Patents by Inventor Robert J. Gruber
Robert J. Gruber has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 4859550Abstract: An electrophotographic process which comprises the generation of latent image; developing the image with a toner composition comprised of resin particles, magnetite particles, and an additive component comprised of an aliphatic hydrocarbon or a polymeric alcohol of the formulaCH.sub.3 (CH.sub.2).sub.n CH.sub.2 OHwherein n is a number of from about 30 to about 500; and subsequently providing the developed image with magnetic ink characters thereon to a reader/sorter device whereby toner offsetting and image smearing is minimized in said device.Type: GrantFiled: September 2, 1988Date of Patent: August 22, 1989Assignee: Xerox CorporationInventors: Robert J. Gruber, Raphael F. Bov, Thomas D. Cometa, Paul W. Eakin, John S. Berkes, Bernard Grushkin
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Patent number: 4851318Abstract: An improved process for the preparation of encapsulated toner compositions which comprises mixing core monomer(s), an initiator, or initiators, pigment particles, and oil soluble shell monomer(s); homogenizing the aforementioned mixture into an aqueous surfactant solution resulting in an oil-in-water suspension; thereafter adding water soluble shell monomer(s) to the oil-in-water suspension enabling an interfacial polymerization reaction between the oil soluble and the water soluble shell monomer(s); subsequently adding a low molecular weight polyethylene oxide surfactant protective colloid; and thereafter affecting a free-radical polymerization of the core monomer(s) by heating.Type: GrantFiled: June 24, 1988Date of Patent: July 25, 1989Assignee: Xerox CorporationInventors: Bing R. Hsieh, Robert J. Gruber, Richard F. Koehler
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Patent number: 4837101Abstract: A negatively charged developer composition comprised of a toner composition with an average particle diameter of from about 4 to about 9 microns containing a mixture of styrene butadiene copolymers, and styrene methacrylate copolymers; pigment particles selected from the group consisting of cyan, magenta, yellow, red, blue, green, brown, and mixtures thereof; first external additive particles of colloidal silica; second external additive particles of fatty acid metal salts; and carrier particles comprised of a ferrite core with a polymeric coating thereover, which coating has dispersed therein conductive particles.Type: GrantFiled: February 1, 1988Date of Patent: June 6, 1989Assignee: Xerox CorporationInventors: Robert J. Gruber, John F. Knapp, Ronald J. Koch, Lawrence Floyd, Jr.
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Patent number: 4814253Abstract: Disclosed is an encapsulated toner composition comprised of (1) domains containing a polymer component having dispersed therein a release composition; and thereover (2) a host resin component comprised of toner resin particles and pigment particles.Type: GrantFiled: October 29, 1987Date of Patent: March 21, 1989Assignee: Xerox CorporationInventors: Robert J. Gruber, Raymond A. Yourd, III, Shadi L. Malhotra, John G. Vandusen
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Patent number: 4792513Abstract: A positively charged toner composition comprised of resin particles exhibiting a peak value molecular weight in each of the molecular weight regions of from about 5,000 to about 80,000, and from about 100,000 to about 2,000,000; a wax component with a weight average molecular weight of from about 500 to about 10,000; and a charge enhancing additive selected from the group consisting of alkyl pyridinium halides, organic sulfonates, organic sulfates, distearyl dimethyl ammonium methyl sulfate, behenyl trimethyl ammonium methyl sulfate, and distearyl methyl ethyl ammonium ethyl sulfate.Type: GrantFiled: May 4, 1987Date of Patent: December 20, 1988Assignee: Xerox CorporationInventors: Robert J. Gruber, Robert A. Nelson
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Patent number: 4737434Abstract: A process for generating consistent high quality colored images for extended periods consisting essentially of (1) providing a xerographic imaging or printing apparatus; (2) adding thereto a stable two-component developer composition comprised of first polymer particles, second polymer particles, and blended flow additive particles and carrier particles; (3) forming electrostatic latent images in the apparatus; and (4) developing the images formed wherein the developer composition retains its triboelectric properties of from about 20 to about 40 microcoulombs per gram for over 500,000 imaging cycles, subject to the provision that the second polymer particles are of a different composition than the first polymer particles.Type: GrantFiled: March 31, 1986Date of Patent: April 12, 1988Assignee: Xerox CorporationInventors: Robert J. Gruber, John F. Knapp
