Patents by Inventor Robert J. Gruber

Robert J. Gruber has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 4859550
    Abstract: An electrophotographic process which comprises the generation of latent image; developing the image with a toner composition comprised of resin particles, magnetite particles, and an additive component comprised of an aliphatic hydrocarbon or a polymeric alcohol of the formulaCH.sub.3 (CH.sub.2).sub.n CH.sub.2 OHwherein n is a number of from about 30 to about 500; and subsequently providing the developed image with magnetic ink characters thereon to a reader/sorter device whereby toner offsetting and image smearing is minimized in said device.
    Type: Grant
    Filed: September 2, 1988
    Date of Patent: August 22, 1989
    Assignee: Xerox Corporation
    Inventors: Robert J. Gruber, Raphael F. Bov, Thomas D. Cometa, Paul W. Eakin, John S. Berkes, Bernard Grushkin
  • Patent number: 4851318
    Abstract: An improved process for the preparation of encapsulated toner compositions which comprises mixing core monomer(s), an initiator, or initiators, pigment particles, and oil soluble shell monomer(s); homogenizing the aforementioned mixture into an aqueous surfactant solution resulting in an oil-in-water suspension; thereafter adding water soluble shell monomer(s) to the oil-in-water suspension enabling an interfacial polymerization reaction between the oil soluble and the water soluble shell monomer(s); subsequently adding a low molecular weight polyethylene oxide surfactant protective colloid; and thereafter affecting a free-radical polymerization of the core monomer(s) by heating.
    Type: Grant
    Filed: June 24, 1988
    Date of Patent: July 25, 1989
    Assignee: Xerox Corporation
    Inventors: Bing R. Hsieh, Robert J. Gruber, Richard F. Koehler
  • Patent number: 4837101
    Abstract: A negatively charged developer composition comprised of a toner composition with an average particle diameter of from about 4 to about 9 microns containing a mixture of styrene butadiene copolymers, and styrene methacrylate copolymers; pigment particles selected from the group consisting of cyan, magenta, yellow, red, blue, green, brown, and mixtures thereof; first external additive particles of colloidal silica; second external additive particles of fatty acid metal salts; and carrier particles comprised of a ferrite core with a polymeric coating thereover, which coating has dispersed therein conductive particles.
    Type: Grant
    Filed: February 1, 1988
    Date of Patent: June 6, 1989
    Assignee: Xerox Corporation
    Inventors: Robert J. Gruber, John F. Knapp, Ronald J. Koch, Lawrence Floyd, Jr.
  • Patent number: 4814253
    Abstract: Disclosed is an encapsulated toner composition comprised of (1) domains containing a polymer component having dispersed therein a release composition; and thereover (2) a host resin component comprised of toner resin particles and pigment particles.
    Type: Grant
    Filed: October 29, 1987
    Date of Patent: March 21, 1989
    Assignee: Xerox Corporation
    Inventors: Robert J. Gruber, Raymond A. Yourd, III, Shadi L. Malhotra, John G. Vandusen
  • Patent number: 4792513
    Abstract: A positively charged toner composition comprised of resin particles exhibiting a peak value molecular weight in each of the molecular weight regions of from about 5,000 to about 80,000, and from about 100,000 to about 2,000,000; a wax component with a weight average molecular weight of from about 500 to about 10,000; and a charge enhancing additive selected from the group consisting of alkyl pyridinium halides, organic sulfonates, organic sulfates, distearyl dimethyl ammonium methyl sulfate, behenyl trimethyl ammonium methyl sulfate, and distearyl methyl ethyl ammonium ethyl sulfate.
    Type: Grant
    Filed: May 4, 1987
    Date of Patent: December 20, 1988
    Assignee: Xerox Corporation
    Inventors: Robert J. Gruber, Robert A. Nelson
  • Patent number: 4737434
    Abstract: A process for generating consistent high quality colored images for extended periods consisting essentially of (1) providing a xerographic imaging or printing apparatus; (2) adding thereto a stable two-component developer composition comprised of first polymer particles, second polymer particles, and blended flow additive particles and carrier particles; (3) forming electrostatic latent images in the apparatus; and (4) developing the images formed wherein the developer composition retains its triboelectric properties of from about 20 to about 40 microcoulombs per gram for over 500,000 imaging cycles, subject to the provision that the second polymer particles are of a different composition than the first polymer particles.
