Patents by Inventor Robert A. Dubois
Robert A. Dubois has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 6552110Abstract: The subject invention pertains to thermoplastic marking compositions comprising a binder, which in turn comprise at least one homogeneous polymer. Accordingly, the subject invention provides a thermoplastic marking composition comprising: (a) from 10 to 80 weight percent of a binder, which in turn comprises: (i) from 1 to 99 weight percent of at least one homogeneous polymer; (ii) from 5 to 70 weight percent of at least one tackifier; (iii) from 0 to 10 weight percent of a polyethylene which has pendant acid functionality moieties of a non-functionalized wax; and (iv) from 0 to 20 weight percent of a plasticizer; and (b) from 20 to 90 weight percent of an inorganic filler. The subject formulations are usefully applied via spray, screed, and extrusion techniques.Type: GrantFiled: June 12, 2000Date of Patent: April 22, 2003Assignees: Dow Global Technologies Inc., Nor-SkiltInventors: Selim Yalvac, Teresa Karjala, Robert A. Dubois, Mark W. Murphy, Stein Dietrichson, Bjorn Nossen, Ingvild J. B. Stene
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Patent number: 6319979Abstract: Disclosed are packages, cartons, cases, and trays comprising a hot melt adhesive, in turn comprising at least one first homogenous linear or substantially linear ethylene polymer having a particular density and melt viscosity at 350° F. (177° C.), up to 60 weight percent wax and up to 40 weight percent tackifier. In particular, disclosed are packages, cartons, cases, and trays comprising a hot melt adhesive characterized by: a) at least one homogeneous linear or substantially linear interpolymer of ethylene with at least one C3-C20 &agr;-olefin interpolymer having a density from 0.850 g/cm3 to 0.895 g/cm3; and b) up to 60 weight percent of at least one tackifying resin; and c) up to 40 weight percent of at least one wax, wherein the hot melt adhesive has a viscosity of less than about 5000 cPs (50 grams/(cm.second)) at 150° C.Type: GrantFiled: February 2, 2000Date of Patent: November 20, 2001Assignees: The Dow Chemical Company, H. B. Fuller Licensing & Financing, Inc.Inventors: Robert A. Dubois, Cynthia L. Rickey, Steven W. Albrecht, Thomas F. Kauffman, Beth M. Eichler, Maynard Lawrence, Thomas H. Quinn
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Patent number: 6107430Abstract: Disclosed are hot melt adhesives comprising at least one first homogeneous linear etylene polymer having a particular density and melt viscosity at 350.degree.F. (177.degree.C.), and an optional wax and tackifier. In particular, disclosed is a hot melt adhesive characterized by: a) at least one homogeneous linear or substantially linear interpolymer of ethylene with at least ibe C.sub.2 --C.sub.20 .alpha.-olefin interpolymer having a density from 0.850 g/cm.sup.3 to 0.895 g/cm.sup.3 ; and b) optionally at least one tackifying resin; and c) optionally at least one wax wherein the hot melt adhesive has a viscosity of less than about 5000 cPs (50 grams/cm.second) at 150.degree.C. Preferred hot melt adhesives for use in adhering cardboard or paperboard are disclosed, as well as the resultant adhered products. Also disclosed is a dual reactor process for the preparation of the inventive hot melt adhesives.Type: GrantFiled: January 8, 1998Date of Patent: August 22, 2000Assignees: The Dow Chemical Company, H.B. Fuller Licensing & Financing Inc.Inventors: Robert A. Dubois, Cynthia L. Rickey, Steven W. Albrecht, Beth M. Eichler, Thomas F. Kauffman, Maynard Lawrence, Thomas H. Quinn
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Patent number: 5688331Abstract: In CVD processes susceptors can be made of a thermally conductive ceramic such as aluminum nitride which has superior durability with respect to fluorine plasma. Such aluminum nitride susceptors can include an embedded heater element and/or embedded ground or RF electrodes which as a result of their embedment are protected from the deleterious effects of the processing chamber environment. The conductors leading to these elements are protected from exposure to the process chamber environment by passing through a cylindrical member filled with inert gas supporting the wafer support plate of said susceptor. Alternately, the conductors leading to these elements can be run through passages in a hermetically sealed stem supporting the susceptor wafer support plate. The stem passes through the wall of the processing chamber so that connections to the susceptor wafer support plate can be made outside the processing chamber.Type: GrantFiled: July 1, 1996Date of Patent: November 18, 1997Assignee: Applied Materisls, Inc.Inventors: Michio Aruga, Atsunobu Ohkura, Akihiko Saito, Kenji Suzuki, Kenichi Taguchi, Dale Robert DuBois, Alan Ferris Morrison
