Patents by Inventor Robert A. Valeri

Robert A. Valeri has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20240022849
    Abstract: The UV-curable coating compositions disclosed herein are provided for use as coatings for plastic (organic glass) substrates, and ophthalmic lenses, in particular. The compositions may be applied by a variety of means, including spin coating and inkjet coating. The coating compositions exhibit abrasion resistance comparable to conventional thermally-cured sol-gel coatings.
    Type: Application
    Filed: September 21, 2023
    Publication date: January 18, 2024
    Inventor: Robert Valeri
  • Patent number: 11752713
    Abstract: The present invention proposes a polymer composition of manufacturing ophthalmic lens by polymerization of polymerizable composition wherein the shrinkage phenomenon is minimized. The polymerizable composition comprised two different categories of monomers which are able during crosslinking to control and limit said chemical shrinkage. The present invention comprises also ophthalmic lens obtained from said polymer composition using a manufacturing process of casting or additive manufacturing.
    Type: Grant
    Filed: October 8, 2020
    Date of Patent: September 12, 2023
    Assignee: Essilor International
    Inventors: Robert Valeri, John Biteau
  • Publication number: 20230220232
    Abstract: The present invention relates to a curable coating composition, especially a radiation curable coating composition comprising at least one poly(meth)acrylate compound comprising at least 6 (meth)acrylate groups, at least one unsaturated silane compound, and at least one photoinitiator. Said at least one poly(meth)acrylate compound comprising at least 6 (meth)acrylate groups and said at least one unsaturated silane compound represent at least 95% of the weight of polymerizable compounds present in the composition. Upon radiation-curing, the composition provides an abrasion- and/or scratch-resistant coating.
    Type: Application
    Filed: June 3, 2021
    Publication date: July 13, 2023
    Inventor: Robert VALERI
  • Publication number: 20220411645
    Abstract: The radiation-curable coating compositions disclosed herein are provided for use as photo-stable coatings for an optical article substrate. The compositions may be applied by a variety of methods, including spin coating, dip coating, and inkjet coating. The coating compositions are fast cured and exhibit robust adhesion to the substrates.
    Type: Application
    Filed: May 10, 2020
    Publication date: December 29, 2022
    Inventors: Robert VALERI, Haipeng ZHENG
  • Patent number: 11434401
    Abstract: Disclosed are UV curable adhesive compositions and methods to adhere polycarbonate substrates containing UV absorbers to glass for use in ophthalmic lenses.
    Type: Grant
    Filed: April 25, 2018
    Date of Patent: September 6, 2022
    Assignee: Essilor International
    Inventor: Robert Valeri
  • Patent number: 11242431
    Abstract: The present invention relates to a heat-curable composition comprising at least one epoxy monomer comprising two or three epoxy groups, which is not a hydrolysis-polymerizable silicon compound, at least one epoxy compound bearing at least one silicon atom having at least one hydrolyzable group directly linked to the silicon atom and at least one epoxy group, and at least one epoxy ring-opening catalyst. The composition comprises at least 50% by weight of compounds having at least one epoxy group, relative to the total weight of polymerizable compounds present in the composition and provides upon pre-curing a tack-free coating that can be removed by treatment with a solution of sodium hydroxide, and upon post-curing a coating that cannot be removed by treatment with a solution of sodium hydroxide.
    Type: Grant
    Filed: October 25, 2017
    Date of Patent: February 8, 2022
    Assignee: Essilor International
    Inventors: Robert Valeri, Haipeng Zheng, Matthew Freeman
  • Publication number: 20210072425
    Abstract: The present invention proposes a polymer composition of manufacturing ophthalmic lens by polymerization of polymerizable composition wherein the shrinkage phenomenon is minimized. The polymerizable composition comprised two different categories of monomers which are able during crosslinking to control and limit said chemical shrinkage. The present invention comprises also ophthalmic lens obtained from said polymer composition using a manufacturing process of casting or additive manufacturing.
    Type: Application
    Filed: October 8, 2020
    Publication date: March 11, 2021
    Applicant: ESSILOR INTERNATIONAL
    Inventors: Robert VALERI, John BITEAU
  • Publication number: 20200241174
    Abstract: The invention relates to an optical article having a substrate made of an optical material comprising a polymer matrix and an improved abrasion and/or scratch resistance. The substrate comprises an external layer in which particles functionalized by a silane coupling agent are embedded into the polymer matrix, the Bayer value of said substrate determined in accordance with the ASTM F735-81 standard being at least 30% greater than the Bayer value of the same substrate with no embedded particles.
