Patents by Inventor Robert A. Grigsby

Robert A. Grigsby has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 11542358
    Abstract: A catalyst system useful in the production of polyurethane and/or polyisocyanurate foams using hydrohaloolefin blowing agents.
    Type: Grant
    Filed: September 5, 2018
    Date of Patent: January 3, 2023
    Assignee: Huntsman Petrochemical LLC
    Inventors: Cheng-Kuang Li, Charles E. Serrano, Dianne Trang Pham, Robert A. Grigsby
  • Publication number: 20220356291
    Abstract: The present disclosure relates to acid-blocked pyrrolidine catalysts for use in a polyurethane formulation. The polyurethane formulation includes the acid-blocked pyrrolidine catalyst, a compound containing an isocyanate functional group, an active hydrogen-containing compound and a halogenated olefin compound. The use of such acid-blocked pyrrolidine catalysts show surprisingly low reactivity with halogenated olefin compounds yet sufficient reactivity to catalyze polyurethane formation.
    Type: Application
    Filed: July 14, 2020
    Publication date: November 10, 2022
    Applicant: Huntsman Petrochemical LLC
    Inventors: DiAnne Pham, Matthew T. Meredith, Robert A. Grigsby
  • Publication number: 20220340705
    Abstract: The present disclosure relates to a polyol resin blend for use in a polyurethane formulation. The polyol resin blend generally includes (a) an amine having a pKa value between about 6 and about 8.5 and a protonated amine obtained by contacting a methylamino-containing tertiary amine or primary etheramine having a pKa value greater than about 9 and an acid compound, (b) a polyol, and (c) a halogenated olefin. The present disclosure also provides polyurethane formulations containing the polyol resin blend and methods of making polyurethane foam from such polyurethane formulations.
    Type: Application
    Filed: September 16, 2020
    Publication date: October 27, 2022
    Inventors: DiAnne Pham, Matthew T. Meredith, Robert A. Grigsby
  • Patent number: 11472739
    Abstract: An admixture composition for use in cementitious compositions for improving the properties of the cementitious composition wherein the admixture composition comprises at least a polycarboxylate type comb-polymer dispersant and a hydroxyl amine compound selected from EDIPA (N,N-bis (2 hydroxypropyl)-N-(hydroxyethyl) amine) and optionally one or more polyhydroxyalkyl ethyleneamine compounds.
    Type: Grant
    Filed: September 29, 2014
    Date of Patent: October 18, 2022
    Assignee: Huntsman Petrochemical LLC
    Inventors: Antonius Wibowo, Howard P Klein, Robert A Grigsby, Jr.
  • Patent number: 11198756
    Abstract: The present disclosure provides a curable composition that includes an epoxy resin and a curing component comprising a blend of at least two amines. The curable composition may be combined with reinforced fibers and cured to form a composite article which can be used in various applications, such as in wind turbine blades.
    Type: Grant
    Filed: June 16, 2017
    Date of Patent: December 14, 2021
    Assignee: HUNTSMAN Petrochemical LLC
    Inventors: Hui Zhou, David C Lewis, Howard P. Klein, Robert A. Grigsby, Feixia Chen, Katty Darragas
  • Patent number: 11073361
    Abstract: A modular ballistic wall system uses a military standard shipping pallet as a floor. A wall frame is rotatably affixed to the pallet. The wall frame receives and supports a plurality of modular ballistic wall panels. The wall frame folds down against the pallet when the system is in a stowed position, e.g., during transport. The wall frame is generally perpendicular to the pallet when the system is in a deployed position. The modular ballistic wall panels can be solid metal ballistic panels, ballistic panels with firing ports, or ballistic glass.
    Type: Grant
    Filed: May 21, 2019
    Date of Patent: July 27, 2021
    Assignee: Advanced American Technologies, LLC
    Inventors: Robert Grigsby, Shannon McCall
  • Patent number: 10766994
    Abstract: The present disclosure provides a method for reducing the aldehyde content in an amine catalyst by treating the amine catalyst with a treating agent selected from a non-cyclic amide substituted with an isocyanate reactive group, a guanidine substituted with an isocyanate reactive group, a polyether amine adducted with a urea compound or a guanidine compound, a free radical scavenger and a mixture thereof. The treated amine catalyst may then be used in the production of polyurethane materials which exhibit reduced aldehyde emissions.
