Patents by Inventor Robert Alan Woloszynek

Robert Alan Woloszynek has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20230046273
    Abstract: This invention is based upon the unexpected finding that a hydrocarbon traction resin can be dispersed into the oil used in making an oil extended emulsion and solution rubbers to attain improved performance characteristics. For instance, this technique allows for the hydrocarbon traction resin to be incorporated into the rubber at a higher level than would ordinarily be possible using conventional mixing techniques. In tire tread compounds this provides improved wet traction characteristics without compromising cured stiffness (dry traction) and ultimate properties (chip/chunk resistance). This technique can be used to incorporate a resin into virtually any synthetic rubber that can benefit from being oil extended. It is of particular value in making resin modified solution styrene-butadiene rubber (SSBR), emulsion styrene-butadiene rubber (ESBR), high cis-1.4-polybutadiene rubber, and synthetic polyisoprene rubber which are formulated for use in tire tread compounds.
    Type: Application
    Filed: October 10, 2022
    Publication date: February 16, 2023
    Inventors: Nihat Ali Isitman, Robert Alan Woloszynek, Joseph John Kulig, Hannah Long, Manuela Pompei, Jennifer Labbe
  • Patent number: 11505683
    Abstract: This invention is based upon the unexpected finding that a hydrocarbon traction resin can be dispersed into the oil used in making an oil extended emulsion and solution rubbers to attain improved performance characteristics. For instance, this technique allows for the hydrocarbon traction resin to be incorporated into the rubber at a higher level than would ordinarily be possible using conventional mixing techniques. In tire tread compounds this provides improved wet traction characteristics without compromising cured stiffness (dry traction) and ultimate properties (chip/chunk resistance). This technique can be used to incorporate a resin into virtually any synthetic rubber that can benefit from being oil extended. It is of particular value in making resin modified solution styrene-butadiene rubber (SSBR), emulsion styrene-butadiene rubber (ESBR), high cis-1.4-polybutadiene rubber, and synthetic polyisoprene rubber which are formulated for use in tire tread compounds.
    Type: Grant
    Filed: September 13, 2019
    Date of Patent: November 22, 2022
    Assignee: THE GOODYEAR TIRE & RUBBER COMPANY
    Inventors: Nihat Ali Isitman, Robert Alan Woloszynek, Joseph John Kulig, Hannah Long, Manuela Pompei, Jennifer Labbe
  • Patent number: 11492426
    Abstract: A functionalized elastomer comprising the reaction product of a living elastomeric polymer and a polymerization terminator of formula I [R1]n—B—[X—R2]m??I where B is boron; X is oxygen or nitrogen; R1 is independently vinyl, oxiranyl, phenyl, 1-alkenyl of 2 to 8 carbon atoms, alkyl of 1 to 8 carbon atoms including at least one halogen atom, 1-alkenyl of 2 to 8 carbon atoms including at least one halogen or one hydrogen; R2 is independently C1 to C8 alkyl, C8 to C14 aryl; or when m>1 R2 may be taken together to form a substituted or unsubstituted cyclic structure comprising 2 to 16 carbon atoms where the cyclic structure may be heterocyclic or non-heterocyclic; n is 1 or 2, m is 1 or 2, and n+m=3.
    Type: Grant
    Filed: August 7, 2020
    Date of Patent: November 8, 2022
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Seth Cody Ensign, Robert Alan Woloszynek
  • Publication number: 20220041771
    Abstract: A functionalized elastomer comprising the reaction product of a living elastomeric polymer and a polymerization terminator of formula I [R1]n—B—[X—R2]m??I where B is boron; X is oxygen or nitrogen; R1 is independently vinyl, oxiranyl, phenyl, 1-alkenyl of 2 to 8 carbon atoms, alkyl of 1 to 8 carbon atoms including at least one halogen atom, 1-alkenyl of 2 to 8 carbon atoms including at least one halogen or one hydrogen; R2 is independently C1 to C8 alkyl, C8 to C14 aryl; or when m>1 R2 may be taken together to form a substituted or unsubstituted cyclic structure comprising 2 to 16 carbon atoms where the cyclic structure may be heterocyclic or non-heterocyclic; n is 1 or 2, m is 1 or 2, and n+m=3.