    Type: Application
    Filed: August 8, 2018
    Publication date: July 30, 2020
    Inventors: Pierre FROMENTIN, Thanisararat SALEESUNG, Tipparat LERTWATTANASERI, Haipeng ZHENG, Robert VALERI, Ronald BERZON, Mathieu FEUILLADE
  • Publication number: 20200095487
    Abstract: Disclosed are UV curable adhesive compositions and methods to adhere polycarbonate substrates containing UV absorbers to glass for use in ophthalmic lenses.
    Type: Application
    Filed: April 25, 2018
    Publication date: March 26, 2020
    Applicant: Essilor International
    Inventor: Robert VALERI
  • Publication number: 20200048472
    Abstract: The UV-curable coating compositions disclosed herein are provided for use as coatings for plastic (organic glass) substrates, and ophthalmic lenses, in particular. The compositions may be applied by a variety of means, including spin coating and inkjet coating. The coating compositions exhibit abrasion resistance comparable to conventional thermally-cured sol-gel coatings.
    Type: Application
    Filed: August 7, 2019
    Publication date: February 13, 2020
    Inventor: Robert Valeri
  • Publication number: 20190345286
    Abstract: The present invention relates to a heat-curable composition comprising at least one epoxy monomer comprising two or three epoxy groups, which is not a hydrolysis-polymerizable silicon compound, at least one epoxy compound bearing at least one silicon atom having at least one hydrolyzable group directly linked to the silicon atom and at least one epoxy group, and at least one epoxy ring-opening catalyst. The composition comprises at least 50% by weight of compounds having at least one epoxy group, relative to the total weight of polymerizable compounds present in the composition and provides upon pre-curing a tack-free coating that can be removed by treatment with a solution of sodium hydroxide, and upon post-curing a coating that cannot be removed by treatment with a solution of sodium hydroxide.
    Type: Application
    Filed: October 25, 2017
    Publication date: November 14, 2019
    Inventors: Robert VALERI, Haipeng ZHENG, Matthew FREEMAN
  • Patent number: 10459248
    Abstract: An ophthalmic article and methods of manufacturing the ophthalmic article are described herein. The ophthalmic article can include a first coating and a second coating. The first coating can include an abrasion resistant coating that includes flexible materials. The abrasion resistant coating can be radiation cured. The second coating can include a sputter-applied anti-reflective (AR) coating. Such an ophthalmic article can have a Bayer value of at or between 1.25 and 2.6, between 1.25 and 2.0 or 1.25 and 1.75; and a hand steel wool value of 3 or less.
    Type: Grant
    Filed: December 30, 2014
    Date of Patent: October 29, 2019
    Assignee: Essilor International
    Inventor: Robert Valeri
  • Patent number: 9969135
    Abstract: A method using additive manufacturing technologies and processes to manufacture a three-dimensional ophthalmic lens with a high management level of the homogeneity during the construction of the ophthalmic lens, through a control of two technical characteristics of voxel: the ability to modify their viscosity, and the ability to inter-diffuse together to provide a final homogeneous element. These two technical characteristics are managed by the choice of component(s) used to manufacture each voxel and by the kind of physical and/or chemical treatment apply to each of them.
    Type: Grant
    Filed: July 31, 2013
    Date of Patent: May 15, 2018
    Assignee: ESSILOR INTERNATIONAL (COMPAGNIE GENERALE D'OPTIQUE)
    Inventors: Robert A. Valeri, Steven Weber, John Biteau
  • Publication number: 20180113239
    Abstract: The present invention provides abrasion resistant UV-curable coating compositions that exhibit robust adhesion to all organic ophthalmic lens substrates, including thermoplastics and thermoset resins, such as polycarbonates, poly allyl carbonates, polythiourethanes and acrylics.
    Type: Application
    Filed: May 5, 2015
    Publication date: April 26, 2018
    Inventor: Robert VALERI
  • Publication number: 20180003861
    Abstract: An ophthalmic article and methods of manufacturing the ophthalmic article are described herein. The ophthalmic article can include a first coating and a second coating. The first coating can include an abrasion resistant coating that includes flexible materials. The abrasion resistant coating can be radiation cured. The second coating can include a sputter-applied anti-reflective (AR) coating. Such an ophthalmic article can have a Bayer value of at or between 1.25 and 2.6, between 1.25 and 2.0 or 1.25 and 1.75; and a hand steel wool value of 3 or less.
