Patents by Inventor Richard R. Klimpel

Richard R. Klimpel has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 4735711
    Abstract: This invention relates to a froth flotation process for selectively recovering metal-containing sulfide or sulfidized metal-containing oxide minerals from ores using a froth flotation process. The collector employed in the process is an organic monosulfide of the formula:R.sub.1 --S--R.sub.2wherein R.sub.1 is a methyl, ethyl, epoxy (i.e., ##STR1## group or R.sub.3 --S--R.sub.4 wherein R.sub.3 is a hydrocarbyl or substituted hydrocarbyl group and R.sub.4 is a hydrocarbylene or substituted hydrocarbylene; and R.sub.2 is an alkyl or cycloalkyl group having from 5 to 11 carbon atoms.
    Type: Grant
    Filed: May 6, 1986
    Date of Patent: April 5, 1988
    Assignee: The Dow Chemical Company
    Inventors: Richard R. Klimpel, Robert D. Hansen, Edwin J. Strojny
  • Patent number: 4732668
    Abstract: This invention relates to a froth flotation process for selectively recovering nonferrous metal-containing sulfide minerals or sulfidized metal-containing oxide minerals from ores using froth flotation. The collector employed in the process is an epithio compound of the formula: ##STR1## wherein m=1, 2 or 3; each R is independently hydrogen, a hydrocarbyl group or substituted hydrocarbyl group; each R.sup.1 is independently hydrogen, a hydrocarbyl group or substituted hydrocarbyl group, provided one R or R.sup.1 is not hydrogen; and each R.sup.2 is independently hydrogen, hydrocarbyl, hydrocarbyloxy or hydrocarbyl thioether.
    Type: Grant
    Filed: May 6, 1986
    Date of Patent: March 22, 1988
    Assignee: The Dow Chemical Company
    Inventors: Richard R. Klimpel, Robert D. Hansen, Edwin J. Strojny
  • Patent number: 4702822
    Abstract: This invention relates to a novel composition which is useful as a collector for the recovery of nonferrous metal-containing sulfide minerals and sulfidized metal-containing oxide minerals from ores in a froth flotation process. The novel composition comprises (a) an organic compound containing one or more monosulfide units wherein the sulfur atom(s) are bound to aliphatic or cycloaliphatic carbon atoms, and the total carbon content of the compound is such that the compound has sufficient hydrophobic character to cause metal-containing sulfide mineral or sulfidized metal-containing oxide mineral particles to be driven to an air/bubble interface; and (b) an alkyl thiocarbonate, a thionacarbamate, a thiophosphate, or mixtures thereof.
    Type: Grant
    Filed: June 18, 1986
    Date of Patent: October 27, 1987
    Assignee: The Dow Chemical Company
    Inventors: Richard R. Klimpel, Robert D. Hansen
  • Patent number: 4684459
    Abstract: A collector composition for use in froth flotation processes comprises two collectors. One of the collectors is preferably an omega-(hydrocarbylthio)alkylamine, S-(omega-aminoalkyl) hydrocarbyl thioate, N-(hydrocarbyl)-alpha, omega-alkanediamine, (omega-aminoalkyl) hydrocarbon amide, omega-(hydrocarbyloxy)alkylamine, omega-aminoalkyl hydrocarbonoate or mixture thereof. The second collector is a thiocarbonate, a thionocarbamate, a thiophosphate, thiocarbinilide, thiophosphinate, mercaptan, xanthogen formate, xanthic ester or mixture thereof. The collector composition floats a broad range of metal-containing minerals.
    Type: Grant
    Filed: April 28, 1986
    Date of Patent: August 4, 1987
    Assignee: The Dow Chemical Company
    Inventors: Richard R. Klimpel, Robert D. Hansen
  • Patent number: 4676890
    Abstract: A collector composition useful for the recovery of metal values from metal ores in a froth flotation process comprises two collectors. One collector is an organic compound containing at least 4 carbon atoms and one or more monosulfide units, wherein the carbon atoms to which the sulfur atoms are bound are aliphatic or cycloaliphatic carbons. The other collector is preferably an omega-(hydrocarbylthio)alkylamine, S-(omega-aminoalkyl)hydrocarbyl thioate, N-(hydrocarbyl)-alpha, omega-alkanediamine, N-(omega-aminoalkyl)hydrocarbon amide, omega-(hydrocarbyloxy)alkalamine, omega-aminoalkyl hydrocarbonate or mixture thereof. The collector composition floats a broad range of metal values including sulfide ores, oxide ores and precious metals.
    Type: Grant
    Filed: April 28, 1986
    Date of Patent: June 30, 1987
    Assignee: The Dow Chemical Company
    Inventors: Richard R. Klimpel, Robert D. Hansen
  • Patent number: 4582596
    Abstract: The invention is a process for recovering coal or mineral values from raw coal or mineral ore which comprises subjecting the raw coal or mineral ore in the form of an aqueous pulp, to a floatation process in the presence of a floatation collector, and a flotating amount of a floatation frother which comprises the reaction product of an alitphatic C.sub.6 alcohol and between about 1 and 5 moles of propylene oxide, butylene oxide or mixtures thereof, under conditions such that the coal or mineral values are recovered.
