Patents by Inventor Robert Ashley Cooper BENSON

Robert Ashley Cooper BENSON has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20180258450
    Abstract: A process is defined for the continuous steam pretreatment and fractionation of low lignin lignocellulosic biomass to produce a concentrated cellulose solid stream that is sensitive to enzymatic hydrolysis. Valuable chemicals are recovered by fractionating the liquid and vapor stream composed of hydrolysis and degradation products of the hemicellulose. Cellulosic derived glucose is produced for fermentation to biofuels. A xylo-oligosaccharides rich liquids fraction is recovered that can be converted to value added products including ethanol.
    Type: Application
    Filed: May 15, 2018
    Publication date: September 13, 2018
    Inventors: Frank A. DOTTORI, Robert Ashley Cooper BENSON, Regis-Olivier BENECH
  • Patent number: 9932707
    Abstract: A process is defined for the continuous steam pretreatment and fractionation of bagasse to produce a concentrated cellulose solid stream that is sensitive to enzymatic hydrolysis. Valuable chemicals are recovered by fractionating the liquid and vapor stream composed of hydrolysis and degradation products of the hemicellulose. Cellulosic derived glucose is produced for fermentation to biofuels. A hemicellulose concentrate is recovered that can be converted to value added products including ethanol.
    Type: Grant
    Filed: November 13, 2015
    Date of Patent: April 3, 2018
    Assignee: GreenField Specialty Alcohols Inc.
    Inventors: Frank A. Dottori, Robert Ashley Cooper Benson, Régis-Olivier Benech
  • Publication number: 20160376621
    Abstract: A method for optimization of a fed batch hydrolysis process wherein the hydrolysis time is minimized by controlling the feed addition volume and/or batch addition frequency of the prehydrolysate and optionally also the enzyme feed. The increase over time in hydrolysate consistency and volume and/or concentration of sugars released in the reactor, so that the enzymatic hydrolysis is controlled, significantly reduces the impact of cellulase feedback inhibition, especially for enzyme contents lower than 1%. The overall time to reach conversion of the total prehydrolysate feed is reduced significantly where the batch addition frequency is equal to one batch each time 70% to 90%, preferably 80%, conversion of the previous batch is reached in the reaction mixture. At an enzyme load of 0.3% in the reaction mixture, the optimum frequency each time 80% conversion was reached was found to be one batch every 80 to 105 minutes.
    Type: Application
    Filed: September 8, 2016
    Publication date: December 29, 2016
    Inventors: Robert Ashley Cooper BENSON, Regis-Olivier BENECH
  • Patent number: 9434961
    Abstract: A continuous process for the recovery of ethanol from hemicellulose and cellulose from lignocellulosic biomass. Yield of fermentable sugars can be maximized by continuous operation of the pre-treatment system and careful selection of pretreatment conditions including the addition of only small amounts of dilute mineral acid and low pressure. With this approach, the xylose component that is mainly present in its unfermentable oligomeric form in known pre-hydrolysis Kraft processes can be recovered more efficiently and as a monomer that can be fermented by xylose fermenting yeasts and bacteria. Due to the use of only dilute acids, there is a very low loss of glucose and xylose hence very low production of toxic chemicals (e.g. HMF, furfural) in the pretreatment step. The resulting overall fermentation efficiency of both hexose and pentose sugars is 90% of the theoretical maximum.
    Type: Grant
    Filed: November 8, 2011
    Date of Patent: September 6, 2016
    Assignee: GREENFIELD SPECIALTY ALCOHOLS INC.
    Inventors: Frank A. Dottori, Robert Ashley Cooper Benson, Régis-Olivier Benech, Richard Romeo Lehoux, Christopher Bruce Bradt
  • Publication number: 20160251682
    Abstract: A process is defined for the continuous steam pretreatment and fractionation of low lignin lignocellulosic biomass to produce a concentrated cellulose solid stream that is sensitive to enzymatic hydrolysis. Valuable chemicals are recovered by fractionating the liquid and vapor stream composed of hydrolysis and degradation products of the hemicellulose. Cellulosic derived glucose is produced for fermentation to biofuels. A xylo-oligosaccharides rich liquids fraction is recovered that can be converted to value added products including ethanol.
