Abstract: A metal halogen electrochemical energy cell system that generates an electrical potential. One embodiment of the system includes at least one cell including at least one positive electrode and at least one negative electrode, at least one electrolyte, a mixing venturi that mixes the electrolyte with a halogen reactant, and a circulation pump that conveys the electrolyte mixed with the halogen reactant through the positive electrode and across the metal electrode. Preferably, the positive electrode comprises porous carbonaceous material, the negative electrode comprises zinc, the metal comprises zinc, the halogen comprises chlorine, the electrolyte comprises an aqueous zinc-chloride electrolyte, and the halogen reactant comprises a chlorine reactant. Also, variations of the system and a method of operation for the systems.

Abstract: An apparatus including at least one electrochemical flow cell in which the electrochemical flow cell includes an anode electrode, a cathode electrode and a reaction zone between the anode and the cathode. The electrochemical flow cell also includes an electrolyte storage reservoir configured to hold a molten salt electrolyte and a gas generated during charging of the at least one electrochemical flow cell and at least one conduit configured to supply the molten salt electrolyte and the gas from the storage reservoir to the at least one electrochemical flow cell. The electrochemical flow cell also includes at least one pump configured to pump the molten salt electrolyte from the storage reservoir to the reaction zone.

Abstract: An embodiment relates an electrochemical system. The system includes (a) at least one cell that comprises a first electrode, a second electrode and a reaction zone between the first and second electrode. The system also includes (b) a liquefied halogen reactant (c) at least one metal halide electrolyte and (d) a flow circuit configured to deliver the halogen reactant and the at least one metal-halide electrolyte to the at least one cell. The flow circuit includes an electrolyte reservoir and a halogen reactant/electrolyte separation device comprising a halophilic material.

Abstract: An electrochemical system, such as a flow battery, includes a vessel. The vessel contains at least one cell that includes a first electrode, a second electrode and a reaction zone between the first and second electrodes. The vessel also contains a flow circuit configured to deliver a fluid comprising a liquefied halogen reactant and at least one metal halide electrolyte to the at least one cell, and at least one sensor configured to measure a property of the electrochemical system indicative of a state of charge (SOC) of the electrochemical system.

Abstract: A leak detection sensor for detecting a leakage of an electrolyte solution in a flow battery system is provided. The sensor includes a sensor housing, the sensor housing being at least partially surrounded by a fluid and having mounted therein at least one light source.

Abstract: A flow battery and method of operating a flow battery. The flow battery includes a first electrode, a second electrode and a reaction zone located between the first electrode and the second electrode. The flow battery is configured with a first electrolyte flow configuration in charge mode and a second flow configuration in discharge mode. The first electrolyte flow configuration is at least partially different from the second electrolyte flow configuration.

Abstract: A flow battery electrode assembly including a first impermeable, substantially metal electrode consisting essentially of a metal and a second permeable electrode. The assembly also includes at least one electrically conductive spacer connecting the first impermeable, substantially metal electrode and the second permeable electrode such that the first impermeable, substantially metal electrode and the second permeable electrode are spaced apart from each other by an electrolyte flow path. At least one electrically conductive spacer includes a plurality of electrically conductive spacers which mechanically and electrically connect adjacent first impermeable, substantially metal and second permeable electrodes.

Abstract: A leak detection system for a flowing electrolyte battery comprising a containment member associated with at least one of a stack of a flowing electrolyte battery and an electrolyte reservoir of a flowing electrolyte battery and a sensing member for sensing a fluid leak within the containment member.

Abstract: An electrochemical energy generation system includes plural electrochemical cells connected electrically in series that utilize a common electrolyte that can be delivered to each of the cells and/or collected from each of the cells using one or more manifolds. The system provides a possibility for reducing shunt currents by applying a shunt-current minimizing voltage to terminals of the manifolds from the terminal electrodes of the cells connected in series.

Abstract: An electrochemical energy generation system can include a sealed vessel that contains inside (i) at least one electrochemical cell, which has two electrodes and a reaction zone between them; (ii) a liquefied halogen reactant, such as a liquefied molecular chlorine; (iii) at least one metal halide electrolyte; and (iv) a flow circuit that can be used for delivering the halogen reactant and the electrolyte to the at least one cell. The sealed vessel can maintain an inside pressure above a liquefication pressure for the halogen reactant. Also disclosed are methods of using and methods of making for electrochemical energy generation systems.

