Patents by Inventor Rob BRONNEBERG

Rob BRONNEBERG has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 10266477
    Abstract: The present invention relates to a process for preparing a terephthalic diester by reacting terephthalic acid with at least one alcohol, wherein terephthalic acid is suspended in the alcohol in a dispersing tank, the preliminary suspension is passed from the dispersing tank into a reactor and converted in the presence of an esterification catalyst, and water of reaction is distilled off together with the vapor as alcohol-water azeotrope, the vapor is at least partly condensed, the condensate is separated into an aqueous phase and an organic phase and the organic phase is conducted through a column in which the organic phase is run counter to at least a portion of the vapor, and the organic phase is collected in the lower region of the column and at least partly passed into the dispersing tank.
    Type: Grant
    Filed: September 21, 2015
    Date of Patent: April 23, 2019
    Assignee: BASF SE
    Inventors: Armin Schraut, Martin Kaller, Rob Bronneberg, Jasmin Stammer, Martin Das, Gerrit Harnischmacher
  • Patent number: 10239818
    Abstract: The present invention relates to a process for preparing a terephthalic diester by reacting terephthalic acid with at least one alcohol, wherein terephthalic acid is suspended in the alcohol in a dispersing tank, the preliminary suspension is passed from the dispersing tank into a reactor and converted in the presence of an esterification catalyst, a reaction suspension is drawn off from a region between the upper region and the lower region of the reactor, a first stream of the reaction suspension is recycled into the upper region of the reactor and a second stream of the reaction suspension is introduced into the lower region of the reactor, and the reaction suspension is thus mixed, wherein the stream drawn off and/or the first stream is passed through a heat exchanger outside the reactor and heated; and water of reaction is distilled off together with the vapor as alcohol-water azeotrope, the vapor is at least partly condensed, the condensate is separated into an aqueous phase and an organic phase and the
    Type: Grant
    Filed: September 21, 2015
    Date of Patent: March 26, 2019
    Assignee: BASF SE
    Inventors: Armin Schraut, Martin Kaller, Rob Bronneberg, Jasmin Stammer, Martin Das, Gerrit Harnischmacher
  • Patent number: 10207978
    Abstract: The present invention relates to a process for preparing a terephthalic diester by reacting terephthalic acid with at least one alcohol, wherein terephthalic acid is suspended in the alcohol in a dispersing tank, the preliminary suspension is passed from the dispersing tank into a reactor and converted in the presence of an esterification catalyst, and water of reaction is distilled off together with the vapor as alcohol-water azeotrope, the vapor is at least partly condensed, the condensate is separated into an aqueous phase and an organic phase, the organic phase is dewatered and the dewatered organic phase is passed at least partly into the dispersing tank.
    Type: Grant
    Filed: September 21, 2015
    Date of Patent: February 19, 2019
    Assignee: BASF SE
    Inventors: Armin Schraut, Martin Kaller, Rob Bronneberg, Jasmin Stammer, Martin Das, Gerrit Harnischmacher
  • Patent number: 9988338
    Abstract: The present invention relates to a process for preparing a terephthalic diester by reacting terephthalic acid with at least one alcohol, wherein terephthalic acid is suspended in the alcohol in a dispersing tank, the preliminary suspension is passed from the dispersing tank into a reactor and converted in the presence of an esterification catalyst to obtain a reaction suspension, a stream of the reaction suspension is drawn off from the reactor, passed through a heat exchanger outside the reactor and heated and the heated reaction suspension is recycled into the reactor, and water of reaction is distilled off together with the vapor as alcohol-water azeotrope, the vapor is at least partly condensed, the condensate is separated into an aqueous phase and an organic phase and the organic phase is at least partly recycled into the reactor.