    Type: Application
    Filed: May 10, 2016
    Publication date: September 1, 2016
    Inventors: Frank A. DOTTORI, Robert Ashley Cooper BENSON, Regis-Olivier BENECH
  • Publication number: 20160152737
    Abstract: Disclosed is a method of steam explosion pretreating biomass in a two stage steam pretreatment process for improved carbohydrate fractionation. The first stage steam pretreatment is carried out by heating the biomass to a first stage temperature of 140° C. to 180° C. for a first stage time of 30 minutes to 2 hours at a first stage pressure of 105 to 150 psig. The second stage steam pretreatment is carried out by heating the biomass to a second stage temperature of 190° C. to 210° C. for a second stage time of 2 to 10 minutes at a second stage pressure of 167 to 262 psig. The biomass may be initially conditioned by atmospheric steam heating and adjusting the moisture content of the biomass. Hemicellulose sugars and inhibitors (inhibitory compounds) to downstream hydrolysis and fermentation are preferably removed between the first and second steam pretreating stages, more preferably after each steam pretreatment stage.
    Type: Application
    Filed: February 2, 2016
    Publication date: June 2, 2016
    Inventors: Frank A. DOTTORI, Robert Ashley Cooper BENSON, Régis-Olivier BENECH
  • Publication number: 20160069020
    Abstract: A process is defined for the continuous steam pretreatment and fractionation of bagasse to produce a concentrated cellulose solid stream that is sensitive to enzymatic hydrolysis. Valuable chemicals are recovered by fractionating the liquid and vapor stream composed of hydrolysis and degradation products of the hemicellulose. Cellulosic derived glucose is produced for fermentation to biofuels. A hemicellulose concentrate is recovered that can be converted to value added products including ethanol.
    Type: Application
    Filed: November 13, 2015
    Publication date: March 10, 2016
    Inventors: Frank A. DOTTORI, Robert Ashley Cooper BENSON, Régis-Olivier BENECH
  • Patent number: 9255189
    Abstract: Disclosed is a method of producing ethanol from lignocellulosic biomass, including a two stage steam pretreatment process. The first stage of the steam pretreatment is carried out by heating the biomass with high pressure steam to a first stage temperature of 140° C. to 180° C. for a first stage time of 30 minutes to 2 hours at a first stage pressure of 105 to 150 psig; and the second steam pretreatment stage is carried out by heating the biomass with high pressure steam to raise the biomass temperature to a second stage temperature of 190° C. to 210° C. for a second stage time of 2 to 10 minutes at a second stage pressure of 167 to 262 psig. Hemicellulose and inhibitors (inhibitory compounds) to downstream hydrolysis and fermentation are preferably removed between the first and second pretreating stages, more preferably after each pretreatment stage.
    Type: Grant
    Filed: July 20, 2012
    Date of Patent: February 9, 2016
    Assignee: GreenField Specialty Alcohols Inc.
    Inventors: Frank A. Dottori, Robert Ashley Cooper Benson, Regis-Olivier Benech
  • Patent number: 9187862
    Abstract: A process is defined for the continuous steam pretreatment and fractionation of bagasse to produce a concentrated cellulose solid stream that is sensitive to enzymatic hydrolysis. Valuable chemicals are recovered by fractionating the liquid and vapor stream composed of hydrolysis and degradation products of the hemicellulose. Cellulosic derived glucose is produced for fermentation to biofuels. A hemicellulose concentrate is recovered that can be converted to value added products including ethanol.
    Type: Grant
    Filed: November 4, 2011
    Date of Patent: November 17, 2015
    Assignee: GreenField Specialty Alcohols Inc.
    Inventors: Frank A. Dottori, Robert Ashley Cooper Benson, Régis-Olivier Benech
  • Patent number: 9150936
    Abstract: Disclosed is an improvement in a conventional process for C5 and C6 sugar recovery from lignocellulosic biomass for fermentation to ethanol, which process including the conventional steps of pretreatment of the biomass with steam at elevated temperature and pressure, collection of C5 sugars from hemicellulose breakdown, cellulose hydrolysis and collection of C6 sugars from cellulose breakdown. The improvement includes conditioning of the biomass prior to the pretreatment step by heating the biomass with steam for a time period between 5 minutes to 60 minutes to achieve a steam treated biomass having a temperature of about 80 to 100° C.; and adjusting a moisture content of the steam treated biomass to about 45% to 80%. An increased recovery of C5 and C6 sugars is achieved compared to the conventional process.
    Type: Grant
    Filed: July 12, 2012
    Date of Patent: October 6, 2015
    Assignee: GreenField Specialty Alcohols Inc.
