Abstract: Disclosed is an organic phase change carrier and a method for forming same, and a phase change ink including same. The organic phase change carrier comprises a colloidal dispersion of nanoparticles exhibiting a substantially uniform distribution of said nanoparticles discretely distributed therewithin, at least one curable monomer; a phase change inducing component, and an initiator. The organic phase change carrier exhibits a substantially uniform distribution of the nanoparticles so that they are discretely distributed therewithin, and are substantially resistant to the aggregation of the nanoparticles distributed therewithin.

Abstract: Processes for preparing diacryl-functional compounds are provided. Processes include reacting AB2 monomers with acryloyl halides, and then further reacting with long-chain, mono-functional aliphatic compounds to form long-chain diacrylates. Further processes include reacting difunctional tic compounds with acrylic acid to form difunctional diacrylate, and diacrylamide compounds.

Abstract: Processes for preparing diacryl-functional compounds are provided. Processes include reacting AB2 monomers with acryloyl halides, and then further reacting with long-chain, mono-functional aliphatic compounds to form long-chain diacrylates.

Abstract: A radiation curable phase change ink preferably used in piezoelectric ink jet devices includes an ink vehicle that includes at least one gellant comprised of a curable polyamide-epoxy acrylate component and a polyamide component, and at least one colorant. The use of the gellant enables the ink to form a gel state having a viscosity of at least 103 mPa·s at very low temperatures of about 25° C. to about 100° C. The ink may thus be jetted at very low jetting temperatures of, for example, about 40° C. to about 110° C. The ink may be used to form an image by heating the ink to a first temperature at which the ink may be jetted, jetting onto a member or substrate maintained at a second temperature at which the ink forms a gel state, and exposing the ink to radiation energy to polymerize curable components of the ink.

Abstract: The phase change ink a viscosity of from about 4 mPa-s to about 50 mPa-s at a first temperature and has a viscosity of from 104 mPa-s to about 109 mPa-s at a second lower temperature. The second temperature may be below the first temperature by at least 10° C. but by no more than 50° C. The first temperature may be from about 60° C. to about 110° C. and the second temperature may be from about 20° C. to about 70 ° C. A curve of log10 viscosity of the phase change ink plotted against temperature in degrees Celsius may have a slope having an absolute value less than 0.02 at the first temperature and have a slope having an absolute value greater than 0.08 for at least a region second temperatures.

Abstract: Disclosed is a phase change ink comprising a colorant, an initiator, and a phase change ink carrier, said carrier comprising (A) a first isocyanate-derived compound which is the reaction product of a mixture comprising (1) an isocyanate; and (2) a component comprising (a) an alcohol having at least one ethylenic unsaturation; (b) an amine having at least one ethylenic unsaturation; (c) an acid having at least one ethylenic unsaturation; or (d) mixtures thereof, (B) a second isocyanate-derived compound which is the reaction product of (1) a diisocyanate; (2) a monoalcohol having exactly one hydroxyl group and having at least one ethylenic unsaturation; and (3) a polyol having two or more hydroxyl groups, (C) an optional phase change inducing component, said phase change inducing component containing at least one hydroxyl group, said phase change inducing component having a melting point of about 40° C.

Abstract: A radiation curable phase change ink preferably used in piezoelectric ink jet devices includes an ink vehicle that includes at least one curable epoxy-polyamide gellant, and at least one colorant. The use of the gellant enables the ink to form a gel state having a viscosity of at least 103 mPa·s at very low temperatures of about 25° C. to about 100° C. The ink may thus be jetted, for example onto an intermediate tansfer member surface or directly to an image receiving substrate, at very low jetting temperatures of, for example, about 40° C. to about 110° C.

Abstract: Disclosed is a phase change ink comprising a colorant, an initiator, and a phase change ink carrier, said carrier comprising (A) a urethane which is the reaction product of a mixture comprising (1) an isocyanate; and (2) an alcohol selected from the group consisting of 1,4 butanediol vinyl ether, 2-allyloxy ethanol, 1,4-cyclohexanedimethanol vinyl ether, ethylene glycol vinyl ether, di(ethylene glycol) vinyl ether, and mixtures thereof; (B) a compound which is the reaction product of a mixture comprising (1) an isocyanate; and (2) a component comprising (a) an amine having at least one ethylenic unsaturation; (b) an acid having at least one ethylenic unsaturation; (c) a mixture of an amine having at least one ethylenic unsaturation and an alcohol having at least one ethylenic unsaturation; (d) a mixture of an acid having at least one ethylenic unsaturation and an alcohol having at least one ethylenic unsaturation; or (e) mixtures thereof; or (C) a mixture of (A) and (B); said ink being curable upon exposure t

