Patents by Inventor Roberto Zennaro

Roberto Zennaro has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 9890333
    Abstract: A reactor for Fischer-Tropsch reaction effected in a three-phase system essentially consisting of a gaseous reagent phase, a liquid reacted phase and a solid catalytic phase, wherein the solid catalytic phase is composed of packed bodies encaged in at least one open-cell foam structure with a high thermal conductivity.
    Type: Grant
    Filed: September 2, 2014
    Date of Patent: February 13, 2018
    Assignee: ENI S.p.A.
    Inventors: Gianpiero Groppi, Enrico Tronconi, Carlo Giorgio Visconti, Andrea Tasso, Roberto Zennaro
  • Patent number: 9403693
    Abstract: A process for the purification of an aqueous stream coming from the Fischer-Tropsch reaction using distillation and/or stripping treatment, a treatment with at least one inorganic base and a treatment with at least one organic base. This process allows at least a part of the aqueous stream coming from the Fischer-Tropsch reaction to be used as process water in the synthesis gas production plant, subsequently sent to the Fischer-Tropsch plant for the production of hydrocarbons.
    Type: Grant
    Filed: December 16, 2009
    Date of Patent: August 2, 2016
    Assignee: ENI S.p.A.
    Inventors: Lino Carnelli, Roberta Miglio, Roberto Zennaro
  • Publication number: 20160208175
    Abstract: A reactor for Fischer-Tropsch reaction effected in a three-phase system essentially consisting of a gaseous reagent phase, a liquid reacted phase and a solid catalytic phase, wherein the solid catalytic phase is composed of packed bodies encaged in at least one open-cell foam structure with a high thermal conductivity.
    Type: Application
    Filed: September 2, 2014
    Publication date: July 21, 2016
    Applicant: ENI S.p.A
    Inventors: Gianpiero GROPPI, Enrico TRONCONI, Carlo Giorgio VISCONTI, Andrea TASSO, Roberto ZENNARO
  • Patent number: 9387456
    Abstract: Reactor for Fischer-Tropsch reaction which is carried out in a three-phase system essentially consisting of a reacting gaseous phase, a reacted liquid phase and a solid catalytic phase, wherein the solid catalytic phase consists of packed or structured bodies of catalytic material encaged within at least one honeycomb monolithic structure with a high thermal conductivity.
    Type: Grant
    Filed: May 10, 2010
    Date of Patent: July 12, 2016
    Assignee: ENI S.p.A.
    Inventors: Massimo Iovane, Roberto Zennaro, Pio Forzatti, Gianpiero Groppi, Luca Lietti, Enrico Tronconi, Carlo Giorgio Visconti, Stefano Rossini, Elsa Mignone
  • Patent number: 9289725
    Abstract: Process for the purification of an aqueous stream coming from the Fischer-Tropsch reaction which comprises: feeding said aqueous stream containing the organic by products of the reaction to one or more pervaporation units, said one or more pervaporation units comprising at least one polymeric pervaporation membrane, obtaining two outgoing streams: —an aqueous stream (i) enriched in alcohols having from 1 to 8 carbon atoms, preferably from 2 to 4 carbon atoms; —an aqueous stream (ii) enriched in water.
    Type: Grant
    Filed: August 7, 2009
    Date of Patent: March 22, 2016
    Assignee: ENI S.p.A.
    Inventors: Roberta Miglio, Lino Carnelli, Gabriele Carlo Ettore Clerici, Roberto Zennaro
  • Publication number: 20130008774
    Abstract: Process for the purification of an aqueous stream coming from the Fischer-Tropsch reaction which comprises a distillation and/or stripping treatment, a treatment with at least one inorganic base and a treatment with at least one organic base. Said process allows at least a part of the aqueous stream coming from the Fischer-Tropsch reaction to be used as process water in the synthesis gas production plant, subsequently sent to the Fischer-Tropsch plant for the production of hydrocarbons.
    Type: Application
    Filed: December 16, 2009
    Publication date: January 10, 2013
    Inventors: Lino Carnelli, Roberta Miglio, Lino Locatelli, Roberto Zennaro, Palma Pizzocchi, Oliviero Perotti, Ines Perotti, Serafino Tonani
  • Publication number: 20120184631
    Abstract: Reactor for Fischer-Tropsch reaction which is carried out in a three-phase system essentially consisting of a reacting gaseous phase, a reacted liquid phase and a solid catalytic phase, wherein the solid catalytic phase consists of packed or structured bodies of catalytic material encaged within at least one honeycomb monolithic structure with a high thermal conductivity.
