Patents by Inventor Robert Allison Grigsby
Robert Allison Grigsby has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
-
Patent number: 11680130Abstract: An isocyanate reactive composition including at least one component selected from the group consisting of a polyether polyol, a polyester polyol, a polyether polyamide and a polyester polyamide; one or more amine components, each of said amine components having a given structure. In some embodiments, the average number of nitrogen atoms of said amine components is in the range of 5 to 10.Type: GrantFiled: June 2, 2021Date of Patent: June 20, 2023Assignee: HUNTSMAN Petrochemical LLCInventors: Geert Lodewijk Dries, Robert Allison Grigsby, Ernest Lee Rister, Jr., Eugene P. Wiltz, Jr.
-
Publication number: 20220135727Abstract: The present disclosure generally relates to a dispersant obtained from the reaction of a liquid isocyanate compound and a polyoxyalkylene amine and its use in dispersing various particulate solids in an aqueous or organic medium.Type: ApplicationFiled: March 3, 2020Publication date: May 5, 2022Inventors: Robert Allison Grigsby, JR., Xiaohua Fang, Donald Hugh Champion
-
Publication number: 20210347932Abstract: An isocyanate reactive composition including at least one component selected from the group consisting of a polyether polyol, a polyester polyol, a polyether polyamide and a polyester polyamide; one or more amine components, each of said amine components having a given structure. In some embodiments, the average number of nitrogen atoms of said amine components is in the range of 5 to 10.Type: ApplicationFiled: June 2, 2021Publication date: November 11, 2021Inventors: Geert Lodewijk Dries, Robert Allison Grigsby, Ernest Lee Rister, JR., Eugene P. Wiltz, JR.
-
Patent number: 11053338Abstract: An isocyanate reactive composition comprising At least one component selected from the group consisting of a polyether polyol, a polyester polyol, a polyether polyamide and a polyester polyamide; one or more amine components, each of said amine components having a given structure. In some embodiments, the average number of nitrogen atoms of said amine components is in the range of 5 to 10.Type: GrantFiled: April 17, 2019Date of Patent: July 6, 2021Assignee: HUNTSMAN Petrochemical LLCInventors: Geert Lodewijk Dries, Robert Allison Grigsby, Ernest Lee Rister, Jr., Eugene P. Wiltz, Jr.
-
Patent number: 10472456Abstract: An isocyanate reactive composition comprising At least one component selected from the group consisting of an isocyanate reactive component; a treating agent selected from the group consisting of cyclic urea substituted with at least one isocyanate reactive group, a free radical scavenger, or a polymer acid, or a mixture thereof; one or more amine components, each of said amine components having a given structure.Type: GrantFiled: July 9, 2015Date of Patent: November 12, 2019Assignee: HUNTSMAN Petrochemical LLCInventors: Geert Lodewijk Dries, Eugene P Wiltz, Jr., Robert Allison Grigsby, Jr.
-
Publication number: 20190263958Abstract: An isocyanate reactive composition comprising At least one component selected from the group consisting of a polyether polyol, a polyester polyol, a polyether polyamide and a polyester polyamide; one or more amine components, each of said amine components having a given structure. In some embodiments, the average number of nitrogen atoms of said amine components is in the range of 5 to 10.Type: ApplicationFiled: April 17, 2019Publication date: August 29, 2019Inventors: Geert Lodewijk Dries, Robert Allison Grigsby, Ernest Lee Rister, JR., Eugene P. Wiltz, JR.
-
Patent number: 10308754Abstract: An isocyanate reactive composition comprising At least one component selected from the group consisting of a polyether polyol, a polyester polyol, a polyether polyamide and a polyester polyamide; one or more amine components, each of said amine components having a given structure. In some embodiments, the average number of nitrogen atoms of said amine components is in the range of 5 to 10.Type: GrantFiled: July 10, 2013Date of Patent: June 4, 2019Assignee: HUNTSMAN PETROCHEMICAL LLCInventors: Geert Lodewijk Dries, Robert Allison Grigsby, Jr., Ernest Lee Rister, Jr., Eugene P. Wiltz, Jr.