Abstract: Disclosed is a phase change ink composition comprising a phase change ink carrier and a bis(urea-urethane) compound of the formula wherein R1 and R1? each, independently of the other, is an alkyl group, an aryl group, an arylalkyl group, or an alkylaryl group, R2 and R2? each, independently of the other, is an alkylene group, an arylene group, an arlyalkylene group, or an alkylarylene group, R3 is an alkylene group, an arylene group, an arylalkylene group, or an alkylarylene group, and R4 and R5 each independently of the other, is a hydrogen atom or an alkyl group.

Abstract: Phase change inks comprising a phase change ink carrier and one or more curable trans-1,2-cyclohexane bis[urea-urethane] compounds of the formulae wherein R1 and R?1 are alkylene, arylene, arylalkylene, or alkylarylene groups, R2 and R?2 are alkyl, aryl, arylalkyl, or alkylaryl groups, R3 and R?3 are hydrogen atoms or alkyl groups, R4 and R?4 are hydrogen atoms, fluorine atoms, alkyl groups, or phenyl groups, n is an integer of 0, 1, 2, 3, or 4, and R5 is an alkyl, aryl, arylalkyl, or alkylaryl group, or a substituent other than an alkyl, aryl, arylalkyl, or alkylaryl group, provided that at least one of R1, R?1, R2, R?2, R3, R?3, R4, R?4, or one or more of R5 is an alkyl, alkylene, arylalkyl, arylalkylene, alkylaryl, or alkylarylene group containing an ethylenic unsaturation rendering the compound curable upon exposure to heat and/or actinic radiation.

Abstract: Disclosed are phase change inks comprising a phase change ink carrier and a trans-1,2-cyclohexane bis(urea-urethane) compound of the formula or mixtures thereof, wherein R1 and R?1 each, independently of the other, is an alkylene group, an arylene group, an arylalkylene group, or an alkylarylene group, R2 and R?2 each, independently of the other, is an alkyl group, an aryl group, an arylalkyl group, or an alkylaryl group, R3 and R?3 each, independently of the other, is a hydrogen atom or an alkyl group, R4 and R?4 each, independently of the other, is a hydrogen atom, a fluorine atom, an alkyl group, or a phenyl group, n is an integer of 0, 1, 2, 3, or 4, and R5 is an alkyl group, an aryl group, an arylalkyl group, an alkylaryl group, or a substituent other than an alkyl, aryl, arylalkyl, or alkylaryl group.

Abstract: An ink jet ink includes an ink vehicle, wherein the ink vehicle includes at least one wax monomer functionalized to include in the chain at least one reactive group curable upon exposure to radiation. The reactive group is preferably curable via cationic or free radical polymerization. In a preferred embodiment, the ink vehicle includes a wax monomer having a structure: wherein C represents a cationically curable group and R represents a radically curable group. The inks may be used to form an image by jetting the ink onto a transfuse member surface, increasing the viscosity of the ink upon the transfuse member surface, subsequently transferring the ink from the transfuse member surface to an image receiving substrate, and exposing the ink to radiation following the transfer to the image receiving substrate to effect reaction of the at least one reactive group.

Abstract: Disclosed is a bis(urea-urethane) compound of the formula wherein R1 and R1? each, independently of the other, is an alkyl group, wherein at least one of R1 and R1? has at least about 6 carbon atoms, R2 and R2? each, independently of the other, is an alkylene group, wherein at least one of R2 and R2? has at least about 3 carbon atoms, R3 is an alkylene group having at least about 2 carbon atoms, and R4 and R5 each, independently of the other, is a hydrogen atom or an alkyl group, and wherein R1 and R1? each contain no more than 2 fully fluorinated carbon atoms.

