Patents by Inventor Robert Allison Grigsby

Robert Allison Grigsby has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 11680130
    Abstract: An isocyanate reactive composition including at least one component selected from the group consisting of a polyether polyol, a polyester polyol, a polyether polyamide and a polyester polyamide; one or more amine components, each of said amine components having a given structure. In some embodiments, the average number of nitrogen atoms of said amine components is in the range of 5 to 10.
    Type: Grant
    Filed: June 2, 2021
    Date of Patent: June 20, 2023
    Assignee: HUNTSMAN Petrochemical LLC
    Inventors: Geert Lodewijk Dries, Robert Allison Grigsby, Ernest Lee Rister, Jr., Eugene P. Wiltz, Jr.
  • Publication number: 20220135727
    Abstract: The present disclosure generally relates to a dispersant obtained from the reaction of a liquid isocyanate compound and a polyoxyalkylene amine and its use in dispersing various particulate solids in an aqueous or organic medium.
    Type: Application
    Filed: March 3, 2020
    Publication date: May 5, 2022
    Inventors: Robert Allison Grigsby, JR., Xiaohua Fang, Donald Hugh Champion
  • Publication number: 20210347932
    Abstract: An isocyanate reactive composition including at least one component selected from the group consisting of a polyether polyol, a polyester polyol, a polyether polyamide and a polyester polyamide; one or more amine components, each of said amine components having a given structure. In some embodiments, the average number of nitrogen atoms of said amine components is in the range of 5 to 10.
    Type: Application
    Filed: June 2, 2021
    Publication date: November 11, 2021
    Inventors: Geert Lodewijk Dries, Robert Allison Grigsby, Ernest Lee Rister, JR., Eugene P. Wiltz, JR.
  • Patent number: 11053338
    Abstract: An isocyanate reactive composition comprising At least one component selected from the group consisting of a polyether polyol, a polyester polyol, a polyether polyamide and a polyester polyamide; one or more amine components, each of said amine components having a given structure. In some embodiments, the average number of nitrogen atoms of said amine components is in the range of 5 to 10.
    Type: Grant
    Filed: April 17, 2019
    Date of Patent: July 6, 2021
    Assignee: HUNTSMAN Petrochemical LLC
    Inventors: Geert Lodewijk Dries, Robert Allison Grigsby, Ernest Lee Rister, Jr., Eugene P. Wiltz, Jr.
  • Patent number: 10472456
    Abstract: An isocyanate reactive composition comprising At least one component selected from the group consisting of an isocyanate reactive component; a treating agent selected from the group consisting of cyclic urea substituted with at least one isocyanate reactive group, a free radical scavenger, or a polymer acid, or a mixture thereof; one or more amine components, each of said amine components having a given structure.
    Type: Grant
    Filed: July 9, 2015
    Date of Patent: November 12, 2019
    Assignee: HUNTSMAN Petrochemical LLC
    Inventors: Geert Lodewijk Dries, Eugene P Wiltz, Jr., Robert Allison Grigsby, Jr.
  • Publication number: 20190263958
    Abstract: An isocyanate reactive composition comprising At least one component selected from the group consisting of a polyether polyol, a polyester polyol, a polyether polyamide and a polyester polyamide; one or more amine components, each of said amine components having a given structure. In some embodiments, the average number of nitrogen atoms of said amine components is in the range of 5 to 10.
    Type: Application
    Filed: April 17, 2019
    Publication date: August 29, 2019
    Inventors: Geert Lodewijk Dries, Robert Allison Grigsby, Ernest Lee Rister, JR., Eugene P. Wiltz, JR.
  • Patent number: 10308754
    Abstract: An isocyanate reactive composition comprising At least one component selected from the group consisting of a polyether polyol, a polyester polyol, a polyether polyamide and a polyester polyamide; one or more amine components, each of said amine components having a given structure. In some embodiments, the average number of nitrogen atoms of said amine components is in the range of 5 to 10.
    Type: Grant
    Filed: July 10, 2013
    Date of Patent: June 4, 2019
    Assignee: HUNTSMAN PETROCHEMICAL LLC
    Inventors: Geert Lodewijk Dries, Robert Allison Grigsby, Jr., Ernest Lee Rister, Jr., Eugene P. Wiltz, Jr.
