Abstract: The present invention is directed to a unique heat transfer material for use in transferring a discontinuous coating onto a substrate, such as an article of clothing. The heat transfer material of the present invention may be used cold peel transfer processes, resulting in an image-bearing coating having superior crack resistance, washability, and breathability compared to conventional image-bearing coatings. Additionally, the materials may be used on dark colored fabrics without washed-out appearance typically associated with printing on darker fabrics. The heat transfer material of the present invention produces superior results due to the use of discontinuous coatings.

Abstract: A composition for forming an elastomeric article is disclosed. The composition includes an elastomeric material and a film leveler, where the film leveler is present in an amount of from about 0.05% to about 5.0% by mass of the composition.

Abstract: An elastomeric article includes a substrate body formed from an elastomeric material. The substrate body has a first surface, and a donning layer overlying at least a portion of the first surface. The donning layer is formed from a modified vinyl acetate polymer.

Abstract: Disclosed is an elastomeric article, such as a glove, and a process for making the elastomeric articles. The elastomeric articles include a primary matrix including one or more layers of elastomeric polymer, such as a natural or synthetic latex or a block copolymer, and a polymeric coating on a surface of the primary matrix. The polymeric coating is formed of crosslinked polymers which are crosslinked with a cationic crosslinking agent such as a polyamide epichlorohydrin crosslinking agent. The polymeric coating can be a crosslinked polyarcylate, polyacrylamide, or polysaccharise, for example. In one embodiment, the crosslinking agent crosslinks the polymeric coating to the primary matrix layer of the article, forming secure attachments between the primary matrix and the polymeric coating. In one embodiment, the crosslinking agent may crosslink the elastomeric polymer as well as the polymeric coating.

Abstract: An elastomeric article includes a substrate body formed from an elastomeric material, and a plurality of functionalized beads covalently bonded to the elastomeric material.

Abstract: An elastomeric article includes a substrate body formed from an elastomeric material, and a plurality of functionalized beads covalently bonded to the elastomeric material.

Abstract: A composition for forming an elastomeric article is disclosed. The composition includes an elastomeric material and a film leveler, where the film leveler is present in an amount of from about 0.05% to about 5.0% by mass of the composition.

Abstract: An elastomeric article includes a substrate body formed from an elastomeric material. The substrate body has a first surface, and a donning layer overlying at least a portion of the first surface. The donning layer is formed from a modified vinyl acetate polymer.

Abstract: A method of forming an elastomeric article includes providing a former, coating the former with a coagulant composition including zinc stearate, dipping the former into a polymer composition including an elastomeric polymer and water, curing the elastomeric polymer at a temperature above the melting point of the zinc stearate, and removing the water from the polymer composition on the former to form the elastomeric article.

Abstract: Disclosed is an elastomeric article, such as an elastomeric glove, for example, and a method for making the disclosed elastomeric article. The elastomeric article includes a fluorocarbon graft on the donning surface of the article. In addition, a hydrophilic lubricant including a modified siloxane displaying polar functionality may be applied to the surface of the article. In one embodiment, the modified siloxane may be an amino modified siloxane. The silicone lubricant and the fluorocarbon graft display a synergy, providing an article with improved dry slip characteristics and improved wet slip characteristics. In addition, a fatty alcohol may be applied to the surface of the article, further improving the damp slip characteristics of the article.

Abstract: Disclosed is an elastomeric article, such as an elastomeric glove, for example, and a method for making the disclosed elastomeric article. The elastomeric article includes a fluorocarbon graft on the donning surface of the article. In addition, a hydrophilic lubricant including a modified siloxane displaying polar functionality may be applied to the surface of the article. In one embodiment, the modified siloxane may be an amino modified siloxane. The silicone lubricant and the fluorocarbon graft display a synergy, providing an article with improved dry slip characteristics and improved wet slip characteristics. In addition, a fatty alcohol may be applied to the surface of the article, further improving the damp slip characteristics of the article.