    Type: Application
    Filed: August 7, 2020
    Publication date: February 10, 2022
    Inventors: Seth Cody Ensign, Robert Alan Woloszynek
  • Publication number: 20200087489
    Abstract: This invention is based upon the unexpected finding that a hydrocarbon traction resin can be dispersed into the oil used in making an oil extended emulsion and solution rubbers to attain improved performance characteristics. For instance, this technique allows for the hydrocarbon traction resin to be incorporated into the rubber at a higher level than would ordinarily be possible using conventional mixing techniques. In tire tread compounds this provides improved wet traction characteristics without compromising cured stiffness (dry traction) and ultimate properties (chip/chunk resistance). This technique can be used to incorporate a resin into virtually any synthetic rubber that can benefit from being oil extended. It is of particular value in making resin modified solution styrene-butadiene rubber (SSBR), emulsion styrene-butadiene rubber (ESBR), high cis-1.4-polybutadiene rubber, and synthetic polyisoprene rubber which are formulated for use in tire tread compounds.
    Type: Application
    Filed: September 13, 2019
    Publication date: March 19, 2020
    Inventors: Nihat Ali Isitman, Robert Alan Woloszynek, Joseph John Kulig, Hannah Long, Manuela Pompei, Jennifer Labbe
  • Patent number: 8299290
    Abstract: The present invention relates to functionalizing agents that are particularly useful for functionalizing living rubbery polymers to make the polymer more compatible with fillers, such as carbon black and silica. These functionalizing agents are comprised of a boron containing compound having a structural formula selected from the group consisting of: wherein R is selected from the group consisting of hydrogen atoms, alkyl groups and aryl groups, wherein R1, R2, and R3 can be the same or different and are selected from the group consisting of alkyl groups, and aryl groups, and wherein R4 represents an alkylene group or a bridging aromatic group.
    Type: Grant
    Filed: October 4, 2011
    Date of Patent: October 30, 2012
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Robert Alan Woloszynek, Stephan Rodewald
  • Publication number: 20120029234
    Abstract: The present invention relates to functionalizing agents that are particularly useful for functionalizing living rubbery polymers to make the polymer more compatible with fillers, such as carbon black and silica. These functionalizing agents are comprised of a boron containing compound having a structural formula selected from the group consisting of: wherein R is selected from the group consisting of hydrogen atoms, alkyl groups and aryl groups, wherein R1, R2, and R3 can be the same or different and are selected from the group consisting of alkyl groups, and aryl groups, and wherein R4 represents an alkylene group or a bridging aromatic group.
    Type: Application
    Filed: October 4, 2011
    Publication date: February 2, 2012
    Applicant: THE GOODYEAR TIRE & RUBBER COMPANY
    Inventors: Robert Alan Woloszynek, Stephan Rodewald
  • Patent number: 8063152
    Abstract: The present invention relates to functionalizing agents that are particularly useful for functionalizing living rubbery polymers to make the polymer more compatible with fillers, such as carbon black and silica. These functionalizing agents are comprised of a boron containing compound having a structural formula selected from the group consisting of: wherein R is selected from the group consisting of hydrogen atoms, alkyl groups and aryl groups, wherein R1, R2, and R3 can be the same or different and are selected from the group consisting of alkyl groups, and aryl groups, and wherein R4 represents an alkylene group or a bridging aromatic group.
    Type: Grant
    Filed: February 25, 2009
    Date of Patent: November 22, 2011
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Robert Alan Woloszynek, Stephan Rodewald
  • Patent number: 8022159
    Abstract: The invention includes terminating compounds, polymers, rubber compositions and tires. The terminating compounds can provide terminating groups on the polymer. Polymers can be homopolymers, copolymers and terpolymers, and can include repeat units provided from conjugated diene monomers. Rubber compositions can be made from the polymers, and tires and various parts of tires can be made from those rubber compositions.
    Type: Grant
    Filed: November 24, 2008
    Date of Patent: September 20, 2011
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Michael Joseph Rachita, Joseph John Kulig, Robert Alan Woloszynek
  • Patent number: 7847048
    Abstract: The invention includes terminating compounds, polymers, rubber compositions and tires. The terminating compounds can provide terminating groups on the polymer. Polymers can be homopolymers, copolymers and terpolymers, and can include repeat units provided from conjugated diene monomers. Rubber compositions can be made from the polymers, and tires and various parts of tires can be made from those rubber compositions.
