Abstract: An exposed-lens retroreflective article including a binder layer and a plurality of retroreflective elements. Each retroreflective element includes a transparent microsphere partially embedded in the binder layer. At least some of the retroreflective elements comprise at least one color layer comprising a bi-layer structure.

Abstract: A curable composition including: at least one polyorganosiloxane including at least one hydrosilyl moiety (in certain embodiments, two different polyorganosiloxanes); at least one silane including hydrolyzable functionality; and at least one base selected from an amidine, a guanidine, a phosphazene, a proazaphosphatrane, and a combination thereof; a method of coating such curable composition; and an article having a substrate surface with a coating formed from such method.

Abstract: A composition is provided, including water, a base, and surface-modified inorganic oxide nanoparticles dispersed in the water. The nanoparticles are functionalized with an alpha-hydroxy acid or its salt. An article is also provided, including a substrate in and layers containing bi-layers. A portion of the layers include surface-modified inorganic oxide nanoparticles functionalized with an alpha-hydroxy acid or its salt. A dielectric mirror is also provided, including a substrate, a first stack of bi-layers disposed on the substrate, and a second stack of bi-layers positioned in planar contact with the first stack. The second stack of bi-layers exhibits a refractive index of less than 1.50. Further, an exposed lens retroreflective article is provided including a binder layer, a layer of transparent microspheres partially embedded in the binder layer, and a reflective layer between the binder layer and the microspheres including a dielectric mirror.

Abstract: An exposed-lens retroreflective article including a binder layer and a plurality of retroreflective elements. Each retroreflective element includes a transparent microsphere partially embedded in the binder layer. At least some of the retroreflective elements comprise at least one color layer comprising a bi-layer structure.

Abstract: Methods of protecting a substrate from light-induced degradation are described. The methods comprise providing a substrate and disposing onto the substrate a plurality of layers deposited by layer-by-layer self-assembly. At least a portion of the layers comprise an organic light absorbing compound, an organic light stabilizing compound, or a combination thereof dispersed within a polyelectrolyte. Also described are articles comprising a substrate and a plurality of layers deposited by layer-by-layer self-assembly wherein at least a portion of the layers comprise an organic light absorbing compound, an organic light stabilizing compound, or a combination thereof dispersed within a polyelectrolyte. Random copolymers suitable for use in the method and articles are also described.

Abstract: An adhesive article including a pressure sensitive adhesive layer and a release layer in contact with the pressure sensitive adhesive layer. The release layer includes a polymer matrix that includes polymerized (meth)acrylated silicone and a plurality of nanovoids.

Abstract: Methods of protecting a substrate from light-induced degradation are described. The methods comprise providing a substrate and disposing onto the substrate a plurality of layers deposited by layer-by-layer self-assembly. At least a portion of the layers comprise an organic light absorbing compound, an organic light stabilizing compound, or a combination thereof dispersed within a polyelectrolyte. Also described are articles comprising a substrate and a plurality of layers deposited by layer-by-layer self-assembly wherein at least a portion of the layers comprise an organic light absorbing compound, an organic light stabilizing compound, or a combination thereof dispersed within a polyelectrolyte. Random copolymers suitable for use in the method and articles are also described.

Abstract: A moisture-curable polysiloxane composition consists essentially of (a) at least one polyorganosiloxane, fluorinated polyorganosiloxane, or combination thereof comprising reactive silane functionality comprising at least one hydrosilyl moiety; and (b) at least one base selected from amidines, guanidines, phosphazenes, proazaphosphatranes, and combinations thereof; wherein the curable composition is non-foaming and has an average condensation-curable, reactive silane functionality greater than two.

Abstract: A moisture-curable polysiloxane composition consists essentially of (a) at least one polyorganosiloxane, fluorinated polyorganosiloxane, or combination thereof comprising reactive silane functionality comprising at least one hydrosilyl moiety; and (b) at least one base selected from amidines, guanidines, phosphazenes, proazaphosphatranes, and combinations thereof; wherein the curable composition is non-foaming and has an average condensation-curable, reactive silane functionality greater than two.