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Patent number: 4695524Abstract: Disclosed is a process for generating consistent high quality images comprised of (1) providing a xerographic imaging or printing apparatus; (2) adding thereto a stable two component developer composition comprised of toner composition with an average particle diameter of from about 6 to about 10 microns with resin particles, first pigment particles, second magnetite pigment particles, which are present in a greater amount than the first pigment particles, and blended flow additive particles; and carrier particles consisting of a ferrite core, or a steel core, and a coating thereover selected from the group consisting of terpolymers of styrene, methacrylate, and triethoxysilane; and polymethacrylate, which coating has incorporated therein conductive particles; (3) forming electrostatic latent images or magnetic images in the apparatus; and (4) developing the images formed.Type: GrantFiled: May 21, 1986Date of Patent: September 22, 1987Assignee: Xerox CorporationInventors: John F. Knapp, Robert J. Gruber, Lawrence Floyd, Jr., Steven B. Bolte, Michael G. Swales
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Patent number: 4634649Abstract: Disclosed is a two-component developer composition enabling smudge resistant images which is comprised of improved two-component contamination free developer composition comprised of (1) magnetite; (2) a polyester resin comprised of the polymeric esterification product of a dicarboxylic acid and a diol comprising a diphenol of the following formula ##STR1## wherein R is selected from substituted and unsubstituted alkylene radicals of from about 2 to about 12 carbon atoms, alkylidene radicals of from 1 to 12 carbon atoms and cycloalkylidene radicals of from 3 to 12 carbon atoms; R' and R" are selected from substituted and unsubstituted alkylene radicals of from 2 to 12 carbon atoms, alkylene arylene radicals of from 8 to 12 carbon atoms and arylene radicals; X and X' are selected from hydrogen or any alkyl radical having from 1 to 4 carbon atoms; and each n is a number of from 0 (zero) to 4; and (3) carrier particles.Type: GrantFiled: March 20, 1985Date of Patent: January 6, 1987Assignee: Xerox CorporationInventors: John F. Knapp, Robert J. Gruber
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Patent number: 4609603Abstract: A process for generating consistent high quality images for extended periods, consisting essentially of (1) providing a xerographic imaging, or printing apparatus; (2) adding thereto a stable two component developer composition comprised of resin particles, first pigment particles, second magnetite pigment particles, which are present in a greater amount than the first pigment particles, and blended flow additive particles; and carrier particles consisting of a ferrite core, or a steel core and a coating thereover selected from the group consisting of terpolymers of styrene, methacrylate, and triethoxysilane; and polymethacrylate, which coating has incorporated therein conductive particles; (3) forming electrostatic latent images, or magnetic images in the apparatus; and (4) developing the images formed, wherein the developer composition retains its electrical properties for over 2.5 million imaging cycles.Type: GrantFiled: December 14, 1984Date of Patent: September 2, 1986Assignee: Xerox CorporationInventors: John F. Knapp, Robert J. Gruber, Lawrence Floyd, Jr., Steven B. Bolte
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Patent number: 4604338Abstract: Disclosed is an improved positively charged dry electrostatic colored toner composition comprised of first resin particles; crosslinked second resin particles; colored pigment particles excluding black; and selected from the group consisting of cyan, magenta, yellow, blue, red, and brown; a low molecular weight wax; and a charge enhancing additive selected from the group consisting of alkyl pyridinium halides, organic sulfonate compositions and organic sulfate compositions of the following formulas: ##STR1## wherein R is a hydrocarbon group containing from about 8 to about 22 carbon atoms, and A is an anion; ##STR2## wherein R.sub.1 is an alkyl group of from about 12 carbon atoms to about 22 carbon atoms, R.sub.2 and R.sub.3 are independently selected from alkyl groups containing from about 1 carbon atom to about 5 carbon atoms, R.sub.4 is an alkylene group of from about 1 carbon atom to about 5 carbon atoms, R.sub.Type: GrantFiled: August 9, 1985Date of Patent: August 5, 1986Assignee: Xerox CorporationInventors: Robert J. Gruber, Raymond A. Yourd, III, Ronald J. Koch
