Patents by Inventor Robert Schulz

Robert Schulz has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20050053106
    Abstract: A nitric oxide-stimulation laser has an applicator packet (1) containing at least one diode chip (2) with dedicated emission of infrared (IR) light in wavelengths of predeterminedly proximate 1,550 nanometers for being eye safe and non-invasive with battery power for a duty cycle of one on and three off at a desired rate of repetition for operating periods of fifteen minutes with automatic shutoff. The IR laser light is generated by passing a set current current of predeterminedly proximate 160 milliamps axially through a diode chip of preferably GaInAsP/InP. From a light-emission end (14) of the diode chip, an astigmatic and non-coherent beam (12) of IR light is emitted and converted with a beam processor (10) to collimated light beams (13) for effectively deep penetrative entry into a select portion of an animate body (15) for stimulation of animate generation of nitric oxide for improvement of the animate body.
    Type: Application
    Filed: September 10, 2003
    Publication date: March 10, 2005
    Inventors: Raymond Herron, Robert Schulz, Noel Bouyett
  • Publication number: 20050013770
    Abstract: The present invention relates to a hydrogen storage container containing at least an hydrogen storage composition and hydrogen, the hydrogen including solid state hydrogen and gaseous hydrogen, the hydrogen storage composition including at least a portion of the solid state hydrogen and having an high equilibrium plateau pressure, wherein the solid state hydrogen defines at least 5% by weight of the total weight of the contained hydrogen, and wherein the gaseous hydrogen has a pressure greater than the high equilibrium plateau pressure and defines at least 5% by weight of the total weight of the contained hydrogen.
    Type: Application
    Filed: January 8, 2004
    Publication date: January 20, 2005
    Inventors: Robert Schulz, Guoxian Liang, Jacques Huot, Patrick Larochelle
  • Publication number: 20040247481
    Abstract: New alloys of the AB5 type are disclosed which are of the formula:
    Type: Application
    Filed: February 3, 2004
    Publication date: December 9, 2004
    Applicant: HERA, Hydrogen Storage Systems, Inc.
    Inventors: Guoxian Liang, Robert Schulz
  • Publication number: 20040111153
    Abstract: An intraocular lens having a light-transmitting optic (32, 94a, 94b, 142, 148, 216) comprised of a synthetic light-refractive material (40, 102) operably coupled with a flexible optic positioning member (34, 62, 74, 84, 100, 150, 210) to refract light onto the retina in order to correct refractive errors in the eye (10). The refractive material has an index of refraction of from about 1.36 to 1.5 or higher. The optic positioning member (34, 62, 74, 84, 100, 150, 210) is constructed of a flexible synthetic resin material such as polymethylmethacrylate and permits focusing upon objects located near to and far from the viewer. The optic (32, 94a, 94b, 142, 148, 216) of the present invention possess greater refractive capability than optics conventionally used in IOL construction, and permits retinal receipt of the image being viewed in order to correct refractive errors.
    Type: Application
    Filed: August 5, 2003
    Publication date: June 10, 2004
    Inventors: Randall Woods, Robert Schulz
  • Patent number: 6680042
    Abstract: Disclosed is a method for rapidly carrying out a hydrogenation of a material capable of absorbing hydrogen. It was discovered that when a powder of a material capable of absorbing hydrogen is ground under a hydrogen pressure, not at room temperature but at a higher temperature (about 300° C. in the case of magnesium) and in the presence of a hydrogenation activator such as graphite and optionally a catalyst, it is possible to transform completely the powder of this material into a hydride. Such a transformation is achieved in a period of time less than 1 hour whereas the known methods call for periods of time as much as 10 times longer. This is an unexpected result which gives rise to a considerable reduction in the cost of manufacture of an hydride, particularly MgH2.
    Type: Grant
    Filed: November 7, 2000
    Date of Patent: January 20, 2004
    Assignee: Hydro-Quebec
    Inventors: Robert Schulz, Salim Bouaricha, Jacques Huot, Daniel Guay
  • Patent number: 6620346
    Abstract: The invention concerns novel varistors based on zinc oxide and a method for making same, which consists in using as base products nanocrystalline powders obtained by high-intensity mechanical grinding and in subjecting the mixture resulting from said nanocrystalline powders a consolidating treatment such as sintering, in suitably selected temperature and time conditions so as to retain the smallest possible grain size of ZnO. The resulting varistors have a very fine homogeneous microstructure and an average grain size characteristically not more than 3 mu m, i.e. five times smaller than standard materials. Said novel varistors have a larger number of grain boundaries per length unit and therefore a much higher breakdown voltage. Said voltage is characteristically higher than 10 kV/cm and can reach 17 kV/cm which is almost one order of magnitude above the breakdown voltage of standard varistors.
