Abstract: Adsorbents and methods of use thereof are provided. One representative, among others, includes an adsorbent having an alkali metal promoted, mixed trivalent layered double hydroxide (LDH) composition. When the mixed trivalent layered double hydroxide (LDH) composition is heated to a temperature ranging from about 300° C. to 450° C., an the adsorbent having an adsorption capacity of at least 0.8 millimoles of CO2 adsorbed per gram of adsorbent is formed.

Abstract: This invention relates to an improvement in a process for removing water from a hydride gas, and particularly ammonia, by contacting the hydride gas with a drying agent under conditions for effecting removal of the water. The improvement for significantly reducing the water content to trace levels in said hydride gas resides in the use of at least Group 1 metal oxide and at least one Group 2 metal oxide as a drying agent.

Abstract: This invention relates to an improvement in a process for removing water from a hydride gas, and particularly ammonia, by contacting the hydride gas with a drying agent under conditions for effecting removal of the water. The improvement for significantly reducing the water content to trace levels in said hydride gas resides in the use of at least Group 1 metal oxide and at least one Group 2 metal oxide as a drying agent.

Abstract: A process for separating a feed gas into at least one product gas includes: (a) providing a gas separation apparatus with at least one adsorption layer including a lithium-exchanged FAU adsorbent having water desorption characteristics, defined by drying curves, similar to those for the corresponding fully sodium-exchanged FAU, a heat of adsorption for carbon dioxide equal to or lower than that for the corresponding fully sodium-exchanged FAU at high loadings of carbon dioxide, and onto which the adsorption layer water and/or carbon dioxide adsorb; (b) feeding into the gas separation apparatus a feed gas including nitrogen, oxygen, and at least one of water and carbon dioxide; and (c) collecting from a product end of the gas separation apparatus at least one product gas containing oxygen.

Abstract: Xenon and/or krypton are recovered from oxygen containing gas, typically derived from liquid oxygen bottoms in a cryogenic air separation plant, by selective adsorption on a Li and Ag exchange zeolite containing 5 to 40% Ag exchange capacity on an equivalents basis, with periodic thermal regeneration of the adsorbent.

Abstract: A pressure swing adsorption process which comprises introducing a feed gas mixture into an inlet of an adsorber vessel during a feed period, wherein the feed gas mixture contains a more strongly adsorbable component and a less strongly adsorbable component and the adsorber vessel contains a bed of adsorbent material which selectively adsorbs the more strongly adsorbable component, and withdrawing a product gas enriched in the less strongly adsorbable component from an outlet of the adsorber vessel during at least a portion of the feed period, wherein a dimensionless cycle-compensated mass transfer coefficient defined as K tfeedVads/Vfeed is maintained in the range of about 23 to about 250.

Abstract: A process for separating a feed gas into at least one product gas includes: (a) providing a gas separation apparatus with at least one adsorption layer including a lithium-exchanged FAU adsorbent having water desorption characteristics, defined by drying curves, similar to those for the corresponding fully sodium-exchanged FAU, a heat of adsorption for carbon dioxide equal to or lower than that for the corresponding fully sodium-exchanged FAU at high loadings of carbon dioxide, and onto which the adsorption layer water and/or carbon dioxide adsorb; (b) feeding into the gas separation apparatus a feed gas including nitrogen, oxygen, and at least one of water and carbon dioxide; and (c) collecting from a product end of the gas separation apparatus at least one product gas containing oxygen.

Abstract: Xenon and/or krypton are recovered from oxygen containing gas, typically derived from liquid oxygen bottoms in a cryogenic air separation plant, by selective adsorption on a Li and Ag exchange zeolite containing 5 to 40% Ag exchange capacity on an equivalents basis, with periodic thermal regeneration of the adsorbent.

Abstract: Pressure swing adsorption process for the recovery of high purity oxygen from a feed gas comprising oxygen, nitrogen, and argon. The process includes a forward flow stage which comprises (a) passing the feed gas into a first adsorption zone containing an adsorbent selective for the adsorption of nitrogen over oxygen and argon, and withdrawing therefrom a nitrogen-depleted intermediate gas; (b) passing the nitrogen-depleted intermediate gas into a second adsorption zone containing an adsorbent which is selective for the adsorption of nitrogen over argon and selective for the adsorption of argon over oxygen; (c) withdrawing an oxygen-enriched product gas from the second adsorption zone; and (d) terminating the passing of feed gas into the first adsorption zone and withdrawing an oxygen-enriched depressurization gas from the second adsorption zone in the same flow direction as (c).

Abstract: Pressure swing adsorption process for the recovery of high purity oxygen from a feed gas comprising oxygen, nitrogen, and argon. The process includes a forward flow stage which comprises (a) passing the feed gas into a first adsorption zone containing an adsorbent selective for the adsorption of nitrogen over oxygen and argon, and withdrawing therefrom a nitrogen-depleted intermediate gas; (b) passing the nitrogen-depleted intermediate gas into a second adsorption zone containing an adsorbent which is selective for the adsorption of nitrogen over argon and selective for the adsorption of argon over oxygen; (c) withdrawing an oxygen-enriched product gas from the second adsorption zone; and (d) terminating the passing of feed gas into the first adsorption zone and withdrawing an oxygen-enriched depressurization gas from the second adsorption zone in the same flow direction as (c).

Abstract: An AgX-type zeolite having a silver exchange level of 20-70% and a Ar/O2 Henry's law selectivity ratio at 23° C. of 1.05 or greater has an optimum combination of selectivity for argon over oxygen at lower cost than higher silver exchange levels. This material can be used in oxygen VSA/PSA processes to produce oxygen at purities above 97%.

Abstract: An AgX-type zeolite having a silver exchange level of 20-70% and a Ar/O2 Henry's law selectivity ratio at 23° C. of 1.05 or greater has an optimum combination of selectivity for argon over oxygen at lower cost than higher silver exchange levels. This material can be used in oxygen VSA/PSA processes to produce oxygen at purities above 97%.