Patents by Inventor Robert McGuire
Robert McGuire has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 10870583Abstract: A process for preparing a zeolitic material containing YO2 and X2O3, where Y and X represent a tetravalent element and a trivalent element, respectively, is described. The process includes (1) a step of preparing a mixture containing one or more structure directing agents, seed crystals, and a first zeolitic material containing YO2 and X2O3 and having FAU-, GIS-, MOR-, and/or LTA-type framework structures; and (2) a step of heating the mixture for obtaining a second zeolitic material containing YO2 and X2O3 and having a different framework structure than the first zeolitic material. The mixture prepared in (1) and heated in (2) contains 1000 wt % or less of H2O based on 100 wt % of YO2 in the framework structure of the first zeolitic material. A zeolitic material obtainable and/or obtained by the process and its use are also described.Type: GrantFiled: December 13, 2017Date of Patent: December 22, 2020Assignee: BASF SEInventors: Robert McGuire, Mathias Feyen, Ulrich Mueller, Xinhe Bao, Weiping Zhang, Dirk De Vos, Hermann Gies, Feng-Shou Xiao, Toshiyuki Yokoi, Ute Kolb, Bernd Marler, Chuan Shi, Xiulian Pan, Xiangju Meng, Stefan Maurer, Yu Dai, Yong Wang, Trees De Baerdemaeker
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Publication number: 20200368734Abstract: The present invention relates to a composition comprising a) a molding comprising a zeolitic material having framework type CHA, wherein the zeolitic material comprises one or more alkaline earth metals M and b) a mixed metal oxide comprising chromium, zinc, and aluminium. It also relates to the use of the composition in a process for producing C2 to C4 olefins from syngas.Type: ApplicationFiled: August 8, 2018Publication date: November 26, 2020Inventors: Robert MCGUIRE, Achim WECHSUNG, Christiane KURETSCHKA, Ivana JEVTOVIKJ, Andreas KUSCHEL, Stephan A. SCHUNK
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Publication number: 20200360907Abstract: A process for preparing a zeolitic material having a framework structure type RTH and having a framework structure comprising a tetravalent element Y, a trivalent element X and oxygen, said process comprising (i) preparing a synthesis mixture comprising a zeolitic material having a framework structure type FAU and having a framework structure comprising the tetravalent element Y, the trivalent element X and oxygen, water, a source of a base, and an RTH framework structure type directing agent comprising a N-methyl-2, 6-dimethylpyridinium cation containing compound; (ii) subjecting the mixture obtained in (i) to hydrothermal crystallization conditions, obtaining the zeolitic material having a framework structure type RTHType: ApplicationFiled: January 22, 2019Publication date: November 19, 2020Applicant: BASF SEInventors: Robert MCGUIRE, Ulrich MUELLER, Xiangju MENG, Feng-Shou XIAO
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Publication number: 20200317532Abstract: A process for preparing a zeolitic material having a zeolitic framework structure which exhibits a molar ratio (aAl2O3):SiO2 or a crystalline precursor thereof, comprising (i) preparing a mixture comprising H2O, one or more compounds comprising Si from which SiO2 in the zeolitic framework structure is formed, said one or more compounds comprising a silica gel exhibiting a molar ratio (c H2O):SiO2 and optionally one or more compounds comprising Al from which Al2O3 in the zeolitic framework structure is formed; (ii) subjecting the mixture obtained in (i) to crystallization at a crystallization temperature in the range of from 110 to 350° C., preferably in the range of from 190 to 350° C., and for a crystallization time in the range of from 0.1 to 48 h.Type: ApplicationFiled: September 22, 2017Publication date: October 8, 2020Applicant: BASF SEInventors: Andrei-Nicolae PARVULESCU, Stefan MAURER, Yu DAI, UIrich MUELLER, Fengshou XIAO, Chaoqun BIAN, Robert MCGUIRE
