Patents by Inventor Robert Kunin

Robert Kunin has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 6340712
    Abstract: Non-chloride containing regenerant compositions of potassium acetate or potassium formate, at least one surfactant and at least one chelating agent as well as methods for efficient regeneration of water softeners utilizing the regenerant compositions are disclosed. A preferred regenerant composition is a solution of potassium acetate or potassium formate with citric acid and octyl phenol ethoxylate.
    Type: Grant
    Filed: February 10, 2000
    Date of Patent: January 22, 2002
    Assignee: Graver Technologies, Inc.
    Inventors: Robert Kunin, Peter A. Yarnell, Nichole L. Pennisi
  • Patent number: 6281255
    Abstract: Regeneration of weakly basic anion exchange resins with a combination of an alkali metal carbonate and an alkali metal bicarbonate is disclosed. Preferably, the alkali metal is sodium. The combination can be naturally available sodium sesquicarbonate.
    Type: Grant
    Filed: June 6, 2000
    Date of Patent: August 28, 2001
    Assignee: Graver Technologies, Inc.
    Inventors: Robert Kunin, Peter A. Yarnell, Nichole L. Pennisi
  • Patent number: 6217629
    Abstract: Provided herein are novel porous phosphate sulfur fertilizer particles which are in a continuous phase, and have applications in supplying soluble phosphates to plants and crops, thus increasing the yield of such crops. Also provided are novel methods of producing such porous phosphate sulfur fertilizer particles.
    Type: Grant
    Filed: April 15, 1999
    Date of Patent: April 17, 2001
    Assignee: Rutgers, The State University of New Jersey
    Inventor: Robert Kunin
  • Patent number: 6156942
    Abstract: A process for the preparation of an alkylene glycol by reacting an alkylene oxide with water in the presence of a solid catalytic composition which includes a strongly basic ion exchange resin coordinated with one or more anions, and a stabilising additive which is an acidic ion exchange resin. Preferably the acidic ion exchange resin is of the weakly acidic methacrylate type.
    Type: Grant
    Filed: December 14, 1998
    Date of Patent: December 5, 2000
    Assignee: Shell Oil Company
    Inventors: Michael Francis Lemanski, Eugene Marie Godfried Andre Van Kruchten, Robert Kunin
  • Patent number: 5840339
    Abstract: A salt comprising the reaction product of nicotinic acid and an anion exchange resin having a degree of crosslinking with divinylbenzene of less than 4%. These salts are useful in reducing blood cholesterol levels.
    Type: Grant
    Filed: September 3, 1992
    Date of Patent: November 24, 1998
    Inventor: Robert Kunin
  • Patent number: 5403492
    Abstract: The invention provides a method for removing metal oxides and colloidal material from high-resistivity water streams at a relatively high removal efficiency. The method includes hydrating a highly ionized dual morphology ion exchange resin in a macroreticular, desiccated morphology to produce a macroreticular, hydrated morphology. A water stream which is brought into contact with the resin is purified. The water stream may, optionally, also be contacted with both a cation exchange resin and an anion exchange resin.The invention additionally provides a method for selecting ion exchange resins which are particularly suited for use in removing metal oxides from a condensate stream. The method serves to narrow the field of candidates for pilot-scale resin testing with industrial water streams.
    Type: Grant
    Filed: September 1, 1993
    Date of Patent: April 4, 1995
    Assignee: The Graver Company
    Inventors: Eli Salem, Robert Kunin
  • Patent number: 5397477
    Abstract: The invention provides a method for removing metal oxides and colloidal material from high-resistivity water streams at a relatively high removal efficiency. The method includes hydrating a highly ionized dual morphology ion exchange resin in a macroreticular, desiccated morphology to produce a macroreticular, hydrated morphology. A water stream which is brought into contact with the resin is purified. The water stream may, optionally, also be contacted with both a cation exchange resin and an anion exchange resin.The invention additionally provides a method for selecting ion exchange resins which are particularly suited for use in removing metal oxides from a condensate stream. The method serves to narrow the field of candidates for pilot-scale resin testing with industrial water streams.