-
Publication number: 20170129988Abstract: An isocyanate reactive composition comprising At least one component selected from the group consisting of an isocyanate reactive component; a treating agent selected from the group consisting of cyclic urea substituted with at least one isocyanate reactive group, a free radical scavenger, or a polymer acid, or a mixture thereof; one or more amine components, each of said amine components having a given structure.Type: ApplicationFiled: July 9, 2015Publication date: May 11, 2017Inventors: Geert Lodewijk Dries, Eugene P Wiltz, JR., Robert Allison Grigsby, JR.
-
Patent number: 9505870Abstract: An amine according to the invention has a formula (CH3)2NCH2CH2OCH2CH2CH2N(R1)(R2) wherein R1 is selected from (CH3)2NCH2CH2OCH2CH2CH2— and R2 is selected from the group consisting of H—, CH3(CnH2n)—, HO(CmH2m)— and (CH3)2NCH2CH2OCH2CH2CH2—, n being an integer in the range of 0 to 5, m being an integer in the range of 2 to 4.Type: GrantFiled: April 23, 2013Date of Patent: November 29, 2016Assignee: HUNTSMAN PETROCHEMICAL LLCInventors: Eugene P Wiltz, Jr., Robert Allison Grigsby, Jr., Jennifer Price, Jingjun Zhou
-
Patent number: 9382397Abstract: The invention relates to a primary amine component corresponding to formula I being (R1R2NR3)2NR4 wherein each of R1 and R2 are chosen from the group consisting of a methyl group, an ethyl group, an iso-propyl group and an n-propyl group; R3 being an alkoxyalkyl group chosen from the group consisting of —CH2CH2OCH2CH2—, —CH2CH2OCH2CH2CH2— and —CH2CH2CH2OCH2CH2CH2—; R4 is chosen from the group consisting of a hydrogen and —CH2CH2CH2NH2, and the use of said primary amine component corresponding to Formula I as a blowing catalyst of a catalyst system in a reaction of at least one polyisocyanate component and at least one isocyanate-reactive component, the catalyst system further comprising at least one gelling catalyst different from said component of formula I.Type: GrantFiled: November 22, 2011Date of Patent: July 5, 2016Assignees: Huntsman Corporation Hungary Zrt, Huntsman International LLCInventors: Zsolt Gaspar, Heiko Heinrich Humbert, Gabor Felber, Attila Gaspar, Robert Allison Grigsby, Jr., Imre Kordas, Petra Emma Vanderstraeten
-
Publication number: 20150191564Abstract: An isocyanate reactive composition comprising At least one component selected from the group consisting of a polyether polyol, a polyester polyol, a polyether polyamide and a polyester polyamide; one or more amine components, each of said amine components having a given structure. In some embodiments, the average number of nitrogen atoms of said amine components is in the range of 5 to 10.Type: ApplicationFiled: July 10, 2013Publication date: July 9, 2015Inventors: Geert Lodewijk Dries, Robert Allison Grigsby, JR., Ernest Lee Rister, JR., Eugene P. Wiltz, JR.
