Abstract: Provided are methods for making shaped fluoropolymer by additive processing using a polymerizable binder. Also are 3D printable compositions for making shaped fluoropolymer articles and articles comprising a shaped fluoropolymer.

Abstract: A lightning protective seal cap comprising a seal cap that defines an interior, and a quantity of an uncured sealant that is curable by the application of actinic radiation so as to bind the seal cap to a fastener. The interior of the seal cap contains the quantity of uncured sealant, the seal cap is positionable over the fastener such that at least a portion of the fastener resides in the interior of the seal cap, and when the seal cap is in position over the fastener, the sealant containing seal cap prevents electrical arcing to the fastener from a lightning strike.

Abstract: A method of preparing a crosslinked pressure-sensitive adhesive is provided, including exposing at least one radiation crosslinkable pressure-sensitive adhesive composition to radiation from at least one light-emitting diode to crosslink the radiation crosslinkable pressure-sensitive adhesive composition. The crosslinked pressure-sensitive adhesive is optionally a hot melt processable pressure-sensitive adhesive. A radiation crosslinked pressure-sensitive adhesive is provided, prepared by the method. Also, an adhesive article is provided including a flexible backing layer and the radiation crosslinked pressure-sensitive adhesive prepared by the method. The crosslinked pressure-sensitive adhesive tends to exhibit high shear without sacrificing peel force or tack.

Abstract: A lightning protective seal cap comprising a seal cap that defines an interior, and a quantity of an uncured sealant that is curable by the application of actinic radiation so as to bind the seal cap to a fastener. The interior of the seal cap contains the quantity of uncured sealant, the seal cap is positionable over the fastener such that at least a portion of the fastener resides in the interior of the seal cap, and when the seal cap is in position over the fastener, the sealant containing seal cap prevents electrical arcing to the fastener from a lightning strike.

Abstract: The present disclosure provides methods and articles useful in sealing fasteners, including seal caps and methods of their use, and in particular light weight seal caps having higher dielectric breakdown strength, lower weight, and/or lower wall thickness. In some embodiments, the seal caps according to the present invention are made of a material having a dielectric breakdown strength of greater than 1.0 kV/mm, in some embodiments greater than 15.0 kV/mm, and in some embodiments greater than 50.0 kV/mm. In some embodiments, the seal caps according to the present invention are thin-walled, having an average wall thickness of less than 1.5 mm and in some embodiments less than less than 0.5 mm. In some embodiments, the seal cap comprises a polyurethane polymer, a polythioether polymer, a polysulfide polymer, a fluorinated thermoplastic polymer, a THV polymer, a fluorinated thermoset polymer, an engineering thermoplastic, and/or a PEEK polymer.

Abstract: The present disclosure provides methods and articles useful in sealing fasteners, including seal caps and methods of their use, and in particular light weight seal caps having higher dielectric breakdown strength, lower weight, and/or lower wall thickness. In some embodiments, the seal caps according to the present invention are made of a material having a dielectric breakdown strength of greater than 1.0 kV/mm, in some embodiments greater than 15.0 kV/mm, and in some embodiments greater than 50.0 kV/mm. In some embodiments, the seal caps according to the present invention are thin-walled, having an average wall thickness of less than 1.5 mm and in some embodiments less than less than 0.5 mm. In some embodiments, the seal cap comprises a polyurethane polymer, a polythioether polymer, a polysulfide polymer, a fluorinated thermoplastic polymer, a THV polymer, a fluorinated thermoset polymer, an engineering thermoplastic, and/or a PEEK polymer.

Abstract: An adhesive article comprising a poly(meth)acrylate-based primer layer and methods of making same. The article can include a backing, a primer layer located on a first major surface of the backing, and a silicone-based adhesive located on the primer layer. The primer layer can be derived from a primer precursor comprising poly(meth)acrylate functionalities. The method can include applying a primer precursor onto a first major surface of a backing, the primer precursor comprising a compound comprising poly(meth)acrylate functionalities; irradiating the primer precursor; applying an adhesive on the irradiated primer precursor; and irradiating the adhesive and the irradiated primer precursor to form a primer layer located between the adhesive and the first major surface of the backing.

Abstract: The present disclosure describes articles, such as medical articles, containing a substrate having disposed thereon a hydrophilic gel material (e.g., a shaped hydrophilic gel material or a coating of a hydrophilic gel material) and methods for making such articles. Methods are provided for making hydrophilic gel materials from a precursor composition that contains a polar solvent and a polymerizable material that is miscible with the polar solvent.

Abstract: The present disclosure provides methods for forming asymmetric membranes. More specifically, methods are provided for applying a polymerizable species to a porous substrate for forming a coated porous substrate. The coated porous substrate is exposed to an ultraviolet radiation source having a peak emission wavelength less than 340 nm to polymerize the polymerizable species forming a polymerized material retained within the porous substrate so that the concentration of polymerized material is greater at the first major surface than at the second major surface.

Abstract: A lightning protective seal cap comprising a seal cap that defines an interior, and a quantity of an uncured sealant that is curable by the application of actinic radiation so as to bind the seal cap to a fastener. The interior of the seal cap contains the quantity of uncured sealant, the seal cap is positionable over the fastener such that at least a portion of the fastener resides in the interior of the seal cap, and when the seal cap is in position over the fastener, the sealant containing seal cap prevents electrical arcing to the fastener from a lightning strike.