    Inventors: Frank A. Dottori, Robert Ashley Cooper Benson, Regis-Olivier Benech
  • Publication number: 20140099690
    Abstract: A process for the production of ethanol wherein a hydrolyzed lignocellulosic biomass is fermented in the presence of a stillage residue. The fermentation of cellulosic hydrolysates is improved by adding prior to and/or during fermentation a stillage residue side stream from a corn starch-to-ethanol process as a nutrient source for the yeast organisms used in the fermentation. Stillage residues from the grain dry mill ethanol producing process, including the whole stillage, wet cake, thin stillage, and/or syrup are added to assist as a nitrogen and nutrient source for the fermentive processes. The stillage residue is produced by any grain-to-ethanol process.
    Type: Application
    Filed: December 13, 2013
    Publication date: April 10, 2014
    Applicant: GREENFIELD SPECIALTY ALCOHOLS INC.
    Inventors: Robert Ashley Cooper BENSON, Regis-Olivier BENECH
  • Patent number: 8642303
    Abstract: A process for the production of ethanol wherein a hydrolyzed lignocellulosic biomass is fermented in the presence of a stillage residue. The fermentation of cellulosic hydrolysates is improved by adding prior to and/or during fermentation a stillage residue side stream from a corn starch-to-ethanol process as a nutrient source for the yeast organisms used in the fermentation. Stillage residues from the grain dry mill ethanol producing process, including the whole stillage, wet cake, thin stillage, and/or syrup are added to assist as a nitrogen and nutrient source for the fermentive processes. The stillage residue is produced by any grain-to-ethanol process.
    Type: Grant
    Filed: December 22, 2009
    Date of Patent: February 4, 2014
    Assignee: GreenField Specialty Alcohols Inc.
    Inventors: Robert Ashley Cooper Benson, Regis-Olivier Benech
  • Patent number: 8603295
    Abstract: A process for separating the components of lignocellulosic biomass for the purpose of producing a pure reactive cellulose is disclosed. The process has two stages. In the first stage, the lignocellulosic biomass is pretreated with steam, with or without an acid catalyst, and then pressed, with or without the presence of an eluent, to remove hemicellulose and other impurities. In the second stage, the pretreated biomass is extracted with a solvent such as ethanol with or without acid catalysts in order to remove lignin and release a purified cellulose stream. The extracted cellulose is then rapidly decompressed to rupture the fibrous structure. The process provides a purified cellulose stream that is relatively easy to hydrolyze with enzymes and ferment to biofuels and other chemicals such as ethanol.
    Type: Grant
    Filed: April 23, 2010
    Date of Patent: December 10, 2013
    Assignee: Greenfield Specialty Alcohols Inc.
    Inventors: Frank A. Dottori, Robert Ashley Cooper Benson, Régis-Olivier Benech
  • Publication number: 20130029406
    Abstract: Disclosed is a method of pretreating biomass in two pretreatment stages as part of a biofuel production process. The first stage pretreatment is carried out by heating the biomass to a first stage temperature of 140° C. to 180° C. for a first stage time of 30 minutes to 2 hours at a first stage pressure of 105 to 150 psig; and the second stage is carried out by heating the biomass to a second stage temperature of 190° C. to 210° C. for a second stage time of 2 to 10 minutes at a second stage pressure of 167 to 262 psig. The biomass may be initially conditioned prior to the first pretreatment stage by atmospheric steam heating and adjusting the moisture content of the biomass. Hemicellulose and inhibitors (inhibitory compounds) to downstream hydrolysis and fermentation are preferably removed between the first and second pretreating stages, more preferably after each pretreatment stage.
    Type: Application
    Filed: July 20, 2012
    Publication date: January 31, 2013
    Applicant: GreenField Ethanol Inc.
    Inventors: Frank A. DOTTORI, Robert Ashley Cooper BENSON, Regis-Olivier BENECH
  • Publication number: 20130014749
    Abstract: Disclosed is an improvement in a conventional process for C5 and C6 sugar recovery from lignocellulosic biomass for fermentation to ethanol, which process including the conventional steps of pretreatment of the biomass with steam at elevated temperature and pressure, collection of C5 sugars from hemicellulose breakdown, cellulose hydrolysis and collection of C6 sugars from cellulose breakdown. The improvement includes conditioning of the biomass prior to the pretreatment step by heating the biomass with steam for a time period between 5 minutes to 60 minutes to achieve a steam treated biomass having a temperature of about 80 to 100°C.; and adjusting a moisture content of the steam treated biomass to about 45% to 80%. An increased recovery of C5 and C6 sugars is achieved compared to the conventional process.
    Type: Application
    Filed: July 12, 2012
    Publication date: January 17, 2013
    Applicant: GREENFIELD ETHANOL INC.