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Patent number: 4578338Abstract: An improved process for the development and fixing of electrostatic latent images which comprises (1) generating an electrostatic latent image on a photoconductive imaging member, (2) developing this image with a toner composition comprised of toner resin particles, pigment particles, and a wax component of a molecular weight of from about 500 to about 20,000, (3) transferring the developed image to a suitable substrate, and subsequently (4) fusing the transferred image with a compliant oil fuser roll, wherein the amount of fuser oil consumed is from about one microliter to about three microliters per page of developed image.Type: GrantFiled: August 31, 1984Date of Patent: March 25, 1986Assignee: Xerox CorporationInventors: Robert J. Gruber, Ronald J. Koch, John F. Knapp
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Patent number: 4565765Abstract: This invention is directed to an improved process for developing electrostatic latent images comprising (1) providing a development zone situated between an imaging member and a transporting member, comprised of a stationary shell containing rotating magnets therein, (2) transporting synthetic developer composition into the development zone by causing rotation of the magnets in the stationary shell, (3) effecting movement of the imaging member in a direction opposite to the direction of movement of the rotating magnets, wherein the developer composition is desirably agitated in the development zone by magnetic means, and wherein developer particles are available immediately adjacent the imaging member; the developer particles comprised of toner resin particles and carrier particles comprised of resin particles and magnetite; with the distance between the imaging member and stationary shell being from about 0.1 millimeter to about 1.5 millimeters.Type: GrantFiled: November 17, 1983Date of Patent: January 21, 1986Assignee: Xerox CorporationInventors: John F. Knapp, Leon A. Howland, Robert J. Gruber, Ronald J. Koch
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Patent number: 4563086Abstract: An electrophotographic printing machine in which a magnetic toner image is transferred to a copy sheet from a photoconductive member and fused thereto. The toner image fused to the copy sheet is magnetized and the intensity of the magnetic field generated by the toner image detected to provide a continuous indication of the quality of the toner image fused to the copy sheet.Type: GrantFiled: October 22, 1984Date of Patent: January 7, 1986Assignee: Xerox CorporationInventors: John F. Knapp, Robert J. Gruber, Steven B. Bolte
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Patent number: 4556624Abstract: Disclosed are improved positively charged electrostatic toner compositions comprised of a polyblend mixture of a crosslinked copolymer composition, and a second polymer, pigment particles, a wax component of a molecular weight of from 500 to about 20,000, and a charge enhancing additive. These compositions are particularly useful in imaging systems wherein release oils, such as silicone, are not required.Type: GrantFiled: September 27, 1984Date of Patent: December 3, 1985Assignee: Xerox CorporationInventors: Robert J. Gruber, Ronald J. Koch, John F. Knapp, Steven B. Bolte
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Patent number: 4539284Abstract: An improved infrared sensitive flash fusible colored toner composition comprised of (1) resin particles, (2) pigment particles selected from the group consisting of cyan, magenta, yellow, blue, red and green, and (3) additives selected from the group consisting of vanadyl phthalocyanines, naphthalocyanines, and the quaternary ammonium salts selected from the group consisting of 1,1',3,3,3',3 hexylmethyl-4,4',5,5'-dibenzo-2,2'-indotricarbocyanine perchlorate, 5,5'-dichloro-11-diphenylamine-3,3'-diethyl-10,12-ethylenethiatricarbocyan ine perchlorate, 1,1',3,3,3',3'-hexamethylindotricarbocyanine perchlorate, and 3,3'-di(3-acetoxypropyl)-11-diphenylamine-10,12-ethylene-5,6,5',6'-dibenzo thiatricarbocyanine perchlorate.Type: GrantFiled: April 16, 1984Date of Patent: September 3, 1985Assignee: Xerox CorporationInventors: Angello J. Barbetta, Robert J. Gruber, Louis V. Isganitis, Kock-Yee Law, John W. Lin, Ronald J. Koch, Steven T. Dunn
