Abstract: A composition comprising a fluorocarbon thermoplastic random copolymer having the subunits of: —(CH2CF2)x-, —(CF2CF(CF3))y-, and —(CF2CF2)z-, wherein x is from 1 to 40 or 60 to 80 mole percent, z is greater than 40 to no more than 89 mole percent, and y is such that x+y+z equals 100 mole percent; wherein the fluorocarbon thermoplastic random copolymer is crosslinked with an organic primary amine. The composition may be formed by curing an aqueous coated composition of the fluorocarbon thermoplastic random copolymer and a water soluble organic primary amine, such as triethylenetetraamine (TETA). A fuser member comprises a substrate having an outer substrate surface, and an outer layer disposed over the outer substrate surface where the outer layer comprises such a composition.

Abstract: An apparatus for enabling the uniform application of a layer of a coating composition to a tubular substrate includes a shaft, and upper and lower circular rim members of equal diameter that are concentrically attached to the shaft. A pneumatically inflatable tube disposed on each circular rim member has an outer diameter that is variable with changes in its internal pressure. A first flexible cylindrical sheet in contact with the inflatable tubes has parallel edges that form a first slit sufficiently wide to permit movement of the first sheet in response to pressure variation in the tubes. A second flexible cylindrical sheet surrounding the first cylindrical sheet has parallel edges that form a second slit sufficiently wide to permit movement of the second sheet also in response to pressure variation. The second slit is laterally displaced from the first slit, and the second cylindrical sheet has a diameter nearly equal to the specified diameter of the substrate.

Abstract: The present invention is a fuser member that includes a core member having a rigid outer surface. A resilient layer made of an elastomer is disposed on outer surface. A primer layer of perfluoroalkoxy resin and trifluoroethylene-perfluoroethylvinyl ether-perfluoroethylene vinyl phosphate or a mixture of perfluoroalkoxy resin and trifluoroethylene-perfluoroethylvinyl bonds the resilient layer and an outer layer. The outer layer comprises fluoropolymer resin selected from the group consisting of polytetrafluoroethylene, polyperfluoroalkoxy-tetrafluoroethylene, polyfluorinated ethylene-propylene, and blends thereof.

Abstract: An apparatus for enabling the uniform application of a layer of a coating composition to a tubular substrate includes a shaft, and upper and lower circular rim members of equal diameter that are concentrically attached to the shaft. A pneumatically inflatable tube disposed on each circular rim member has an outer diameter that is variable with changes in its internal pressure. A first flexible cylindrical sheet in contact with the inflatable tubes has parallel edges that form a first slit sufficiently wide to permit movement of the first sheet in response to pressure variation in the tubes. A second flexible cylindrical sheet surrounding the first cylindrical sheet has parallel edges that form a second slit sufficiently wide to permit movement of the second sheet also in response to pressure variation. The second slit is laterally displaced from the first slit, and the second cylindrical sheet has a diameter nearly equal to the specified diameter of the substrate.

Abstract: An apparatus for enabling the uniform application of a layer of a coating composition to a tubular substrate includes a shaft, and upper and lower circular rim members of equal diameter that are concentrically attached to the shaft. A pneumatically inflatable tube disposed on each circular rim member has an outer diameter that is variable with changes in its internal pressure. A first flexible cylindrical sheet in contact with the inflatable tubes has parallel edges that form a first slit sufficiently wide to permit movement of the first sheet in response to pressure variation in the tubes. A second flexible cylindrical sheet surrounding the first cylindrical sheet has parallel edges that form a second slit sufficiently wide to permit movement of the second sheet also in response to pressure variation. The second slit is laterally displaced from the first slit, and the second cylindrical sheet has a diameter nearly equal to the specified diameter of the substrate.

Abstract: This invention relates to a low camping fluorocarbon thermoplastic random copolymer roller coating having a closely controlled curing agent content.

Abstract: The present invention is a fuser member that includes a core member having a rigid outer surface. A resilient layer made of an elastomer is disposed on outer surface. A primer layer of perfluoroalkoxy resin and trifluoroethylene-perfluoroethylvinyl ether-perfluoroethylene vinyl phosphate or a mixture of perfluoroalkoxy resin and trifluoroethylene-perfluoroethylvinyl bonds the resilient layer and an outer layer. The outer layer comprises fluoropolymer resin selected from the group consisting of polytetrafluoroethylene, polyperfluoroalkoxy-tetrafluoroethylene, polyfluorinated ethylene-propylene, and blends thereof.

Abstract: This invention relates to an improved fuser roller for use in a high speed fusing station where improved heat transfer from the fuser roller to the fused substrates is required. The invention also relates to an improved fuser system using the improved fuser roller of the present invention in combination with an improved pressure roller to produce an improved fuser section.

