Patents by Inventor Robert J. Pollet
Robert J. Pollet has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 4859565Abstract: Method for making images by image-wise exposing a silver halide emulsion layer, developing it with an alkaline processing solution in the presence of a silver halide solvent, development nuclei, and a density- and tone-controlling compound, transferring silver complexes from the emulsion layer to a non-light-sensitive image-receiving layer and forming an image therein, said density- and tone-controlling compound being contained in said image-receiving layer and/or in said processing solution and corresponding to the general formula: ##STR1## wherein R.sup.1, R.sup.2, and R.sup.3 (same or different) represent hydrogen, C.sub.1 -C.sub.8 alkyl, or Alk.sub.1 --X--Alk.sub.2 --Y--; Alk.sub.1 is (substituted) C.sub.1 -C.sub.8 alkyl; X is --O-- or --S--; Alk.sub.2 is (substituted) C.sub.1 -C.sub.8 alkylene; Y is a single bond, --O--, --S--, --CONH--, --SO.sub.2 NH--, or --NHCONH--; R.sup.3 can alternatively represent (substituted) C.sub.1 -C.sub.8 alkylthio; at least one of R.sup.1, R.sup.2, and R.sup.Type: GrantFiled: April 26, 1988Date of Patent: August 22, 1989Assignee: Agfa-Gevaert, N.V.Inventors: Rene M. De Keyzer, Robert J. Pollet, Leon L. Vermeulen
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Patent number: 4756990Abstract: A method of effecting high contrast development of an image-wise exposed photographic silver halide emulsion layer material wherein the developing proceeds in an aqueous medium having a pH of 10 to 12 and containing:(a)(i) hydroquinone or a substituted hydroquinone,(ii) an auxiliary developing agent having a developing activity of such degree as to give when utilized in the Standard Development Test defined in the specification a relative development rate (f.sub.x) in the range of about 1-2(b) free sulphite ions in an amount of at least 5 grams per liter of the medium,(c) an organic anti-fogging agent, and(d) a polymer containing a plurality of alkylene oxide units having a molecular weight of at least about 1500.Type: GrantFiled: March 24, 1986Date of Patent: July 12, 1988Assignee: AGFA-Gevaert N.V.Inventors: Richard A. Ooms, Robert J. Pollet
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Patent number: 4727017Abstract: Photographic element comprising a support and a silver halide emulsion layer comprising in said emulsion layer and/or in a water-permeable layer coated at the same side of the support as said emulsion layer a compound corresponding to the following general formula: ##STR1## wherein: each of R.sup.1, R.sup.2, and R.sup.3, which may be the same or different, can represent hydrogen, C.sub.1 -C.sub.8 alkyl, or Alk.sub.1 - X - Alk.sub.2 - Y -, wherein: Alk.sub.1 is C.sub.1 -C.sub.8 alkyl, which may be substituted, X is --O-- or --S--, Alk.sub.2 is C.sub.1 -C.sub.8 alkylene, which may be substituted, and Y is a single bond, --O--, --S--, --CONH--, --SO.sub.2 NH--, or --NHCONH--, R.sup.3 can alternatively represent C.sub.1 -C.sub.8 alkyl-thio, the C.sub.1 -C.sub.8 alkyl group of which can be substituted, at least one of R.sup.1, R.sup.2, and R.sup.3, however, being other than hydrogen and other than C.sub.1 -C.sub.8 alkyl.The invention disclosed includes compounds per se, which correspond to said general formula.Type: GrantFiled: January 29, 1986Date of Patent: February 23, 1988Assignee: Agfa-Gevaert, N.V.Inventors: Robert J. Pollet, Antoon L. Vandenberghe, Hendrik E. Kokelenberg, Piet Kok
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Patent number: 4720447Abstract: Method of making images by image-wise exposing a silver halide emulsion layer, developing it with an alkaline processing solution in the presence of a silver halide solvent and causing silver complexes to diffuse from the emulsion layer into a non-light-sensitive image-receiving layer in the presence of development nuclei thereby to form a silver transfer image in that layer, said transfer image formation occurring in the presence of at least one heterocyclic azole compound, which influences the density and tone of said transfer image, said compound being contained in said image-receiving layer and/or in said processing solution and being a heterocyclic azole corresponding to the general formula: ##STR1## wherein Y is .dbd.N-- or .dbd.HC--; Z represents atoms completing a heterocycle; A is a chemical bond or the group --(L.sup.1).sub.n --Alk--(L.sup.2).sub.m -- wherein n is 0 or 1, L.sup.Type: GrantFiled: October 9, 1986Date of Patent: January 19, 1988Assignee: AGFA-Gevaert, N.V.Inventors: Rene M. De Keyzer, Leon L. Vermeulen, Robert J. Pollet