    Type: Grant
    Filed: January 13, 2015
    Date of Patent: September 8, 2020
    Assignee: Huntsman Petrochemical LLC
    Inventors: Ernest L. Rister, Jr., Haibo Zhao, Robert A. Grigsby, Jr., Robert B. Moore
  • Publication number: 20200247938
    Abstract: A catalyst system useful in the production of polyurethane and/or polyisocyanurate foams using hydrohaloolefin blowing agents.
    Type: Application
    Filed: September 5, 2018
    Publication date: August 6, 2020
    Inventors: Cheng-Kuang Li, Charles E. Serrano, Dianne Trang Pham, Robert A. Grigsby
  • Patent number: 10364337
    Abstract: In an embodiment, an amine-oxidation inhibitor, such as a free radical scavenger and/or antioxidant, is added to an oxidation-sensitive amine, such as an amine catalyst, to inhibit oxidation of the amine. The inhibitor-treated amine may then be used in an application such as a polyurethane application to reduce the emission of undesired oxidation products from the polyurethane.
    Type: Grant
    Filed: January 18, 2016
    Date of Patent: July 30, 2019
    Assignee: HUNTSMAN Petrochemical LLC
    Inventors: Bhajendra Narayan Barman, Robert A Grigsby, Jr.
  • Publication number: 20190100616
    Abstract: The present disclosure provides a curable composition that includes an epoxy resin and a curing component comprising a blend of at least two amines. The curable composition may be combined with reinforced fibers and cured to form a composite article which can be used in various applications, such as in wind turbine blades.
    Type: Application
    Filed: June 16, 2017
    Publication date: April 4, 2019
    Inventors: Hui Zhou, David C Lewis, Howard P. Klein, Robert A. Grigsby, Feixia Chen, Katty Darragas
  • Publication number: 20180355093
    Abstract: The present disclosure provides a method for reducing the aldehyde content in an amine catalyst by treating the amine catalyst with a treating agent selected from a non-cyclic amide substituted with an isocyanate reactive group, a guanidine substituted with an isocyanate reactive group, a polyether amine adducted with a urea compound or a guanidine compound, a free radical scavenger and a mixture thereof. The treated amine catalyst may then be used in the production of polyurethane materials which exhibit reduced aldehyde emissions.
    Type: Application
    Filed: January 13, 2015
    Publication date: December 13, 2018
    Inventors: Ernest L. Rister, Jr., Haibo ZHAO, Robert A. GRIGSBY, Robert B. MOORE
  • Patent number: 10131737
    Abstract: The present disclosure provides a method for reducing the aldehyde content in an amine catalyst by treating the amine catalyst with a treating agent selected from a cyclic urea substituted with at least one isocyanate reactive group, a free radical scavenger and a mixture thereof. The treated amine catalyst may then be used in the production of polyurethane materials which exhibit reduced aldehyde emissions.
    Type: Grant
    Filed: September 30, 2014
    Date of Patent: November 20, 2018
    Assignee: HUNTSMAN PETROCHEMICAL LLC
    Inventors: Ernest L Rister, Jr., Srinivasa S Godavarthy, Henry Robertson, Robert A Grigsby, Jr., Robert B Moore, Geert Lodewijk Dries, Eugene P Wiltz, Jr.
  • Patent number: 9987588
    Abstract: Amine compositions comprising sterically hindered amines and associated methods are provided. In some embodiments, amine compositions of the present disclosure may be useful for selective removal of H2S from an acidic gas stream.
    Type: Grant
    Filed: February 6, 2017
    Date of Patent: June 5, 2018
    Assignee: HUNTSMAN PETROCHEMICAL LLC
    Inventors: Wei-Yang Su, Robert A. Grigsby, Jr., Jingjun Zhou
  • Patent number: 9988483
    Abstract: The present disclosure relates to pyrrolidine-based catalysts for use in a polyurethane formulation. The polyurethane formulation includes the pyrrolidine-based catalyst, a compound containing an isocyanate functional group, an active hydrogen-containing compound. The use of such catalysts produces high quality polyurethane foam while reducing environmental concerns that can arise during the production of polyurethane foam as well as in the foam that is produced.