    Type: Grant
    Filed: March 31, 1986
    Date of Patent: April 12, 1988
    Assignee: Xerox Corporation
    Inventors: Robert J. Gruber, John F. Knapp
  • Patent number: 4695524
    Abstract: Disclosed is a process for generating consistent high quality images comprised of (1) providing a xerographic imaging or printing apparatus; (2) adding thereto a stable two component developer composition comprised of toner composition with an average particle diameter of from about 6 to about 10 microns with resin particles, first pigment particles, second magnetite pigment particles, which are present in a greater amount than the first pigment particles, and blended flow additive particles; and carrier particles consisting of a ferrite core, or a steel core, and a coating thereover selected from the group consisting of terpolymers of styrene, methacrylate, and triethoxysilane; and polymethacrylate, which coating has incorporated therein conductive particles; (3) forming electrostatic latent images or magnetic images in the apparatus; and (4) developing the images formed.
    Type: Grant
    Filed: May 21, 1986
    Date of Patent: September 22, 1987
    Assignee: Xerox Corporation
    Inventors: John F. Knapp, Robert J. Gruber, Lawrence Floyd, Jr., Steven B. Bolte, Michael G. Swales
  • Patent number: 4634649
    Abstract: Disclosed is a two-component developer composition enabling smudge resistant images which is comprised of improved two-component contamination free developer composition comprised of (1) magnetite; (2) a polyester resin comprised of the polymeric esterification product of a dicarboxylic acid and a diol comprising a diphenol of the following formula ##STR1## wherein R is selected from substituted and unsubstituted alkylene radicals of from about 2 to about 12 carbon atoms, alkylidene radicals of from 1 to 12 carbon atoms and cycloalkylidene radicals of from 3 to 12 carbon atoms; R' and R" are selected from substituted and unsubstituted alkylene radicals of from 2 to 12 carbon atoms, alkylene arylene radicals of from 8 to 12 carbon atoms and arylene radicals; X and X' are selected from hydrogen or any alkyl radical having from 1 to 4 carbon atoms; and each n is a number of from 0 (zero) to 4; and (3) carrier particles.
    Type: Grant
    Filed: March 20, 1985
    Date of Patent: January 6, 1987
    Assignee: Xerox Corporation
    Inventors: John F. Knapp, Robert J. Gruber
  • Patent number: 4609603
    Abstract: A process for generating consistent high quality images for extended periods, consisting essentially of (1) providing a xerographic imaging, or printing apparatus; (2) adding thereto a stable two component developer composition comprised of resin particles, first pigment particles, second magnetite pigment particles, which are present in a greater amount than the first pigment particles, and blended flow additive particles; and carrier particles consisting of a ferrite core, or a steel core and a coating thereover selected from the group consisting of terpolymers of styrene, methacrylate, and triethoxysilane; and polymethacrylate, which coating has incorporated therein conductive particles; (3) forming electrostatic latent images, or magnetic images in the apparatus; and (4) developing the images formed, wherein the developer composition retains its electrical properties for over 2.5 million imaging cycles.
    Type: Grant
    Filed: December 14, 1984
    Date of Patent: September 2, 1986
    Assignee: Xerox Corporation
    Inventors: John F. Knapp, Robert J. Gruber, Lawrence Floyd, Jr., Steven B. Bolte
  • Patent number: 4604338
    Abstract: Disclosed is an improved positively charged dry electrostatic colored toner composition comprised of first resin particles; crosslinked second resin particles; colored pigment particles excluding black; and selected from the group consisting of cyan, magenta, yellow, blue, red, and brown; a low molecular weight wax; and a charge enhancing additive selected from the group consisting of alkyl pyridinium halides, organic sulfonate compositions and organic sulfate compositions of the following formulas: ##STR1## wherein R is a hydrocarbon group containing from about 8 to about 22 carbon atoms, and A is an anion; ##STR2## wherein R.sub.1 is an alkyl group of from about 12 carbon atoms to about 22 carbon atoms, R.sub.2 and R.sub.3 are independently selected from alkyl groups containing from about 1 carbon atom to about 5 carbon atoms, R.sub.4 is an alkylene group of from about 1 carbon atom to about 5 carbon atoms, R.sub.