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Patent number: 4600552Abstract: Film-forming cellulose ester compositions containing at least one solvent and at least one phosphate as stripping aid, said phosphate being a mono- or di-C.sub.12 -C.sub.20 alkyl phosphate, the non-esterified hydroxyl group(s) of which is (are) in the free acid form. The invention also relates to a method of manufacturing cellulose ester film, comprising adding to cellulose ester, at least one solvent and at least one above defined phosphate, casting the resulting film-forming cellulose ester composition on a smooth casting surface, and stripping said cellulose ester composition in the form of a film.Type: GrantFiled: March 21, 1985Date of Patent: July 15, 1986Assignee: Agfa-Gevaert, N.V.Inventors: Francis J. Sels, Josephus F. Paulussen, Robert J. Pollet
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Patent number: 4451555Abstract: The present invention deals with novel antifogging compounds and their use in a method of photographic reproduction comprising developing a photographic material having at least one exposed silver halide emulsion layer in the presence of a 1-phenyl-5-mercaptotetrazole compound wherein the phenyl group bears a substituent comprising at least one thioether function.Type: GrantFiled: November 25, 1981Date of Patent: May 29, 1984Assignee: AGFA-GEVAERT, N.V.Inventors: Robert J. Pollet, Antoon L. Vandenberghe, Roger A. Spriet
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Patent number: 4307175Abstract: A photographic material comprising in at least one light-sensitive silver halide emulsion layer and/or in a hydrophilic colloid layer in water-permeable relationship with such an emulsion layer an antifoggant precursor corresponding to one of the following general formulae: ##STR1## wherein: each of Y.sup.1 and Y.sup.2 (same or different) is an acyl groupeach of Y.sup.10 and Y.sup.20 (same or different) is an aromatic acyl group,R is an alkyl group, an aryl group or a heterocyclic nitrogen-containing 5-, 6- or 7-membered ring,R.sup.1 is hydrogen, an alkyl group, an aryl group, a carboxyl group in free acid, salt or esterified form, a carbamoyl group or a N-substitued carbamoyl group,R.sup.2 is hydrogen, an alkyl group or an aryl group,R.sup.3 has the same meaning as Y.sup.10, or is hydrogen, or is an alkyl group or an aryl group, or is a R.sup.7 -S- group wherein R.sup.7 is an alkyl group, an aryl group, or a heterocyclic group,R.sup.4 is hydrogen, an aryl group or a heterocyclic group,R.sup.Type: GrantFiled: September 10, 1980Date of Patent: December 22, 1981Assignee: AGFA-GEVAERT, N.V.Inventors: Robert J. Pollet, Hendrik E. Kokelenberg, Antoon L. Vandenberghe
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Patent number: 4292402Abstract: Fluorine-containing surfactants according to formula (Rf--X).sub.n --A--L--Z wherein Rf is a short-chain fluorine-containing group derived from hexafluoropropylene or trifluorochloroethylene, X is --O--, --S--, or --SO.sub.2 --, n is at least 2, the Rf groups being same or different, L is a monovalent bond or a bivalent bridging group such as --COO--alkylene, --CONR.sup.1 --alkylene, or --SO.sub.2 NR.sup.1 --alkylene, wherein R.sup.1 is hydrogen or C.sub.1 -C.sub.5 alkyl, and Z represents a hydrophilic polyoxyethylene group or a hydrophilic group such as ##STR1## wherein M is hydrogen, an alkali metal, ammonium, or organic ammonium, and R.sup.3 is alkyl; A is an aliphatic, aromatic, or aliphatic-aromatic group. These surfactants can be used in hydrophilic colloid layers, which may form part of light-sensitive silver halide materials.Type: GrantFiled: February 8, 1980Date of Patent: September 29, 1981Assignee: Agfa-Gevaert, N.V.Inventors: Robert J. Pollet, Hendrik E. Kokelenberg, Rafael P. Samijn, Francis J. Sels, Frans J. Ville, Nikolaas C. de Jaeger