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Publication number: 20200308083Abstract: Disclosed is a process for the alkylation of an aliphatic organic compound comprising: (a) providing a catalyst comprising one or more zeolitic materials having a BEA framework structure, wherein the BEA framework structure comprises YO2 and optionally comprises X2O3, wherein Y is a tetravalent element, and X is a trivalent element, (b) contacting the catalyst with one or more aliphatic organic compounds in the presence of one or more alkylating agents in one or more reactors for obtaining one or more alkylated organic compounds, wherein the one or more zeolitic materials are obtainable from a synthetic process which does not employ an organotemplate as structure directing agent.Type: ApplicationFiled: December 20, 2018Publication date: October 1, 2020Applicant: BASF SEInventors: Robert MCGUIRE, Andrei-Nicolae PARVULESCU, Ulrich MUELLER, Dirk DE VOS, Patrick TOMKINS
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Publication number: 20200224102Abstract: A zeolite fluid catalytic cracking catalyst is provided that passivates nickel and vanadium during catalytic cracking. The zeolite fluid catalytic cracking catalyst includes Y-faujasite crystallized in-situ from a metakaolin-containing calcined microsphere. The zeolite fluid catalytic cracking catalyst further includes an alumina-containing matrix obtained by calcination of a dispersible crystalline boehmite and a kaolin contained in the metakaolin-containing calcined microsphere, where the dispersible crystalline boehmite has a crystallite size of less than 500 ?. Also provided are a method of reducing contaminant coke and hydrogen yields and a method of catalytic cracking of heavy hydrocarbon feed stocks.Type: ApplicationFiled: March 19, 2020Publication date: July 16, 2020Inventors: Robert McGuire, Gary Smith, Bilge Yilmaz, Sven Serneels
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Patent number: 10683458Abstract: A method of cracking a hydrocarbon feed under fluid catalytic cracking conditions includes adding FCC compatible inorganic particles having a first particle type including one or more boron oxide components and a first matrix component into a FCC unit and adding cracking microspheres having a second particle type including a second matrix component, a phosphorus component and 20% to 95% by weight of a zeolite component into the FCC unit.Type: GrantFiled: September 18, 2017Date of Patent: June 16, 2020Assignee: BASF CORPORATIONInventors: Gary M. Smith, Robert McGuire, Jr., Bilge Yilmaz
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Publication number: 20200140354Abstract: The present invention relates to a process for the conversion of methanol in p-xylene comprising the use a molding which comprises a zeolitic material, phosphorous, one or more metals M of the groups 3, 6, 10 to 14 of the periodic system of the elements, and a binder material.Type: ApplicationFiled: April 24, 2018Publication date: May 7, 2020Inventors: Robert MCGUIRE, Christiane KURETSCHKA, Sven TITLBACH, Ekkehard SCHWAB, Ulrich MÜLLER
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Publication number: 20200139357Abstract: The present invention relates to a molding comprising a zeolitic material, phosphorous, one or more metals M of groups 3, 6, 10 to 14 of the periodic system of the elements, and a binder material. The molding is useful as a catalyst, in particular for preparing aromatic compounds from methanol with selectivity toward p-xylene.Type: ApplicationFiled: April 24, 2018Publication date: May 7, 2020Applicant: BASF SEInventors: Robert MCGUIRE, Christiane KURETSCHKA, Sven TITLBACH, Ekkehard SCHWAB, Ulrich MUELLER
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Patent number: 10633596Abstract: A zeolite fluid catalytic cracking catalyst is provided that passivates nickel and vanadium during catalytic cracking. The zeolite fluid catalytic cracking catalyst includes Y-faujasite crystallized in-situ from a metakaolin-containing calcined microsphere. The zeolite fluid catalytic cracking catalyst further includes an alumina-containing matrix obtained by calcination of a dispersible crystalline boehmite and a kaolin contained in the metakaolin-containing calcined microsphere, where the dispersible crystalline boehmite has a crystallite size of less than 500 ?. Also provided are a method of reducing contaminant coke and hydrogen yields and a method of catalytic cracking of heavy hydrocarbon feed stocks.Type: GrantFiled: September 13, 2016Date of Patent: April 28, 2020Assignee: BASF CorporationInventors: Robert McGuire, Gary M. Smith, Bilge Yilmaz, Sven Serneels
