Abstract: A method includes determining a total expansion value for a coin cell based on processing of first sensor data captured by a magnetic force dilatometry sensor. The first sensor data is representative of the coin cell during a cycling program of the coin cell with the coin cell held at a fixture. Based on processing of second sensor data captured by an imaging sensor, the method includes determining a reversible expansion value for the coin cell. The second sensor data is representative of the coin cell during the cycling program of the coin cell with the coin cell held at the fixture. Based on the total expansion value and the reversible expansion value, the method includes determining an irreversible expansion value for the coin cell.

Abstract: A hybrid solid-state electrolyte layer for use in an electrochemical cell is provided. The hybrid solid-state electrolyte layer includes a polymeric material, a ceramic material, and an interfacial material adhering the polymeric material and the ceramic material. The interfacial material includes a branched copolymer that includes dopamine and a second monomer. The second monomer forms a polymeric moiety in the copolymer that is the same or similar to the polymeric material. In certain variations, the polymeric material defines a polymeric layer, the ceramic material defines a ceramic layer, and the interfacial material defines an interfacial layer that is disposed between the polymeric layer and the ceramic layer. In other variations, the polymeric material defines a polymeric matrix, the ceramic material defines a plurality of ceramic particles dispersed in the polymeric matrix, and the plurality of ceramic particles are coated with the interfacial material.

Abstract: Aspects of the disclosure include a system for monitoring a capacitance across a battery cell during electrolyte wetting and cell formation and methods of using the same. An exemplary system includes a battery cell, a first conductive plate positioned over a first end of the battery cell, and a second conductive plate positioned on a second end of the battery cell. The first conductive plate is separated from the first end of the battery cell by a gap and the second conductive plate includes a component of the battery cell. The second end of the battery cell is opposite the first end of the battery cell. The system includes a capacitance measurement system electrically coupled to the first conductive plate and the second conductive plate. The capacitance measurement system is configured to measure a capacitance across the first conductive plate and the second conductive plate.

Abstract: A device for thermal control of a battery system includes a heating control module configured to generate an alternating current (AC) heating current and heat the battery system to a desired temperature by applying the AC heating current to the battery system over a selected heating time duration. The heating control module is configured to monitor a rate of increase of a temperature of the battery system during the applying, during the heating time duration, perform a periodic impedance measurement, the periodic impedance measurement including application of a measurement signal having a selected frequency range to the battery system for a measurement period, a length of the measurement period select to minimize a difference between a desired rate of increase and the monitored rate of increase, and adjust the AC heating current during the applying based on the temperature and the impedance measurement.

Abstract: A solid-state electrolyte for an electrochemical cell that cycles lithium ions is provided. The solid-state electrolyte includes a sintered layer that includes a plurality of lithiated zeolite particles having pores and a lithium-containing material disposed in at least a portion of the pores of the lithiated zeolite particles. For example, each lithiated zeolite particle has a porosity greater than or equal to about 20 vol. % to less than or equal to about 80 vol. %, and the lithium-containing material occupies greater than or equal to about 20% to less than or equal to about 80% of a total porosity of each lithiated zeolite particle. In certain instances, the sintered layer further includes a superionic additive that is also disposed in a portion of the pores of the lithiated zeolite particles, such that the sintered layer has an ionic conductivity between about 1×10?5 S·cm?1 and about 1×10?1 S·cm?1.

Abstract: A dilatometer for measuring battery dilation including: a battery cell with a first electrode and a second electrode; an internal magnetic sensing element; and a magnetic force sensor. The internal magnetic sensing element is configured to move in response to expansion the first electrode and remain stationary in response to expansion of the second electrode during dilation of the battery cell. The magnetic force sensor is stationary relative to the battery cell and configured to sense a change in magnetic force strength between the internal magnetic sensing element and the magnetic force sensor. A controller is configured to measure dilation of the first electrode independent of dilation of the second electrode based on the change in the magnetic force strength between the internal magnetic sensing element and the magnetic force sensor.

Abstract: Methods for forming sulfur polyacrylonitrile are provide. In certain variations, the method includes contacting sulfur and polyacrylonitrile to form an admixture, sealing a container holding the admixture, heating the admixture to a first temperature venting the container holding the admixture to release gases generated during the heating of the admixture to the first temperature, re-sealing the container holding the admixture, and heating the admixture to a second temperature. In other variations, the method includes contacting sulfur and polyacrylonitrile to form an admixture, heating the admixture to a first temperature, sealing a container holding the admixture, and heating the admixture to a second temperature. The second temperature is greater than the first temperature.