  • Publication number: 20170129988
    Abstract: An isocyanate reactive composition comprising At least one component selected from the group consisting of an isocyanate reactive component; a treating agent selected from the group consisting of cyclic urea substituted with at least one isocyanate reactive group, a free radical scavenger, or a polymer acid, or a mixture thereof; one or more amine components, each of said amine components having a given structure.
    Type: Application
    Filed: July 9, 2015
    Publication date: May 11, 2017
    Inventors: Geert Lodewijk Dries, Eugene P Wiltz, JR., Robert Allison Grigsby, JR.
  • Patent number: 9505870
    Abstract: An amine according to the invention has a formula (CH3)2NCH2CH2OCH2CH2CH2N(R1)(R2) wherein R1 is selected from (CH3)2NCH2CH2OCH2CH2CH2— and R2 is selected from the group consisting of H—, CH3(CnH2n)—, HO(CmH2m)— and (CH3)2NCH2CH2OCH2CH2CH2—, n being an integer in the range of 0 to 5, m being an integer in the range of 2 to 4.
    Type: Grant
    Filed: April 23, 2013
    Date of Patent: November 29, 2016
    Assignee: HUNTSMAN PETROCHEMICAL LLC
    Inventors: Eugene P Wiltz, Jr., Robert Allison Grigsby, Jr., Jennifer Price, Jingjun Zhou
  • Patent number: 9382397
    Abstract: The invention relates to a primary amine component corresponding to formula I being (R1R2NR3)2NR4 wherein each of R1 and R2 are chosen from the group consisting of a methyl group, an ethyl group, an iso-propyl group and an n-propyl group; R3 being an alkoxyalkyl group chosen from the group consisting of —CH2CH2OCH2CH2—, —CH2CH2OCH2CH2CH2— and —CH2CH2CH2OCH2CH2CH2—; R4 is chosen from the group consisting of a hydrogen and —CH2CH2CH2NH2, and the use of said primary amine component corresponding to Formula I as a blowing catalyst of a catalyst system in a reaction of at least one polyisocyanate component and at least one isocyanate-reactive component, the catalyst system further comprising at least one gelling catalyst different from said component of formula I.
    Type: Grant
    Filed: November 22, 2011
    Date of Patent: July 5, 2016
    Assignees: Huntsman Corporation Hungary Zrt, Huntsman International LLC
    Inventors: Zsolt Gaspar, Heiko Heinrich Humbert, Gabor Felber, Attila Gaspar, Robert Allison Grigsby, Jr., Imre Kordas, Petra Emma Vanderstraeten
  • Publication number: 20150191564
    Abstract: An isocyanate reactive composition comprising At least one component selected from the group consisting of a polyether polyol, a polyester polyol, a polyether polyamide and a polyester polyamide; one or more amine components, each of said amine components having a given structure. In some embodiments, the average number of nitrogen atoms of said amine components is in the range of 5 to 10.
    Type: Application
    Filed: July 10, 2013
    Publication date: July 9, 2015
    Inventors: Geert Lodewijk Dries, Robert Allison Grigsby, JR., Ernest Lee Rister, JR., Eugene P. Wiltz, JR.
  • Publication number: 20150152213
    Abstract: An amine according to the invention has a formula (CH3)2NCH2CH2OCH2CH2CH2N(R1)(R2) wherein R1 is selected from (CH3)2NCH2CH2OCH2CH2CH2— and R2 is selected from the group consisting of H—, CH3(CnH2n)—, HO(CmH2m)— and (CH3)2NCH2CH2OCH2CH2CH2—, n being an integer in the range of 0 to 5, m being an integer in the range of 2 to 4.
