Patents by Inventor Robert J. Wittenbrink

Robert J. Wittenbrink has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 11441023
    Abstract: A film, preferably, a multi-layered film, including a polymer composition, wherein the polymer composition includes: within a range from 1 wt % to 25 wt % of a cyclic olefin copolymer based on the weight of the polymer composition, and within a range from 75 wt % to 99 wt % (the remainder of material) of a polyethylene based on the weight of the polymer composition, wherein the cyclic olefin copolymer has a glass transition temperature (T.sub.g) of at least 80.degree. C. The films may be used in shrink packaging application.
    Type: Grant
    Filed: April 27, 2018
    Date of Patent: September 13, 2022
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Keran Chen, Yong Yang, Ling Ge, Xiao-Chuan Wang, Zhen-Yu Zhu, LeiLei Ma, Xin Hao Cai, Gregory K. Hall, Caiguo Gong, Jean-Marc C. De Koninck, Robert J. Wittenbrink
  • Patent number: 11370902
    Abstract: Disclosed are propylene-based articles which can provide desired glossy surface including an impact copolymer substrate and a propylene-based elastomer body part overmolding, and a method of making such articles.
    Type: Grant
    Filed: June 7, 2018
    Date of Patent: June 28, 2022
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Bin Zhao, Na Li, Jie Hui Xu, William A. Ramsey, Robert J. Wittenbrink
  • Publication number: 20210363336
    Abstract: A film, preferably, a multi-layered film, comprising a polymer composition, wherein the polymer composition comprises: within a range from 1 wt % to 25 wt % of a cyclic olefin copolymer based on the weight of the polymer composition, and within a range from 75 wt % to 99 wt % (the remainder of material) of a polyethylene based on the weight of the polymer composition, wherein the cyclic olefin copolymer has a glass transition temperature (Tg) of at least 80° C. The films may be used in shrink packaging application.
    Type: Application
    Filed: April 27, 2018
    Publication date: November 25, 2021
    Inventors: Keran Chen, Yong Yang, Ling Ge, Xiao-Chuan Wang, Zhen-Yu Zhu, LeiLei Ma, Xin Hao Cai, Gregory K. Hall, Caiguo Gong, Jean-Marc C. De Koninck, Robert J. Wittenbrink
  • Publication number: 20200207961
    Abstract: Disclosed are propylene-based articles which can provide desired glossy surface including an impact copolymer substrate and a propylene-based elastomer body part overmolding, and a method of making such articles.
    Type: Application
    Filed: June 7, 2018
    Publication date: July 2, 2020
    Inventors: Bin Zhao, Na Li, Jie Hui Xu, William A. Ramsey, Robert J. Wittenbrink
  • Patent number: 10208143
    Abstract: Disclosed are polyethylene polymers with good melt strength that can provide enhanced properties for compositions including such polyethylene polymers and films made therefrom.
    Type: Grant
    Filed: August 14, 2015
    Date of Patent: February 19, 2019
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Wen Li, Steven A. Best, Robert J. Wittenbrink
  • Publication number: 20170233507
    Abstract: Disclosed are polyethylene polymers with good melt strength that can provide enhanced properties for compositions including such polyethylene polymers and films made therefrom.
    Type: Application
    Filed: August 14, 2015
    Publication date: August 17, 2017
    Applicant: ExxonMobil Chemical Patents Inc.
    Inventors: Wen Li, Steven A. Best, Robert J. Wittenbrink
  • Patent number: 7319083
    Abstract: A composition is provided that includes a product of combining, in the presence of a free radical initiator a catalyst precursor and at least one monomer wherein the monomer and the catalyst precursor are poiymerizable by free-radical polymerization and wherein the catalyst precursor compound is represented by the formula: wherein each X is an abstractable ligand; each R, R?, R?, R??, Rp1 and Rp2 is independently hydrogen or a hydrocarbyl group provided at least one of Rp1, Rp2, and R?? can be polymerized by a free radical initiator; and M is a Group-4-11 metal.