    Inventors: Frank A. DOTTORI, Robert Ashley Cooper BENSON, Regis-Olivier BENECH
  • Publication number: 20130017589
    Abstract: A process is defined for the continuous steam pretreatment and fractionation of corn cobs and low lignin lignocellulosic biomass to produce a concentrated cellulose solid stream that is sensitive to enzymatic hydrolysis. Valuable chemicals are recovered by fractionating the liquid and vapor stream composed of hydrolysis and degradation products of the hemicellulose. Cellulosic derived glucose is produced for fermentation to biofuels. A hemicellulose concentrate is recovered that can be converted to value added products including ethanol.
    Type: Application
    Filed: July 17, 2012
    Publication date: January 17, 2013
    Applicant: GreenField Ethanol Inc.
    Inventors: Frank A. DOTTORI, Robert Ashley Cooper BENSON, Regis-Olivier BENECH
  • Publication number: 20120329116
    Abstract: A process for the pretreatment of lignocellulosic biomass is disclosed, which includes the steps of pretreating the lignocellulosic biomass to hydrolyze and solubilize hemicelluloses in the biomass; explosively decomposing the biomass into fibers; and extracting from the resulting solids fraction a liquefied portion of the lignocellulosic biomass before or after explosive decomposition. This removes compounds from the lignocellulosic biomass which are inhibitory to enzymatic cellulose hydrolysis and sugar fermentation to ethanol. For improved economy, the inhibitory compounds are not completely removed. The extraction step is controlled on the basis of the xylose equivalent content in the reaction mixture and the extracting step is discontinued once a xylose equivalent content of 4-8% w/w of xylose in the dry matter of the solids fraction is achieved.
    Type: Application
    Filed: July 23, 2012
    Publication date: December 27, 2012
    Applicant: GREENFIELD ETHANOL INC.
    Inventors: Frank A. DOTTORI, Robert Ashley Cooper BENSON, Regis-Olivier BENECH
  • Publication number: 20120115200
    Abstract: A continuous process for the recovery of ethanol from hemicellulose and cellulose from lignocellulosic biomass. Yield of fermentable sugars can be maximized by continuous operation of the pre-treatment system and careful selection of pretreatment conditions including the addition of only small amounts of dilute mineral acid and low pressure. With this approach, the xylose component that is mainly present in its unfermentable oligomeric form in known pre-hydrolysis Kraft processes can be recovered more efficiently and as a monomer that can be fermented by xylose fermenting yeasts and bacteria. Due to the use of only dilute acids, there is a very low loss of glucose and xylose hence very low production of toxic chemicals (e.g. HMF, furfural) in the pretreatment step. The resulting overall fermentation efficiency of both hexose and pentose sugars is 90% of the theoretical maximum.
    Type: Application
    Filed: November 8, 2011
    Publication date: May 10, 2012
    Applicant: GREENFIELD ETHANOL INC.
    Inventors: Frank A. DOTTORI, Robert Ashley Cooper BENSON, Régis-Olivier BENECH
  • Publication number: 20120111514
    Abstract: A process is defined for the continuous steam pretreatment and fractionation of bagasse to produce a concentrated cellulose solid stream that is sensitive to enzymatic hydrolysis. Valuable chemicals are recovered by fractionating the liquid and vapor stream composed of hydrolysis and degradation products of the hemicellulose. Cellulosic derived glucose is produced for fermentation to biofuels. A hemicellulose concentrate is recovered that can be converted to value added products including ethanol.
    Type: Application
    Filed: November 4, 2011
    Publication date: May 10, 2012
    Applicant: GREENFIELD ETHANOL INC.
    Inventors: Frank A. DOTTORI, Robert Ashley Cooper BENSON, Régis-Olivier BENECH
  • Publication number: 20100313882
    Abstract: A process is defined for the continuous steam pretreatment and fractionation of corn cobs and low lignin lignocellulosic biomass to produce a concentrated cellulose solid stream that is sensitive to enzymatic hydrolysis. Valuable chemicals are recovered by fractionating the liquid and vapor stream composed of hydrolysis and degradation products of the hemicellulose. Cellulosic derived glucose is produced for fermentation to biofuels. A hemicellulose concentrate is recovered that can be converted to value added products including ethanol.
    Type: Application
    Filed: April 23, 2010
    Publication date: December 16, 2010
    Applicant: GREENFIELD ETHANOL INC.
    Inventors: Frank A. Dottori, Robert Ashley Cooper Benson, Regis-Olivier Benech