Patents by Inventor Rimantas Glemza

Rimantas Glemza has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 6958375
    Abstract: The present invention is directed to a novel one-step method for forming a supported catalyst complex of high activity by substantially simultaneously contacting a bidentate or tridentate ligand forming compound, a transition metal compound and a chromium immobilized Lewis acid support-agglomerate. The catalyst can be formed prior to polymerization of olefins or within the polymerization reaction zone.
    Type: Grant
    Filed: April 10, 2002
    Date of Patent: October 25, 2005
    Assignee: W.R. Grace & Co.-Conn.
    Inventors: Keng-Yu Shih, Dean Alexander Denton, Rimantas Glemza
  • Patent number: 6946420
    Abstract: The present invention is directed to a coordinating catalyst system comprising at least one pre-catalyst selected from late transition metal bidentate or tridentate ligand containing compounds, at least one support-agglomerate having chromium immobilized thereto (e.g., spray dried silica/clay agglomerate), and optionally at least one organometallic compound in controlled amounts, and methods for preparing the same. The resulting catalyst system exhibits enhanced activity for polymerizing olefins and yields polymer products having very good morphology.
    Type: Grant
    Filed: April 10, 2002
    Date of Patent: September 20, 2005
    Assignee: W. R. Grace & Co.-Conn
    Inventors: Keng-Yu Shih, Dean Alexander Denton, Rimantas Glemza
  • Patent number: 6734131
    Abstract: A chromium containing catalyst wherein the chromium atom is in one of its higher valence states and is immobilized to a support-agglomerate composed of at least one inorganic oxide component and at least one ion-containing layered component.
    Type: Grant
    Filed: April 10, 2002
    Date of Patent: May 11, 2004
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: Keng-Yu Shih, Dean Alexander Denton, Rimantas Glemza
  • Patent number: 6670302
    Abstract: High melt index polyolefins have been obtained with chromium silica catalysts under conventional polymerization conditions without the use of titanium or other additives. The useful chromium silica catalysts have a pore volume in the range of 1.9-2.9 cc/g and a narrow pore size distribution. The silica is a silica gel preferably obtained from a low solids, rapid gelation process.
    Type: Grant
    Filed: October 31, 2002
    Date of Patent: December 30, 2003
    Assignee: W. R. Grace & Co.-Conn
    Inventors: Rimantas Glemza, Dean A. Denton
  • Publication number: 20030204032
    Abstract: The present invention is directed to a novel one-step method for forming a supported catalyst complex of high activity by substantially simultaneously contacting a bidentate or tridentate ligand forming compound, a transition metal compound and a chromium immobilized Lewis acid support-agglomerate. The catalyst can be formed prior to polymerization of olefins or within the polymerization reaction zone.
    Type: Application
    Filed: April 10, 2002
    Publication date: October 30, 2003
    Applicant: W.R. Grace & Co.-Conn.
    Inventors: Keng-Yu Shih, Dean Alexander Denton, Rimantas Glemza
  • Publication number: 20030162917
    Abstract: A chromium containing catalyst wherein the chromium atom is in one of its higher valence states and is immobilized to a support-agglomerate composed of at least one inorganic oxide component and at least one ion-containing layered component.
    Type: Application
    Filed: April 10, 2002
    Publication date: August 28, 2003
    Inventors: Keng-Yu Shih, Dean Alexander Denton, Rimantas Glemza
  • Publication number: 20030130111
    Abstract: The present invention is directed to a coordinating catalyst system comprising at least one pre-catalyst selected from late transition metal bidentate or tridentate ligand containing compounds, at least one support-agglomerate having chromium immobilized thereto (e.g., spray dried silica/clay agglomerate), and optionally at least one organometallic compound in controlled amounts, and methods for preparing the same. The resulting catalyst system exhibits enhanced activity for polymerizing olefins and yields polymer products having very good morphology.
    Type: Application
    Filed: April 10, 2002
    Publication date: July 10, 2003
    Inventors: Keng-Yu Shih, Dean Alexander Denton, Rimantas Glemza
  • Publication number: 20030065112
    Abstract: High melt index polyolefins have been obtained with chromium silica catalysts under conventional polymerization conditions without the use of titanium or other additives. The useful chromium silica catalysts have a pore volume in the range of 1.9-2.9 cc/g and a narrow pore size distribution. The silica is a silica gel preferably obtained from a low solids, rapid gelation process.
