Abstract: A fiber optics based optical emission line monitoring system is provided in which selected spectral emission lines, such as the sodium emission line, may be detected in the presence of interfering background radiation. A combustion flame is fed by a diverted portion of a process stream and the common end of a bifurcated or quadfurcated fiber optic light guide is adapted to collect light from the flame. The light is guided through the branches of the fiber optic cable to bandpass filters, one of which is adapted to each of the branches of the fiber optic light guide. The bandpass filters are centered at wavelengths corresponding to the emission lines to be detected and two separate filters are required for each species being detected. The first filter has a bandwidth of about 3 nms and the second filter has a bandwidth of about 10 nms. Light detectors are located to view the light passing through the bandpass filters and amplifiers are connected to receive signals from the light detectors.