Patents by Inventor Robert F. Watkins

Robert F. Watkins has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 11567239
    Abstract: The disclosed aliphatic thermoplastic polyurethane composition is well suited for use in thin, flexible light directing articles to impart flexibility, toughness, or protection to the light directing articles that contain optically active elements. The disclosed aliphatic thermoplastic polyurethanes have improved thermostability at higher temperatures. Specifically, the disclosed aliphatic thermoplastic polyurethanes have a cross-over temperature greater than 110° C. In one embodiment, the cross-over temperature is greater than 130° C. In one embodiment, the cross-over temperature is less than 170° C. and a Tg greater than 35° C. and less than 70° C.
    Type: Grant
    Filed: December 8, 2020
    Date of Patent: January 31, 2023
    Assignee: 3M INNOVATIVE PROPERTIES COMPANY
    Inventors: Bimal V. Thakkar, Jay M. Jennen, Robert D. Hamann, Ryan M. Braun, Robert F. Watkins, Joseph D. Rule, Todd D. Jones, Charlie C. Ho
  • Patent number: 11397286
    Abstract: A light directing article comprises an acrylic polyvinyl acetal film to protect the optical elements of the light directing article. The acrylic polyvinyl acetal film has a Tg of at least 30° C. and comprises a (meth)acrylic polymer and polyvinyl acetal polymer. The acrylic polyvinyl acetal film is flexible and durable to mechanical deformation.
    Type: Grant
    Filed: June 5, 2017
    Date of Patent: July 26, 2022
    Assignee: 3M INNOVATIVE PROPERTIES COMPANY
    Inventors: Todd D. Jones, Bimal V. Thakkar, Duane D. Fansler, Anthony F. Schultz, Jonathan E. Janoski, David C. Lueneburg, Carla S. Thomas, Tien Yi T. H. Whiting, Robert F. Watkins
  • Publication number: 20210088695
    Abstract: The disclosed aliphatic thermoplastic polyurethane composition is well suited for use in thin, flexible light directing articles to impart flexibility, toughness, or protection to the light directing articles that contain optically active elements. The disclosed aliphatic thermoplastic polyurethanes have improved thermostability at higher temperatures. Specifically, the disclosed aliphatic thermoplastic polyurethanes have a cross-over temperature greater than 110° C. In one embodiment, the cross-over temperature is greater than 130° C. In one embodiment, the cross-over temperature is less than 170° C. and a Tg greater than 35° C. and less than 70° C.
    Type: Application
    Filed: December 8, 2020
    Publication date: March 25, 2021
    Inventors: Bimal V. Thakkar, Jay M. Jennen, Robert D. Hamann, Ryan M. Braun, Robert F. Watkins, Joseph D. Rule, Todd D. Jones, Charlie C. Ho
  • Patent number: 10884163
    Abstract: The disclosed aliphatic thermoplastic polyurethane composition is well suited for use in thin, flexible light directing articles to impart flexibility, toughness, or protection to the light directing articles that contain optically active elements. The disclosed aliphatic thermoplastic polyurethanes have improved thermostability at higher temperatures. Specifically, the disclosed aliphatic thermoplastic polyurethanes have a cross-over temperature greater than 110° C. In one embodiment, the cross-over temperature is greater than 130° C. In one embodiment, the cross-over temperature is less than 170° C. and a Tg greater than 35 C and less than 70 C.
    Type: Grant
    Filed: June 24, 2016
    Date of Patent: January 5, 2021
    Assignee: 3M INNOVATIVE PROPERTIES COMPANY
    Inventors: Bimal V. Thakkar, Jay M. Jennen, Robert D. Hamann, Ryan M. Braun, Robert F. Watkins, Joseph D. Rule, Todd D. Jones, Charlie C. Ho
  • Publication number: 20190302317
    Abstract: A light directing article comprises an acrylic polyvinyl acetal film to protect the optical elements of the light directing article. The acrylic polyvinyl acetal film has a Tg of at least 30° C. and comprises a (meth)acrylic polymer and polyvinyl acetal polymer. The acrylic polyvinyl acetal film is flexible and durable to mechanical deformation.
    Type: Application
    Filed: June 5, 2017
    Publication date: October 3, 2019
    Applicant: 3M INNOVATIVE PROPERTIES COMPANY
    Inventors: Todd D. Jones, Bimal V. Thakkar, Duane D. Fansler, Anthony F. Schultz, Jonathan E. Janoski, David C. Lueneburg, Carla S. Thomas, Tien Yi T.H. Whiting, Robert F. Watkins
  • Publication number: 20180203163
    Abstract: The disclosed aliphatic thermoplastic polyurethane composition is well suited for use in thin, flexible light directing articles to impart flexibility, toughness, or protection to the light directing articles that contain optically active elements. The disclosed aliphatic thermoplastic polyurethanes have improved thermostability at higher temperatures. Specifically, the disclosed aliphatic thermoplastic polyurethanes have a cross-over temperature greater than 110° C. In one embodiment, the cross-over temperature is greater than 130° C. In one embodiment, the cross-over temperature is less than 170° C. and a Tg greater than 35 C and less than 70 C.