Abstract: Disclosed are fuser members, apparatus and methods which employ compositions that can be varied to provide a fused toner image with a selected gloss level. In embodiments, the apparatus and methods employ a fusing member having an outer contact surface thereon which contacts a previously fused toner image under conditions of elevated temperature and pressure. The contact surface has a Gardner G60 gloss of up to about 35 and is comprised of a fluorocarbon thermoplastic random copolymer co-cured with a fluorinated resin, such as polyfluoroethylenepropylene (FEP). In embodiments, the contact surface comprises a fluorocarbon thermoplastic random copolymer co-cured with a fluorinated resin including subunits of: —(CH2 CF2)x-, —(CF2CF(CF3))y-, and —(CF2 CF2)z-, wherein: x is from 1 to 50 or 60 to 80 mole percent, y is from 10 to 89 mole percent, z is from 10 to 89 mole percent, and x+y+z equals 100 mole percent.

Abstract: Disclosed are fuser members, apparatus and methods which employ compositions that can be varied to provide a fused toner image with a selected gloss level. In embodiments, the apparatus and methods employ a fusing member having an outer contact surface thereon which contacts a previously fused toner image under conditions of elevated temperature and pressure. The contact surface has a Gardner G60 gloss of up to about 35 and is comprised of a fluorocarbon thermoplastic random copolymer co-cured with a fluorinated resin, such as polyfluoroethylenepropylene (FEP). In embodiments, the contact surface comprises a fluorocarbon thermoplastic random copolymer co-cured with a fluorinated resin including subunits of: —(CH2CF2)x-, —(CF2CF(CF3))y-, and —(CF2CF2)z-, wherein: x is from 1 to 50 or 60 to 80 mole percent, y is from 10 to 89 mole percent, z is from 10 to 89 mole percent, and x+y+z equals 100 mole percent.

Abstract: A method of making a fuser member having a support comprising the steps of: A) providing a support; B) coating from an organic solvent onto the support a coating composition comprising a fluorocarbon thermoplastic random copolymer, a curing agent having a bisphenol residue, a particulate filler containing zinc oxide, an aminosiloxane, and antimony-doped tin oxide particles, the fluorocarbon thermoplastic random copolymer having subunits of: —(CH2CF2)x—, —(CF2CF(CF3)y—, and —(CF2CF2)z—, wherein x is from 1 to 50 or 60 to 80 mole percent, y is from 10 to 90 mole percent, z is from 10 to 90 mole percent, x+y+z equals 100 mole percent; and C) curing the coating composition for 5 to 10 hours at a temperature in the range of 25° C. to 275° C.

Abstract: A controlled modulus fusing-station member inclusive of a durable, tough, elastically deformable layer incorporating hollow flexible filler particles. The elastically deformable layer is preferably a single layer on a substrate, the substrate preferably a core member of a fuser roller or a pressure roller. The elastically deformable layer is made from a dry formulation inclusive of: a fluoro-thermoplastic polymer powder; microspheres in the form of unexpanded microspheres or expanded microballoons; and solid filler particles including strength-enhancing filler particles and thermal-conductivity-enhancing filler particles. The dry formulation can be thermally cured or electron-beam cured. Preferably, the dry formulation is thermally cured and further includes a curing catalyst, preferably a peroxide catalyst. Alternatively, the curing catalyst can be a bisphenol residue.

Abstract: A fuser member comprising a core and a layer overlying the core, the layer including a fluorocarbon random copolymer, a curing agent which cures the fluorocarbon random copolymer, the cured fluorocarbon random copolymer having subunits of: —(CH2CF2)x—, —(CF2CF(CF3))y—, or —(CF2CF2)z—, wherein x is from 30 to 90 mole percent, y is from 10 to 70 mole percent, z is from 0 to 34 mole percent; x+y+z equals 100 mole percent. The layer further including a particulate filler having aluminum oxide, having a total concentration in the layer of from 10 to 140 parts by weight per 100 parts of the fluorocarbon random copolymer, and alkaline earth metal oxides or alkaline earth metal hydroxides or combinations thereof; and siloxane polymer comprising one or more curable, silanol-terminated, polyfunctional poly(C1-6 alkyl)siloxane polymers.

Abstract: A controlled modulus fusing-station member inclusive of a durable, tough, elastically deformable layer incorporating hollow flexible filler particles. The elastically deformable layer is preferably a single layer on a substrate, the substrate preferably a core member of a fuser roller or a pressure roller. The elastically deformable layer is made from a dry formulation inclusive of: a fluoro-thermoplastic polymer powder; microspheres in the form of unexpanded microspheres or expanded microballoons; and solid filler particles including strength-enhancing filler particles and thermal-conductivity-enhancing filler particles. The dry formulation can be thermally cured or electron-beam cured. Preferably, the dry formulation is thermally cured and further includes a curing catalyst, preferably a peroxide catalyst. Alternatively, the curing catalyst can be a bisphenol residue.