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Patent number: 4537848Abstract: Disclosed are improved positively charged toner composition comprised of resin particles, pigment particles, and as a charge enhancing additive a phosphonium compound of the formula: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, and R.sub.4, are selected from the group consisting of alkyl, aryl, substituted alkyl, and substituted aryl, and A is an anion.Type: GrantFiled: June 18, 1984Date of Patent: August 27, 1985Assignee: Xerox CorporationInventors: Raymond A. Yourd, III, Debesh Majumdar, Robert J. Gruber
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Patent number: 4520092Abstract: A process for obtaining smudge resistant images and for preventing the deposition of unwanted toner particles in an imaging apparatus which comprises(a) providing a xerographic imaging apparatus,(b) adding an improved two component contamination free developer composition to said apparatus, which composition consists essentially of from about 50 percent to about 80 percent by weight of a resin comprised of the polymeric esterification product of a dicarboxylic acid and a diol comprising a diphenol of the following formula ##STR1## wherein R is selected from substituted and unsubstituted alkylene radicals having from about 2 to about 12 carbon atoms, alkylidene radicals having from 1 to 12 carbon atoms and cycloalkylidene radicals having from 3 to 12 carbon atoms; R' and R" are selected from substituted and unsubstituted alkylene radicals having from 2 to 12 carbon atoms, alkylene arylene radicals having from 8 to 12 carbon atoms and arylene radicals; X and X'; are selected from hydrogen or any alkyl radical hType: GrantFiled: December 27, 1983Date of Patent: May 28, 1985Assignee: Xerox CorporationInventors: John F. Knapp, Robert J. Gruber
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Patent number: 4517268Abstract: Disclosed is an improved, simple, economical process for generating documents, such as personal checks, suitable for magnetic image character recognition, which process comprises generating such documents with conventional xerographic methods in a high speed electronic laser printing device, and wherein there is selected as the developer composition a magnetic toner containing from about 20 percent by weight to about 70 percent by weight of magnetite particles, and from about 30 percent by weight to about 80 percent by weight of toner resin particles of styrene copolymers, such as a styrene butadiene copolymer, a styrene n-butylmethacrylate copolymer, or polyesters, and wherein the carrier particles are comprised of ferrite cores, coated with various polymeric resinous compositions.Type: GrantFiled: September 12, 1983Date of Patent: May 14, 1985Assignee: Xerox CorporationInventors: Robert J. Gruber, John F. Knapp, Steven B. Bolte
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Patent number: 4493883Abstract: Disclosed are positively charged toner compositions comprised of resin particles, pigment particles, and imide charge enhancing additives of the formula: ##STR1## wherein R.sub.1, R.sub.2, and R.sub.3, are alkyl groups containing from 1 carbon atom to about 25 carbon atoms, R.sub.4 is selected from the group consisting of hydrogen, nitro, halogen, amino, and alkyl and A is an anion.Type: GrantFiled: February 21, 1984Date of Patent: January 15, 1985Assignee: Xerox CorporationInventors: Robert J. Gruber, Doretta Agostine, Paul C. Julien, Raymond A. Yourd, III
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Patent number: 4487825Abstract: This invention relates to a conductive single component magnetic dry toner comprised of resins selected from polystyrene allyl alcohol copolymers, and epoxy resins, a magnetic material such as magnetite, and a conductive carbon black which is adhered and/or embedded on the surface of the copolymer or epoxy resin-magnetic material mixture. Such toner compositions, which have excellent conductivity, superior flow properties and low melt fusing temperatures, 95.degree. C.-130.degree. C., are useful for causing the development of images in commercial printers and recorders such as the Versatec printers.Type: GrantFiled: January 22, 1981Date of Patent: December 11, 1984Assignee: Xerox CorporationInventors: Robert J. Gruber, John F. Knapp