    Type: Grant
    Filed: June 24, 2015
    Date of Patent: June 5, 2018
    Assignee: HUNTSMAN PETROCHEMICAL LLC
    Inventors: Matthew W. Forkner, Robert A. Grigsby, Jr., Eugene P. Wiltz, Jr., Ernest L. Rister, Jr., Frank Rodriguez, Howard P. Klein
  • Patent number: 9856344
    Abstract: The present disclosure provides a method for reducing the aldehyde content in an amine catalyst by treating the amine catalyst with an organic acid. The organic acid-treated amine catalyst may then be used in the production of polyurethane materials which exhibit reduced aldehyde emissions.
    Type: Grant
    Filed: August 26, 2014
    Date of Patent: January 2, 2018
    Assignee: HUNTSMAN PETROCHEMICAL LLC
    Inventors: Frank Rodriguez, Robert A Grigsby, Jr., Eugene P Wiltz, Jr., Ernest L Rister, Jr., Bhajendra N Barman
  • Patent number: 9700832
    Abstract: Amine compositions comprising sterically hindered amines and associated methods are provided. In some embodiments, amine compositions of the present disclosure may be useful for selective removal of H2S from an acidic gas stream.
    Type: Grant
    Filed: March 15, 2016
    Date of Patent: July 11, 2017
    Assignee: HUNTSMAN PETROCHEMICAL LLC
    Inventors: Wei-Yang Su, Robert A. Grigsby, Jr., Jingjun Zhou
  • Publication number: 20170144102
    Abstract: Amine compositions comprising sterically hindered amines and associated methods are provided. In some embodiments, amine compositions of the present disclosure may be useful for selective removal of H2S from an acidic gas stream.
    Type: Application
    Filed: February 6, 2017
    Publication date: May 25, 2017
    Inventors: Wei-Yang Su, Robert A. Grigsby, JR., Jingjun Zhou
  • Publication number: 20170101501
    Abstract: The present disclosure relates to pyrrolidine-based catalysts for use in a polyurethane formulation. The polyurethane formulation includes the pyrrolidine-based catalyst, a compound containing an isocyanate functional group, an active hydrogen-containing compound. The use of such catalysts produces high quality polyurethane foam while reducing environmental concerns that can arise during the production of polyurethane foam as well as in in the foam that is produced.
    Type: Application
    Filed: June 24, 2015
    Publication date: April 13, 2017
    Inventors: Matthew W. FORKNER, Robert A. GRIGSBY, Jr., Eugene P. WILTZ, Jr., Ernest L. RISTER, Jr., Frank RODRIGUEZ, Howard P. KLEIN
  • Publication number: 20160264465
    Abstract: An admixture composition for use in cementitious compositions for improving the properties of the cementitious composition wherein the admixture composition comprises at least a polycarboxylate type comb-polymer dispersant and a hydroxyl amine compound selected from EDIPA (N,N-bis (2 hydroxypropyl)-N-(hydroxyethyl) amine) and optionally one or more polyhydroxyalkyl ethyleneamine compounds.
    Type: Application
    Filed: September 29, 2014
    Publication date: September 15, 2016
    Inventors: Antonius Wibowo, Howard P Klein, Robert A Grigsby, Jr.
  • Publication number: 20160200854
    Abstract: The present disclosure provides a method for reducing the aldehyde content in an amine catalyst by treating the amine catalyst with a treating agent selected from a cyclic urea substituted with at least one isocyanate reactive group, a free radical scavenger and a mixture thereof. The treated amine catalyst may then be used in the production of polyurethane materials which exhibit reduced aldehyde emissions.
    Type: Application
    Filed: September 30, 2014
    Publication date: July 14, 2016
    Inventors: Ernest L Rister, JR., Srinivasa S Godavarthy, Henry Robertson, Robert A Grigsby, JR., Robert B Moore, Geert Lodewijk Dries, Eugene P Wiltz, JR.