    Type: Grant
    Filed: August 9, 1985
    Date of Patent: August 5, 1986
    Assignee: Xerox Corporation
    Inventors: Robert J. Gruber, Raymond A. Yourd, III, Ronald J. Koch
  • Patent number: 4578338
    Abstract: An improved process for the development and fixing of electrostatic latent images which comprises (1) generating an electrostatic latent image on a photoconductive imaging member, (2) developing this image with a toner composition comprised of toner resin particles, pigment particles, and a wax component of a molecular weight of from about 500 to about 20,000, (3) transferring the developed image to a suitable substrate, and subsequently (4) fusing the transferred image with a compliant oil fuser roll, wherein the amount of fuser oil consumed is from about one microliter to about three microliters per page of developed image.
    Type: Grant
    Filed: August 31, 1984
    Date of Patent: March 25, 1986
    Assignee: Xerox Corporation
    Inventors: Robert J. Gruber, Ronald J. Koch, John F. Knapp
  • Patent number: 4565765
    Abstract: This invention is directed to an improved process for developing electrostatic latent images comprising (1) providing a development zone situated between an imaging member and a transporting member, comprised of a stationary shell containing rotating magnets therein, (2) transporting synthetic developer composition into the development zone by causing rotation of the magnets in the stationary shell, (3) effecting movement of the imaging member in a direction opposite to the direction of movement of the rotating magnets, wherein the developer composition is desirably agitated in the development zone by magnetic means, and wherein developer particles are available immediately adjacent the imaging member; the developer particles comprised of toner resin particles and carrier particles comprised of resin particles and magnetite; with the distance between the imaging member and stationary shell being from about 0.1 millimeter to about 1.5 millimeters.
    Type: Grant
    Filed: November 17, 1983
    Date of Patent: January 21, 1986
    Assignee: Xerox Corporation
    Inventors: John F. Knapp, Leon A. Howland, Robert J. Gruber, Ronald J. Koch
  • Patent number: 4563086
    Abstract: An electrophotographic printing machine in which a magnetic toner image is transferred to a copy sheet from a photoconductive member and fused thereto. The toner image fused to the copy sheet is magnetized and the intensity of the magnetic field generated by the toner image detected to provide a continuous indication of the quality of the toner image fused to the copy sheet.
    Type: Grant
    Filed: October 22, 1984
    Date of Patent: January 7, 1986
    Assignee: Xerox Corporation
    Inventors: John F. Knapp, Robert J. Gruber, Steven B. Bolte
  • Patent number: 4556624
    Abstract: Disclosed are improved positively charged electrostatic toner compositions comprised of a polyblend mixture of a crosslinked copolymer composition, and a second polymer, pigment particles, a wax component of a molecular weight of from 500 to about 20,000, and a charge enhancing additive. These compositions are particularly useful in imaging systems wherein release oils, such as silicone, are not required.
    Type: Grant
    Filed: September 27, 1984
    Date of Patent: December 3, 1985
    Assignee: Xerox Corporation
    Inventors: Robert J. Gruber, Ronald J. Koch, John F. Knapp, Steven B. Bolte
  • Patent number: 4539284
    Abstract: An improved infrared sensitive flash fusible colored toner composition comprised of (1) resin particles, (2) pigment particles selected from the group consisting of cyan, magenta, yellow, blue, red and green, and (3) additives selected from the group consisting of vanadyl phthalocyanines, naphthalocyanines, and the quaternary ammonium salts selected from the group consisting of 1,1',3,3,3',3 hexylmethyl-4,4',5,5'-dibenzo-2,2'-indotricarbocyanine perchlorate, 5,5'-dichloro-11-diphenylamine-3,3'-diethyl-10,12-ethylenethiatricarbocyan ine perchlorate, 1,1',3,3,3',3'-hexamethylindotricarbocyanine perchlorate, and 3,3'-di(3-acetoxypropyl)-11-diphenylamine-10,12-ethylene-5,6,5',6'-dibenzo thiatricarbocyanine perchlorate.