    Type: Application
    Filed: May 10, 2010
    Publication date: July 19, 2012
    Applicant: ENI S.p.A
    Inventors: Massimo Iovane, Roberto Zennaro, Pio Forzatti, Gianpiero Groppi, Luca Lietti, Enrico Tronconi, Carlo Giorgio Visconti, Stefano Rossini, Elsa Mignone
  • Publication number: 20110209391
    Abstract: Process for the purification of an aqueous stream coming from the Fischer-Tropsch reaction which comprises: feeding said aqueous stream containing the organic by products of the reaction to one or more pervaporation units, said one or more pervaporation units comprising at least one polymeric pervaporation membrane, obtaining two outgoing streams: —an aqueous stream (i) enriched in alcohols having from 1 to 8 carbon atoms, preferably from 2 to 4 carbon atoms; —an aqueous stream (ii) enriched in water.
    Type: Application
    Filed: August 7, 2009
    Publication date: September 1, 2011
    Applicant: ENI S.P.A.
    Inventors: Roberta Miglio, Lino Carnelli, Gabriele Carlo Ettore Clerici, Roberto Zennaro
  • Publication number: 20080287556
    Abstract: The preparation is described of a Fischer-Tropsch catalytic precursor based on cobalt supported on alumina, optionally containing up to 10% by weight of silica, which comprises: a) treatment of the alumina with a silicon compound selected from those having general formula (I) Si(OR)4-nR?n (I) wherein n ranges from 1 to 3 wherein R? is selected from primary hydrocarbyl radicals having from 1 to 20 carbon atoms; wherein R is selected from primary hydrocarbyl radicals having from 1 to 6 carbon atoms; b) drying and subsequent calcination of the modified carrier obtained at the end of step (a) thus obtaining a silanized carrier; c) subsequent deposition of cobalt on the silanized carrier obtained at the end of step (b); d) drying and subsequent calcination of the supported cobalt obtained at the end of step (c) thus obtaining the final catalytic precursor; the above final catalytic precursor having a content of SiO2 deriving from the compound having general formula (I) ranging from 4.5 to 10% by weight.
    Type: Application
    Filed: July 13, 2006
    Publication date: November 20, 2008
    Applicants: ENI S.P.A., INSTITUT FRANCAIS DU PETROLE
    Inventors: Giuseppe Bellussi, Luciano Cosimo Carluccio, Roberto Zennaro, Gastone Del Piero
  • Patent number: 7241815
    Abstract: A process is described for synthesising hydrocarbons from a mixture comprising carbon monoxide and hydrogen and possibly carbon dioxide CO2, in the presence of a supported catalyst comprising at least one group VIII metal. The support comprises zirconia or a mixed zirconia-alumina oxide and the zirconia is present in the quadratic and/or amorphous form. Said catalyst is used in a liquid phase in a three-phase reactor.
    Type: Grant
    Filed: March 10, 2005
    Date of Patent: July 10, 2007
    Assignees: Institut Francais du Petrole, ENI S.p.A.
    Inventors: Magalie Roy-Auberger, Renaud Revel, Virginie Tissot, Dan Ion Enache, Roberto Zennaro, Giovanni Pederzani
  • Patent number: 7176342
    Abstract: A method for the preparation of hydrogenated hydrocarbons comprising a preliminary treatment of natural gas with a catalyst at a high temperature and the subsequent hydrogenation of the mixture of cyclic and/or aromatic hydrocarbons formed.
    Type: Grant
    Filed: January 25, 2001
    Date of Patent: February 13, 2007
    Assignee: Enitecnologie S.p.A.
    Inventors: Giuseppe Bellussi, Alberto DelBianco, Luigina Maria Flora Sabatino, Roberto Zennaro, Mario Molinari
  • Publication number: 20050282917
    Abstract: A process is described for synthesising hydrocarbons from a mixture comprising carbon monoxide and hydrogen and possibly carbon dioxide CO2, in the presence of a supported catalyst comprising at least one group VIII metal. The support comprises zirconia or a mixed zirconia-alumina oxide and the zirconia is present in the quadratic and/or amorphous form. Said catalyst is used in a liquid phase in a three-phase reactor.
    Type: Application
    Filed: March 10, 2005
    Publication date: December 22, 2005
    Inventors: Magalie Roy-Auberger, Renaud Revel, Virginie Tissot, Dan Enache, Roberto Zennaro, Giovanni Pederzani
  • Patent number: 6977273
    Abstract: A process is described for synthesizing hydrocarbons from a mixture comprising carbon monoxide and hydrogen in the presence of a catalyst comprising at least one group VIII metal supported on a silica-alumina prepared by co-precipitating and calcining at a temperature in the range from about 500° C. to about 1200° C. for at least 6 hours so that said silica-alumina has a specific surface area of less than 260 m2/g. Said catalyst is used in a fixed bed or in suspension in a liquid phase of a three-phase reactor.
    Type: Grant
    Filed: February 15, 2002
    Date of Patent: December 20, 2005
    Assignees: Institut Francais du Petrole, ENI S.p.A., AGIP Petroli S.p.A.
