Abstract: Apparatuses are disclosed for three-dimensionally printing reactive materials which utilize a powder spreading step followed by a binder-jet deposition step. Some such apparatuses include a binder jet three-dimensional printing device, a curing device, and a depowdering device contained within an environmental enclosure which provides an inert atmosphere sufficient to allow a reactive material to be used as a build material without fire or explosion hazards. Some such apparatuses include one or more conveying systems for moving a removable build box among the various devices. Environmental enclosures having unique designs and features are disclosed.

Abstract: Powder layer smoothing devices (34) adapted for use with powder-layer three-dimensional printers (10) are described. The smoothing devices (34) include a counter rotating roller (36, 50, 60) having a complex powder engaging face (38) that may include a series or plurality of flutes (54) or may include knurling (64) extending along at least a portion of the counter rotating roller (36, 50, 60) along its rotational axis (56, 66). The smoothing device (34) may also include a vertically adjustable finishing roller (35) to follow the counter rotating roller (36, 50, 60) across the build box (12) of the powder-layer three-dimensional printer (10).

Abstract: Powder layer smoothing devices (34) adapted for use with powder-layer three-dimensional printers (10) are described. The smoothing devices (34) include a counter rotating roller (36, 50, 60) having a complex powder engaging face (38) that may include a series or plurality of flutes (54) or may include knurling (64) extending along at least a portion of the counter rotating roller (36, 50, 60) along its rotational axis (56, 66). The smoothing device (34) may also include a vertically adjustable finishing roller (35) to follow the counter rotating roller (36, 50, 60) across the build box (12) of the powder-layer three-dimensional printer (10).

Abstract: A powder layer smoothing devices adapted for use with powder-layer three-dimensional printers are described. The smoothing devices include a counter rotating roller having a complex powder engaging face that may include a series or plurality of flutes or may include knurling extending along at least a portion of the roller along the rotational axis. The smoothing device may also include a vertically adjustable finishing roller to follow the counter rotating roller across the build box of the powder-layer three-dimensional printer.

Abstract: Methods and systems (2) are disclosed for making articles (114) by three-dimensional printing. The methods include selectively printing by jet deposition on successive layers (4) of a build material powder (10) at least one of a first binder fluid and a second binder fluid. At least one of the first and second binder fluids includes a particulate matter (16) having mean particle size diameter which is less than that of the build material powder (10). The first binder fluid is characteristically different from the second binder fluid. The particulate matter (16) selectively deposited with a binder fluid can be used to locally tailor the physical properties of the article (114), e.g. by alloying with the build material powder, increasing densification, acting as a local infiltrant or infiltrant stop during heat treatment, locally modulating the local stress fields (e.g. by a mismatch of thermal coefficients of expansion), etc.

Abstract: Methods and systems (20) are disclosed for making articles by three-dimensional printing. The methods include three-dimensionally printing articles by selectively jet-depositing a particle-bearing binder fluid (14) upon successive layers (4) of a build material powder (10) such that the particles (16) deposited with the binder fluid (14) increase the apparent density of the as-printed article. The particulate matter (16) of the binder fluid (12) is smaller than the mean particle size of the build material powder (10). Preferably, this jet-deposited particulate matter (16) has a mean particle size that is larger than about 1 to and smaller than or equal to 50 microns. The jet-deposited matter (16) acts to fill in the interparticle interstices of the build material powder (10) thereby simultaneously increasing the density of the printed article and improving its surface roughness and contour resolution, which in turn, improves the surface finish of the final article.

Abstract: Methods are disclosed for making a hot isostatic pressing container for hot isostatic pressing a powder material to form an article comprising three-dimensionally printing the container from a build powder, the container having a cavity for receiving the powder material and an outer section having an outer surface, the cavity having a surface and being shaped and sized so that hot isostatic pressing the container with the powder material within the cavity results in the production of the article. Methods are also disclosed for making the hot isostatically pressed article using the container.