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Patent number: 10525451Abstract: Described are fluid catalytic cracking (FCC) compositions, methods of manufacture and use. FCC catalyst compositions comprise particles containing a non-zeolitic component and one or more boron oxide components. In embodiments, the FCC catalyst composition contains a zeolite component and optionally a rare earth component and a transition alumina. FCC catalytic compositions may comprise a first particle type containing one or more boron oxide components and a first matrix component mixed with a second particle type containing a second matrix component, and a zeolite. The FCC catalyst compositions can be used to crack hydrocarbon feeds, particularly resid feeds containing high V and Ni, resulting in lower hydrogen and coke yields.Type: GrantFiled: January 3, 2018Date of Patent: January 7, 2020Assignee: BASF CorporationInventors: Robert McGuire, Jr., Gary M. Smith, Bilge Yilmaz
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Publication number: 20190366313Abstract: The present invention relates to catalyst comprising one or more metal oxides and/or metalloid oxides and a zeolitic material having the CHA framework structure comprising YO2 and X2O3, wherein Y is a tetravalent element and X is a trivalent element, wherein the zeolitic material comprises one or more alkaline earth metals selected from the group consisting of Mg, Ca, Sr, Ba, and combinations of two or more thereof, and wherein the framework of the zeolitic material comprised in the catalyst contains substantially no phosphorous, as well as to a process for the preparation of a catalyst comprising one or more alkaline earth metals selected from the group consisting of Mg, Ca, Sr, Ba, and combinations of two or more thereof and to a catalyst obtainable therefrom. Furthermore, the present invention relates to a method for the conversion of oxygenates to olefins employing the inventive catalyst, as well as to the use of the inventive catalyst in specific applications.Type: ApplicationFiled: November 28, 2017Publication date: December 5, 2019Inventors: Robert MCGUIRE, Christiane JANKE, Ulrich MUELLER, Ekkehard SCHWAB
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Publication number: 20190300375Abstract: A process for preparing a zeolitic material containing YO2 and X2O3, where Y and X represent a tetravalent element and a trivalent element, respectively, is described. The process includes (1) a step of preparing a mixture containing one or more structure directing agents, seed crystals, and a first zeolitic material containing YO2 and X2O3 and having FAU-, GIS-, MOR-, and/or LTA-type framework structures; and (2) a step of heating the mixture for obtaining a second zeolitic material containing YO2 and X2O3 and having a different framework structure than the first zeolitic material. The mixture prepared in (1) and heated in (2) contains 1000 wt % or less of H2O based on 100 wt % of YO2 in the framework structure of the first zeolitic material. A zeolitic material obtainable and/or obtained by the process and its use are also described.Type: ApplicationFiled: December 13, 2017Publication date: October 3, 2019Applicant: BASF SEInventors: Robert MCGUIRE, Mathias FEYEN, Ulrich MUELLER, Xinhe BAO, Weiping ZHANG, Dirk DE VOS, Hermann GIES, Feng-Shou XIAO, Toshiyuki YOKOI, Ute KOLB, Bernd MARLER, Chuan SHI, Xiulian PAN, Xiangju MENG, Stefan MAURER, Yu DAI, Yong WANG, Trees DE BAERDEMAEKER
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Patent number: 10137442Abstract: A novel catalyst blend for processing of feedstocks into monoaromatics in a single stage, comprising at least one cracking catalyst, one heterogeneous transition metal catalyst, and optionally at least one hydrogenation catalyst. The process occurs in one-step or single stage with substantially no solvents or external additives, or when the feedstock contains less than 15% oxygen, the process includes additional water or steam to enable sufficient amounts of H2 being produced in-situ.Type: GrantFiled: May 25, 2017Date of Patent: November 27, 2018Assignee: BASF CORPORATIONInventor: Robert McGuire
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Patent number: 10086367Abstract: Described are fluid catalytic cracking (FCC) compositions, methods of manufacture and use. FCC catalyst compositions comprise catalytic microspheres containing a zeolite, a non-zeolitic component, and a rare earth component. The microspheres are modified with phosphorus. The FCC catalyst composition can be used to crack hydrocarbon feeds, particularly resid feeds containing high V and Ni, resulting in lower hydrogen and coke yields.Type: GrantFiled: February 7, 2017Date of Patent: October 2, 2018Assignee: BASF CORPORATIONInventors: Gary M. Smith, Robert McGuire, Jr., Bilge Yilmaz