    Type: Application
    Filed: October 31, 2002
    Publication date: April 3, 2003
    Inventors: Rimantas Glemza, Dean A. Denton
  • Patent number: 5714424
    Abstract: The present invention encompasses a monolithic multi-component composite polyolefin catalyst particle comprising at least two distinct supported catalyst components wherein each catalyst component is capable of producing a resin having a melt index different from at least one other catalyst component under constant reaction conditions. Methods of producing and using the multi-component catalyst are disclosed.
    Type: Grant
    Filed: January 9, 1995
    Date of Patent: February 3, 1998
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: John L. Warthen, Rimantas Glemza
  • Patent number: 5292701
    Abstract: Aluminum phosphate compositions are provided which are characterized simultaneously by high porosity and phosphorous-to-aluminum ratios of approximately 1.0. The high porosity of these compositions is a function of high pore volume coupled with low surface area, resulting in high average pore diameter. These materials have excellent properties as catalysts and catalyst supports. Methods of making the compositions are also provided.
    Type: Grant
    Filed: May 10, 1991
    Date of Patent: March 8, 1994
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: Rimantas Glemza, Yves O. Parent
  • Patent number: 5030431
    Abstract: Aluminum phosphate compositions are provided which are characterized simultaneously by high porosity and phosphorous-to-aluminum ratios of approximately 1.0. The high porosity of these compositions is a function of high pore volume coupled with low surface area, resulting in high average pore diameter. These materials have excellent properties as catalysts and catalyst supports.
    Type: Grant
    Filed: June 7, 1989
    Date of Patent: July 9, 1991
    Assignee: W. R. Grace & Co.-Conn.
    Inventor: Rimantas Glemza
  • Patent number: 4474824
    Abstract: Dentifrice compositions containing a hydrous silica gel having a water content of from about 20 to about 60 weight percent are disclosed. The abrasiveness of the gel is increased by contacting the gel with an alkaline medium to provide a gel pH of about 6 to about 10 and/or preparing the gel by drying and grinding a silica hydrogel that has been washed with an aqueous acidic solution having a temperature of from about 80.degree. to about 100.degree. F.
    Type: Grant
    Filed: February 15, 1980
    Date of Patent: October 2, 1984
    Assignee: W. R. Grace & Co.
    Inventors: Robert B. DeWolf, II, Rimantas Glemza
  • Patent number: 4303641
    Abstract: Dentifrice compositions containing a hydrous silica gel having a water content of from about 20 to about 60 weight percent are disclosed. The abrasiveness of the gel is increased by contacting the gel with an alkaline medium to provide a gel pH of about 6 to about 10 and/or preparing the gel by drying and grinding a silica hydrogel that has been washed with an aqueous acidic solution having a temperature of from about 80.degree. to about 100.degree. F.
    Type: Grant
    Filed: May 24, 1978
    Date of Patent: December 1, 1981
    Assignee: W. R. Grace & Co.
    Inventors: Robert B. DeWolf, II, Rimantas Glemza
  • Patent number: 4260396
    Abstract: A composition for polishing silicon and germanium comprises a synthetic amorphous silica polishing agent and a suspending agent selected from the group consisting of water-soluble carboxypolymethylene gums and xanthum gums. The composition may be used for polishing in the form of an aqueous alkaline slurry.
    Type: Grant
    Filed: January 16, 1978
    Date of Patent: April 7, 1981
    Assignee: W. R. Grace & Co.
    Inventor: Rimantas Glemza
  • Patent number: RE34911
    Abstract: Aluminum phosphate compositions arc provided which are characterized simultaneously by high porosity and phosphorous-to-aluminum ratios of approximately 1.0. The high porosity of these compositions is a function of high pore volume coupled with low surface area, resulting in high average pore diameter. These materials have excellent properties as catalysts and catalyst supports.
    Type: Grant
    Filed: July 1, 1993
    Date of Patent: April 18, 1995
    Assignee: W. R. Grace & Co.-Conn.
    Inventor: Rimantas Glemza