Patents by Inventor Robert McGuire

Robert McGuire has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 10870583
    Abstract: A process for preparing a zeolitic material containing YO2 and X2O3, where Y and X represent a tetravalent element and a trivalent element, respectively, is described. The process includes (1) a step of preparing a mixture containing one or more structure directing agents, seed crystals, and a first zeolitic material containing YO2 and X2O3 and having FAU-, GIS-, MOR-, and/or LTA-type framework structures; and (2) a step of heating the mixture for obtaining a second zeolitic material containing YO2 and X2O3 and having a different framework structure than the first zeolitic material. The mixture prepared in (1) and heated in (2) contains 1000 wt % or less of H2O based on 100 wt % of YO2 in the framework structure of the first zeolitic material. A zeolitic material obtainable and/or obtained by the process and its use are also described.
    Type: Grant
    Filed: December 13, 2017
    Date of Patent: December 22, 2020
    Assignee: BASF SE
    Inventors: Robert McGuire, Mathias Feyen, Ulrich Mueller, Xinhe Bao, Weiping Zhang, Dirk De Vos, Hermann Gies, Feng-Shou Xiao, Toshiyuki Yokoi, Ute Kolb, Bernd Marler, Chuan Shi, Xiulian Pan, Xiangju Meng, Stefan Maurer, Yu Dai, Yong Wang, Trees De Baerdemaeker
  • Publication number: 20200368734
    Abstract: The present invention relates to a composition comprising a) a molding comprising a zeolitic material having framework type CHA, wherein the zeolitic material comprises one or more alkaline earth metals M and b) a mixed metal oxide comprising chromium, zinc, and aluminium. It also relates to the use of the composition in a process for producing C2 to C4 olefins from syngas.
    Type: Application
    Filed: August 8, 2018
    Publication date: November 26, 2020
    Inventors: Robert MCGUIRE, Achim WECHSUNG, Christiane KURETSCHKA, Ivana JEVTOVIKJ, Andreas KUSCHEL, Stephan A. SCHUNK
  • Publication number: 20200360907
    Abstract: A process for preparing a zeolitic material having a framework structure type RTH and having a framework structure comprising a tetravalent element Y, a trivalent element X and oxygen, said process comprising (i) preparing a synthesis mixture comprising a zeolitic material having a framework structure type FAU and having a framework structure comprising the tetravalent element Y, the trivalent element X and oxygen, water, a source of a base, and an RTH framework structure type directing agent comprising a N-methyl-2, 6-dimethylpyridinium cation containing compound; (ii) subjecting the mixture obtained in (i) to hydrothermal crystallization conditions, obtaining the zeolitic material having a framework structure type RTH
    Type: Application
    Filed: January 22, 2019
    Publication date: November 19, 2020
    Applicant: BASF SE
    Inventors: Robert MCGUIRE, Ulrich MUELLER, Xiangju MENG, Feng-Shou XIAO
  • Publication number: 20200317532
    Abstract: A process for preparing a zeolitic material having a zeolitic framework structure which exhibits a molar ratio (aAl2O3):SiO2 or a crystalline precursor thereof, comprising (i) preparing a mixture comprising H2O, one or more compounds comprising Si from which SiO2 in the zeolitic framework structure is formed, said one or more compounds comprising a silica gel exhibiting a molar ratio (c H2O):SiO2 and optionally one or more compounds comprising Al from which Al2O3 in the zeolitic framework structure is formed; (ii) subjecting the mixture obtained in (i) to crystallization at a crystallization temperature in the range of from 110 to 350° C., preferably in the range of from 190 to 350° C., and for a crystallization time in the range of from 0.1 to 48 h.
    Type: Application
    Filed: September 22, 2017
    Publication date: October 8, 2020
    Applicant: BASF SE
    Inventors: Andrei-Nicolae PARVULESCU, Stefan MAURER, Yu DAI, UIrich MUELLER, Fengshou XIAO, Chaoqun BIAN, Robert MCGUIRE
  • Publication number: 20200308083
    Abstract: Disclosed is a process for the alkylation of an aliphatic organic compound comprising: (a) providing a catalyst comprising one or more zeolitic materials having a BEA framework structure, wherein the BEA framework structure comprises YO2 and optionally comprises X2O3, wherein Y is a tetravalent element, and X is a trivalent element, (b) contacting the catalyst with one or more aliphatic organic compounds in the presence of one or more alkylating agents in one or more reactors for obtaining one or more alkylated organic compounds, wherein the one or more zeolitic materials are obtainable from a synthetic process which does not employ an organotemplate as structure directing agent.