    Type: Grant
    Filed: September 21, 2015
    Date of Patent: June 5, 2018
    Assignee: BASF SE
    Inventors: Armin Schraut, Martin Kaller, Rob Bronneberg, Jasmin Stammer, Martin Das, Gerrit Harnischmacher
  • Publication number: 20170297997
    Abstract: The present invention relates to a process for preparing a terephthalic diester by reacting terephthalic acid with at least one alcohol, wherein terephthalic acid is suspended in the alcohol in a dispersing tank, the preliminary suspension is passed from the dispersing tank into a reactor and converted in the presence of an esterification catalyst, and water of reaction is distilled off together with the vapor as alcohol-water azeotrope, the vapor is at least partly condensed, the condensate is separated into an aqueous phase and an organic phase, the organic phase is dewatered and the dewatered organic phase is passed at least partly into the dispersing tank.
    Type: Application
    Filed: September 21, 2015
    Publication date: October 19, 2017
    Inventors: ARMIN SCHRAUT, Martin KALLER, Rob BRONNEBERG, Jasmin STAMMER, Martin DAS, Gerrit HARNISCHMACHER
  • Publication number: 20170297998
    Abstract: The present invention relates to a process for preparing a terephthalic diester by reacting terephthalic acid with at least one alcohol, wherein terephthalic acid is suspended in the alcohol in a dispersing tank, the preliminary suspension is passed from the dispersing tank into a reactor and converted in the presence of an esterification catalyst, and water of reaction is distilled off together with the vapor as alcohol-water azeotrope, the vapor is at least partly condensed, the condensate is separated into an aqueous phase and an organic phase and the organic phase is conducted through a column in which the organic phase is run counter to at least a portion of the vapor, and the organic phase is collected in the lower region of the column and at least partly passed into the dispersing tank.
    Type: Application
    Filed: September 21, 2015
    Publication date: October 19, 2017
    Inventors: Armin SCHRAUT, Martin KALLER, Rob BRONNEBERG, Jasmin STAMMER, Martin DAS, Gerrit HARNISCHMACHER
  • Publication number: 20170297996
    Abstract: The present invention relates to a process for preparing a terephthalic diester by reacting terephthalic acid with at least one alcohol, wherein terephthalic acid is suspended in the alcohol in a dispersing tank, the preliminary suspension is passed from the dispersing tank into a reactor and converted in the presence of an esterification catalyst, a reaction suspension is drawn off from a region between the upper region and the lower region of the reactor, a first stream of the reaction suspension is recycled into the upper region of the reactor and a second stream of the reaction suspension is introduced into the lower region of the reactor, and the reaction suspension is thus mixed, wherein the stream drawn off and/or the first stream is passed through a heat exchanger outside the reactor and heated; and water of reaction is distilled off together with the vapor as alcohol-water azeotrope, the vapor is at least partly condensed, the condensate is separated into an aqueous phase and an organic phase and the
    Type: Application
    Filed: September 21, 2015
    Publication date: October 19, 2017
    Applicant: BASF SE
    Inventors: ARMIN SCHRAUT, Martin KALLER, Rob BRONNEBERG, Jasmin STAMMER, Martin DAS, Gerrit HARNISCHMACHER
  • Publication number: 20170283363
    Abstract: The present invention relates to a process for preparing a terephthalic diester by reacting terephthalic acid with at least one alcohol, wherein terephthalic acid is suspended in the alcohol in a dispersing tank, the preliminary suspension is passed from the dispersing tank into a reactor and converted in the presence of an esterification catalyst to obtain a reaction suspension, a stream of the reaction suspension is drawn off from the reactor, passed through a heat exchanger outside the reactor and heated and the heated reaction suspension is recycled into the reactor, and water of reaction is distilled off together with the vapor as alcohol-water azeotrope, the vapor is at least partly condensed, the condensate is separated into an aqueous phase and an organic phase and the organic phase is at least partly recycled into the reactor.
    Type: Application
    Filed: September 21, 2015
    Publication date: October 5, 2017
    Applicant: BASF SE
    Inventors: ARMIN SCHRAUT, Martin KALLER, Rob BRONNEBERG, Jasmin STAMMER, Martin DAS, Gerrit HARNISCHMACHER