    Type: Grant
    Filed: April 28, 2000
    Date of Patent: September 16, 2003
    Assignee: Hydro-Quebec
    Inventors: Robert Schulz, Sabin Boily, Alain Joly, André Van Neste, Houshang Alamdari
  • Patent number: 6582663
    Abstract: The invention concerns an apparatus for the titration and circulation of gases to determine metal hydride storing properties, with improved response time, greater dynamic range in terms of the usable amount of powder and the maximum pressure accessible and increased sensitivity. The invention also concerns a circulating apparatus considerably reducing the time for analysing and determining the properties of absorbent and adsorbent materials during a large number of adsorption-desorption cycles. Both sets of apparatus are provided with a reference tube inside their oven, near the sample-holder. Said sample-holder tube and reference tube are connected on either side of the differential pressure sensor, thereby considerably enhancing the overall performance of the titration system.
    Type: Grant
    Filed: November 22, 1999
    Date of Patent: June 24, 2003
    Assignee: Hydro-Quebec
    Inventors: Robert Schulz, Sabin Boily, Jacques Huot
  • Patent number: 6572836
    Abstract: An improved method is disclosed for producing gaseous hydrogen by subjecting a metal or a metal hydride to a chemical reaction. In this method, the metal or metal hydride subjected to the chemical reaction is nanocrystalline. Indeed, it has been found that when, instead of using conventional metal hydrides (Mg-based or others), use is made of a metal or metal hydride that is or has been subjected to intensive mechanical deformations, such as a metastable nanocrystalline metal hydride, then the chemical reaction, especially hydrolysis, will take place much more readily, at a much higher rate and, most of the time, up to completion.
    Type: Grant
    Filed: April 10, 2000
    Date of Patent: June 3, 2003
    Assignee: Hydro-Quebec
    Inventors: Robert Schulz, Jacques Huot, Guoxian Liang, Sabin Boily
  • Publication number: 20030042008
    Abstract: A method for storing hydrogen which combines the advantages of at least two known methods for storing hydrogen, selected amongst the methods for storing hydrogen in a gaseous form, in a liquid form and in a solid form.
    Type: Application
    Filed: June 29, 2001
    Publication date: March 6, 2003
    Inventors: Robert Schulz, Guoxian Liang, Jacques Huot, Patrick Larochelle
  • Publication number: 20020141939
    Abstract: Disclosed is a method for rapidly carrying out a hydrogenation of a material capable of absorbing hydrogen. It was discovered that when a powder of a material capable of absorbing hydrogen is ground under a hydrogen pressure, not at room temperature but at a higher temperature (about 300° C. in the case of magnesium) and in the presence of a hydrogenation activator such as graphite and optionally a catalyst, it is possible to transform completely the powder of this material into a hydride. Such a transformation is achieved in a period of time less than 1 hour whereas the known methods call for periods of time as much as 10 times longer. This is an unexpected result which gives rise to a considerable reduction in the cost of manufacture of an hydride, particularly MgH2.
    Type: Application
    Filed: April 2, 2002
    Publication date: October 3, 2002
    Applicant: HYDRO-QUEBEC
    Inventors: Robert Schulz, Salim Bouaricha, Jacques Huot, Daniel Guay
  • Patent number: 6277170
    Abstract: A power of an alloy of Ni and Mg, La, Be or Li, consisting of crystallites having a grain size lower than 100 nm and a crystalline structure allowing hydrogen absorption. This powder which is preferably obtained by mechanical grinding, may consist of cristallites of Mg2Ni, LaNi5 or of Ni-based alloys of Be or Li having a grain size lower than 100 nm. The powder may also consist of cristallites of formula Mg2−xNi1+x, x ranging from −0.3 to +0.3, which have a grain size lower than 100 nm, and preferably lower than 30 nm. This crystalline powder is particularly useful for storing and transporting hydrogen. Indeed, it has been discovered that such Ni-based nanocrystalline powder requires no or only one single activation treatment at low temperature to absorb hydrogen. It has also been discovered that the kinetic of absorption and diffusion of hydrogen within the powder is much faster. This can be explained by the presence of a large number of grain boundaries.