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Patent number: 5654382Abstract: An epoxy resin prepared from a component comprising a bisphenol F having high ortho isomer content is claimed. Ortho isomer content is defined as follows:(A+2B)/2A: content of ortho-para isomer of a bisphenol FO: content of ortho-ortho isomer of a bisphenol FThe epoxy resin of the present invention has lower viscosity (e.g. melt viscosity, solution viscosity) and good physical properties (e.g. flexibility), and suitable for various applications such as coating materials, electrical laminates, adhesives, molding products, encapsulation materials, etc.Type: GrantFiled: June 30, 1995Date of Patent: August 5, 1997Assignee: The Dow Chemical CompanyInventors: Robert A. Dubois, Hideyuki Ohnishi, Allyson J. Malzman
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Patent number: 5386008Abstract: Advanced resins and unadvanced epoxy resins are disclosed wherein the unadvanced compound and at least a portion of the advanced epoxy resin contains at least one --O--R.sup.1 --O-- or --(O--CH.sub.2 --CHR.sup.2).sub.n --O -- group as a bridge between two groups selected independently from the group consisting of (1) a saturated or unsaturated cycloaliphatic group, (2) an aromatic group, (3) a group represented by the formula ##STR1## or (4) a group represented by the formula ##STR2## Also disclosed are nucleophilic derivatives thereof, as well as curable compositions and coating compositions containing the advanced or unadvanced epoxy resins or nucleophilic modified advanced or unadvanced epoxy resins. These advanced resins and unadvanced epoxy resins provide coatings with good flexibility or formability as exhibited by good flexural or formable properties determined by reverse impact, T-bend and wedge-bend tests, chip resistance, and with good corrosion resistance and throwpower.Type: GrantFiled: July 12, 1993Date of Patent: January 31, 1995Assignee: The Dow Chemical CompanyInventors: Robert A. Dubois, Allyson Malzman, Duane S. Treybig, Pong S. Sheih, Alan R. Whetten
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Patent number: 5244998Abstract: Advanced resins and unadvanced epoxy resins are disclosed wherein the unadvanced compound and at least a portion of the advanced epoxy resin contains at least one --O--R.sup.1 --O-- or --(O--CH.sub.2 --CHR.sup.2).sub.n --O-- group as a bridge between two groups selected independently from the group consisting of (1) a saturated or unsaturated cycloaliphatic group, (2) an aromatic group, (3) a group represented by the formula ##STR1## or (4) a group represented by the formula ##STR2## Also disclosed are nucleophilic derivatives thereof, as well as curable compositions and coating compositions containing the advanced or unadvanced epoxy resins or nucleophilic modified advanced or unadvanced epoxy resins. These advanced resins and unadvanced epoxy resins provide coatings with good flexibility or formability as exhibited by good flexural or formable properties determined by reverse impact, T-bend and wedge-bend tests, chip resistance, and with good corrosion resistance and throwpower.Type: GrantFiled: June 17, 1992Date of Patent: September 14, 1993Assignee: The Dow Chemical CompanyInventors: Robert A. Dubois, Allyson Malzman, Pong S. Sheih, Alan R. Whetten
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Patent number: 5147905Abstract: Advanced resins and unadvanced epoxy resins are disclosed wherein the unadvanced compound and at least a portion of the advanced epoxy resin contains at least one --O--R.sup.1 --O-- or --(O--CH.sub.2 --CHR.sup.2).sub.n --O-- group as a bridge between two groups selected independently from the group consisting of (1) a saturated or unsaturated cycloaliphatic group, (2) an aromatic group, (3) a group represented by the formula ##STR1## or (4) a group represented by the formula ##STR2## Also disclosed are nucleophilic derivatives thereof, as well as curable compositions and coating compositions containing the advanced or unadvanced epoxy resins or nucleophilic modified advanced or unadvanced epoxy resins. These advanced resins and unadvanced epoxy resins provide coatings with good flexibility or formability as exhibited by good flexural or formable properties determined by reverse impact, T-bend and wedge-bend tests, chip resistance, and with good corrosion resistance and throwpower.Type: GrantFiled: May 1, 1991Date of Patent: September 15, 1992Assignee: The Dow Chemical CompanyInventors: Robert A. Dubois, Duane S. Treybig, Allyson Malzman, Pong S. Sheih, Alan R. Whetten