Abstract: Apparatuses are disclosed for three-dimensionally printing reactive materials which utilize a powder spreading step followed by a binder-jet deposition step. Some such apparatuses include a binder jet three-dimensional printing device, a curing device, and a depowdering device contained within an environmental enclosure which provides an inert atmosphere sufficient to allow a reactive material to be used as a build material without fire or explosion hazards. Some such apparatuses include one or more conveying systems for moving a removable build box among the various devices. Environmental enclosures having unique designs and features are disclosed.

Abstract: An infiltrated carbon foam composite and method for making the composite is described. The infiltrated carbon foam composite may include a carbonized carbon aerogel in cells of a carbon foam body and a resin is infiltrated into the carbon foam body filling the cells of the carbon foam body and spaces around the carbonized carbon aerogel. The infiltrated carbon foam composites may be useful for mid-density ablative thermal protection systems.

Abstract: A blast energy mitigating composite useful for protecting a surface or an object from a blast, shock waves, or stress waves caused by a sudden, violent release of energy is described. Certain configurations of the blast energy mitigating composite may include energy mitigating units contained in an energy mitigating matrix. If desired, various reinforcement layers may be incorporated on or within the energy mitigating composite. The energy mitigating units may comprise a porous energy mitigating material such as carbon foam.

Abstract: A composite exhaust flue which may be used to shield an area or object from convective, conductive, or radiated heat transfer from hot exhaust combustion gases is described. In certain embodiments, the composite exhaust flue may be used to protect structures from hot exhaust gases and particles such as those produced by cars, trucks, ships, boats, jets, rockets, as well as other vehicles with internal combustion engines, turbines, or rocket motors. In some embodiments, a composite exhaust flue may comprise a ceramic fiber reinforced ceramic composite high temperature face sheet positioned over an insulating layer and a structural support layer comprising a rigid, porous foam material.

Abstract: A high density carbon material produced from coal is described. The carbon material may have a density ranging from about 1.0 g/cc to about 1.6 g/cc and may have a crush strength of up to about 20,000 psi. The high density carbon material is produced by slowly heating comminuted swelling bituminous coal particles under pressures of 400 psi to about 500 psi to a first temperature at about the initial plastic temperature of the coal. The material is held at this temperature for a period of time sufficient to provide for a uniform temperature throughout the coal. The material is then heated to a second temperature for a period of time sufficient to provide for the coal achieving an essentially uniform temperature. The resulting product is a three-dimensional, self-supporting carbon that has a substantially continuous carbon matrix defining grain boundaries within the carbon matrix.

Abstract: A method for increasing the yield of carbon foam is described. The method includes placing a foaming sheet over the top surface of the material to be foamed. In certain embodiments, the foaming sheet is placed over the top surface of particulate coal prior to and during the foaming process. In some embodiments the foaming sheet is a smooth, continuous sheet, such as aluminum foil or the like. The resulting carbon product includes an increased amount of usable carbon foam.

Abstract: A mailer for shipping cells contained in a cell culture device, wherein the mailer comprises a containment system that can absorb and contain within the mailer a fluid that may leak from the cell culture device. The containment system comprises a gas-permeable absorbent material adapted to surround the cell culture apparatus; and a liquid impermeable layer which seals the absorbent material so as to contain any fluid released within the mailer.

Abstract: Provided for heating cultured cells is a controlled heater device comprising a cell culture apparatus, a transparent heater in thermal contact with the cell culture apparatus, and may further comprise one or more of a transparent filter provided to prevent a predetermined spectral range of light from passing through the transparent filter, and a power source for controlling the amount of heat generated by the transparent heater of the controlled heater device.

Abstract: A mailer for shipping cells contained in a cell culture device, wherein the mailer comprises a containment system that can absorb and contain within the mailer a fluid that may leak from the cell culture device. The containment system comprises a gas-permeable absorbent material adapted to surround the cell culture apparatus; and a liquid impermeable layer which seals the absorbent material so as to contain any fluid released within the mailer.

Abstract: Provided for heating cultured cells is a controlled heater device comprising a cell culture apparatus, a transparent heater in thermal contact with the cell culture apparatus, and may further comprise one or more of a transparent filter provided to prevent a predetermined spectral range of light from passing through the transparent filter, and a power source for controlling the amount of heat generated by the transparent heater of the controlled heater device.