    Type: Application
    Filed: June 24, 2016
    Publication date: July 19, 2018
    Inventors: Bimal V. Thakkar, Jay M. Jennen, Robert D. Hamann, Ryan M. Braun, Robert F. Watkins, Joseph D. Rule, Todd D. Jones, Charlie C. Ho
  • Patent number: 9971074
    Abstract: The present application generally relates to retroreflective articles and methods of making retroreflective articles. The retroreflective articles include a substantially amorphous polymeric layer between the body layer and the discrete truncated cube corner elements. The substantially amorphous polymeric layer absorbs, dissipates, and/or accommodates at least some of the stress forces placed on the retroreflective article during processing. As a result, discrete truncated cube corner elements with increased fidelity can be formed. Consequently, retroreflective sheeting including a substantially amorphous polymeric layer has increased brightness compared to similarly made and composed sheeting lacking the substantially amorphous polymeric layer.
    Type: Grant
    Filed: August 14, 2014
    Date of Patent: May 15, 2018
    Assignee: 3M INNOVATIVE PROPERTIES COMPANY
    Inventors: Reema Chatterjee, Stephen A. Johnson, Robert F. Watkins, Bimal V. Thakkar
  • Patent number: 9551816
    Abstract: Retroreflecting optical constructions are disclosed. A disclosed retroreflecting optical construction includes a retroreflecting layer that has a retroreflecting structured major surface, and an optical film that is disposed on the retroreflecting structured major surface of the retroreflecting layer. The optical film has an optical haze that is not less than about 30%. Substantial portions of each two neighboring major surfaces in the retroreflecting optical construction are in physical contact with each other.
    Type: Grant
    Filed: March 21, 2016
    Date of Patent: January 24, 2017
    Assignee: 3M Innovative Properties Company
    Inventors: William D. Coggio, John S. Huizinga, Michael L. Steiner, Robert F. Watkins, Encai Hao, William B. Kolb, Peiwang Zhu, Michael Benton Free, Brant U. Kolb, Kui Chen-Ho, Paul E. Humpal, Scott M. Tapio, Kenneth L. Smith
  • Publication number: 20160209558
    Abstract: The present application generally relates to retroreflective articles and methods of making retroreflective articles. The retroreflective articles include a substantially amorphous polymeric layer between the body layer and the discrete truncated cube corner elements. The substantially amorphous polymeric layer absorbs, dissipates, and/or accommodates at least some of the stress forces placed on the retroreflective article during processing. As a result, discrete truncated cube corner elements with increased fidelity can be formed.
    Type: Application
    Filed: August 14, 2014
    Publication date: July 21, 2016
    Inventors: Reema Chatterjee, Stephen A. Johnson, Robert F. Watkins, Bimal V. Thakkar
  • Patent number: 9291752
    Abstract: Retroreflecting optical constructions are disclosed. A disclosed retroreflecting optical construction includes a retroreflecting layer that has a retroreflecting structured major surface, and an optical film that is disposed on the retroreflecting structured major surface of the retroreflecting layer. The optical film has an optical haze that is not less than about 30%. Substantial portions of each two neighboring major surfaces in the retroreflecting optical construction are in physical contact with each other.
    Type: Grant
    Filed: August 19, 2013
    Date of Patent: March 22, 2016
    Assignee: 3M Innovative Properties Company
    Inventors: William D. Coggio, John S Huizinga, Michael L. Steiner, Robert F. Watkins, Encai Hao, William B. Kolb, Peiwang Zhu, Michael Benton Free, Brant U. Kolb, Kui Chen-Ho, Paul E. Humpal, Scott M. Tapio, Kenneth L. Smith
  • Publication number: 20150049384
    Abstract: Retroreflecting optical constructions are disclosed. A disclosed retroreflecting optical construction includes a retroreflecting layer that has a retroreflecting structured major surface, and an optical film that is disposed on the retroreflecting structured major surface of the retroreflecting layer. The optical film has an optical haze that is not less than about 30%. Substantial portions of each two neighboring major surfaces in the retroreflecting optical construction are in physical contact with each other.
    Type: Application
    Filed: August 19, 2013
    Publication date: February 19, 2015
    Applicant: 3M Innovative Properties Company
    Inventors: William D. Coggio, John S Huizinga, Michael L. Steiner, Robert F. Watkins, Encai Hao, William B. Kolb, Peiwang Zhu, Michael B. Free, Brant U. Kolb, Kui Chen-Ho, Paul E. Humpal, Scott M. Tapio
  • Patent number: 8534849
    Abstract: Retroreflecting optical constructions are disclosed. A disclosed retroreflecting optical construction includes a retroreflecting layer that has a retroreflecting structured major surface, and an optical film that is disposed on the retroreflecting structured major surface of the retroreflecting layer. The optical film has an optical haze that is not less than about 30%. Substantial portions of each two neighboring major surfaces in the retroreflecting optical construction are in physical contact with each other.