    Type: Grant
    Filed: December 2, 1999
    Date of Patent: August 21, 2001
    Assignees: Hydro-Quebec, McGill University
    Inventors: Robert Schulz, John Strom-Olsen, Leszek Zaluski
  • Patent number: 6254695
    Abstract: A ferromagnetic resonator for use in a marker in a magnetomechanical electronic article surveillance system has improved properties and can be manufactured at higher annealing speeds and reduced raw material cost by virtue of being continuously annealed in the simultaneous presence of a magnetic field perpendicular to the ribbon axis and a tensile stress applied along the ribbon axis and by providing an amorphous magnetic alloy containing iron, cobalt and nickel in which the portion of iron is more than about 15 at % and less than about 30 at %.
    Type: Grant
    Filed: August 13, 1998
    Date of Patent: July 3, 2001
    Assignee: Vacuumschmelze GmbH
    Inventors: Giselher Herzer, Robert Schulz
  • Patent number: 6239065
    Abstract: The invention is concerned with a process for the preparation of a supported catalyst having a nanocrystalline structure and a surface area preferably higher than 2 m2/g. The process comprises preparing by mechanical grinding a nanocrystalline material consisting of a metastable composite or alloy of at least two different elements or compounds containing at least one catalytic species and subjecting the nanocrystalline material to leaching with a leaching solution in order to eliminate totally or partially at least of one of the two elements or compounds, other than the at least one catalytic species. At least one further element or compound that is non-leachable and that acts as a support for the at least one catalytic species is added to the material during the grinding step or to the leaching solution during the leaching step.
    Type: Grant
    Filed: December 22, 1998
    Date of Patent: May 29, 2001
    Assignee: Hydro-Quebec
    Inventors: Robert Schulz, Guy Lalande, Marie-Chantal Denis, Jean-Pol Dödelet
  • Patent number: 6080381
    Abstract: Disclosed is a method for inducing desorption of hydrogen for a metal hydride by applying thereto sufficient energy to induce hydrogen desorption by endothermic reaction. The energy that is so-applied is non-thermal and selected from the group consisting of mechanical energy, ultrasonic energy, microwave energy, electric energy, chemical energy and radiation energy.
    Type: Grant
    Filed: March 15, 1999
    Date of Patent: June 27, 2000
    Assignees: Hydro Quebec, McGill University
    Inventors: Alicja Zaluska, Leszek Zaluski, John Strom-Olsen, Robert Schulz
  • Patent number: 6051046
    Abstract: A powder of an alloy of Ni and Mg, La, Be or Li, consisting of crystallites having a grain size lower than 100 nm and a crystalline structure allowing hydrogen absorption. This powder which is preferably obtained by mechanical grinding, may consist of cristallites of Mg.sub.2 Ni, LaNi.sub.5 or of Ni-based alloys of Be or Li having a grain size lower than 100 nm. The powder may also consist of cristallites of formula Mg.sub.2-x Ni.sub.1+x, x ranging from -0.3 to +0.3, which have a grain size lower than 100 nm, and preferably lower than 30 nm. This crystalline powder is particularly useful for storing and transporting hydrogen. Indeed, it has been discovered that such Ni-based nanocrystalline powder requires no or only one single activation treatment at low temperature to absorb hydrogen. It has also been discovered that the kinetic of absorption and diffusion of hydrogen within the powder is much faster. This can be explained by the presence of a large number of grain boundaries.
    Type: Grant
    Filed: May 29, 1998
    Date of Patent: April 18, 2000
    Assignees: Hydro-Quabac, McGill University
    Inventors: Robert Schulz, John Strom-Olsen, Leszek Zaluski
  • Patent number: 5964965
    Abstract: Disclosed is a very light-weight, Mg and Be-based material which has the ability to reversibly store hydrogen with very good kinetics. This material is of the formula (M.sub.1-x A.sub.x) D.sub.y wherein M is Mg, Be or a combination of them; A is an element selected from the group consisting of Li, Ca, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Al, Y, Zr, Nb, Mo, In, Sn, O, Si, B, C and F; D is a metal selected from the group consisting of Fe, Co, Ni, Ru, Rh, Pd, Ir and Pt (preferably Pd); x is a number ranging from 0 to 0.3; and y is a number ranging from 0 to 0.15. This material is in the form of a powder of particles of the formula M.sub.1-x A.sub.x as defined hereinabove, having an average size ranging from 0.1 to 100 .mu.m, each particle consisting of nanocrystalline grains having an average size of 3 to 100 nm or having a nano-layered structure with a layer spacing of 3 to 100 nm. Some of these particles have clusters of metal D attached thereto, with an average size ranging from 2 to 200 nm.
