Patents by Inventor Robert F. Watkins
Robert F. Watkins has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 11567239Abstract: The disclosed aliphatic thermoplastic polyurethane composition is well suited for use in thin, flexible light directing articles to impart flexibility, toughness, or protection to the light directing articles that contain optically active elements. The disclosed aliphatic thermoplastic polyurethanes have improved thermostability at higher temperatures. Specifically, the disclosed aliphatic thermoplastic polyurethanes have a cross-over temperature greater than 110° C. In one embodiment, the cross-over temperature is greater than 130° C. In one embodiment, the cross-over temperature is less than 170° C. and a Tg greater than 35° C. and less than 70° C.Type: GrantFiled: December 8, 2020Date of Patent: January 31, 2023Assignee: 3M INNOVATIVE PROPERTIES COMPANYInventors: Bimal V. Thakkar, Jay M. Jennen, Robert D. Hamann, Ryan M. Braun, Robert F. Watkins, Joseph D. Rule, Todd D. Jones, Charlie C. Ho
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Patent number: 11397286Abstract: A light directing article comprises an acrylic polyvinyl acetal film to protect the optical elements of the light directing article. The acrylic polyvinyl acetal film has a Tg of at least 30° C. and comprises a (meth)acrylic polymer and polyvinyl acetal polymer. The acrylic polyvinyl acetal film is flexible and durable to mechanical deformation.Type: GrantFiled: June 5, 2017Date of Patent: July 26, 2022Assignee: 3M INNOVATIVE PROPERTIES COMPANYInventors: Todd D. Jones, Bimal V. Thakkar, Duane D. Fansler, Anthony F. Schultz, Jonathan E. Janoski, David C. Lueneburg, Carla S. Thomas, Tien Yi T. H. Whiting, Robert F. Watkins
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Publication number: 20210088695Abstract: The disclosed aliphatic thermoplastic polyurethane composition is well suited for use in thin, flexible light directing articles to impart flexibility, toughness, or protection to the light directing articles that contain optically active elements. The disclosed aliphatic thermoplastic polyurethanes have improved thermostability at higher temperatures. Specifically, the disclosed aliphatic thermoplastic polyurethanes have a cross-over temperature greater than 110° C. In one embodiment, the cross-over temperature is greater than 130° C. In one embodiment, the cross-over temperature is less than 170° C. and a Tg greater than 35° C. and less than 70° C.Type: ApplicationFiled: December 8, 2020Publication date: March 25, 2021Inventors: Bimal V. Thakkar, Jay M. Jennen, Robert D. Hamann, Ryan M. Braun, Robert F. Watkins, Joseph D. Rule, Todd D. Jones, Charlie C. Ho
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Patent number: 10884163Abstract: The disclosed aliphatic thermoplastic polyurethane composition is well suited for use in thin, flexible light directing articles to impart flexibility, toughness, or protection to the light directing articles that contain optically active elements. The disclosed aliphatic thermoplastic polyurethanes have improved thermostability at higher temperatures. Specifically, the disclosed aliphatic thermoplastic polyurethanes have a cross-over temperature greater than 110° C. In one embodiment, the cross-over temperature is greater than 130° C. In one embodiment, the cross-over temperature is less than 170° C. and a Tg greater than 35 C and less than 70 C.Type: GrantFiled: June 24, 2016Date of Patent: January 5, 2021Assignee: 3M INNOVATIVE PROPERTIES COMPANYInventors: Bimal V. Thakkar, Jay M. Jennen, Robert D. Hamann, Ryan M. Braun, Robert F. Watkins, Joseph D. Rule, Todd D. Jones, Charlie C. Ho
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Publication number: 20190302317Abstract: A light directing article comprises an acrylic polyvinyl acetal film to protect the optical elements of the light directing article. The acrylic polyvinyl acetal film has a Tg of at least 30° C. and comprises a (meth)acrylic polymer and polyvinyl acetal polymer. The acrylic polyvinyl acetal film is flexible and durable to mechanical deformation.Type: ApplicationFiled: June 5, 2017Publication date: October 3, 2019Applicant: 3M INNOVATIVE PROPERTIES COMPANYInventors: Todd D. Jones, Bimal V. Thakkar, Duane D. Fansler, Anthony F. Schultz, Jonathan E. Janoski, David C. Lueneburg, Carla S. Thomas, Tien Yi T.H. Whiting, Robert F. Watkins
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Publication number: 20180203163Abstract: The disclosed aliphatic thermoplastic polyurethane composition is well suited for use in thin, flexible light directing articles to impart flexibility, toughness, or protection to the light directing articles that contain optically active elements. The disclosed aliphatic thermoplastic polyurethanes have improved thermostability at higher temperatures. Specifically, the disclosed aliphatic thermoplastic polyurethanes have a cross-over temperature greater than 110° C. In one embodiment, the cross-over temperature is greater than 130° C. In one embodiment, the cross-over temperature is less than 170° C. and a Tg greater than 35 C and less than 70 C.Type: ApplicationFiled: June 24, 2016Publication date: July 19, 2018Inventors: Bimal V. Thakkar, Jay M. Jennen, Robert D. Hamann, Ryan M. Braun, Robert F. Watkins, Joseph D. Rule, Todd D. Jones, Charlie C. Ho