    Type: Grant
    Filed: November 24, 2008
    Date of Patent: December 7, 2010
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Michael Joseph Rachita, Joseph John Kulig, Robert Alan Woloszynek
  • Publication number: 20100186868
    Abstract: The present invention is directed to a pneumatic tire having a component comprising a vulcanizable rubber composition comprising, based on 100 parts by weight of elastomer (phr), (A) from about 60 to about 90 phr of a solution polymerized styrene-butadiene rubber functionalized with an alkoxysilane group and a primary amines; (B) from about 40 to about 10 phr of polybutadiene having a microstructure comprised of about 96 to about 99 percent cis 1,4-isomeric units, about 0.1 to about 1 percent trans 1,4-isomeric units and from about 1 to about 3 percent vinyl 1,2-isomeric units; a number average molecular weight (Mn) in a range of from about 75,000 to about 150,000 and a heterogeneity index (Mw/Mn) in a range of from about 3/1 to about 5/1; and (C) from about 50 to about 150 phr of silica.
    Type: Application
    Filed: November 18, 2009
    Publication date: July 29, 2010
    Inventors: Paul Harry Sandstrom, Brad Stephen Gulas, David Mark Frantz, Steven Wayne Cronin, Michael Joseph Rachita, Joseph John Kulig, Robert Alan Woloszynek
  • Patent number: 7745523
    Abstract: The invention includes coupling compounds, rubber compositions, and tires. The coupling compounds can, for example, be used to couple to silica filler. Rubber compositions can comprise the coupling compound and polymers. Polymers can be homopolymers, copolymers and terpolymers, and can include repeat units provided from conjugated diene monomers. Tires and various parts of tires can be made from those rubber compositions.
    Type: Grant
    Filed: December 8, 2008
    Date of Patent: June 29, 2010
    Assignee: The Goodyear Tire & Rubber Company
    Inventor: Robert Alan Woloszynek
  • Publication number: 20100144950
    Abstract: The invention includes coupling compounds, rubber compositions, and tires. The coupling compounds can, for example, be used to couple to silica filler. Rubber compositions can comprise the coupling compound and polymers. Polymers can be homopolymers, copolymers and terpolymers, and can include repeat units provided from conjugated diene monomers. Tires and various parts of tires can be made from those rubber compositions.
    Type: Application
    Filed: December 8, 2008
    Publication date: June 10, 2010
    Applicant: THE GOODYEAR TIRE & RUBBER COMPANY
    Inventor: Robert Alan Woloszynek
  • Publication number: 20100130664
    Abstract: The invention includes terminating compounds, polymers, rubber compositions and tires. The terminating compounds can provide terminating groups on the polymer. Polymers can be homopolymers, copolymers and terpolymers, and can include repeat units provided from conjugated diene monomers. Rubber compositions can be made from the polymers, and tires and various parts of tires can be made from those rubber compositions.
    Type: Application
    Filed: November 24, 2008
    Publication date: May 27, 2010
    Applicant: The Goodyear Tire & Rubber Company
    Inventors: Michael Joseph Rachita, Joseph John Kulig, Robert Alan Woloszynek
  • Publication number: 20090229729
    Abstract: The present invention relates to functionalizing agents that are particularly useful for functionalizing living rubbery polymers to make the polymer more compatible with fillers, such as carbon black and silica. These functionalizing agents are comprised of a boron containing compound having a structural formula selected from the group consisting of: wherein R is selected from the group consisting of hydrogen atoms, alkyl groups and aryl groups, wherein R1, R2, and R3 can be the same or different and are selected from the group consisting of alkyl groups, and aryl groups, and wherein R4 represents an alkylene group or a bridging aromatic group.
    Type: Application
    Filed: February 25, 2009
    Publication date: September 17, 2009
    Applicant: THE GOODYEAR TIRE & RUBBER COMPANY
    Inventors: Robert Alan Woloszynek, Stephan Rodewald