Abstract: Phase change inks comprising a phase change ink carrier and one or more curable trans-1,2-cyclohexane bis[urea-urethane] compounds of the formulae wherein R1 and R?1 are alkylene, arylene, arylalkylene, or alkylarylene groups, R2 and R?2 are alkyl, aryl, arylalkyl, or alkylaryl groups, R3 and R?3 are hydrogen atoms or alkyl groups, R4 and R?4 are hydrogen atoms, fluorine atoms, alkyl groups, or phenyl groups, n is an integer of 0, 1, 2, 3, or 4, and R5 is an alkyl, aryl, arylalkyl, or alkylaryl group, or a substituent other than an alkyl, aryl, arylalkyl, or alkylaryl group, provided that at least one of R1, R?1, R2, R?2, R3, R?3, R4, R?4, or one or more of R5 is an alkyl, alkylene, arylalkyl, arylalkylene, alkylaryl, or alkylarylene group containing an ethylenic unsaturation rendering the compound curable upon exposure to heat and/or actinic radiation.

Abstract: Disclosed is a phase change ink composition comprising a phase change ink carrier and a bis(urea-urethane) compound of the formula wherein R1 and R1? each, independently of the other, is an alkyl group, an aryl group, an arylalkyl group, or an alkylaryl group, R2 and R2? each, independently of the other, is an alkylene group, an arylene group, an aryalkylene group, or an alkylarylene group, R3 is an alkylene group, an arylene group, an arylalkylene group, or an alkylarylene group, and R4 and R5 each independently of the other, is a hydrogen atom or an alkyl group.

Abstract: Disclosed are trans-1,2-cyclohexane bis(urea-urethane) compounds of the formulae wherein R1 and R?1 each, independently of the other, is an alkylene group, an arylene group, an arylalkylene group, or an alkylarylene group, R2 and R?2 each, independently of the other, is an alkyl group, an aryl group, an arylalkyl group, or an alkylaryl group, R3 and R?3 each, independently of the other, is a hydrogen atom or an alkyl group, R4 and R?4 each, independently of the other, is a hydrogen atom, a fluorine atom, an alkyl group, or a phenyl group, n is an integer of 0, 1, 2, 3, or 4, and R5 is an alkyl group, an aryl group, an arylalkyl group, an alkylaryl group, or a substituent other than an alkyl, aryl, arylalkyl, or alkylaryl group.

Abstract: Curable trans-1,2-cyclohexane bis(urea-urethane) compounds of the formulae wherein R1 and R?1 each, independently of the other, are alkylene, arylene, arylalkylene, or alkylarylene groups, R2 and R?2 each, independently of the other, are alkyl, aryl, arylalkyl, or alkylaryl groups, R3 and R?3 each, independently of the other, are hydrogen atoms or alkyl groups, R4 and R?4 each, independently of the other, are hydrogen atoms, fluorine atoms, alkyl groups, or phenyl groups, n is an integer of 0, 1, 2, 3, or 4, and R5 is an alkyl, aryl, arylalkyl, or alkylaryl group, or a substituent other than an alkyl, aryl, arylalkyl, or alkylaryl group, provided that at least one of R1, R?1, R2, R?2, R3, R?3, R4, R?4, or one or more of R5 is an alkyl, alkylene, arylalkyl, arylalkylene, alkylaryl, or alkylarylene group containing an ethylenic unsaturation rendering the compound curable upon exposure to heat and/or actinic radiation.

Abstract: Processes for preparing bis(urea-urethane) compounds wherein R1 is alkyl, aryl, arylalkyl, or alkylaryl, R2 is alkylene, arylene, arylalkylene, or alkylarylene, R3 is alkylene, arylene, arylalkylene, or alkylarylene, and R4 is hydrogen or alkyl, comprising: (1) first bring to a reaction temperature of about 20-125° C. a reaction mixture comprising monoalcohol reactant R1—OH and diisocyanate reactant OCN—R2—NCO, the monoalcohol being present in an amount of about 0.8-1.

Abstract: Disclosed are phase change inks comprising a phase change ink carrier and a trans-1,2-cyclohexane bis(urea-urethane) compound of the formula or mixtures thereof, wherein R1 and R?1 each, independently of the other, is an alkylene group, an arylene group, an arylalkylene group, or an alkylarylene group, R2 and R?2 each, independently of the other, is an alkyl group, an aryl group, an arylalkyl group, or an alkylaryl group, R3 and R?3 each, independently of the other, is a hydrogen atom or an alkyl group, R4 and R?4 each, independently of the other, is a hydrogen atom, a fluorine atom, an alkyl group, or a phenyl group, n is an integer of 0, 1, 2, 3, or 4, and R5 is an alkyl group, an aryl group, an arylalkyl group, an alkylaryl group, or a substituent other than an alkyl, aryl, arylalkyl, or alkylaryl group.

Abstract: Disclosed is a phase change ink composition comprising a phase change ink carrier and a colorant compound of the formula