    Type: Application
    Filed: December 20, 2018
    Publication date: October 1, 2020
    Applicant: BASF SE
    Inventors: Robert MCGUIRE, Andrei-Nicolae PARVULESCU, Ulrich MUELLER, Dirk DE VOS, Patrick TOMKINS
  • Publication number: 20200224102
    Abstract: A zeolite fluid catalytic cracking catalyst is provided that passivates nickel and vanadium during catalytic cracking. The zeolite fluid catalytic cracking catalyst includes Y-faujasite crystallized in-situ from a metakaolin-containing calcined microsphere. The zeolite fluid catalytic cracking catalyst further includes an alumina-containing matrix obtained by calcination of a dispersible crystalline boehmite and a kaolin contained in the metakaolin-containing calcined microsphere, where the dispersible crystalline boehmite has a crystallite size of less than 500 ?. Also provided are a method of reducing contaminant coke and hydrogen yields and a method of catalytic cracking of heavy hydrocarbon feed stocks.
    Type: Application
    Filed: March 19, 2020
    Publication date: July 16, 2020
    Inventors: Robert McGuire, Gary Smith, Bilge Yilmaz, Sven Serneels
  • Patent number: 10683458
    Abstract: A method of cracking a hydrocarbon feed under fluid catalytic cracking conditions includes adding FCC compatible inorganic particles having a first particle type including one or more boron oxide components and a first matrix component into a FCC unit and adding cracking microspheres having a second particle type including a second matrix component, a phosphorus component and 20% to 95% by weight of a zeolite component into the FCC unit.
    Type: Grant
    Filed: September 18, 2017
    Date of Patent: June 16, 2020
    Assignee: BASF CORPORATION
    Inventors: Gary M. Smith, Robert McGuire, Jr., Bilge Yilmaz
  • Publication number: 20200140354
    Abstract: The present invention relates to a process for the conversion of methanol in p-xylene comprising the use a molding which comprises a zeolitic material, phosphorous, one or more metals M of the groups 3, 6, 10 to 14 of the periodic system of the elements, and a binder material.
    Type: Application
    Filed: April 24, 2018
    Publication date: May 7, 2020
    Inventors: Robert MCGUIRE, Christiane KURETSCHKA, Sven TITLBACH, Ekkehard SCHWAB, Ulrich MÜLLER
  • Publication number: 20200139357
    Abstract: The present invention relates to a molding comprising a zeolitic material, phosphorous, one or more metals M of groups 3, 6, 10 to 14 of the periodic system of the elements, and a binder material. The molding is useful as a catalyst, in particular for preparing aromatic compounds from methanol with selectivity toward p-xylene.
    Type: Application
    Filed: April 24, 2018
    Publication date: May 7, 2020
    Applicant: BASF SE
    Inventors: Robert MCGUIRE, Christiane KURETSCHKA, Sven TITLBACH, Ekkehard SCHWAB, Ulrich MUELLER
  • Patent number: 10633596
    Abstract: A zeolite fluid catalytic cracking catalyst is provided that passivates nickel and vanadium during catalytic cracking. The zeolite fluid catalytic cracking catalyst includes Y-faujasite crystallized in-situ from a metakaolin-containing calcined microsphere. The zeolite fluid catalytic cracking catalyst further includes an alumina-containing matrix obtained by calcination of a dispersible crystalline boehmite and a kaolin contained in the metakaolin-containing calcined microsphere, where the dispersible crystalline boehmite has a crystallite size of less than 500 ?. Also provided are a method of reducing contaminant coke and hydrogen yields and a method of catalytic cracking of heavy hydrocarbon feed stocks.
