Abstract: The invention relates to phosphinites I of formulae (1) or (2), in which R1, R2, R5, R6, R7, R8, R9 independently represent hydrogen, an alkyl or alkylene group having 1 to 8 carbon atoms or an alkoxy group having 1 to 8 carbon atoms; R3 is H or methyl; R4 is i-propyl or t-butyl; X is F, Cl or CF3 and n is 1 or 2

Abstract: Phosphonites I of the formula 1 or 2 where R1, R2 are each, independently of one another, hydrogen, an alkyl or alkylene group having from 1 to 8 carbon atoms or an alkoxy group having from 1 to 8 carbon atoms, with the proviso that R1 and R2 are not simultaneously H, R3 is H or methyl, R4 is t-butyl, R5, R6, R7, R8, R9 are each, independently of one another, H or an alkyl or alkylene group having from 1 to 8 carbon atoms.

Abstract: A process for the recovery of a Lewis acid from a reaction mixture (I) which has been obtained in the hydrocyanation of an olefinically unsaturated compound to a nitrile which has a miscibility gap with water under certain pressure and temperature conditions, in the presence of a catalyst system comprising a Lewis acid and a complex compound.

Abstract: A process for the removal of water from a mixture comprising water and zinc chloride, which comprises adding to said mixture comprising water and zinc chloride an aprotic, polar diluent whose boiling point in the case where an azeotrope is not formed between said diluent and water under the pressure conditions of the distillation mentioned below is higher than the boiling point of water and which is in liquid form at this boiling point of water or which forms an azeotrope or heteroazeotrope with water under the pressure and temperature conditions of the distillation mentioned below, and distilling the mixture comprising water, zinc chloride and the diluent with removal of water or said azeotrope or said heteroazeotrope from this mixture, giving an anhydrous mixture comprising zinc chloride and said diluent.

Abstract: A method is disclosed for recovering the properties of single crystal and directionally solidified Nickel based superalloys and articles made thereof, after use in a high temperature environment. The method comprises the steps of a stress relief treatment, a ?? rejuvenation heat treatment at a temperature below the ??-solvus temperature (Tsolvus, ??) of the superalloy, a precipitation heat treatment and an aging heat treatment.

Abstract: The present invention pertains to radiation sources that mimic radiation environment(s) encountered by packaged semiconductor devices. The sources are suitable for use in test systems operative to test for soft error and/or failure rates in devices sensitive to such radiation. The radiation is highly active to exacerbate soft error rates and thereby accelerate testing and reduce test times. The sources are also relatively uniformly distributed within a medium to simulate the direction(s) and energy spectra of radiation that would actually be encountered by semiconductor devices in device operation.

Abstract: Processes for the living polymerization of olefin monomers with terminal carbon-carbon double bonds are disclosed. The processes employ initiators that include a metal atom and a ligand having two group 15 atoms and a group 16 atom or three group 15 atoms. The ligand is bonded to the metal atom through two anionic or covalent bonds and a dative bond. The initiators are particularly stable under reaction conditions in the absence of olefin monomer. The processes provide polymers having low polydispersities, especially block copolymers having low polydispersities. It is an additional advantage of these processes that, during block copolymer synthesis, a relatively small amount of homopolymer is formed.

Abstract: The present invention pertains to radiation sources that mimic radiation environment(s) encountered by packaged semiconductor devices. The sources are suitable for use in test systems operative to test for soft error and/or failure rates in devices sensitive to such radiation. The radiation is highly active to exacerbate soft error rates and thereby accelerate testing and reduce test times. The sources are also relatively uniformly distributed within a medium to simulate the direction(s) and energy spectra of radiation that would actually be encountered by semiconductor devices in device operation.

Abstract: Phosphinites I of the formula 1, 2 or 3 where R1, R2, R4 are each, independently of one another, hydrogen, an alkyl or alkylene group having from 1 to 8 carbon atoms or an alkoxy group having from 1 to 8 carbon atoms, with the proviso that at least one of the groups R1, R2, R4 is not H, R3 is H or methyl X is F, Cl or CF3 n is 0, 1 or 2 can be used as catalysts.

Abstract: The invention relates to phosphinites I of formulae (1) or (2), in which R1, R2, R5, R6, R7, R8, R9 independently represent hydrogen, an alkyl or alkylene group having 1 to 8 carbon atoms or an alkoxy group having 1 to 8 carbon atoms; R3 is H or methyl; R4 is i-propyl or t-butyl; X is F, Cl or CF3 and n is 1 or 2.

Abstract: In a process for the hydroformylation of ethylenically unsaturated compounds, at least one complex of a metal of transition group VIII. with at least one phosphorus-, arsenic- or antimony-containing compound as ligand is used as hydroformylation catalyst, where the compound used as ligand in each case comprises two groups which comprise a P, As or Sb atom and at least two further hetero atoms and are bound to a xanthene-like molecular framework. New compounds of this type and catalysts which comprise at least one complex of a metal of transition group VIII. with at least one such compound as ligand are also provided.