    Type: Application
    Filed: December 30, 2014
    Publication date: January 4, 2018
    Inventor: Robert Valeri
  • Publication number: 20170357032
    Abstract: Hard coating compositions and articles coated with said hard coating compositions are described. The coating compositions include at least a first layer as a hard coating to which is adhered a sputtered silicon containing layer, wherein the hard coating is formed with an unhydrolyzed alkoxysilane monomer cured cationically to increase a total amount of hydroxyl functional groups available in the first layer upon curing. The increased hydroxyl functional groups in the hard coating interact with the sputtered silicon containing layer and promote adherence between the hard coating and the sputtered silicon containing layer.
    Type: Application
    Filed: December 30, 2014
    Publication date: December 14, 2017
    Inventor: Robert Valeri
  • Publication number: 20170031059
    Abstract: The present invention proposes a polymer composition of manufacturing ophthalmic lens by polymerization of polymerizable composition wherein the shrinkage phenomenon is minimized. The polymerizable composition comprised two different categories of monomers which are able during crosslinking to control and limit said chemical shrinkage. The present invention comprises also ophthalmic lens obtained from said polymer composition using a manufacturing process of casting or additive manufacturing.
    Type: Application
    Filed: December 20, 2013
    Publication date: February 2, 2017
    Applicant: ESSILOR INTERNATIONAL (COMPAGNIE GENERALE D'OPTIQUE)
    Inventors: Robert VALERI, John BITEAU
  • Publication number: 20160167323
    Abstract: A method using additive manufacturing technologies and processes to manufacture a three-dimensional ophthalmic lens with a high management level of the homogeneity during the construction of the ophthalmic lens, through a control of two technical characteristics of voxel: the ability to modify their viscosity, and the ability to inter-diffuse together to provide a final homogeneous element. These two technical characteristics are managed by the choice of component(s) used to manufacture each voxel and by the kind of physical and/or chemical treatment apply to each of them.
    Type: Application
    Filed: July 31, 2013
    Publication date: June 16, 2016
    Inventors: Robert A. VALERI, Steven WEBER, John BITEAU
  • Patent number: 8916622
    Abstract: A heat-curable composition comprises—from 25 to 65% by weight of a mixture of epoxy-functional monomers, said mixture consisting of at least one polyfunctional epoxy monomer selected from monomers comprising from 4 to 8 glycidyl groups and/or cycloaliphatic epoxy groups, and at least one bi- or tri-functional epoxy monomer selected from monomers comprising two or three glycidyl groups and/or cycloaliphatic epoxy groups, —from 25 to 70% by weight of at least one organic solvent selected from glycol monoethers, —from 2.5 to 5% by weight, relative to the total weight of epoxyfunctional monomers (a) and (b), of at least one blocked strong acid catalyst, said heat-curable composition not containing any non-epoxyfunctional monomers, in particular not containing any acrylic, methacrylic or silane monomers.
    Type: Grant
    Filed: December 17, 2009
    Date of Patent: December 23, 2014
    Assignee: Essilor Internatonal (Compagnie Générale d'Optique)
    Inventor: Robert Valeri
  • Publication number: 20140070149
    Abstract: A liquid photocurable composition includes: from 25 to 65% by weight relative to the total weight of the composition, of a mixture of polyfunctional acrylic monomers, the mixture consisting of (a) at least one monomer including at least six acrylic functional groups, and (b) at least one monomer including two, three or four (meth)acrylic functional groups, preferably two or three acrylic functional groups, from 25 to 70% by weight, relative to the total weight of the composition, of at least one organic solvent, from 8.0 to 20.0% by weight, relative to the total solids content of the composition, of at least one mineral conductive colloid, from 0.5 to 5% by weight, relative to the total weight of acryl functional monomers (a) and (b), of at least one radical photoinitiator, the photocurable composition not containing any epoxy-functional monomer.
    Type: Application
    Filed: March 18, 2011
    Publication date: March 13, 2014
    Applicant: ESSILOR INTERNATIONAL (COMPAGNIE GENERALE D'OPTIQUE)
    Inventor: Robert Valeri