    Type: Grant
    Filed: August 15, 1997
    Date of Patent: October 12, 1999
    Assignees: Hydro-Quebec, McGill University
    Inventors: Robert Schulz, John Strom-Olsen, Leszek Zaluski, Alicja Zaluska
  • Patent number: 5906792
    Abstract: Disclosed is a nanocrystalline composite useful for hydrogen storage, which provides optimum hydrogenation conditions along with high hydrogen storage capacity. This composite is the combination of at least one high temperature metal hydride such as Mg or Mg.sub.2 Ni, which has a high hydrogen storage capacity by weight but requires high temperatures for hydrogen absorption and desorption, with at least one low temperature metal hydride such as FeTi, LaNi.sub.5, Nb, Mn or Pd, which has a low hydrogen storage capacity by weight but does not require high temperatures for hydrogen absorption and desorption. The high and low temperature metal hydrides are in direct contact with each other and each in the form of a nanocrystalline powder or layer. This composite is particularly useful as a hydrogen supply source for hydrogen-fueled vehicles.
    Type: Grant
    Filed: January 19, 1996
    Date of Patent: May 25, 1999
    Assignee: Hydro-Quebec and McGill University
    Inventors: Robert Schulz, Sabin Boily, Jacques Huot, John Strom-Olsen, Leszek Zaluski, Alicja Zaluska
  • Patent number: 5882623
    Abstract: Disclosed is a method for inducing desorption of hydrogen for a metal hydride by applying thereto sufficient energy to induce hydrogen desorption by endothermic reaction. The energy that is so-applied is non-thermal and selected from the group consisting of mechanical energy, ultrasonic energy, microwave energy, electric energy, chemical energy and radiation energy.
    Type: Grant
    Filed: May 13, 1996
    Date of Patent: March 16, 1999
    Assignees: Hydro Quebec, McGill University
    Inventors: Alicja Zaluska, Leszek Zaluski, John Strom-Olsen, Robert Schulz
  • Patent number: 5872074
    Abstract: Leached nanocrystalline materials having a high specific surface are particularly useful for storing hydrogen or as catalysts or electrocatalysts in the manufacture electrodes, especially for fuel cells. Such materials can be manufactured by preparing a nanocrystalline material consisting of a metastable composite or alloy of at least two different chemical elements. To be nanocrystalline, this material must have a crystalline structure with the grain size lower than 100 nm. Then, the so prepared nanocrystalline material can be subjected to a leaching treatment in order to eliminate partially or totally one of the elements of the composite or alloy. This leaching results in nanocrystalline materials having a porous structure and, thereby, the requested high specific surface.
    Type: Grant
    Filed: January 24, 1997
    Date of Patent: February 16, 1999
    Assignee: Hydro-Quebec
    Inventors: Robert Schulz, Guy Lalande, Jacques Huot, Marie-Chantal Denis, Guoxian Liang, Andre Van Neste, Daniel Guay, Jean-Pol Dodelet
  • Patent number: 5837030
    Abstract: A process is described for preparing a nanocrystalline powder of an alloy of at least two metals by an intensive mechanical grinding step performed upon powders of the metals which make up the alloy. The grinding is performed at atmospheric pressure under an inert atmosphere, and is carried out at a temperature in the range of 100.degree.-400.degree. C. In this manner, one obtains crystallites of the alloy having a grain size lower than 100 nm by grinding for a period of time lower by about an order of magnitude than the time necessary to achieve this grain size by a similar grinding step carried out at ambient temperature.
    Type: Grant
    Filed: November 20, 1996
    Date of Patent: November 17, 1998
    Assignee: Hydro-Quebec
    Inventors: Robert Schulz, Reynald Rioux, Sabin Boily, Jacques Huot