    Type: Grant
    Filed: January 11, 1993
    Date of Patent: March 14, 1995
    Assignee: The Graver Company
    Inventors: Eli Salem, Robert Kunin
  • Patent number: 5192446
    Abstract: The invention provides a method for removing transition metal oxides and soluble cation species from condensate at a relatively high removal efficiency. The method includes hydrating a strongly acidic dual morphology cation exchange resin in a macroeticular, desiccated morphology to produce a macroreticular, hydrated morphology. Condensate which is brought into contact with the resin when it is in a hydrogen form is purified. The condensate may, optionally, also be contacted with an anion exchange resin.The invention additionally provides a method for selecting cation exchange resins which are particularly suited for use in removing metal oxides from a condensate stream. The method serves to narrow the field of condidates for pilot-scale resin testing with industrial condensate.
    Type: Grant
    Filed: January 24, 1992
    Date of Patent: March 9, 1993
    Assignee: The Graver Company
    Inventors: Eli Salem, Robert Kunin
  • Patent number: 5022997
    Abstract: Methods for treating aqueous solutions and for recovering specific chemical products from an aqueous solution by ion exchange or adsorption by passing the aqueous solution through a regenerable filter bed comprising a flocculated mixture of finely divided active particulate material and filter aid materials having a depth of from about 3.0 inches to about 60 inches.
    Type: Grant
    Filed: December 18, 1989
    Date of Patent: June 11, 1991
    Assignee: The Graver Company
    Inventors: Eli Salem, Bruce L. Libutti, Robert Kunin
  • Patent number: 4747955
    Abstract: A method for removing impurities from a liquid utilizing a filter bed having polyester fibers which have been treated with a hot caustic solution to increase the hydrophilicity of the polyester fibers. The caustic solution preferably contains a surfactant to increase the initial wetting of the polyester fibers.
    Type: Grant
    Filed: April 13, 1987
    Date of Patent: May 31, 1988
    Assignee: The Graver Company
    Inventor: Robert Kunin
  • Patent number: 4629571
    Abstract: A layer of precoat filter aid material including powdered activated carbon removes oxygen and impurities from a liquid having hydrazine added thereto. Oxygen concentrations may be reduced to parts per billion concentrations. Suspended solids can be removed by the precoat layer, and if the precoat layer includes an active particulate material, either as a component of the precoat layer or as an underlayer, the concentration of impurities and dissolved solids in the liquid can also be reduced.
    Type: Grant
    Filed: September 11, 1985
    Date of Patent: December 16, 1986
    Assignee: The Graver Company
    Inventors: Eli Salem, Robert Kunin
  • Patent number: 4606894
    Abstract: A process and apparatus for recovering uranium from a carbonate solution containing uranium ions whereby the carbonate solution containing uranium ions is brought in contact with a cation exchanger so that a uranium cation is removed from solution and adsorbed by the cation exchanger, and the uranium cation is then removed from the cation exchanger. The treated carbonate solution from which uranium ions hve been removed by cation exchange is then further processed by removing carbon dioxide from the treated carbonate solution to produce a decarbonated solution, and passing the decarbonated solution through a membrane process to remove some remaining impurities.
    Type: Grant
    Filed: August 19, 1983
    Date of Patent: August 19, 1986
    Assignee: Ecodyne Corporation
    Inventors: Robert Kunin, Terrance LaTerra
  • Patent number: 4572742
    Abstract: A method for treating a sugar syrup to neutralize, decolorize and decalcify the sugar syrup during the clarification and decolorization process of sugar refining comprises contacting a sugar syrup with a neutralizing precoat filter layer disposed on a porous support means. The precoat filter layer comprises a liquid slurry constituted by an aqueous suspension of fibrous filter aid material and a neutralizing amount of particulate, crystalline alumino-siliate molecular sieve having an average particle size of less than 10 microns.
    Type: Grant
    Filed: September 28, 1983
    Date of Patent: February 25, 1986
    Assignee: The Graver Company
    Inventors: Robert Kunin, Eli Salem
  • Patent number: 4568466
    Abstract: A method for treating aqueous solutions by ion exchange uses a weakly acidic cation exchange resin to remove ammonia and other volatile amines along with corrosion products and metal ion leakage from a solution while substantially reducing the quantity of acid required to regenerate the cation exchange resin. The solution can be passed through a conventional mixed bed comprising a strongly acidic cation exchange resin and a strongly basic anion exchange resin after the pretreatment.