    Inventors: Magalie Roy-Auberger, Philippe Courty, Renaud Revel, Roberto Zennaro
  • Patent number: 6689819
    Abstract: A supported cobalt-based catalyst, characterized in that the carrier has an average particle diameter, measured by Coulter LS230, ranging from 70 to 250 &mgr;m, a surface area higher than 175 m2/g and a pore volume higher than 0.35 cm3/g, measured by the B.E.T. method. The catalyst is particularly useful in the Fischer-Tropsch reaction.
    Type: Grant
    Filed: April 2, 2003
    Date of Patent: February 10, 2004
    Assignees: ENI S.p.A., AGIP Petroli S.p.A., Institut Francais du Petrole, Enitecnologie S.p.A.
    Inventors: Giuseppe Bellussi, Roberto Zennaro, Vincenzo Piccolo, Enrico Radaelli, Magalie Roy-Auberger
  • Publication number: 20040015025
    Abstract: Method for the preparation of hydrogenated hydrocarbons comprising a preliminary treatment of natural gas with a catalyst at a high temperature and the subsequent hydrogenation of the mixture of cyclic and/or aromatic hydrocarbons formed.
    Type: Application
    Filed: April 29, 2002
    Publication date: January 22, 2004
    Inventors: Giuseppe Bellussi, Alberto Del Bianco, Luigina Maria Flora Sabatino, Roberto Zennaro, Mario Molinari
  • Publication number: 20030203981
    Abstract: A supported cobalt-based catalyst is described, characterized in that the carrier has an average particle diameter, measured by means of Coulter LS230, ranging from 70 to 250 &mgr;m, a surface area higher than 175 m2/g and a pore volume higher than 0.35 cm3/g, measured with the B.E.T. method. The above catalyst is particularly useful in the Fischer-Tropsch reaction.
    Type: Application
    Filed: April 2, 2003
    Publication date: October 30, 2003
    Applicants: ENI S.p.A., AGIP PETROLI S.p.A., INSTITUT FRANCAIS DU PETROLE, ENITECNOLGIE S.p.A.
    Inventors: Giuseppe Bellussi, Roberto Zennaro, Vincenzo Piccolo, Enrico Radaelli, Magalie Roy-Auberger
  • Patent number: 6596667
    Abstract: A supported cobalt-based catalyst characterized in that the carrier has an average particle diameter, measured by means of Coulter LS230, ranging from 70 to 250 &mgr;m, a surface area higher than 175 m2/g and a pore volume higher than 0.35 cm3/g, measured with the B.E.T. method. The catalyst is useful in the Fischer-Tropsch reaction.
    Type: Grant
    Filed: March 1, 2001
    Date of Patent: July 22, 2003
    Assignees: Eni S.p.A., AGIP Petroli S.p.A., Institut Francais du Petrole, Enitecnologie S.p.A.
    Inventors: Giuseppe Bellussi, Roberto Zennaro, Vincenzo Piccolo, Enrico Radaelli, Magalie Roy-Auberger
  • Patent number: 6586481
    Abstract: A catalyst, which can be used in the Fischer-Tropsch process, and contains cobalt oxide having crystals with an average size ranging from 20 to 80 Å supported on an inert carrier of alumina. A preparation process for the catalyst and a Fischer-Tropsch process utilizing the catalyst are also provided.
    Type: Grant
    Filed: March 4, 2002
    Date of Patent: July 1, 2003
    Assignees: ENI S.p.A., AGIP Petroli S.p.A., Institut Francais du Petrole, Enitecnologie S.p.A.
    Inventors: Giovanni Pederzani, Roberto Zennaro, Sonia Morselli, Gastone Del Piero
  • Patent number: 6515035
    Abstract: A process is described for converting synthesis gas in the presence of a catalyst comprising at least one group VIII element dispersed on a support comprising alumina modified by aqueous impregnation of quaternary ammonium silicate and comprising in the range of about 3% by weight to about 9.5% by weight of silica. Said support can optionally also comprise at least one oxide selected from the group formed by rare earth oxides, alkaline-earth oxides and zirconium oxide.
    Type: Grant
    Filed: October 24, 2001
    Date of Patent: February 4, 2003
    Assignees: Institute Francais du Petrole, AGIP Petroli S.p.A., ENI S.p.A.
    Inventors: Magalie Roy-Auberger, Patrick Euzen, Vincent Zozaya, Roberto Zennaro, Giovanni Pederzani
  • Publication number: 20020183405
    Abstract: A catalyst is described, which can be used in the Fischer-Tropsch process, essentially consisting of cobalt oxide supported on an inert carrier essentially consisting of alumina, characterized in that the above cobalt oxide essentially consists of crystals having an average size ranging from 20 to 80 Å.
    Type: Application
    Filed: March 4, 2002
    Publication date: December 5, 2002
    Applicant: ENI S.p.A.
    Inventors: Giovanni Pederzani, Roberto Zennaro, Sonia Morselli, Gastone Del Piero