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Publication number: 20180126365Abstract: Described are fluid catalytic cracking (FCC) compositions, methods of manufacture and use. FCC catalyst compositions comprise particles containing a non-zeolitic component and one or more boron oxide components. In embodiments, the FCC catalyst composition contains a zeolite component and optionally a rare earth component and a transition alumina. FCC catalytic compositions may comprise a first particle type containing one or more boron oxide components and a first matrix component mixed with a second particle type containing a second matrix component, and a zeolite. The FCC catalyst compositions can be used to crack hydrocarbon feeds, particularly resid feeds containing high V and Ni, resulting in lower hydrogen and coke yields.Type: ApplicationFiled: January 3, 2018Publication date: May 10, 2018Inventors: Robert McGuire, JR., Gary M. Smith, Bilge Yilmaz
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Patent number: 9895680Abstract: Described are fluid catalytic cracking (FCC) compositions, methods of manufacture and use. FCC catalyst compositions comprise particles containing a non-zeolitic component and one or more boron oxide components. In embodiments, the FCC catalyst composition contains a zeolite component and optionally a rare earth component and a transition alumina. FCC catalytic compositions may comprise a first particle type containing one or more boron oxide components and a first matrix component mixed with a second particle type containing a second matrix component, and a zeolite. The FCC catalyst compositions can be used to crack hydrocarbon feeds, particularly resid feeds containing high V and Ni, resulting in lower hydrogen and coke yields.Type: GrantFiled: December 19, 2013Date of Patent: February 20, 2018Assignee: BASF CORPORATIONInventors: Robert McGuire, Jr., Gary M. Smith, Bilge Yilmaz
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Publication number: 20180010054Abstract: A method of cracking a hydrocarbon feed under fluid catalytic cracking conditions includes adding FCC compatible inorganic particles having a first particle type including one or more boron oxide components and a first matrix component into a FCC unit and adding cracking microspheres having a second particle type including a second matrix component, a phosphorus component and 20% to 95% by weight of a zeolite component into the FCC unit.Type: ApplicationFiled: September 18, 2017Publication date: January 11, 2018Inventors: Gary M. Smith, Robert McGuire, JR., Bilge Yilmaz
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Publication number: 20170362513Abstract: A zeolite fluid catalytic cracking catalyst is provided that passivates nickel and vanadium during catalytic cracking. The zeolite fluid catalytic cracking catalyst includes Y-faujasite crystallized in-situ from a metakaolin-containing calcined microsphere. The zeolite fluid catalytic cracking catalyst further includes an alumina-containing matrix obtained by calcination of a dispersible crystalline boehmite and a kaolin contained in the metakaolin-containing calcined microsphere, where the dispersible crystalline boehmite has a crystallite size of less than 500 ?. Also provided are a method of reducing contaminant coke and hydrogen yields and a method of catalytic cracking of heavy hydrocarbon feed stocks.Type: ApplicationFiled: September 13, 2016Publication date: December 21, 2017Inventors: Robert McGuire, Gary M. Smith, Bilge Yilmaz, Sven Serneels
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Patent number: 9796932Abstract: Described are fluid catalytic cracking (FCC) compositions, methods of manufacture and use. FCC catalyst compositions comprise particles first particle type comprising one or more boron oxide components and a first matrix component and a second particle type having a composition different from the first particle type, the second particle type comprising a second matrix component, a phosphorus component and 20% to 95% by weight of a zeolite component. The FCC catalyst compositions can be used to crack hydrocarbon feeds, particularly resid feeds containing high V and Ni, resulting in lower hydrogen and coke yields.Type: GrantFiled: December 19, 2013Date of Patent: October 24, 2017Assignee: BASF CORPORATIONInventors: Gary M. Smith, Robert McGuire, Jr., Bilge Yilmaz