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Patent number: 9971074Abstract: The present application generally relates to retroreflective articles and methods of making retroreflective articles. The retroreflective articles include a substantially amorphous polymeric layer between the body layer and the discrete truncated cube corner elements. The substantially amorphous polymeric layer absorbs, dissipates, and/or accommodates at least some of the stress forces placed on the retroreflective article during processing. As a result, discrete truncated cube corner elements with increased fidelity can be formed. Consequently, retroreflective sheeting including a substantially amorphous polymeric layer has increased brightness compared to similarly made and composed sheeting lacking the substantially amorphous polymeric layer.Type: GrantFiled: August 14, 2014Date of Patent: May 15, 2018Assignee: 3M INNOVATIVE PROPERTIES COMPANYInventors: Reema Chatterjee, Stephen A. Johnson, Robert F. Watkins, Bimal V. Thakkar
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Patent number: 9551816Abstract: Retroreflecting optical constructions are disclosed. A disclosed retroreflecting optical construction includes a retroreflecting layer that has a retroreflecting structured major surface, and an optical film that is disposed on the retroreflecting structured major surface of the retroreflecting layer. The optical film has an optical haze that is not less than about 30%. Substantial portions of each two neighboring major surfaces in the retroreflecting optical construction are in physical contact with each other.Type: GrantFiled: March 21, 2016Date of Patent: January 24, 2017Assignee: 3M Innovative Properties CompanyInventors: William D. Coggio, John S. Huizinga, Michael L. Steiner, Robert F. Watkins, Encai Hao, William B. Kolb, Peiwang Zhu, Michael Benton Free, Brant U. Kolb, Kui Chen-Ho, Paul E. Humpal, Scott M. Tapio, Kenneth L. Smith
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Publication number: 20160209558Abstract: The present application generally relates to retroreflective articles and methods of making retroreflective articles. The retroreflective articles include a substantially amorphous polymeric layer between the body layer and the discrete truncated cube corner elements. The substantially amorphous polymeric layer absorbs, dissipates, and/or accommodates at least some of the stress forces placed on the retroreflective article during processing. As a result, discrete truncated cube corner elements with increased fidelity can be formed.Type: ApplicationFiled: August 14, 2014Publication date: July 21, 2016Inventors: Reema Chatterjee, Stephen A. Johnson, Robert F. Watkins, Bimal V. Thakkar
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Patent number: 9291752Abstract: Retroreflecting optical constructions are disclosed. A disclosed retroreflecting optical construction includes a retroreflecting layer that has a retroreflecting structured major surface, and an optical film that is disposed on the retroreflecting structured major surface of the retroreflecting layer. The optical film has an optical haze that is not less than about 30%. Substantial portions of each two neighboring major surfaces in the retroreflecting optical construction are in physical contact with each other.Type: GrantFiled: August 19, 2013Date of Patent: March 22, 2016Assignee: 3M Innovative Properties CompanyInventors: William D. Coggio, John S Huizinga, Michael L. Steiner, Robert F. Watkins, Encai Hao, William B. Kolb, Peiwang Zhu, Michael Benton Free, Brant U. Kolb, Kui Chen-Ho, Paul E. Humpal, Scott M. Tapio, Kenneth L. Smith
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Publication number: 20150049384Abstract: Retroreflecting optical constructions are disclosed. A disclosed retroreflecting optical construction includes a retroreflecting layer that has a retroreflecting structured major surface, and an optical film that is disposed on the retroreflecting structured major surface of the retroreflecting layer. The optical film has an optical haze that is not less than about 30%. Substantial portions of each two neighboring major surfaces in the retroreflecting optical construction are in physical contact with each other.Type: ApplicationFiled: August 19, 2013Publication date: February 19, 2015Applicant: 3M Innovative Properties CompanyInventors: William D. Coggio, John S Huizinga, Michael L. Steiner, Robert F. Watkins, Encai Hao, William B. Kolb, Peiwang Zhu, Michael B. Free, Brant U. Kolb, Kui Chen-Ho, Paul E. Humpal, Scott M. Tapio
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Patent number: 8534849Abstract: Retroreflecting optical constructions are disclosed. A disclosed retroreflecting optical construction includes a retroreflecting layer that has a retroreflecting structured major surface, and an optical film that is disposed on the retroreflecting structured major surface of the retroreflecting layer. The optical film has an optical haze that is not less than about 30%. Substantial portions of each two neighboring major surfaces in the retroreflecting optical construction are in physical contact with each other.Type: GrantFiled: April 15, 2010Date of Patent: September 17, 2013Assignee: 3M Innovative Properties CompanyInventors: William D. Coggio, John S. Huizinga, Michael L. Steiner, Robert F. Watkins, Encai Hao, William B. Kolb, Peiwang Zhu, Michael Benton Free, Brant U. Kolb, Kui Chen-Ho, Paul E. Humpal, Kenneth L. Smith, Scott M. Tapio