Abstract: The present disclosure provides methods and articles useful in sealing fasteners, including seal caps and methods of their use, and in particular light weight seal caps having higher dielectric breakdown strength, lower weight, and/or lower wall thickness. In some embodiments, the seal caps according to the present invention are made of a material having a dielectric breakdown strength of greater than 1.0 kV/mm, in some embodiments greater than 15.0 kV/mm, and in some embodiments greater than 50.0 kV/mm. In some embodiments, the seal caps according to the present invention are thin-walled, having an average wall thickness of less than 1.5 mm and in some embodiments less than less than 0.5 mm. In some embodiments, the seal cap comprises a polyurethane polymer, a polythioether polymer, a polysulfide polymer, a fluorinated thermoplastic polymer, a THV polymer, a fluorinated thermoset polymer, an engineering thermoplastic, and/or a PEEK polymer.

Abstract: Provided are methods for making shaped fluoropolymer by additive processing using a polymerizable binder. Also are 3D printable compositions for making shaped fluoropolymer articles and articles comprising a shaped fluoropolymer.

Abstract: The present disclosure provides methods and articles useful in sealing fasteners, including seal caps and in particular translucent or transparent seals or seal caps. In some embodiments, a seal cap which is optically translucent and optionally visibly transparent contains an uncured sealant, which is optionally optically translucent or visibly transparent, and is applied to a fastener. In some embodiments, the sealant is cured by application of actinic radiation to the sealant through the seal cap. In another aspect, a protected fastener construction is provided comprising: q) a fastener; r) a seal cap; and s) a cured sealant; wherein the sealant is optically translucent and optionally visibly transparent.

Abstract: The present disclosure provides methods and articles useful in sealing fasteners, including seal caps and methods of their use, and in particular light weight seal caps having higher dielectric breakdown strength, lower weight, and/or lower wall thick-ness. In some embodiments, the seal caps according to the present invention are made of a material having a dielectric breakdown strength of greater than 1.0 kV/mm, in some embodiments greater than 15.0 kV/mm, and in some embodiments greater than 50.0 kV/mm. In some embodiments, the seal caps according to the present invention are thin-walled, having an average wall thickness of less than 1.5 mm and in some embodiments less than less than 0.5 mm In some embodiments, the seal cap comprises a polyurethane polymer, a polythioether polymer, a polysulfide polymer, a fluorinated thermoplastic polymer, a THV polymer, a fluorinated thermo-set polymer, an engineering thermoplastic, and/or a PEEK polymer.

Abstract: A method of preparing a crosslinked pressure-sensitive adhesive is provided, including exposing at least one radiation crosslinkable pressure-sensitive adhesive composition to radiation from at least one light-emitting diode to crosslink the radiation crosslinkable pressure-sensitive adhesive composition. The crosslinked pressure-sensitive adhesive is optionally a hot melt processable pressure-sensitive adhesive. A radiation crosslinked pressure-sensitive adhesive is provided, prepared by the method. Also, an adhesive article is provided including a flexible backing layer and the radiation crosslinked pressure-sensitive adhesive prepared by the method. The crosslinked pressure-sensitive adhesive tends to exhibit high shear without sacrificing peel force or tack.

Abstract: An adhesive article comprising a poly(meth)acrylate-based primer layer and methods of making same. The article can include a backing, a primer layer located on a first major surface of the backing, and a silicone-based adhesive located on the primer layer. The primer layer can be derived from a primer precursor comprising poly(meth)acrylate functionalities. The method can include applying a primer precursor onto a first major surface of a backing, the primer precursor comprising a compound comprising poly(meth)acrylate functionalities; irradiating the primer precursor; applying an adhesive on the irradiated primer precursor; and irradiating the adhesive and the irradiated primer precursor to form a primer layer located between the adhesive and the first major surface of the backing.

Abstract: The present disclosure provides methods for forming asymmetric membranes. More specifically, methods are provided for applying a polymerizable species to a porous substrate for forming a coated porous substrate. The coated porous substrate is exposed to an ultraviolet radiation source having a peak emission wavelength less than 340 nm to polymerize the polymerizable species forming a polymerized material retained within the porous substrate so that the concentration of polymerized material is greater at the first major surface than at the second major surface.

Abstract: The present disclosure provides methods for forming asymmetric membranes. More specifically, methods are provided for applying a polymerizable species to a porous substrate for forming a coated porous substrate. The coated porous substrate is exposed to an ultraviolet radiation source having a peak emission wavelength less than 340 nm to polymerize the polymerizable species forming a polymerized material retained within the porous substrate so that the concentration of polymerized material is greater at the first major surface than at the second major surface.

Abstract: The present disclosure provides methods for forming asymmetric membranes. More specifically, methods are provided for applying a polymerizable species to a porous substrate for forming a coated porous substrate. The coated porous substrate is exposed to an ultraviolet radiation source having a peak emission wavelength less than 340 nm to polymerize the polymerizable species forming a polymerized material retained within the porous substrate so that the concentration of polymerized material is greater at the first major surface than at the second major surface.

Abstract: The present disclosure provides methods and articles useful in sealing fasteners, including seal caps and in particular translucent or transparent seals or seal caps. In some embodiments, a seal cap which is optically translucent and optionally visibly transparent contains an uncured sealant, which is optionally optically translucent or visibly transparent, and is applied to a fastener. In some embodiments, the sealant is cured by application of actinic radiation to the sealant through the seal cap. In another aspect, a protected fastener construction is provided comprising: q) a fastener; r) a seal cap; and s) a cured sealant; wherein the sealant is optically translucent and optionally visibly transparent.