Abstract: Disclosed is an optimized system for more efficiently and economically producing terephthalic acid. The system includes an novel method for heating the slurry and/or reaction medium subjected to oxidative digestion.

Abstract: A process and apparatus for gas phase polymerization of olefins in a fluidized bed reactor are disclosed. The process and apparatus employ a vertically oriented fines ejector in order to reduce fouling and reactor downtime.

Abstract: A process is disclosed that relates to the recovery of a metal catalyst from an oxidizer purge stream produced in the synthesis of carboxylic acid, typically terephthalic. More particularly, the process involves recovery of a metal catalyst from an oxidizer purge stream through the use of a pressure filter, the combining of water with a mother liquor to recover the metal catalyst and then subjecting an aqueous mixture so formed to a single stage extraction with an extraction solvent to produce an extract stream comprising organic impurities and a raffinate stream comprising the metal catalyst.

Abstract: Polyester compositions are disclosed that include polyester polymers or copolymers having incorporated therein titanium nitride particles that improve the reheat properties of the compositions. Processes for making such compositions are also disclosed. The titanium nitride particles are made from titanium oxide particles by heating the titanium oxide particles in a nitrogen-containing gas to a temperature sufficient to convert at least a portion of the titanium oxide particles to titanium nitride particles. The particles are then mixed with a liquid carrier to obtain a slurry of titanium nitride particles, and the slurry is introduced to a polyester polymerization process to obtain a polyester composition having improved reheat.

Abstract: A process is disclosed that relates to the recovery of a metal catalyst from an oxidizer purge stream produced in the synthesis of carboxylic acid, typically terephthalic. More particularly, the process involves recovery of a metal catalyst from an oxidizer purge stream through the use of a pressure filter, the combining of water with a mother liquor to recover the metal catalyst and then subjecting an aqueous mixture so formed to a single stage extraction with an extraction solvent to produce an extract stream comprising organic impurities and a raffinate stream comprising the metal catalyst.

Abstract: Disclosed is an optimized process and apparatus for more efficiently and economically producing aromatic discarboxylic acids.

Abstract: In this invention, a process is provided by which a carboxylic acid/diol mixture suitable as starting material for a polyester production is obtained from a decolorized carboxylic acid solution without isolation of a substantially dry carboxylic acid solid. More specifically, in this invention, a process is provided by which a terephthalic acid/ethylene glycol mixture suitable as starting material for a polyester production is obtained from a decolorized terephthalic acid solution without isolation of a substantially dry terephthalic acid solid.

Abstract: Disclosed is an optimized system for more efficiently and economically producing terephthalic acid. The system includes an novel method for heating the slurry and/or reaction medium subjected to oxidative digestion.

Abstract: Disclosed is an optimized system for more efficiently and economically producing terephthalic acid. The system includes an oxidative digestion reactor/zone configured to provide optimized residence time distribution for the solid and liquid phases of the reaction medium processed therein.

Abstract: Disclosed is a process to produce a purified carboxylic acid product. The process comprises removing impurities from a crude carboxylic acid slurry in a solid-liquid displacement zone to form a slurry product. The slurry product if further treated in a staged oxidation zone.

Abstract: An apparatus and process for purifying crude particles of an aromatic dicarboxylic acid (e.g., crude terephthalic acid) via oxidative digestion in an agitated reactor. Purification and particle size of the particles exiting the digestion reactor are optimized by controlling the amount of mechanical agitation imparted to the reaction medium in the digestion reactor.

Abstract: The present invention relates to a process by which a carboxylic acid/diol mixture is obtained from a carboxylic acid/solvent slurry without isolation of a substantially dry carboxylic acid solid. More specifically, the present invention relates to a process by which a terephthalic acid/ethylene glycol mixture is obtained from a terephthalic acid/solvent slurry without isolation of a substantially dry terephthalic acid solid.

Abstract: A collapsible squeeze tube having a soft buffer member with a spout hole formed integral with and covered on the front side of the head in front of the collapsible tube body thereof for buffering flowing of the contained fluid material that is squeezed out of the collapsible tube body and the head by the user for application.

Abstract: The present invention relates to a process by which a carboxylic acid/diol mixture is obtained from a slurry or cake carboxylic acid product without isolation of a substantially dry carboxylic acid solid. More specifically, the present invention relates to a process by which a terephthalic acid/ethylene glycol mixture suitable as a starting material for polyester or co-polyester production is obtained from a slurry or cake terephthalic acid product without isolation of a substantially dry terephthalic acid solid.

Abstract: Disclosed is a method for the re-compression of process generated steam to create a higher pressure steam that is useful as a heating medium in other parts of a carboxylic acid production process or, in general utilized in another process. The invention comprises the following basic steps: (a) recovering thermal energy from at least a portion of the high temperature process stream resulting from an aromatic carboxylic acid production process in a first heat transfer zone to produce a low pressure stream; (b) subjecting the low pressure steam to a compression zone to generate an intermediate pressure steam; (c) utilizing the intermediate pressure steam as a heating medium, specifically within other parts of the carboxylic acid process or generally in another process thereby generating steam condensate; and (d) optionally, recycling all or part of the steam condensate to the second heat transfer zone for low pressure steam generation.

Abstract: Disclosed is a process for the production of terephthalic acid by a plurality of process steps including the catalyst oxidation of a dialkylbenzene compound, a second oxidation, a hydrogenation of the product of the second oxidation, and crystallization of the hydrogenation terephthalic acid using a plurality of series-connected crystallizers.

Abstract: A process and apparatus which reduces the fines in a liquid discharge stream and/or increases the dryness of a solids discharge stream while under a pressure equal to or greater than the vapor pressure of the liquid. There is provided a process for separating particles such as polyethylene terephthalate or polyethylene naphthalate from a liquid in a slurry comprising: a. feeding a slurry comprising solid particles and a liquid into a within a separation zone maintained at a pressure equal to or greater than the vapor pressure of the liquid; b.

Abstract: The present invention relates to a process by which a carboxylic acid/diol mixture is obtained from a carboxylic acid/solvent slurry without isolation of a substantially dry carboxylic acid solid. More specifically, the present invention relates to a process by which a terephthalic acid/ethylene glycol mixture is obtained from a terephthalic acid/solvent slurry without isolation of a substantially dry terephthalic acid solid.

Abstract: A process is disclosed that relates to the removal of impurities, specifically benzoic acid, from a mother liquor produced in the synthesis of carboxylic acid, typically terephthalic acid.

Abstract: A process is disclosed that relates to the removal of impurities, specifically benzoic acid, from a mother liquor produced in the synthesis of carboxylic acid, typically terephthalic acid.