    Type: Grant
    Filed: December 13, 1983
    Date of Patent: February 4, 1986
    Assignee: The Graver Company
    Inventors: Eli Salem, Robert Kunin
  • Patent number: 4564455
    Abstract: The present invention relates to a method for purifying aqueous solutions or condensate in a three component resin system comprising a mixed bed of a strongly basic anion exchange resin, a strongly acidic cation exchange resin and a weakly acidic cation exchange resin. According to the present method, aqueous solutions can be treated to remove metal ions and corrosion products along with ammonia and other volatile amines so that metal ion leakage is substantially reduced and the run length of the resin system is increased. A method for separating and isolating the resins of the three component system is also described.
    Type: Grant
    Filed: December 13, 1983
    Date of Patent: January 14, 1986
    Assignee: The Graver Company
    Inventors: George C. Flynn, Eli Salem, Robert Kunin
  • Patent number: 4548717
    Abstract: A method for treating aqueous solutions by ion exchange uses a weakly acidic cation exchange resin and a strongly basic anion exchange resin to remove ammonia and other volatile amines along with corrosion products and metal ion leakage from a solution while substantially reducing the quantity of acid required to regenerate the cation exchange resin.
    Type: Grant
    Filed: December 13, 1983
    Date of Patent: October 22, 1985
    Assignee: The Graver Company
    Inventors: Robert Kunin, Eli Salem
  • Patent number: 4547291
    Abstract: A method for treating aqueous solutions by ion exchange uses a weakly acidic cation exchange resin and a strongly basic anion exchange resin to remove corrosion products and metal ion leakage from a solution while substantially reducing the quantity of acid required to regenerate the cation exchange resin. Substantial quantities of ammonia and other volatile amines are not removed from the solution during the treatment process.
    Type: Grant
    Filed: December 12, 1983
    Date of Patent: October 15, 1985
    Assignee: The Graver Company
    Inventors: Robert Kunin, Eli Salem
  • Patent number: 4187120
    Abstract: A method for purification of polyhydric alcohols such as sugar syrup by removing chromophoric components, trace metals, and other impurities comprising preparing a liquid slurry mixture of filter particles, including an anion exchange resin, a cation exchange resin, and a filter aid material, the anion and cation exchange resins being smaller than about 100 mesh (about 150 microns); precoating a porous support means with the slurry mixture; and passing the polyhydric alcohol through the precoat layer and the porous support means to purify the alcohol. A further embodiment includes the step of regenerating the precoat layer by delivering a brine solution having a pH between 7 and 10 through the precoat layer.
    Type: Grant
    Filed: May 30, 1978
    Date of Patent: February 5, 1980
    Assignee: Ecodyne Corporation
    Inventors: Robert Kunin, Louis I. Blaine
  • Patent number: 4116860
    Abstract: A composition for regenerating weak acid cation exchange resin comprising about 70-80 weight percent alkali metal chloride, about 5-15 weight percent alkali metal carbonate, and the balance an alkali metal chelating polycarboxylate and a method of regeneration comprising contacting the resin with a solution of the composition are disclosed.
    Type: Grant
    Filed: September 28, 1977
    Date of Patent: September 26, 1978
    Assignee: Rohm and Haas Company
    Inventor: Robert Kunin
  • Patent number: 4083782
    Abstract: Water is conditioned by contacting it with a weak acid cation exchange resin based upon a crosslinked methacrylic acid copolymer structure in the alkali metal (or ammonium) form. The resin when exhausted may be regenerated by either a two-step acid/alkali technique or by a one-step technique using a citric or fumaric acid solution or a poly or hexamethaphosphate solution. Water by this method is substantially free of hardness ion, dissolved heavy metal ions and has a corrected pH between 7 and 9.5, preferably between 8 and 8.5.
    Type: Grant
    Filed: November 4, 1974
    Date of Patent: April 11, 1978
    Assignee: Rohm and Haas Company
    Inventor: Robert Kunin