Abstract: System to detect coking in at least one component of refinery equipment is provided. The system includes a fiber optic assembly having at least one optical fiber operably coupled with the component, the fiber optic assembly further including a light source to transmit light having a known parameter through the optical fiber and a receiver to receive the light from the optical fiber, and a processor in communication with the fiber optic assembly to identify a shift in the parameter received by the receiver, the shift corresponding to an operating characteristic of the component. Method also provided for detecting coking using the system to detect coking disclosed herein.

Abstract: System to detect coking in at least one component of refinery equipment is provided. The system includes a fiber optic assembly having at least one optical fiber operably coupled with the component, the fiber optic assembly further including a light source to transmit light having a known parameter through the optical fiber and a receiver to receive the light from the optical fiber, and a processor in communication with the fiber optic assembly to identify a shift in the parameter received by the receiver, the shift corresponding to an operating characteristic of the component. Method also provided for detecting coking using the system to detect coking disclosed herein.

Abstract: Described herein is a catalyst precursor composition comprising at least one metal from Group 6 of the Periodic Table of the Elements, at least one metal from Groups 8-10 of the Periodic Table of the Elements, and a reaction product formed from (i) a first organic compound containing at least one amine group and at least 10 carbon atoms or (ii) a second organic compound containing at least one carboxylic acid group and at least 10 carbon atoms, but not both, wherein the reaction product contains additional unsaturated carbon atoms, relative to the first or second organic compound, wherein the metals of the catalyst precursor composition are arranged in a crystal lattice, and wherein the reaction product is not located within the crystal lattice. A process for preparing the catalyst precursor composition is also described, as is sulfiding the catalyst precursor composition to form a hydroprocessing catalyst.

Abstract: Described herein is a catalyst precursor composition comprising at least one metal from Group 6 of the Periodic Table of the Elements, at least one metal from Groups 8-10 of the Periodic Table of the Elements, and a reaction product formed from (i) a first organic compound containing at least one amine group, and (ii) a second organic compound separate from said first organic compound and containing at least one carboxylic acid group. A process for preparing the catalyst precursor composition is also described, as is sulfiding the bulk mixed metal oxide catalyst precursor composition to form a hydroprocessing catalyst.

Abstract: The present invention is a method to determine models to predict physical or chemical properties of a petroleum fluid when such properties of such fluids cannot be measured by conventional analytical methods. The invention includes the steps of determining one or more models that predict one or more predetermined properties from a set of oils whose optical spectra and properties are known wherein a model corresponds to each predetermined property which is related to the spectrum, estimating the quality of the models, estimating the predictive quality for samples with unknown properties, augmenting the spectrum with shape parameters and/or properties that are predicted by the step above, and determining the quality and predictive quality of the models. The models are then used to predict properties of very small samples.

Abstract: Described herein is a catalyst precursor composition comprising at least one metal from Group 6 of the Periodic Table of the Elements, at least one metal from Groups 8-10 of the Periodic Table of the Elements, and a reaction product formed from (i) a first organic compound containing at least one amine group and at least 10 carbon atoms or (ii) a second organic compound containing at least one carboxylic acid group and at least 10 carbon atoms, but not both, wherein the reaction product contains additional unsaturated carbon atoms, relative to the first or second organic compound, wherein the metals of the catalyst precursor composition are arranged in a crystal lattice, and wherein the reaction product is not located within the crystal lattice. A process for preparing the catalyst precursor composition is also described, as is sulfiding the catalyst precursor composition to form a hydroprocessing catalyst.

Abstract: Described herein is a catalyst precursor composition comprising at least one metal from Group 6 of the Periodic Table of the Elements, at least one metal from Groups 8-10 of the Periodic Table of the Elements, and a reaction product formed from (i) a first organic compound containing at least one amine group, and (ii) a second organic compound separate from said first organic compound and containing at least one carboxylic acid group. A process for preparing the catalyst precursor composition is also described, as is sulfiding the bulk mixed metal oxide catalyst precursor composition to form a hydroprocessing catalyst.

Abstract: A method to remove coke from a coker drum is disclosed. The method includes the steps of impinging fluid from a fluid jet on the inside surface of the coker and then determining the vibration signal of the coker drum. The signal is then transformed to determine the amplitude versus frequency by a Fourier Transform of the vibration signal. The amplitude change of the vibration signal as it goes through a maximum, determines when the coke layer has been cut. The fluid jet is lowered into a new layer of coke.

Abstract: The present invention is a method to determine models to predict physical or chemical properties of a petroleum fluid when such properties of such fluids cannot be measured by conventional analytical methods. The invention includes the steps of determining one or more models that predict one or more predetermined properties from a set of oils whose optical spectra and properties are known wherein a model corresponds to each predetermined property which is related to the spectrum, estimating the quality of the models, estimating the predictive quality for samples with unknown properties, augmenting the spectrum with shape parameters and/or properties that are predicted by the step above, and determining the quality and predictive quality of the models. The models are then used to predict properties of very small samples.

Abstract: The present invention includes a method and system of measuring alteration, alteration type, and alteration-causing species in process fluids and equipment and for controlling the process feeds and conditions to maximize the yields and equipment lifetime by minimizing the alteration. The invention includes an optical sensor comprising an optical fiber, a fiber grating written within the optical fiber, strain-tuned elements fixed to the optical fiber and an unaltered element, and an altered element fixed to the unaltered element.

Abstract: The present invention is a method to remove coke from a coker drum. The invention includes the steps of impinging fluid from a fluid jet on the inside surface of the coker and then determining the vibration signal of the coker drum. The signal is then transformed to determine the amplitude versus frequency by a Fourier Transform of the vibration signal. The amplitude change of the vibration signal as it goes through a maximum, determines when the coke layer has been cut. The fluid jet is lowered into a new layer of coke.

Abstract: A method for evaluating sedimentary basins for hydrocarbon potential using aqueous fluid inclusions. Aqueous fluid inclusions are identified in a rock sample. The homogenization temperatures of the fluid inclusions are determined, the optical spectra of the water and methane in the fluid inclusions are measured, and the formation pressures are estimated from the relationship of homogenization temperature and optical spectrum to formation pressure. Formation pressure of the fluid inclusions can be combined with history of the fluid inclusion formation to reconstruct the paleo-history of the basin to evaluate hydrocarbon potential.