Abstract: A process for coating a cylinder or a liner of an internal combustion engine may involve a plasma assisted chemical vapour deposition (PACVD) technique. The process may include placing a component to be coated in a PACVD system; forming a negative pressure within the system in an inert atmosphere including argon, hydrogen, or a mixture thereof; activating a surface of the component at a bias voltage of 300 to 550 Vbias; performing an ionization of the component at a bias voltage of 800 to 1200 Vbias; depositing an adhesive layer having a precursor element on the surface of the component; depositing a transition layer having a gradient content of increasing amorphous carbon and decreasing precursor element; and depositing an upper layer composed of an amorphous carbon with the precursor element.