Abstract: A process is provided for producing lithium directly from a lithium feed solution selected from the group consisting of lithium chloride brine, lithium sulfate spodumene liquor, lithium hydroxide, and a combination thereof. The lithium feed solution is provided in an electrolysis cell comprising a cathode suitable for electrolysis of lithium, and an anode. An ionizing electric current is provided to the electrolysis cell, thereby providing lithium metal at the cathode. The present process can advantageously streamline the lithium production process, reduce operating costs, and/or improve energy efficiency in production of lithium.