Abstract: Disclosed is an elastomeric article, such as a glove, and a process for making the elastomeric articles. The elastomeric articles include a primary matrix including one or more layers of elastomeric polymer, such as a natural or synthetic latex or a block copolymer, and a polymeric coating on a surface of the primary matrix. The polymeric coating is formed of crosslinked polymers which are crosslinked with a cationic crosslinking agent such as a polyamide epichlorohydrin crosslinking agent. The polymeric coating can be a crosslinked polyarcylate, polyacrylamide, or polysaccharise, for example. In one embodiment, the crosslinking agent crosslinks the polymeric coating to the primary matrix layer of the article, forming secure attachments between the primary matrix and the polymeric coating. In one embodiment, the crosslinking agent may crosslink the elastomeric polymer as well as the polymeric coating.

Abstract: An apparatus and method for uniformly contacting an article with a treatment solution. Preferred embodiments are methods of uniformly tinting of contact lenses or uniformly surface modifying contact lenses. The method involves suspending the lens in the treatment solution by application of fluid flow, preferably sinusoidal or pulsed, in a direction opposite the stagnant force (i.e., sum of buoyancy and gravity forces) on the article. The fluid flow prevents the lens from contacting the container structure for periods sufficient to cause non-uniform treatment conditions, while continuously mixing the treatment solution to maintain uniform concentrations throughout.

Abstract: The invention relates to a process for modifying the surface characteristics of a preformed polymer substrate to impart altered properties thereto by graft polymerization on the substrate which includes: placing the polymer substrate in a plasma to form free radicals on the substrate; contacting the substrate having free radicals with oxygen to form hydroperoxy groups on the surface of the substrate; and graft polymerizing an ethylenically unsaturated monomer onto the surface of the polymer substrate.

Abstract: An apparatus and method for uniformly contacting an article with a treatment solution. Preferred embodiments are methods of uniformly tinting of contact lenses or uniformly surface modifying contact lenses. The method involves suspending the lens in the treatment solution by application of fluid flow, preferably sinusoidal or pulsed, in a direction opposite the stagnant force (i.e., sum of buoyancy and gravity forces) on the article. The fluid flow prevents the lens from contacting the container structure for periods sufficient to cause non-uniform treatment conditions, while continuously mixing the treatment solution to maintain uniform concentrations throughout.

Abstract: A method and composition useful in fabricating radiation-absorbing contact lenses, especially ultraviolet (UV) and visible (tint) light-absorbing lenses. The radiation-absorber is incorporated into a contact lens in the presence of a buffer which maintains the pH near neutral. Subsequently, the radiation-absorber is chemically affixed to the lens by raising the pH to a highly basic level.

Abstract: A method of tinting an unhydrated contact lens involves the steps of providing an unhydrated contact lens; providing a dyestuff solution; providing a printing block comprising a hydrophilic polymer material containing a dye complexing agent capable of noncovalently bonding the dyestuff; placing the dyestuff solution onto the printing block; contacting the unhydrated contact lens and the printing block for a time sufficient to allow the dyestuff solution to diffuse to the lens; and removing the lens from the printing block.

Abstract: A dimensionally stable hydrogel contact lens of polyvinyl alcohol having an equilibrium water content of between about 70 to about 80 weight percent, based upon the total swollen lens weight, said lens having been annealed in a mold essentially conforming to the contact lens dimensions under substantially ambient non-drying setting conditions in the presence of an aqueous-organic annealing promoter solvent, for a period of time substantially sufficient to reach annealing equilibrium.

Abstract: A process for encapsulating a preformed polymeric substrate comprises peroxidizing and hydroperoxidizing the surface of said preformed substrate using ozone and then carrying out a crosslinked graft copolymerization of selected ethylenically unsaturated monomers both on and surrounding (encapsulating) said substrate. Such encapsulation of substrates provides protective coatings, ablative coatings and, particularly, soft skirts for hard contact lenses.

Abstract: A process for modifying the surface characteristics of a preformed polymeric substrate to impart hydrophilicity, hydrophobicity or other desired properties thereto comprises peroxidizing and hydroperoxidizing the surface of said preformed substrate using ozone, directing the subsequent graft polymerization of selected ethylenically unsaturated monomers essentially solely to the surface of said substrate to achieve the desired alteration of substrate surface characteristics while maintaining substrate structural integrity. Substrates so modified are useful in biomedical devices, semipermeable membranes, films, fibers and especially contact lenses.