    Type: Grant
    Filed: September 13, 2016
    Date of Patent: April 28, 2020
    Assignee: BASF Corporation
    Inventors: Robert McGuire, Gary M. Smith, Bilge Yilmaz, Sven Serneels
  • Patent number: 10525451
    Abstract: Described are fluid catalytic cracking (FCC) compositions, methods of manufacture and use. FCC catalyst compositions comprise particles containing a non-zeolitic component and one or more boron oxide components. In embodiments, the FCC catalyst composition contains a zeolite component and optionally a rare earth component and a transition alumina. FCC catalytic compositions may comprise a first particle type containing one or more boron oxide components and a first matrix component mixed with a second particle type containing a second matrix component, and a zeolite. The FCC catalyst compositions can be used to crack hydrocarbon feeds, particularly resid feeds containing high V and Ni, resulting in lower hydrogen and coke yields.
    Type: Grant
    Filed: January 3, 2018
    Date of Patent: January 7, 2020
    Assignee: BASF Corporation
    Inventors: Robert McGuire, Jr., Gary M. Smith, Bilge Yilmaz
  • Publication number: 20190366313
    Abstract: The present invention relates to catalyst comprising one or more metal oxides and/or metalloid oxides and a zeolitic material having the CHA framework structure comprising YO2 and X2O3, wherein Y is a tetravalent element and X is a trivalent element, wherein the zeolitic material comprises one or more alkaline earth metals selected from the group consisting of Mg, Ca, Sr, Ba, and combinations of two or more thereof, and wherein the framework of the zeolitic material comprised in the catalyst contains substantially no phosphorous, as well as to a process for the preparation of a catalyst comprising one or more alkaline earth metals selected from the group consisting of Mg, Ca, Sr, Ba, and combinations of two or more thereof and to a catalyst obtainable therefrom. Furthermore, the present invention relates to a method for the conversion of oxygenates to olefins employing the inventive catalyst, as well as to the use of the inventive catalyst in specific applications.
    Type: Application
    Filed: November 28, 2017
    Publication date: December 5, 2019
    Inventors: Robert MCGUIRE, Christiane JANKE, Ulrich MUELLER, Ekkehard SCHWAB
  • Publication number: 20190300375
    Abstract: A process for preparing a zeolitic material containing YO2 and X2O3, where Y and X represent a tetravalent element and a trivalent element, respectively, is described. The process includes (1) a step of preparing a mixture containing one or more structure directing agents, seed crystals, and a first zeolitic material containing YO2 and X2O3 and having FAU-, GIS-, MOR-, and/or LTA-type framework structures; and (2) a step of heating the mixture for obtaining a second zeolitic material containing YO2 and X2O3 and having a different framework structure than the first zeolitic material. The mixture prepared in (1) and heated in (2) contains 1000 wt % or less of H2O based on 100 wt % of YO2 in the framework structure of the first zeolitic material. A zeolitic material obtainable and/or obtained by the process and its use are also described.
    Type: Application
    Filed: December 13, 2017
    Publication date: October 3, 2019
    Applicant: BASF SE
    Inventors: Robert MCGUIRE, Mathias FEYEN, Ulrich MUELLER, Xinhe BAO, Weiping ZHANG, Dirk DE VOS, Hermann GIES, Feng-Shou XIAO, Toshiyuki YOKOI, Ute KOLB, Bernd MARLER, Chuan SHI, Xiulian PAN, Xiangju MENG, Stefan MAURER, Yu DAI, Yong WANG, Trees DE BAERDEMAEKER
  • Patent number: 10137442
    Abstract: A novel catalyst blend for processing of feedstocks into monoaromatics in a single stage, comprising at least one cracking catalyst, one heterogeneous transition metal catalyst, and optionally at least one hydrogenation catalyst. The process occurs in one-step or single stage with substantially no solvents or external additives, or when the feedstock contains less than 15% oxygen, the process includes additional water or steam to enable sufficient amounts of H2 being produced in-situ.
    Type: Grant
    Filed: May 25, 2017
    Date of Patent: November 27, 2018
    Assignee: BASF CORPORATION
    Inventor: Robert McGuire
  • Patent number: 10086367
    Abstract: Described are fluid catalytic cracking (FCC) compositions, methods of manufacture and use. FCC catalyst compositions comprise catalytic microspheres containing a zeolite, a non-zeolitic component, and a rare earth component. The microspheres are modified with phosphorus. The FCC catalyst composition can be used to crack hydrocarbon feeds, particularly resid feeds containing high V and Ni, resulting in lower hydrogen and coke yields.