    Type: Application
    Filed: April 23, 2013
    Publication date: June 4, 2015
    Inventors: Eugene P Wiltz, Jr., Robert Allison Grigsby, Jr., Jennifer Price, Jingjun Zhou
  • Publication number: 20130261199
    Abstract: The invention relates to a primary amine component corresponding to formula I being (R1R2NR3)2NR4 wherein each of R1 and R2 are chosen from the group consisting of a methyl group, an ethyl group, an iso-propyl group and an n-propyl group; R3 being an alkoxyalkyl group chosen from the group consisting of —CH2CH2OCH2CH2—, —CH2CH2OCH2CH2CH2— and —CH2CH2CH2OCH2CH2CH2—; R4 is chosen from the group consisting of a hydrogen and —CH2CH2CH2NH2, and the use of said primary amine component corresponding to Formula I as a blowing catalyst of a catalyst system in a reaction of at least one polyisocyanate component and at least one isocyanate-reactive component, the catalyst system further comprising at least one gelling catalyst different from said component of formula I.
    Type: Application
    Filed: November 22, 2011
    Publication date: October 3, 2013
    Applicant: Huntsman Corporation Hungary ZRt
    Inventors: Zsolt Gaspar, Heiko Heinrich Humbert, Gabor Felber, Attila Gaspar, Robert Allison Grigsby, JR., Imre Kordas, Petra Emma Vanderstraeten
  • Patent number: 6552121
    Abstract: A process for preparing alkali silicate—polyisocyanate composites without catalyst separation. The process involves blending a catalyst and a polyisocyanate to form a first component, and blending an alkali silicate and water to form a second component. The first and second components are then mixed together to form a reactive mixture that reacts to form a hardened composite. The progression of the reaction proceeds without excessive foaming, high exotherms, or the release of an offensive odor. Sodium silicate—polyisocyanate composites prepared according to the above process, and a process for using the alkali silicate—polyisocyanate composites to consolidate and seal various types of formations in mining, tunneling, and other construction projects are also disclosed. Any void volume which is capable of receiving a flowable precursor of a composite formulation according to the invention prior to its cure is suitable for treatment according to the present invention.
    Type: Grant
    Filed: December 11, 2001
    Date of Patent: April 22, 2003
    Assignee: Huntsman Petrochemical Corporation
    Inventor: Robert Allison Grigsby, Jr.
  • Patent number: 6458860
    Abstract: Provided herein are catalyst systems useful for providing polyurethane foam products which exhibit low fogging characteristics while possessing favorable overall physical properties when used as interior components of automobiles and other motorized vehicles.
    Type: Grant
    Filed: January 7, 2002
    Date of Patent: October 1, 2002
    Assignee: Huntsman Petrochemical Corporation
    Inventors: Heiko H. Humbert, Robert Allison Grigsby, Jr.
  • Publication number: 20020120061
    Abstract: A process for preparing alkali silicate-polyisocyanate composites without catalyst separation. The process involves blending a catalyst and a polyisocyanate to form a first component, and blending an alkali silicate and water to form a second component. The first and second components are then mixed together to form a reactive mixture that reacts to form a hardened composite. The progression of the reaction proceeds without excessive foaming, high exotherms, or the release of an offensive odor. Sodium silicate-polyisocyanate composites prepared according to the above process, and a process for using the alkali silicate-polyisocyanate composites to consolidate and seal various types of formations in mining, tunneling, and other construction projects are also disclosed. Any void volume which is capable of receiving a flowable precursor of a composite formulation according to the invention prior to its cure is suitable for treatment according to the present invention.
    Type: Application
    Filed: December 11, 2001
    Publication date: August 29, 2002
    Applicant: Huntsman Petrochemical Corporation
    Inventor: Robert Allison Grigsby
  • Patent number: 5700846
    Abstract: A process, and the product produced thereby, for preparing a polyurea foam which comprises reacting an aliphatic polyamine having an average functionality from about 2 to about 6 wherein about 55 to about 95 percent of the functional groups are primary amine functional groups and about 5 to about 40 percent of the functional groups are primary or secondary hydroxyl groups with a polyisocyanate in the presence of a blowing agent that comprises water. The use of polyether polyamines having primary hydroxyl groups improves the cross-linking characteristics of the polyurea foam.
    Type: Grant
    Filed: August 18, 1995
    Date of Patent: December 23, 1997
    Assignee: Huntsman Petrochemical Corporation
    Inventors: Robert Allison Grigsby, Jr., Robert LeRoy Zimmerman