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Patent number: 4292400Abstract: Photographic elements containing image-wise developable silver halide are developed in the presence of an oxathioether development activator according to the formula:R.sup.1 --A--(OCH.sub.2 CH.sub.2).sub.n --S--A'--(X--A").sub.m --Y--R.sup.2wherein:R.sup.1 is H, alkyl, hydroxyalkyl, or R.sup.2 --Y--(A"--X).sub.m --A'--S--,A, A', and A" is alkylene, with the proviso that A is a monovalent bond when R.sup.1 is hydrogen or alkyl or hydroxyalkyl,X is --OCO--, --SO.sub.2 --, --CONH--, or Y,Y is ligand or complexing function of the type of --S-- and --N(Q)-- (Q=H or alkyl),R.sup.2 is alkyl, which may be substituted by OH, or when Y is --N(Q)--, R.sup.2 together with Q may represent the atoms needed to complete a nitrogen-containing saturated ring,n is at least 2, and m is 0 or 1.The development activators can be used in black-and-white development or in color development. They can be incorporated in the photographic material or in the developing solution.Type: GrantFiled: September 10, 1980Date of Patent: September 29, 1981Assignee: Agfa-Gevaert, N.V.Inventors: Robert J. Pollet, Francis J. Sels, Karel A. Brems, Maurice A. de Ramaix
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Patent number: 4269923Abstract: Novel photographic imaging process and materials suitable therefor are provided, which can find their application in multi-color motion picture and simultaneous sound recording, in direct-positive image formation, in image-intensification processes, etc. A photographic silver image is formed in at least one hydrophilic colloid layer of a light-sensitive photographic material incorporating silver halide, by means of exposure and alkaline development steps, followed by bleaching of quantities of silver which are present in areas of said layer extraneous to those where imaging silver is required.Type: GrantFiled: January 22, 1980Date of Patent: May 26, 1981Assignee: AGFA-GEVAERT N.V.Inventors: Raymond A. Roosen, Robert J. Pollet, Antoon L. Vandenberghe
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Patent number: 4202695Abstract: Fine-grain silver halide emulsions of the Lippmann-type are described which comprise derivatives of heterocyclic mercaptans corresponding to the formulae: ##STR1## wherein: each of Z.sub.1 and Z.sub.2 represents the atoms necessary to complete a 5- or 6-membered heterocyclic ring system,n is 0 or 1,X is --CO-- or --CS--,R is an alkyl group or an aryl group, andY is --CO--, --COO--, --CS--, --SO.sub.2 --, --CON(R.sub.1)-- or --CSN(R.sub.1)--, R.sub.1 being hydrogen, alkyl or aryl.Both in reversal and negative processing sharpness of fine detail is improved and the distortion of image-details is reduced. Upon reversal processing yellow staining is also reduced.Type: GrantFiled: January 30, 1975Date of Patent: May 13, 1980Assignee: AGFA-GEVAERT N.V.Inventors: Herman A. Philippaerts, Robert J. Pollet, Wolfgang Muller-Bardorff, Wilhelm Saleck, Anita von Konig, Walter Gauss, Franz Moll, Theofiel H. Ghys
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Patent number: 4201585Abstract: The processing of exposed photographic silver halide color materials is described while using a bleach or bleach-fixing bath containing better bleach-accelerating compounds. The bleach-accelerating compounds are polyoxyethylene compounds comprising at least 20 mol % of recurring oxyethylene units, which carry a thioether group in a sidechain.Type: GrantFiled: October 17, 1978Date of Patent: May 6, 1980Assignee: Agfa-Gevaert, N.V.Inventors: Robert J. Pollet, Camille A. Vandeputte, Francis J. Sels, George F. van Veelen
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Patent number: 4186012Abstract: Non-diffusible thioether compounds capable of releasing, on reaction with color developer oxidation compounds, a diffusible silver halide development inhibitor without at the same time forming permanent dyes to any substantial extent are characterized by containing a group of the formula ##STR1## or its tautomeric form, wherein Z.sup.1 represents an electron attracting substituent and X represents an aliphatic, aromatic or heterocyclic group that if released together with the sulfur atom, forms a diffusible silver halide development inhibiting mercaptane.Type: GrantFiled: March 2, 1978Date of Patent: January 29, 1980Assignee: Agfa-Gevaert AktiengesellschaftInventors: Heinrich Odenwalder, Walter Puschel, Robert J. Pollet, Erwin Ranz