Abstract: A dilatometer for measuring battery dilation including: a battery cell with a first electrode and a second electrode; an internal magnetic sensing element; and a magnetic force sensor. The internal magnetic sensing element is configured to move in response to expansion the first electrode and remain stationary in response to expansion of the second electrode during dilation of the battery cell. The magnetic force sensor is stationary relative to the battery cell and configured to sense a change in magnetic force strength between the internal magnetic sensing element and the magnetic force sensor. A controller is configured to measure dilation of the first electrode independent of dilation of the second electrode based on the change in the magnetic force strength between the internal magnetic sensing element and the magnetic force sensor.

Abstract: Organosulfur cathodes having low porosity and reduced surface area for lithium-sulfur batteries generally include sulfurized poly(1,2-butadiene), wherein the sulfurized poly (1, 2-butadiene) is a reaction product of a poly (1, 2-butadiene) monomer and a cyclic octaatomic sulfur; conductive carbon; and a binder. Optionally, the reaction product that further includes co-monomers including an alkene functionality. The co-monomers can include one or more sulfide groups selected from the group consisting of sulfide, disulfide, and polysulfide.

Abstract: A method to create a garnet-based solid electrolyte separator for a battery cell is provided. The method includes coating a garnet-based material powder, initially including a lithium carbonate layer upon an outer surface of the garnet-based material powder, with aluminum fluoride to create a fluoride-treated garnet-based material powder. The method further includes operating a solid-state reaction upon the fluoride-treated garnet-based material powder, such that the aluminum fluoride reacts with the lithium carbonate layer to create aluminum oxide, carbon dioxide, and lithium fluoride. The solid-state reaction creates a fluoride-treated and solid-state reacted garnet-based material powder including the aluminum oxide and the lithium fluoride. The method further includes sintering the fluoride-treated and solid-state reacted garnet-based material powder including the aluminum oxide and the lithium fluoride.

Abstract: A monitoring assembly for an electrochemical cell of a secondary lithium battery includes a porous sensory structure and a transducer. The porous sensory structure includes a sensory layer disposed on a major surface of a porous separator and a buffer layer disposed between the sensory layer and a facing surface of a negative electrode layer. The buffer layer electrically isolates the sensory layer from the facing surface of the negative electrode layer. The sensory layer includes an electrically conductive material and is configured to produce a response to an input signal or to a physical stimulus received within the electrochemical cell. The transducer is configured to process the response produced by the sensory layer to generate an output signal indicative of a diagnostic condition within the electrochemical cell.

Abstract: A device for thermal control of a battery system includes a heating control module configured to generate an alternating current (AC) heating current and heat the battery system to a desired temperature by applying the AC heating current to the battery system over a selected heating time duration. The heating control module is configured to monitor a rate of increase of a temperature of the battery system during the applying, during the heating time duration, perform a periodic impedance measurement, the periodic impedance measurement including application of a measurement signal having a selected frequency range to the battery system for a measurement period, a length of the measurement period select to minimize a difference between a desired rate of increase and the monitored rate of increase, and adjust the AC heating current during the applying based on the temperature and the impedance measurement.

Abstract: A hybrid solid-state electrolyte layer for use in an electrochemical cell is provided. The hybrid solid-state electrolyte layer includes a polymeric material, a ceramic material, and an interfacial material adhering the polymeric material and the ceramic material. The interfacial material includes a branched copolymer that includes dopamine and a second monomer. The second monomer forms a polymeric moiety in the copolymer that is the same or similar to the polymeric material. In certain variations, the polymeric material defines a polymeric layer, the ceramic material defines a ceramic layer, and the interfacial material defines an interfacial layer that is disposed between the polymeric layer and the ceramic layer. In other variations, the polymeric material defines a polymeric matrix, the ceramic material defines a plurality of ceramic particles dispersed in the polymeric matrix, and the plurality of ceramic particles are coated with the interfacial material.