Abstract: Disclosed are apparatus and methods to adjust gloss of a fused toner image, and in particular to reduce differential gloss within the fused toner image so as to provide prints which more closely resemble lithographic prints in image quality. In embodiments, the apparatus and methods employ a finishing member having an outer contact surface thereon which contacts a previously fused toner image under conditions of elevated temperature and pressure. The contact surface is comprised of a fluorocarbon thermoplastic random copolymer co-cured with a fluorinated resin, such as polyfluoroethylenepropylene (FEP). In embodiments, the contact surface comprises a fluorocarbon thermoplastic random copolymer co-cured with a fluorinated resin including subunits of: —(CH2CF2)x—, —(CF2CF(CF3))y—, and —(CF2CF2)z—, wherein: x is from 1 to 50 or 60 to 80 mole percent, y is from 10 to 90 mole percent, z is from 10 to 90 mole percent, and x +y+z equals 100 mole percent.

Abstract: Disclosed are fuser members, apparatus and methods which employ compositions that can be varied to provide a fused toner image with a selected gloss level. In embodiments, the apparatus and methods employ a fusing member having an outer contact surface thereon which contacts a previously fused toner image under conditions of elevated temperature and pressure. The contact surface has a Gardner G60 gloss of up to about 35 and is comprised of a fluorocarbon thermoplastic random copolymer co-cured with a fluorinated resin, such as polyfluoroethylenepropylene (FEP).

Abstract: Disclosed are apparatus and methods to adjust gloss of a fused toner image, and in particular to reduce differential gloss within the fused toner image so as to provide prints which more closely resemble lithographic prints in image quality. In embodiments, the apparatus and methods employ a finishing member having an outer contact surface thereon which contacts a previously fused toner image under conditions of elevated temperature and pressure. The contact surface is comprised of a fluorocarbon thermoplastic random copolymer co-cured with a fluorinated resin, such as polyfluoroethylenepropylene (FEP).

Abstract: A fusing apparatus for heat fixing toner images onto a receiver medium. The apparatus includes a fuser member including an elastomeric contact surface; a pressure member forming a fusing nip to receive the receiver medium; a heater member including a conformable base cushion layer and an outer polymeric layer disposed over the base cushion layer, the heater member being in contact with the fuser and external thereto; and a radiant heat subsystem positioned externally of the heater member to provide heat to the surface of the first heater member which then contacts the fuser member so as to transfer heat thereto. The heater member is adapted to controllably exert pressure on the fuser member in order to controllably transfer heat to the fuser member, thereby providing control over the fusing capabilities of an eletrophotographic process.

Abstract: A laminator member for color proofing comprising a belt substrate; and a surface layer, said surface layer comprising: a polyamic-imide organic polymer binder; a fluorinated resin polymer; and a perfluoroalkylsubstituted fluororesin-reactive compound having the formula: where R5 is H or F; Q is OH, SiR6R7R8; R6, R7, and R8 being independently selected from the group consisting of Cl, OH, an alkyl group containing 1 to about 4 carbon atoms, an alkoxy group containing 1 to about 4 carbon atoms, an acyloxy group containing 2 to about 4 carbon atoms, and an amino group containing 0 to about 4 carbon atoms; and n is an integer from 1 to about 15; with the proviso that, at least one of R6, R7, and R8 is Cl, OH, or an alkoxy, acyloxy, or amino group; and wherein said surface layer is adhered to said belt substrate by the polyamide-imide polymer binder.

Abstract: A fusing station including an externally heated deformable fuser roller and a relatively harder pressure roller, the fuser roller including a heat distribution layer. A fuser roller embodiment includes a core member, a base cushion layer around the core member, a heat storage layer around the base cushion layer, a heat distribution layer around the heat storage layer, and a thin gloss control layer around the heat distribution layer. Ratios of thermal conductivity divided by thickness for the layers are, respectively: for the base cushion layer, less than approximately 13.3 BTU/hr/ft2/°F.; for the heat storage layer, approximately between 300 BTU/hr/ft2/°F.-1400 BTU/hr/ft2/°F.; for the heat distribution layer, approximately between 600 BTU/hr/ft2/°F.-4,800 BTU/hr/ft2/°F.; and, for the gloss control layer, approximately between 600 BTU/hr/ft2/°F.-6,000 BTU/hr/ft2/°F.