    Type: Grant
    Filed: October 24, 2003
    Date of Patent: January 15, 2008
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Guo-Xin Jin, Zerong Lin, Robert J. Wittenbrink, Chang-Kun Liu
  • Patent number: 7265193
    Abstract: This invention relates to a process to polymerize olefins comprising: contacting: (i) propylene and (ii) a mixture comprising, optionally ethylene, and three or more different alpha olefins having 4 to 20 carbon atoms, wherein at least one alpha olefin is present at Z percent or more, based upon the weight of the mixture, where Z=Y+X, where X=(100 divided by the number of alpha olefins present in the mixture) and Y equals 1 to 75, where Z is not more than 95%, with (iii) a metallocene catalyst system.
    Type: Grant
    Filed: January 13, 2004
    Date of Patent: September 4, 2007
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Weiqing Weng, Srivatsan Srinivas, Robert J. Wittenbrink
  • Patent number: 7176158
    Abstract: Copolymerization of Ni(H) or Co(II) acenaphthene diimine complexes containing olefinic substituents on aryl groups in the presence of a free radical initiator results in polymerized late transition metal catalysts which can be used for olefin polymerization or oligomerization. These catalysts have high catalyst activity for olefin polymerization or oligomerization.
    Type: Grant
    Filed: October 24, 2003
    Date of Patent: February 13, 2007
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Stanley Wai-Yan Chow, Guo-Xin Jin, Zerong Lin, Robert J. Wittenbrink, Dao Zhang
  • Patent number: 7119155
    Abstract: Copolymerization of Ni(II) phenol imine complexes containing olefinic substituents on aryl groups with styrene in the presence of a radical initiator results in polymerized late transition metal catalysts which can be used for olefin polymerization or oligomerization. These catalysts have high catalyst activity for olefin polymerization or oligomerization.
    Type: Grant
    Filed: October 24, 2003
    Date of Patent: October 10, 2006
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Stanley Wai-Yan Chow, Guo-Xin Jin, Zerong Lin, Robert J. Wittenbrink, Dao Zhang
  • Patent number: 6822131
    Abstract: Clean distillate useful as a diesel fuel or diesel blending stock is produced from Fischer-Tropsch wax by separating wax into heavier and lighter fractions; further separating the lighter fraction and hydroisomerizing the heavier fraction and that portion of the light fraction below about 500° F. The isomerized product is blended with the untreated portion of the lighter fraction.
    Type: Grant
    Filed: November 17, 1997
    Date of Patent: November 23, 2004
    Assignee: ExxonMobil Reasearch and Engineering Company
    Inventors: Paul J. Berlowitz, Robert J. Wittenbrink, Bruce R. Cook
  • Patent number: 6776898
    Abstract: A novel process for forming hydrocarbon waxes from synthesis gas is disclosed. This invention teaches a process whereby a Fischer-Tropsch wax can be formulated such that the wax softness as defined by ASTM Standard Test Method for Needle Penetration of waxes (ASTM D-1321) can be adjusted to within a region most preferred for end use applications while simultaneously removing undesirable impurities, such as oxygenates (e.g., primary alcohols), olefins, and trace levels of aromatics. In a Fischer-Tropsch reactor, Fischer-Tropsch wax is formed from synthesis gas in a catalyzed reaction. The Fischer Tropsch wax is then subjected to a relatively mild hydroprocessing over a hydroisomerization catalyst under conditions such that essentially no boiling point conversion is obtained, but yet chemical conversions (e.g., hydrogenation and mild isomerization) occur yielding a high purity, hydrocarbon wax product of reduced hardness.
    Type: Grant
    Filed: April 4, 2000
    Date of Patent: August 17, 2004
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Robert J. Wittenbrink, Daniel Francis Ryan
  • Publication number: 20040157728
    Abstract: Copolymerization of Fe(II) or Co(II) pyridine diimine complexes containing olefinic substituents on aryl groups with styrene in the presence of a radical initiator results in polymerized late transition metal catalysts which can be used for olefin polymerization or oligomerization. These catalysts have high catalyst activity for olefin polymerization or oligomerization.