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Patent number: 4177071Abstract: Radiographic silver halide emulsions are provided comprising silver halide grains the average silver halide grain diameter of which is at least 250 nm and which consist substantially of silver bromide dispersed in a hydrophilic colloid binder e.g. gelatin wherein the silver halide grains have high primitive surface sensitivity for direct exposure to penetrating radiation and are substantially regular in shape and wherein the ratio of hydrophilic colloid to silver halide is at most about 1.0. These emulsions have high sensitivity for direct exposure to penetrating radiation and are themselves substantially insensitive to formation of pressure marks upon rapid processing.Type: GrantFiled: September 12, 1977Date of Patent: December 4, 1979Assignee: Agfa-Gevaert, N.V.Inventors: Luc A. De Brabandere, Hendrik A. Borginon, Herman A. Pattyn, Robert J. Pollet
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Patent number: 4138351Abstract: A liquid toner developer composition suitable for use in developing electrostatic charge patterns, characterized in that the developer contains a metal alkyl sulphonate ionic surfactant in which the metal ion is a bivalent metal ion selected from the group consisting of zinc(II), lead(II), cadmium(II) and copper(II) and the sulphonate group thereof is present directly on an alkyl chain containing at least 6 carbon atoms in a straight chain, which sulphonate has a positive charging effect on the toner, and the sizes of the toner particles and the amount in which said sulphonate is present are selected such that the toner can develop a charge pattern having a charge level corresponding to 50 V for a capacitance of 1.5.times.10.sup.-11 F.cm.sup.-2 up to an optical density of at least 0.8.Type: GrantFiled: September 14, 1976Date of Patent: February 6, 1979Assignee: AGFA-GEVAERT N.V.Inventors: Yvan K. Gilliams, Noel J. De Volder, Robert J. Pollet, Bernard H. Tavernier, Nikolaas C. De Jaeger, Francis J. Sels
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Patent number: 4132551Abstract: A method for producing photographic images by development of an exposed silver halide element at elevated temperature is provided wherein the development occurs in the presence of a non-quaternary, non-heterocyclic nitrobenzene compound of the formula: ##STR1## WHEREIN: (R).sub.n stands for one or more substituents selected from hydrogen, halogen, alkyl, substituted alkyl, alkenyl, substituted alkenyl, alkynyl, substituted alkynyl, alkoxy, substituted alkoxy, alkylmercapto, substituted alkylmercapto, amino, substituted amino, aryl, substituted aryl, hydroxy, nitro, cyano, sulpho or carboxy in acid or salt form, alkoxycarbonyl and an acyl group derived from a carboxylic or sulphonic acid.The nitrobenzene compounds have a favorable effect on the sensitometric properties of the silver halide emulsion that are developed at elevated temperature. They reduce the supplemental fog produced by development at elevated temperature.Type: GrantFiled: January 15, 1975Date of Patent: January 2, 1979Assignee: AGFA-GEVAERT N.V.Inventors: Robert J. Pollet, Robrecht J. Thiers, Theofiel H. Ghys, Antoon L. Vandenberghe, Herman A. Philippaerts, Hubert Vandenabeele
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Patent number: 4072523Abstract: A method is described of developing a photographic silver halide element containing developable silver halide by development in the presence of a development accelerator which is a compound corresponding to the following general formula and containing in its molecule at least one thioether sulphur atom linked to two carbon atoms: ##STR1## WHEREIN: R is hydrogen, hydroxy, hydroxyalkyl, alkoxy, alkylthio or alkylamino,Alk is en alkylene group which may be interrupted by --O--, --S--, or --N(Q)-- wherein Q is hydrogen or a C.sub.1 -C.sub.Type: GrantFiled: January 13, 1976Date of Patent: February 7, 1978Assignee: AGFA-GEVAERT, N.V.Inventors: Robert J. Pollet, Francis J. Seis, Camille A. Vandeputte