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Patent number: 4982867Abstract: A two-part drum includes a blow molded self supporting plastic liner with circumferential reinforcing grooves, and a shell. The shell and the liner have matching cross-sections defined by curved sidewalls and curved sections cooperating to form a nominally rectangular or square cross-section.Type: GrantFiled: March 2, 1990Date of Patent: January 8, 1991Assignee: Greif Brothers CorporationInventors: Robert A. Dubois, Richard A. Caron
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Patent number: 4962253Abstract: A process for the preparation of vinyl aromatic compounds comprises contacting an aromatic compound and an olefin in the presence of a catalytic amount of a cyclopentadienyl, indenyl, or fluorenyl rhodium complex under reaction conditions sufficient to form the corresponding vinyl aromatic compound. Novel alkyl- or trimethylsilyl-substituted indenyl or fluorenyl compounds are among the compounds suitable for use in the process of the invention.Type: GrantFiled: August 21, 1989Date of Patent: October 9, 1990Assignee: The Dow Chemical CompanyInventor: Robert A. Dubois
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Patent number: 4772734Abstract: 1-Butenes are selectively produced via the dimerization of 1-olefins in the presence of novel organotantalum catalysts comprising tantalum and a silyl-substituted cyclopentadienyl moiety having the formula C.sub.5 H.sub.5-x (SiR.sup.6.sub.3).sub.x, wherein each R.sup.6 may be the same or different and is hydrogen, alkyl, cycloalkyl, aryl, aralkyl or alkoxy, and x is an integer from 1 to 5.Type: GrantFiled: July 17, 1987Date of Patent: September 20, 1988Assignee: The Dow Chemical CompanyInventors: Robert A. Dubois, Richard R. Schrock
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Patent number: 4717783Abstract: 1-Butenes are selectively produced via the dimerization of 1-olefins in the presence of novel organotantalum catalysts comprising tantalum and a silyl-substituted cyclopentadienyl moiety having the formula C.sub.5 H.sub.5-x (SiR.sup.6.sub.3).sub.x, wherein each R.sup.6 may be the same or different and is hydrogen, alkyl, cycloalkyl, aryl, aralkyl or alkoxy, and x is an integer from 1 to 5.Type: GrantFiled: March 16, 1987Date of Patent: January 5, 1988Assignee: The Dow Chemical CompanyInventors: Robert A. Dubois, Richard R. Schrock
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Patent number: 4595112Abstract: The present invention pertains to a container for shipping and storing a substance at a constant temperature. The container is made up of an inner liner with outlets, an insulating shell enveloping the liner and a fiber drum which houses the shell and the liner. A slip-on removal cover is used to close the drum.Type: GrantFiled: July 12, 1984Date of Patent: June 17, 1986Assignee: Greif Bros. CorporationInventor: Robert A. Dubois
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Patent number: 4567281Abstract: This invention is a process for cyclizing an ortho-alkenyl arenol, wherein the double bond of the alkenyl moiety is one or two carbons removed from the aromatic ring, with carbon monoxide, wherein the process comprises contacting an ortho-alkenyl arenol with carbon monoxide in the presence of a catalytic amount of a catalyst comprising (1) a rhodium-carbonyl complex and (2) an amine with a pK.sub.a of 6 or greater, arsine, phosphine, stibine or mixture thereof, under conditions such that a lactone-fused aromatic compound is prepared.Type: GrantFiled: June 6, 1983Date of Patent: January 28, 1986Assignee: The Dow Chemical CompanyInventor: Robert A. Dubois
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Patent number: 4434190Abstract: A road surface has fixed thereon a salt which lowers the freezing point of water by means of an aqueous fixation composition which comprises a mixture of an adhesion-promoting agent formed by an aqueous dispersion of a film-forming polymer or copolymer and a water-soluble hydrophobic agent which, in air, becomes insoluble in water. The proportion by weight of hydrophobic agent relatively to the dry extract of the adhesion-promoting agent is from 5 to 25%. The fixation composition is used in a proportion such that all the adhesion-promoting agent and the hydrophobic agent represents, in dry weight, from 10 to 120% of the weight of the salt. The aqueous fixation composition may in addition possibly comprise a foam-inhibiting agent and/or a second hydrophobic agent.Type: GrantFiled: August 3, 1982Date of Patent: February 28, 1984Assignee: Selfixat, S.A.Inventors: Robert Dubois, Pierre-Yves Dubois