    Type: Application
    Filed: October 24, 2003
    Publication date: August 12, 2004
    Inventors: Guo-Xin Jin, Zerong Lin, Robert J. Wittenbrink, Chang-Kun Liu
  • Publication number: 20040152591
    Abstract: Free-radical-initiated copolymerization of metallocene complexes containing olefinic substituents on aryl groups with styrene results in polymerized late transition metal catalysts that can be used for olefin polymerization or oligomerization. These catalysts have high catalyst activity for olefin polymerization or oligomerization.
    Type: Application
    Filed: October 24, 2003
    Publication date: August 5, 2004
    Inventors: Guo-Xin Jin, William M. Chien, Zerong Lin, Robert J. Wittenbrink, Guangyuan Zhou
  • Publication number: 20040152851
    Abstract: This invention relates to a process to polymerize olefins comprising:
    Type: Application
    Filed: January 13, 2004
    Publication date: August 5, 2004
    Inventors: Weiqing Weng, Srivatsan Srinivas, Robert J. Wittenbrink
  • Publication number: 20040147391
    Abstract: Copolymerization of Ni(II) phenol imine complexes containing olefinic substituents on aryl groups with styrene in the presence of a radical initiator results in polymerized late transition metal catalysts which can be used for olefin polymerization or oligomerization. These catalysts have high catalyst activity for olefin polymerization or oligomerization.
    Type: Application
    Filed: October 24, 2003
    Publication date: July 29, 2004
    Inventors: Stanley Wai-Yan Chow, Guo-Xin Jin, Zerong Lin, Robert J. Wittenbrink, Dao Zhang
  • Publication number: 20040147771
    Abstract: Copolymerization of Ni(II) or Co(II) acenaphthene imine complexes containing olefinic substituents on aryl groups with styrene in the presence of a radical initiator results in polymerized late transition metal catalysts which can be used for olefin polymerization or oligomerization. These catalysts have high catalyst activity for olefin polymerization or oligomerization.
    Type: Application
    Filed: October 24, 2003
    Publication date: July 29, 2004
    Inventors: Stanley Wai-Yan Chow, Guo-Xin Jin, Zerong Lin, Robert J. Wittenbrink, Dao Zhang
  • Patent number: 6755961
    Abstract: A Fischer-Tropsch derived distillate fraction is blended with either a raw virgin condensate fraction or a mildly hydrotreated virgin condensate to obtain a stable inhibited distillate fuel.
    Type: Grant
    Filed: July 25, 2000
    Date of Patent: June 29, 2004
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Paul J Berlowitz, Robert J. Wittenbrink, Bruce R. Cook
  • Patent number: 6695965
    Abstract: A wax blending process is disclosed which retains the desirable properties of a Fischer-Tropsch wax, while adjusting the hardness of the wax to within to a desired range. The invention utilizes a synergistic effect between hard virgin Fischer-Tropsch wax and softer mildly isomerized Fischer-Tropsch wax in a blending process which allows the artisan to adjust the hardness of a wax product to within desired ranges. The process involves passing a Fischer-Tropsch wax over a hydroisomerization catalyst under predetermined conditions including relatively mild temperatures such that chemical conversions (e.g., hydrogenation and mild isomerization) take place while less than 10% boiling point conversion (hydrocracking) occurs, thus preserving overall isomerized wax yield.
    Type: Grant
    Filed: April 4, 2000
    Date of Patent: February 24, 2004
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Robert J. Wittenbrink, Daniel Francis Ryan
  • Patent number: 6669743
    Abstract: Clean distillate useful as a jet fuel or jet blending stock is produced from Fischer-Tropsch wax by separating wax into heavier and lighter fractions; further separating the lighter fraction and hydroisomerizing the heavier fraction and that portion of the light fraction above about 475° F. The isomerized product is blended with the untreated portion of the lighter fraction to produce high quality, clean, jet fuel.
    Type: Grant
    Filed: February 27, 2001
    Date of Patent: December 30, 2003
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Robert J. Wittenbrink, Paul J Berlowitz, Bruce R. Cook