    Type: Grant
    Filed: February 7, 2017
    Date of Patent: October 2, 2018
    Assignee: BASF CORPORATION
    Inventors: Gary M. Smith, Robert McGuire, Jr., Bilge Yilmaz
  • Publication number: 20180126365
    Abstract: Described are fluid catalytic cracking (FCC) compositions, methods of manufacture and use. FCC catalyst compositions comprise particles containing a non-zeolitic component and one or more boron oxide components. In embodiments, the FCC catalyst composition contains a zeolite component and optionally a rare earth component and a transition alumina. FCC catalytic compositions may comprise a first particle type containing one or more boron oxide components and a first matrix component mixed with a second particle type containing a second matrix component, and a zeolite. The FCC catalyst compositions can be used to crack hydrocarbon feeds, particularly resid feeds containing high V and Ni, resulting in lower hydrogen and coke yields.
    Type: Application
    Filed: January 3, 2018
    Publication date: May 10, 2018
    Inventors: Robert McGuire, JR., Gary M. Smith, Bilge Yilmaz
  • Patent number: 9895680
    Abstract: Described are fluid catalytic cracking (FCC) compositions, methods of manufacture and use. FCC catalyst compositions comprise particles containing a non-zeolitic component and one or more boron oxide components. In embodiments, the FCC catalyst composition contains a zeolite component and optionally a rare earth component and a transition alumina. FCC catalytic compositions may comprise a first particle type containing one or more boron oxide components and a first matrix component mixed with a second particle type containing a second matrix component, and a zeolite. The FCC catalyst compositions can be used to crack hydrocarbon feeds, particularly resid feeds containing high V and Ni, resulting in lower hydrogen and coke yields.
    Type: Grant
    Filed: December 19, 2013
    Date of Patent: February 20, 2018
    Assignee: BASF CORPORATION
    Inventors: Robert McGuire, Jr., Gary M. Smith, Bilge Yilmaz
  • Publication number: 20180010054
    Abstract: A method of cracking a hydrocarbon feed under fluid catalytic cracking conditions includes adding FCC compatible inorganic particles having a first particle type including one or more boron oxide components and a first matrix component into a FCC unit and adding cracking microspheres having a second particle type including a second matrix component, a phosphorus component and 20% to 95% by weight of a zeolite component into the FCC unit.
    Type: Application
    Filed: September 18, 2017
    Publication date: January 11, 2018
    Inventors: Gary M. Smith, Robert McGuire, JR., Bilge Yilmaz
  • Publication number: 20170362513
    Abstract: A zeolite fluid catalytic cracking catalyst is provided that passivates nickel and vanadium during catalytic cracking. The zeolite fluid catalytic cracking catalyst includes Y-faujasite crystallized in-situ from a metakaolin-containing calcined microsphere. The zeolite fluid catalytic cracking catalyst further includes an alumina-containing matrix obtained by calcination of a dispersible crystalline boehmite and a kaolin contained in the metakaolin-containing calcined microsphere, where the dispersible crystalline boehmite has a crystallite size of less than 500 ?. Also provided are a method of reducing contaminant coke and hydrogen yields and a method of catalytic cracking of heavy hydrocarbon feed stocks.
    Type: Application
    Filed: September 13, 2016
    Publication date: December 21, 2017
    Inventors: Robert McGuire, Gary M. Smith, Bilge Yilmaz, Sven Serneels
  • Patent number: 9796932
    Abstract: Described are fluid catalytic cracking (FCC) compositions, methods of manufacture and use. FCC catalyst compositions comprise particles first particle type comprising one or more boron oxide components and a first matrix component and a second particle type having a composition different from the first particle type, the second particle type comprising a second matrix component, a phosphorus component and 20% to 95% by weight of a zeolite component. The FCC catalyst compositions can be used to crack hydrocarbon feeds, particularly resid feeds containing high V and Ni, resulting in lower hydrogen and coke yields.
    Type: Grant
    Filed: December 19, 2013
    Date of Patent: October 24, 2017
    Assignee: BASF CORPORATION
    Inventors: Gary M. Smith, Robert McGuire, Jr., Bilge Yilmaz