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Patent number: 8012550Abstract: An ink receptive article including a substrate having on at least a portion of a major surface thereof an antistatic layer, and wherein the antistatic layer has on at least a portion of a major surface thereof an ink receptive layer, wherein the ink receptive layer includes a crosslinked polymer selected from the group consisting of polyurethanes, polyethers, polyesters, polyacrlylics, polyureas, copolymers thereof, and blends thereof.Type: GrantFiled: October 4, 2006Date of Patent: September 6, 2011Assignee: 3M Innovative Properties CompanyInventors: Caroline M. Ylitalo, Scott A. Boyd, Joseph C. Carls, Eugene H. Carlson, Christopher K. Haas, James M. Jonza, Mark J. Pellerite, Robert F. Watkins
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Publication number: 20100265584Abstract: Retroreflecting optical constructions are disclosed. A disclosed retroreflecting optical construction includes a retroreflecting layer that has a retroreflecting structured major surface, and an optical film that is disposed on the retroreflecting structured major surface of the retroreflecting layer. The optical film has an optical haze that is not less than about 30%. Substantial portions of each two neighboring major surfaces in the retroreflecting optical construction are in physical contact with each other.Type: ApplicationFiled: April 15, 2010Publication date: October 21, 2010Inventors: William D. Coggio, John S. Huizinga, Michael L. Steiner, Robert F. Watkins, Encai Hao, William B. Kolb, Peiwang Zhu, Michael Benton Free, Brant U. Kolb, Kui Chen-Ho, Paul E. Humpal, Kenneth L. Smith, Scott M. Tapio
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Publication number: 20080085384Abstract: An ink receptive article including a substrate having on at least a portion of a major surface thereof an antistatic layer, and wherein the antistatic layer has on at least a portion of a major surface thereof an ink receptive layer, wherein the ink receptive layer includes a crosslinked polymer selected from the group consisting of polyurethanes, polyethers, polyesters, polyacrlylics, polyureas, copolymers thereof, and blends thereof.Type: ApplicationFiled: October 4, 2006Publication date: April 10, 2008Inventors: Caroline M. Ylitalo, Scott A. Boyd, Joseph C. Carls, Eugene H. Carlson, Christopher K. Haas, James M. Jonza, Mark J. Pellerite, Robert F. Watkins
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Patent number: 7048989Abstract: The invention relates to retroreflective articles such as retroreflective sheeting that comprises a core sheet comprising retroreflective elements and a topcoat wherein the topcoat comprises certain water-borne acrylic polymer(s).Type: GrantFiled: April 17, 2003Date of Patent: May 23, 2006Assignee: 3M Innovative Properties CompanyInventors: Robert F. Watkins, Terry R. Bailey, Joey L. Reule, Scott A. Boyd
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Publication number: 20040018344Abstract: The invention relates to retroreflective articles such as retroreflective sheeting that comprises a core sheet comprising retroreflective elements and a topcoat wherein the topcoat comprises certain water-borne acrylic polymer(s).Type: ApplicationFiled: April 17, 2003Publication date: January 29, 2004Inventors: Robert F. Watkins, Terry R. Bailey, Joey L. Reule, Scott A. Boyd
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Patent number: 5508105Abstract: Polymeric sheeting materials directly thermally printed upon with a thermal printing system and a resin-based colorant/binder. The polymeric sheeting materials comprise a core sheet and a thermally print receptive surface on the core sheet. The thermally print receptive surface may be formed from compositions comprising a polyurethane dispersion. The thermally print receptive surface is smooth, transparent, durable, and weatherable.Signage articles made from the polymeric sheeting materials of the invention may be configured to have the desired combination of frangibility, durability, retroreflectivity and/or low production cost. Frangible, retroreflective signage articles may be produced from the polymeric sheeting materials and may have durable variable information thermally and variably printed directly on the articles.Type: GrantFiled: February 2, 1994Date of Patent: April 16, 1996Assignee: Minnesota Mining and Manufacturing CompanyInventors: Bruce D. Orensteen, Thomas F. Look, Robert F. Watkins, Joseph M. McGrath, Robert V. O'Keefe, Joseph R. Zwack
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Patent number: 4307490Abstract: An electrical potential is applied to suspended animal carcasses by a cylindrical carcass-contacting electrode which is continuously rotated about its central axis. A rear portion of the electrode circumference is surrounded by an enclosure within which a cleansing spray is directed on the electrode to avoid cross contamination of carcasses.Type: GrantFiled: December 28, 1979Date of Patent: December 29, 1981Assignee: Iowa Beef Processors, Inc.Inventors: Robert F. Watkins, Robert L. Davis, Leslie B. Arndt