Abstract: An apparatus including at least one electrochemical flow cell in which the electrochemical flow cell includes an anode electrode, a cathode electrode and a reaction zone between the anode and the cathode. The electrochemical flow cell also includes an electrolyte storage reservoir configured to hold a molten salt electrolyte and a gas generated during charging of the at least one electrochemical flow cell and at least one conduit configured to supply the molten salt electrolyte and the gas from the storage reservoir to the at least one electrochemical flow cell. The electrochemical flow cell also includes at least one pump configured to pump the molten salt electrolyte from the storage reservoir to the reaction zone.

Abstract: An electrochemical energy generation system can include a sealed vessel that contains inside (i) at least one electrochemical cell, which has two electrodes and a reaction zone between them; (ii) a liquefied halogen reactant, such as a liquefied molecular chlorine; (iii) at least one metal halide electrolyte; and (iv) a flow circuit that can be used for delivering the halogen reactant and the electrolyte to the at least one cell. The sealed vessel can maintain an inside pressure above a liquefication pressure for the halogen reactant. Also disclosed are methods of using and methods of making for electrochemical energy generation systems.

Abstract: A leak detection system for a flowing electrolyte battery comprising a containment member associated with at least one of a stack of a flowing electrolyte battery and an electrolyte reservoir of a flowing electrolyte battery and a sensing member for sensing a fluid leak within the containment member.

Abstract: A flow battery electrode assembly with a first impermeable, substantially metal electrode, a second permeable, substantially metal electrode and at least one electrically conductive spacer. The electrically conductive spacer connects the first impermeable, substantially metal electrode and the second permeable, substantially metal electrode such that the first impermeable, substantially metal electrode and the second permeable, substantially metal electrode are spaced apart from each other by an electrolyte flow path.

Abstract: An electrochemical energy generation system can include a sealed vessel that contains inside (i) at least one electrochemical cell, which has two electrodes and a reaction zone between them; (ii) a liquefied halogen reactant, such as a liquefied molecular chlorine; (iii) at least one metal halide electrolyte; and (iv) a flow circuit that can be used for delivering the halogen reactant and the electrolyte to the at least one cell. The sealed vessel can maintain an inside pressure above a liquefication pressure for the halogen reactant. Also disclosed are methods of using and methods of making for electrochemical energy generation systems.

Abstract: A flow battery and method of operating a flow battery. The flow battery includes a first electrode, a second electrode and a reaction zone located between the first electrode and the second electrode. The flow battery is configured with a first electrolyte flow configuration in charge mode and a second flow configuration in discharge mode. The first electrolyte flow configuration is at least partially different from the second electrolyte flow configuration.

Abstract: An electrochemical flow cell includes a permeable electrode, an impermeable electrode located adjacent to and spaced apart from the permeable electrode and a reaction zone electrolyte flow channel located between a first side of the permeable electrode and a first side of the impermeable electrode. The electrochemical flow cell also includes at least one electrolyte flow channel located adjacent to a second side of the permeable electrode, at least one central electrolyte flow conduit extending through a central portion of the permeable electrode and through a central portion of the impermeable electrode and at least one peripheral electrolyte flow inlet/outlet located in a peripheral portion of the electrochemical cell above or below the permeable electrode.

Abstract: A flow battery and method of operating a flow battery. The flow battery includes a first electrode, a second electrode and a reaction zone located between the first electrode and the second electrode. The flow battery is configured with a first electrolyte flow configuration in charge mode and a second flow configuration in discharge mode. The first electrolyte flow configuration is at least partially different from the second electrolyte flow configuration.

Abstract: An electrochemical energy generation system can include a sealed vessel that contains inside (i) at least one electrochemical cell, which has two electrodes and a reaction zone between them; (ii) a liquefied halogen reactant, such as a liquefied molecular chlorine; (iii) at least one metal halide electrolyte; and (iv) a flow circuit that can be used for delivering the halogen reactant and the electrolyte to the at least one cell. The sealed vessel can maintain an inside pressure above a liquefication pressure for the halogen reactant. Also disclosed are methods of using and methods of making for electrochemical energy generation systems.

Abstract: An electrochemical energy generation system can include a sealed vessel that contains inside (i) at least one electrochemical cell, which has two electrodes and a reaction zone between them; (ii) a liquefied halogen reactant, such as a liquefied molecular chlorine; (iii) at least one metal halide electrolyte; and (iv) a flow circuit that can be used for delivering the halogen reactant and the electrolyte to the at least one cell. The sealed vessel can maintain an inside pressure above a liquefication pressure for the halogen reactant. Also disclosed are methods of using and methods of making for electrochemical energy generation systems.