Abstract: A process is provided for the distillative separation of pentene nitrile isomers which have a relative volatility alpha ranging from 1.0 to 1.3 in the pressure range from 1 to 500 kPa, wherein the distillation is carried out in the presence of a liquid diluent which forms with the pentene nitrile isomers, under the same pressure conditions, azeotropes whose relative volatility alpha is higher than that of the pentene nitrile isomers to be separated.

Abstract: Phosphonites I of the formula 1 or 2 1

Abstract: A catalyst system containing a) Ni (0), b) 4-10 mol per mol Ni (0) according to a) a compound (I) of formula P (X1R1) (X2R2) (X3R3) (I) wherein X1, X2, X3 independently represent oxygen or a single bond R1, R2, R3 represent independently, the same or different organic radicals, and c) 1-4 mol per mol Ni (0) according to a) a compound (II) of formula (II) wherein X11, X12, X13, X21, X22, X23 independently oxygen or a single bond, R11, R12 independently represent the same or different individual or bridged organic radicals, R21, R22 independently represent the same or different, individual or bridged organic radicals, Y represents a bridge group.

Abstract: Novel phosphites have the formula I P(O—R1)x(O—R2)y(O—R3)z(O—R4)p  I where R1: aromatic radical having a C1-C18-alkyl substituent in the o position relative to the oxygen atom which connects the phosphorus atom to the aromatic system, or having an aromatic substituent in the o position relative to the oxygen atom which connects the phosphorus atom to the aromatic system, or having an aromatic system fused on in the o position relative to the oxygen atom which connects the phosphorus atom to the aromatic system, R2: aromatic radical having a C1-C18-alkyl substituent in the m position relative to the oxygen atom which connects the phosphorus atom to the aromatic system, or having an aromatic substituent in the m position relative to the oxygen atom which connects the phosphorus atom to the aromatic system, or having an aromatic system fused on in the m position relative to the oxygen atom which connects the phosphorus atom to the aromatic system, where the aromatic radical

Abstract: Processes for the living polymerization of olefin monomers with terminal carbon-carbon double bonds are disclosed. The processes employ initiators that include a metal atom and a ligand having two group 15 atoms and a group 16 atom or three group 15 atoms. The ligand is bonded to the metal atom through two anionic or covalent bonds and a dative bond. The initiators are particularly stable under reaction conditions in the absence of olefin monomer. The processes provide polymers having low polydispersities, especially block copolymers having low polydispersities. It is an additional advantage of these processes that, during block copolymer synthesis, a relatively small amount of homopolymer is formed.

Abstract: A master tool for a reception station on a press for shaping sheets of paper or cardboard, comprising a moving slide and a number of bars (1) adapted to form a grid for non-stop reception of blanks and a bottom separating tool comprising two boards (4, 5) adjustable on two transverse beams (9, 10) of the moving slide, the beams having top edges having the same profile, the profile of the top edge comprising a number of serrated recesses in shape matching the cross-section of the bars (1), the serrated recesses being adjusted to correspond to the transverse positions of the openings in the bottom blank-separating tool.

Abstract: The invention relates to a nickel-base superalloy for producing single-crystal components. The alloy according to the invention is characterized by the following chemical composition (details in % by weight): 7-13 Cr, 4-10 Co, 0.5-2 Mo, 2-8 W, 4-6 Ta, 3-6 Al, 1-4 Ti, 0.1-6 Ru, 0.01-0.5 Hf, 0.001-0.15 Si, 0-700 ppm C, 0-300 ppm B, remainder Ni and production-related impurities.

Abstract: A process is provided for the distillative separation of pentene nitrile isomers which have a relative volatility alpha ranging from 1.0 to 1.3 in the pressure range from 1 to 500 kPa, wherein the distillation is carried out in the presence of a liquid diluent which forms with the pentene nitrile isomers, under the same pressure conditions, azeotropes whose relative volatility alpha is higher than that of the pentene nitrile isomers to be separated.

Abstract: In a method for the nondestructive quality testing of a thermocouple (10) which can be used in particular at high temperatures and/or under high levels of vibration, which thermocouple (10) comprises at least two wires (13, 14) which run substantially parallel to one another in one plane, are connected to one another at their ends by a welded joint (15), are surrounded by a hermetically sealed sheath (11) and inside the sheath (11) are embedded in insulation (16, 17) comprising a compacted powder, simple and reliable assessment is achieved by the fact that the X-radiation is passed through the thermocouple (10) perpendicular to the plane of the wires (13, 14) and an X-ray image is taken, that the position of the wires (13, 14) in the vicinity of the welded joint (15) is determined from the X-ray image, and that the quality of the thermocouple (10) is established from the position of the wires (13, 14) in the vicinity of the welded joint (15).