Abstract: A solid-state electrolyte for an electrochemical cell that cycles lithium ions is provided. The solid-state electrolyte includes a sintered layer that includes a plurality of lithiated zeolite particles having pores and a lithium-containing material disposed in at least a portion of the pores of the lithiated zeolite particles. For example, each lithiated zeolite particle has a porosity greater than or equal to about 20 vol. % to less than or equal to about 80 vol. %, and the lithium-containing material occupies greater than or equal to about 20% to less than or equal to about 80% of a total porosity of each lithiated zeolite particle. In certain instances, the sintered layer further includes a superionic additive that is also disposed in a portion of the pores of the lithiated zeolite particles, such that the sintered layer has an ionic conductivity between about 1×10?5 S·cm?1 and about 1×10?1 S·cm?1.

Abstract: Methods for forming sulfur polyacrylonitrile are provide. In certain variations, the method includes contacting sulfur and polyacrylonitrile to form an admixture, sealing a container holding the admixture, heating the admixture to a first temperature venting the container holding the admixture to release gases generated during the heating of the admixture to the first temperature, re-sealing the container holding the admixture, and heating the admixture to a second temperature. In other variations, the method includes contacting sulfur and polyacrylonitrile to form an admixture, heating the admixture to a first temperature, sealing a container holding the admixture, and heating the admixture to a second temperature. The second temperature is greater than the first temperature.

Abstract: The present disclosure provides an electrochemical cell that includes an electrically conductive material layer, a precursor material disposed on or adjacent to a first surface of the electrically conductive material layer, and an electroactive material layer disposed on or adjacent to the precursor material. In certain variations, the precursor material forms a continuous layer and a solid-electrolyte interface layer is disposed on or adjacent to an exposed surface of the electroactive material layer. In other variations, the precursor material forms a plurality of distinct precursor structures disposed on the first surface of the electrically conductive material layer in a predetermined pattern, such that at least a portion of each distinct precursor structure is unobstructed by the electroactive material layer. The distinct precursor structures are configured to form surface structures that chemically attach the solid-electrolyte interface layer and the electrically conductive material layer.

Abstract: The present disclosure provides an electrochemical cell that includes an electrically conductive material layer, a precursor material disposed on or adjacent to a first surface of the electrically conductive material layer, and an electroactive material layer disposed on or adjacent to the precursor material. In certain variations, the precursor material forms a continuous layer and a solid-electrolyte interface layer is disposed on or adjacent to an exposed surface of the electroactive material layer. In other variations, the precursor material forms a plurality of distinct precursor structures disposed on the first surface of the electrically conductive material layer in a predetermined pattern, such that at least a portion of each distinct precursor structure is unobstructed by the electroactive material layer. The distinct precursor structures are configured to form surface structures that chemically attach the solid-electrolyte interface layer and the electrically conductive material layer.

Abstract: A lithium metal electrode including ceramic particles is provided herein as well as electrochemical cells including the lithium metal electrode and methods of making the lithium metal electrode. The lithium metal electrode includes ceramic particles present as a ceramic layer adjacent to a first surface of the lithium metal electrode, embedded within the first surface, or a combination thereof. The ceramic particles include lithium lanthanum zirconium oxide (LLZO) particles, alumina particles, or a combination thereof.

Abstract: Methods of making a solid-state electrochemical cell that cycles lithium ions are provided that include applying a liquid metal composition comprising gallium to a first major surface of either a solid-state electrolyte or a solid electrode (e.g., lithium metal) in the presence of an oxidant and in an environment substantially free of water to reduce surface tension of the liquid metal composition so that it forms a continuous layer over the first major surface. The first major surface having the continuous layer of liquid metal composition is contacted with a second major surface to form a continuous interfacial layer between the solid-state electrolyte and the solid electrode. Solid-state electrochemical cells formed by such methods are also provided, where the metal composition comprising gallium is a liquid in a temperature range of greater than or equal to about 20° C. to less than or equal to about 30° C.

Abstract: One embodiment is directed to a system for providing wireless coverage and capacity for a public land mobile network within a building. The system comprises a pico base station comprising multiple transceiver units. The pico base station is installed in the building. The system further comprises a plurality of antennas located within the building. The plurality of antennas are located remotely from the pico base station. The pico base station is communicatively coupled to the public land mobile network. The pico base station is communicatively coupled to the plurality of antennas.