Abstract: An adhesive article including a pressure sensitive adhesive layer and a release layer in contact with the pressure sensitive adhesive layer. The release layer includes a polymer matrix that includes polymerized (meth)acrylated silicone and a plurality of nanovoids.

Abstract: The invention relates to articles such as protective films and displays having a fluorochemical surface layer comprising an antistatic agent and the reaction products of at least one fluoropolyether (meth)acryl compound and at least 50 wt-% of non-fluorinated crosslinking agent(s).

Abstract: The present invention provides a method of preparing an aqueous dispersion of poly(perfluorovinyl ether) homopolymers. The present invention further relates to a method of making an aqueous fluoropolymer dispersion comprising bicomponent particles of poly(perfluorovinyl ether) homopolymers and a second fluoropolymer. The dispersions of the present invention may be used for rendering fibrous substrates oil repellent, water repellent and/or stain repellent without altering the looks and feel of the substrate.

Abstract: The invention relates to display and protective articles having a fluorochemical surface layer, and methods of making such articles. The invention also relates to fluoropolyether acrylate compositions.

Abstract: The use of perfluorinated polymers and/or fluorinated ionomers as surfactant emulsifiers in emulsion polymerization of fluorinated monomers.

Abstract: Fluorochemical composition for rendering fibrous substrates oil repellent, water repellent, and/or stain or soil repellent. The composition comprises a dispersion or a solution of a fluorinated compound which comprises the reaction product of the following combination of reactants: (i) a fluorinated polyether according to the formula: Rf—Q—Tk ??(I) ?wherein Rf represents a monovalent perfluorinated polyether group having a molecular weight of at least 750 g/mol, Q represents a chemical bond or a divalent or trivalent organic linking group, T represents a functional group capable of reacting with an isocyanate and k is 1 or 2; (ii) an isocyanate component selected from a polyisocyanate compound that has at least 3 isocyanate groups or a mixture of polyisocyanate compounds wherein the average number of isocyanate groups per molecule is more than 2; and (iii) optionally one or more co-reactants capable of reacting with an isocyanate group.

Abstract: The present invention provides a method of preparing an aqueous dispersion of poly(perfluorovinyl ether) homopolymers. The present invention further relates to a method of making an aqueous fluoropolymer dispersion comprising bicomponent particles of poly(perfluorovinyl ether) homopolymers and a second fluoropolymer. The dispersions of the present invention may be used for rendering fibrous substrates oil repellent, water repellent and/or stain repellent.

Abstract: The invention relates to display and protective articles having a fluorochemical surface layer, and methods of making such articles. The invention also relates to fluoropolyether acrylate compositions.

Abstract: A fluorochemical composition for rendering fibrous substrates oil repellent, water repellent, and/or stain repellent and comprising a fluorinated polymer dispersed in water or dissolved or dispersed in an organic solvent, the fluorinated polymer comprising units derived from (i) a mixture of two or more fluorinated polyether monomers that differ in at least their molecular weight, the fluorinated polyether monomers having an ethylenically unsaturated group and a perfluorinated polyether group and wherein at least 90% by weight of the mixture consists of fluorinated polyether monomers that have a perfluorinated polyether group having a molecular weight of at least 750 g/mol and (ii) one or more units derived from one or more co-monomers other than a fluorinated polyether monomer and wherein the co-monomers comprise at least one non-fluorinated monomer. Also, method for treating fibrous substrate with such composition, fluorinated polyether monomers, and fluorinated polymers derived from such monomers.

Abstract: The use of perfluorinated polymers and/or fluorinated ionomers as surfactant emulsifiers in emulsion polymerization of fluorinated monomers.

Abstract: Coating compositions are described that can be used to impart hydrophobicity, oleophobicity, stain resistance, or combinations thereof to various substrates. The coating compositions include an amino resin and a reactive fluorinated copolymer. The reactive fluorinated copolymer has pendant perfluoropolyether groups as well as pendant groups capable of reacting with the amino resin. The pendant perfluoropolyether groups of the reactive fluorinated copolymer have a molecular weight of at least 750 g/mole. Articles and methods of preparing articles using the coating compositions are also described.