    Type: Grant
    Filed: April 15, 2010
    Date of Patent: September 17, 2013
    Assignee: 3M Innovative Properties Company
    Inventors: William D. Coggio, John S. Huizinga, Michael L. Steiner, Robert F. Watkins, Encai Hao, William B. Kolb, Peiwang Zhu, Michael Benton Free, Brant U. Kolb, Kui Chen-Ho, Paul E. Humpal, Kenneth L. Smith, Scott M. Tapio
  • Patent number: 8012550
    Abstract: An ink receptive article including a substrate having on at least a portion of a major surface thereof an antistatic layer, and wherein the antistatic layer has on at least a portion of a major surface thereof an ink receptive layer, wherein the ink receptive layer includes a crosslinked polymer selected from the group consisting of polyurethanes, polyethers, polyesters, polyacrlylics, polyureas, copolymers thereof, and blends thereof.
    Type: Grant
    Filed: October 4, 2006
    Date of Patent: September 6, 2011
    Assignee: 3M Innovative Properties Company
    Inventors: Caroline M. Ylitalo, Scott A. Boyd, Joseph C. Carls, Eugene H. Carlson, Christopher K. Haas, James M. Jonza, Mark J. Pellerite, Robert F. Watkins
  • Publication number: 20100265584
    Abstract: Retroreflecting optical constructions are disclosed. A disclosed retroreflecting optical construction includes a retroreflecting layer that has a retroreflecting structured major surface, and an optical film that is disposed on the retroreflecting structured major surface of the retroreflecting layer. The optical film has an optical haze that is not less than about 30%. Substantial portions of each two neighboring major surfaces in the retroreflecting optical construction are in physical contact with each other.
    Type: Application
    Filed: April 15, 2010
    Publication date: October 21, 2010
    Inventors: William D. Coggio, John S. Huizinga, Michael L. Steiner, Robert F. Watkins, Encai Hao, William B. Kolb, Peiwang Zhu, Michael Benton Free, Brant U. Kolb, Kui Chen-Ho, Paul E. Humpal, Kenneth L. Smith, Scott M. Tapio
  • Publication number: 20080085384
    Abstract: An ink receptive article including a substrate having on at least a portion of a major surface thereof an antistatic layer, and wherein the antistatic layer has on at least a portion of a major surface thereof an ink receptive layer, wherein the ink receptive layer includes a crosslinked polymer selected from the group consisting of polyurethanes, polyethers, polyesters, polyacrlylics, polyureas, copolymers thereof, and blends thereof.
    Type: Application
    Filed: October 4, 2006
    Publication date: April 10, 2008
    Inventors: Caroline M. Ylitalo, Scott A. Boyd, Joseph C. Carls, Eugene H. Carlson, Christopher K. Haas, James M. Jonza, Mark J. Pellerite, Robert F. Watkins
  • Patent number: 7048989
    Abstract: The invention relates to retroreflective articles such as retroreflective sheeting that comprises a core sheet comprising retroreflective elements and a topcoat wherein the topcoat comprises certain water-borne acrylic polymer(s).
    Type: Grant
    Filed: April 17, 2003
    Date of Patent: May 23, 2006
    Assignee: 3M Innovative Properties Company
    Inventors: Robert F. Watkins, Terry R. Bailey, Joey L. Reule, Scott A. Boyd
  • Publication number: 20040018344
    Abstract: The invention relates to retroreflective articles such as retroreflective sheeting that comprises a core sheet comprising retroreflective elements and a topcoat wherein the topcoat comprises certain water-borne acrylic polymer(s).
    Type: Application
    Filed: April 17, 2003
    Publication date: January 29, 2004
    Inventors: Robert F. Watkins, Terry R. Bailey, Joey L. Reule, Scott A. Boyd
  • Patent number: 5508105
    Abstract: Polymeric sheeting materials directly thermally printed upon with a thermal printing system and a resin-based colorant/binder. The polymeric sheeting materials comprise a core sheet and a thermally print receptive surface on the core sheet. The thermally print receptive surface may be formed from compositions comprising a polyurethane dispersion. The thermally print receptive surface is smooth, transparent, durable, and weatherable.Signage articles made from the polymeric sheeting materials of the invention may be configured to have the desired combination of frangibility, durability, retroreflectivity and/or low production cost. Frangible, retroreflective signage articles may be produced from the polymeric sheeting materials and may have durable variable information thermally and variably printed directly on the articles.
    Type: Grant
    Filed: February 2, 1994
    Date of Patent: April 16, 1996
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Bruce D. Orensteen, Thomas F. Look, Robert F. Watkins, Joseph M. McGrath, Robert V. O'Keefe, Joseph R. Zwack
  • Patent number: 4307490
    Abstract: An electrical potential is applied to suspended animal carcasses by a cylindrical carcass-contacting electrode which is continuously rotated about its central axis. A rear portion of the electrode circumference is surrounded by an enclosure within which a cleansing spray is directed on the electrode to avoid cross contamination of carcasses.
    Type: Grant
    Filed: December 28, 1979
    Date of Patent: December 29, 1981
    Assignee: Iowa Beef Processors, Inc.
    Inventors: Robert F. Watkins, Robert L. Davis, Leslie B. Arndt