    Type: Grant
    Filed: April 16, 1984
    Date of Patent: September 3, 1985
    Assignee: Xerox Corporation
    Inventors: Angello J. Barbetta, Robert J. Gruber, Louis V. Isganitis, Kock-Yee Law, John W. Lin, Ronald J. Koch, Steven T. Dunn
  • Patent number: 4537848
    Abstract: Disclosed are improved positively charged toner composition comprised of resin particles, pigment particles, and as a charge enhancing additive a phosphonium compound of the formula: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, and R.sub.4, are selected from the group consisting of alkyl, aryl, substituted alkyl, and substituted aryl, and A is an anion.
    Type: Grant
    Filed: June 18, 1984
    Date of Patent: August 27, 1985
    Assignee: Xerox Corporation
    Inventors: Raymond A. Yourd, III, Debesh Majumdar, Robert J. Gruber
  • Patent number: 4520092
    Abstract: A process for obtaining smudge resistant images and for preventing the deposition of unwanted toner particles in an imaging apparatus which comprises(a) providing a xerographic imaging apparatus,(b) adding an improved two component contamination free developer composition to said apparatus, which composition consists essentially of from about 50 percent to about 80 percent by weight of a resin comprised of the polymeric esterification product of a dicarboxylic acid and a diol comprising a diphenol of the following formula ##STR1## wherein R is selected from substituted and unsubstituted alkylene radicals having from about 2 to about 12 carbon atoms, alkylidene radicals having from 1 to 12 carbon atoms and cycloalkylidene radicals having from 3 to 12 carbon atoms; R' and R" are selected from substituted and unsubstituted alkylene radicals having from 2 to 12 carbon atoms, alkylene arylene radicals having from 8 to 12 carbon atoms and arylene radicals; X and X'; are selected from hydrogen or any alkyl radical h
    Type: Grant
    Filed: December 27, 1983
    Date of Patent: May 28, 1985
    Assignee: Xerox Corporation
    Inventors: John F. Knapp, Robert J. Gruber
  • Patent number: 4517268
    Abstract: Disclosed is an improved, simple, economical process for generating documents, such as personal checks, suitable for magnetic image character recognition, which process comprises generating such documents with conventional xerographic methods in a high speed electronic laser printing device, and wherein there is selected as the developer composition a magnetic toner containing from about 20 percent by weight to about 70 percent by weight of magnetite particles, and from about 30 percent by weight to about 80 percent by weight of toner resin particles of styrene copolymers, such as a styrene butadiene copolymer, a styrene n-butylmethacrylate copolymer, or polyesters, and wherein the carrier particles are comprised of ferrite cores, coated with various polymeric resinous compositions.
    Type: Grant
    Filed: September 12, 1983
    Date of Patent: May 14, 1985
    Assignee: Xerox Corporation
    Inventors: Robert J. Gruber, John F. Knapp, Steven B. Bolte
  • Patent number: 4493883
    Abstract: Disclosed are positively charged toner compositions comprised of resin particles, pigment particles, and imide charge enhancing additives of the formula: ##STR1## wherein R.sub.1, R.sub.2, and R.sub.3, are alkyl groups containing from 1 carbon atom to about 25 carbon atoms, R.sub.4 is selected from the group consisting of hydrogen, nitro, halogen, amino, and alkyl and A is an anion.
    Type: Grant
    Filed: February 21, 1984
    Date of Patent: January 15, 1985
    Assignee: Xerox Corporation
    Inventors: Robert J. Gruber, Doretta Agostine, Paul C. Julien, Raymond A. Yourd, III
  • Patent number: 4487825
    Abstract: This invention relates to a conductive single component magnetic dry toner comprised of resins selected from polystyrene allyl alcohol copolymers, and epoxy resins, a magnetic material such as magnetite, and a conductive carbon black which is adhered and/or embedded on the surface of the copolymer or epoxy resin-magnetic material mixture. Such toner compositions, which have excellent conductivity, superior flow properties and low melt fusing temperatures, 95.degree. C.-130.degree. C., are useful for causing the development of images in commercial printers and recorders such as the Versatec printers.
    Type: Grant
    Filed: January 22, 1981
    Date of Patent: December 11, 1984
    Assignee: Xerox Corporation
    Inventors: Robert J. Gruber, John F. Knapp