-
Publication number: 20150152213Abstract: An amine according to the invention has a formula (CH3)2NCH2CH2OCH2CH2CH2N(R1)(R2) wherein R1 is selected from (CH3)2NCH2CH2OCH2CH2CH2— and R2 is selected from the group consisting of H—, CH3(CnH2n)—, HO(CmH2m)— and (CH3)2NCH2CH2OCH2CH2CH2—, n being an integer in the range of 0 to 5, m being an integer in the range of 2 to 4.Type: ApplicationFiled: April 23, 2013Publication date: June 4, 2015Inventors: Eugene P Wiltz, Jr., Robert Allison Grigsby, Jr., Jennifer Price, Jingjun Zhou
-
Publication number: 20130261199Abstract: The invention relates to a primary amine component corresponding to formula I being (R1R2NR3)2NR4 wherein each of R1 and R2 are chosen from the group consisting of a methyl group, an ethyl group, an iso-propyl group and an n-propyl group; R3 being an alkoxyalkyl group chosen from the group consisting of —CH2CH2OCH2CH2—, —CH2CH2OCH2CH2CH2— and —CH2CH2CH2OCH2CH2CH2—; R4 is chosen from the group consisting of a hydrogen and —CH2CH2CH2NH2, and the use of said primary amine component corresponding to Formula I as a blowing catalyst of a catalyst system in a reaction of at least one polyisocyanate component and at least one isocyanate-reactive component, the catalyst system further comprising at least one gelling catalyst different from said component of formula I.Type: ApplicationFiled: November 22, 2011Publication date: October 3, 2013Applicant: Huntsman Corporation Hungary ZRtInventors: Zsolt Gaspar, Heiko Heinrich Humbert, Gabor Felber, Attila Gaspar, Robert Allison Grigsby, JR., Imre Kordas, Petra Emma Vanderstraeten
-
Patent number: 6552121Abstract: A process for preparing alkali silicate—polyisocyanate composites without catalyst separation. The process involves blending a catalyst and a polyisocyanate to form a first component, and blending an alkali silicate and water to form a second component. The first and second components are then mixed together to form a reactive mixture that reacts to form a hardened composite. The progression of the reaction proceeds without excessive foaming, high exotherms, or the release of an offensive odor. Sodium silicate—polyisocyanate composites prepared according to the above process, and a process for using the alkali silicate—polyisocyanate composites to consolidate and seal various types of formations in mining, tunneling, and other construction projects are also disclosed. Any void volume which is capable of receiving a flowable precursor of a composite formulation according to the invention prior to its cure is suitable for treatment according to the present invention.Type: GrantFiled: December 11, 2001Date of Patent: April 22, 2003Assignee: Huntsman Petrochemical CorporationInventor: Robert Allison Grigsby, Jr.
-
Patent number: 6458860Abstract: Provided herein are catalyst systems useful for providing polyurethane foam products which exhibit low fogging characteristics while possessing favorable overall physical properties when used as interior components of automobiles and other motorized vehicles.Type: GrantFiled: January 7, 2002Date of Patent: October 1, 2002Assignee: Huntsman Petrochemical CorporationInventors: Heiko H. Humbert, Robert Allison Grigsby, Jr.
-
Publication number: 20020120061Abstract: A process for preparing alkali silicate-polyisocyanate composites without catalyst separation. The process involves blending a catalyst and a polyisocyanate to form a first component, and blending an alkali silicate and water to form a second component. The first and second components are then mixed together to form a reactive mixture that reacts to form a hardened composite. The progression of the reaction proceeds without excessive foaming, high exotherms, or the release of an offensive odor. Sodium silicate-polyisocyanate composites prepared according to the above process, and a process for using the alkali silicate-polyisocyanate composites to consolidate and seal various types of formations in mining, tunneling, and other construction projects are also disclosed. Any void volume which is capable of receiving a flowable precursor of a composite formulation according to the invention prior to its cure is suitable for treatment according to the present invention.Type: ApplicationFiled: December 11, 2001Publication date: August 29, 2002Applicant: Huntsman Petrochemical CorporationInventor: Robert Allison Grigsby
-
Patent number: 5700846Abstract: A process, and the product produced thereby, for preparing a polyurea foam which comprises reacting an aliphatic polyamine having an average functionality from about 2 to about 6 wherein about 55 to about 95 percent of the functional groups are primary amine functional groups and about 5 to about 40 percent of the functional groups are primary or secondary hydroxyl groups with a polyisocyanate in the presence of a blowing agent that comprises water. The use of polyether polyamines having primary hydroxyl groups improves the cross-linking characteristics of the polyurea foam.Type: GrantFiled: August 18, 1995Date of Patent: December 23, 1997Assignee: Huntsman Petrochemical CorporationInventors: Robert Allison Grigsby, Jr., Robert LeRoy Zimmerman