    Type: Grant
    Filed: June 4, 1984
    Date of Patent: April 15, 1986
    Assignee: The Dow Chemical Company
    Inventors: Robert D. Hansen, Roger W. Bergman, Richard R. Klimpel
  • Patent number: 4411927
    Abstract: Cereal grains, particularly corn, are effectively ground in the presence of an aqueous grinding medium by employing a hydrophilic polysaccharide, e.g., a cellulose ether such as hydroxypropyl methylcellulose, as a grinding aid.
    Type: Grant
    Filed: June 30, 1982
    Date of Patent: October 25, 1983
    Assignee: The Dow Chemical Company
    Inventors: Mauricio Bermudez, Richard R. Klimpel, Steven D. Sands
  • Patent number: 4384010
    Abstract: The efficiency of grinding cereal grains, particularly corn, is improved by grinding the cereal grain in the presence of a hygroscopic polyhydric alcohol, e.g., propylene glycol.
    Type: Grant
    Filed: October 10, 1980
    Date of Patent: May 17, 1983
    Assignee: The Dow Chemical Company
    Inventors: Mauricio Bermudez, Richard R. Klimpel, Steven D. Sands
  • Patent number: 4274599
    Abstract: A process for grinding coal or ores containing metal values comprising carrying out said grinding in a liquid medium and with a grinding aid comprising an anionic polyelectrolyte dispersible in the liquid medium and having a hydrocarbon backbone and a plurality of pendant anionic groups, said grinding aid being present in an amount effective to provide increased grinding efficiency.
    Type: Grant
    Filed: August 11, 1978
    Date of Patent: June 23, 1981
    Assignee: The Dow Chemical Company
    Inventors: Willy Manfroy, Richard R. Klimpel
  • Patent number: 4162045
    Abstract: A process for grinding coal or ores containing metal values comprising carrying out said grinding in a liquid medium and with a grinding aid system comprising an anionic polyelectrolyte derived from polyacrylic acid and certain inorganic metal salts, said system being dispersible in the liquid medium and being present in an amount effective to provide increased grinding efficiency.
    Type: Grant
    Filed: August 11, 1978
    Date of Patent: July 24, 1979
    Assignee: The Dow Chemical Company
    Inventors: Melvin F. Katzer, Richard R. Klimpel, Willy Manfroy
  • Patent number: 4162044
    Abstract: A process for grinding coal or ores containing metal values comprising carrying out said grinding in a liquid medium and with a grinding aid comprising an anionic polyelectrolyte derived from polyacrylic acid and dispersible in the liquid medium, said grinding aid being present in an amount effective to provide increased grinding efficiency.
    Type: Grant
    Filed: August 11, 1978
    Date of Patent: July 24, 1979
    Assignee: The Dow Chemical Company
    Inventors: Willy Manfroy, Richard R. Klimpel
  • Patent number: 4136830
    Abstract: A process for grinding coal or ores containing metal values comprising carrying out said grinding in a liquid medium and with a grinding aid comprising copolymers or salts of copolymers of styrene with maleic anhydride, itaconic or citraconic acids dispersible in the liquid medium, said grinding aid being present in an amount effective to provide increased grinding efficiency.
    Type: Grant
    Filed: November 21, 1977
    Date of Patent: January 30, 1979
    Assignee: The Dow Chemical Company
    Inventors: Willy Manfroy, Richard R. Klimpel
  • Patent number: 4130401
    Abstract: Combustible fuel slurries are prepared by admixing solid particulate carbonaceous material, liquid hydrocarbon fuel such as gasoline, fuel oil, and the like, a polar liquid flocculating third phase, and a wetting agent having an HLB value in the range of about 6.5 to about 10 and which is soluble in the third phase. Such slurries are mobile and readily processible in conventional fuel oil transporting, storage, and burning equipment.
    Type: Grant
    Filed: January 3, 1978
    Date of Patent: December 19, 1978
    Assignee: The Dow Chemical Company
    Inventors: Wilfred C. Meyer, Richard R. Klimpel
  • Patent number: 4126278
    Abstract: A process for grinding coal or ores containing metal values comprising carrying out said grinding in a liquid medium and with a grinding aid comprising an anionic polyelectrolyte derived from sulfoethylmethacrylic acid and dispersible in the liquid medium, said grinding aid being present in an amount effective to provide increased grinding efficiency.
    Type: Grant
    Filed: November 21, 1977
    Date of Patent: November 21, 1978
    Assignee: The Dow Chemical Company
    Inventors: Willy Manfroy, Richard R. Klimpel
  • Patent number: 4126276
    Abstract: A process for grinding coal or ores containing metal values comprising carrying out said grinding in a liquid medium and with a polyelectrolyte grinding aid comprising N-(sulfoalkyl)-derivatives of acrylamide and methacrylamide, said grinding aid being dispersible in the liquid medium, and being present in an amount effective to provide increased grinding efficiency.
    Type: Grant
    Filed: November 21, 1977
    Date of Patent: November 21, 1978
    Assignee: The Dow Chemical Company
    Inventors: Willy Manfroy, Richard R. Klimpel
  • Patent number: 4126277
    Abstract: A process for grinding coal or ores containing metal values comprising carrying out said grinding in a liquid medium and with a grinding aid comprising sulfonated polystyrene or sulfonated polyvinyl toluene or an anionic polyelectrolyte derived therefrom and dispersible in the liquid medium, said grinding aid being present in an amount effective to provide increased grinding efficiency.
    Type: Grant
    Filed: November 21, 1977
    Date of Patent: November 21, 1978
    Assignee: The Dow Chemical Company
    Inventors: Willy Manfroy, Richard R. Klimpel