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Patent number: 4299777Abstract: Cyano acetals prepared by the reaction of an alcohol with a nitrile CO and H.sub.2 in the presence of a Co.sub.2 (CO).sub.8 catalyst are more selectively produced at elevated temperatures by the addition of an effective amount of a cyano alkyl amine or carboxy alkyl amine promoter.Type: GrantFiled: June 13, 1980Date of Patent: November 10, 1981Assignee: The Dow Chemical CompanyInventors: Philip E. Garrou, Robert A. Dubois, Bart J. Bremmer
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Patent number: 4201306Abstract: An all-plastic drum construction permits a variety of sizes and capacity of drum by utilizing an extruded tube for the drum side walls of selected diameter and length proportional to the drum capacity desired. An injection molded bottom closure is welded to the bottom end of the tube by a thermoplastic bonding material having dispersed iron particles which are excited when exposed to induction heating thereby facilitating the melting of the thermoplastic. This welding material is disposed within a cavity defined by the bottom closure and bottom end of the tube and when subjected to induction heating and pressure fills the cavity to effectuate the bond between surfaces of the bottom closure and bottom end of the tube. A tight head drum is formed by securing by a similar welding technique a top closure to the upper end of the tube. In forming an open head drum, a thermoplastic chime is initially welded in similar fashion to the upper end of the tube.Type: GrantFiled: October 27, 1978Date of Patent: May 6, 1980Assignee: Greif Bros. CorporationInventors: Robert A. Dubois, George F. Smith
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Patent number: 4170623Abstract: An all plastic tubular drum is blow molded into the selected configuration from an extruded parison. The parison is provided with at least two spaced circumferentially extending thickened sections. These thickened sections are captured in a compression mold cavity during the blow molding cycle. Thereafter the captured thickened sections are compression molded into outwardly extending projections, undercuts, reinforcing gussets, or the like.Type: GrantFiled: June 28, 1978Date of Patent: October 9, 1979Assignee: Greif Bros. CorporationInventors: Robert A. Dubois, George F. Smith
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Patent number: 4136796Abstract: A closure is provided for a container opening. The opening is defined by a neck extending outwardly from the top of the container. The closure includes a liner cap disposed both interiorly and exteriorly of the neck and defines a central passage. A plug extends across the top of the cap to close off the passage from the exterior. The plug is provided with at least one longitudinal hole. The lower end of the plug has attached thereto a membrane extending across the passage. This membrane does not permit liquids within the container to pass therethrough, but possesses the property of being capable of venting gasses therethrough. A dust cap may extend across the top of the closure during shipment and storage.Type: GrantFiled: November 20, 1975Date of Patent: January 30, 1979Assignee: Greif Bros. CorporationInventors: Robert A. Dubois, William H. Gushard
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Patent number: 4094686Abstract: An additive for admixture with road surface preparation materials to prevent formation of ice and to melt snow on the finished road surface. The additive is distributed throughout the road surface and comprises coated particles of a halide, e.g. calcium chloride, coated particles of an alkali metal hydroxide, e.g. sodium hydroxide and a trace of coated or uncoated particles of calcium hydride, the coatings being of a water-tight inert substance such as linseed oil. These coatings are worn away at the road surface by traffic to expose the particles.Type: GrantFiled: November 24, 1976Date of Patent: June 13, 1978Assignee: Plastiroute S.A.Inventor: Robert Dubois