x or 0 or 1; each Ar is the same or different and independently is a substituted or unsubstituted aryl or heteroaryl group and R and R? each is hydrogen or a substituent group and a second repeat unit that is the same or different from the first repeat unit and comprises a substituted or unsubstituted, aryl or heteroaryl group.

Abstract: Monomers having the formula X1—Ar1-[triarylamine]—Ar2-X2 wherein the triarylamine unit comprises at least one nitrogen atom in the backbone of the monomer and at least three substituted or unsubstituted aryl or heteroaryl groups and wherein X1 and X2 are the same or different polymerizable groups and wherein Ar1 and Ar2 are the same or different substituted or unsubstituted aryl or heteroaryl groups. Polymers and copolymers comprising such monomers are also described. The polymers have particular application in organic optoelectronic devices such as organic electroluminescent devices and organic photovoltaic devices.

Abstract: A luminescent polymer comprising a triarylene repeat unit which comprises a triarylene of general formula (I) which is substituted or unsubstituted and an arylene repeat unit -[-Ar-]- that is different from the triarylene repeat unit wherein X, Y, and Z are each independently O, S, CR2, SiR2 or NR and each R is independently alkyl, aryl or H.

Abstract: A polymer for use in an optical device comprising one or more regions, where each region comprises (i) a first structural unit having general formula I: where m=1 or 2 and which contains at least one substituent selected from the group consisting of alkyl, alkoxy, aryl, aryloxy, heteroaryl, and heteroaryloxy groups, each of which may be further substituted; and (ii) a second structural unit Ar selected from the group consisting of heteroaryl, triarylamine and 2,7-fluorenyl; such that where m=1 each region comprises a unit having general formula II: wherein, the substituent has a molecular weight of less than 300.

Abstract: A polymer for use in an optical device comprising one or more regions, where each region comprises (i) a first structural unit having general formula I: where m=1 or 2 and which contains at least one substituent selected from the group consisting of alkyl, alkoxy, aryl, aryloxy, heteroaryl, and heteroaryloxy groups, each of which may be further substituted; and (ii) a second structural unit Ar selected from the group consisting of heteroaryl, triarylamine and 2,7-fluorenyl; such that where m=1 each region comprises a unit having general formula II: first structural unit—Ar??(II) wherein, the substituent has a molecular weight of less than 300.

Abstract: The present invention relates to new semiconductive oligomers and polymers, a process for their manufacture and their use in thin film electronic and optical devices, such as organic light emitting diodes (OLED) and photovoltaic devices, eg. solar cells and photodetectors.

Abstract: A polymer including a region having a conjugated backbone capable of transporting negative charge carriers, which region includes a plurality of repeat units each including a core group which includes an [Ar?] group substituted with at least one pendant group X and the [Ar?] groups form at least a part of the backbone, wherein each Ar? includes an aromatic or heteroaromatic group and each X includes NAr2 in which each Ar is the same or different and independently includes a substituted or unsubstituted aromatic or heteroaromatic group and N is conjugated with the backbone.

Abstract: A polymer for use in an optical device comprising a first, optionally substituted, repeat unit of formula and a second, optionally substituted, repeat unit of formula wherein each Ar and Ar? is the same or different and comprises an optionally substituted aryl or heteroaryl group and optionally a third, optionally substituted, repeat unit in a molar ratio of no greater than 5%, the third repeat unit having a formula —Ar—N(Ar)—Ar— and having a single nitrogen atom in its backbone.

Abstract: An organic polymer comprising a conjugated backbone for transporting negative charge carriers and having a first band gap and at least one side unit pendent from the backbone for transporting positive charge carriers and having a second band gap, wherein the structure of the organic polymer is selected so that the first and second band gaps are distinct from one another in the polymer.

Abstract: Monomers having the formula X1—Ar1-[triarylamine]-Ar2—X2 wherein the triarylamine unit comprises at least one nitrogen atom in the backbone of the monomer and at least three substituted or unsubstituted aryl or heteroaryl groups and wherein X1 and X2 are the same or different polymerizable groups and wherein Ar1 and Ar2 are the same or different substituted or unsubstituted aryl or heteroaryl groups. Polymers and copolymers comprising such monomers are also described. The polymers have particular application in organic optoelectronic devices such as organic electroluminescent devices and organic photovoltaic devices.

Abstract: A soluble luminescent polymer comprising a first repeat unit [Ar1] and a second repeat unit comprising a unit of general formula (I) which is substituted or unsubstituted: wherein X is RC?CR, S, O or NR; Ar1, Ar2 and Ar3 are each independently an aromatic or heteroaromatic group; and each R independently is hydrogen or a substituent group.