Abstract: The invention concerns an additive manufacturing process by extrusion for forming a three-dimensional part with an additive manufacturing machine comprising a nozzle, the process comprising: i) providing a pseudo-amorphous composition having a glass temperature Tg; ii) softening the composition at a softening temperature above Tg and below 300° C. to form a softened composition which is fluid enough to flow and, extruding the softened composition from the nozzle to form an extruded part section; and, iii) solidifying the extruded part section; wherein the composition is based on a homopolymer or a copolymer of poly-ether-ketone-ketone, consisting of: at least an isophthalic (I) repeating unit, having the formula: and, in the case of the copolymer, a terephthalic (T) repeating unit, having the formula: wherein the molar proportion of T units relative to the sum of the T and I units ranges from 0% to 45% or from 55% to 65%.

Abstract: Sheets having thicknesses of from 1000 to 10,000 microns which are useful for the production of thermoformed semi-crystalline articles are based on polyaryletherketones having viscosities at 360° C. of at least about 400 Pas at 100 s?1 as measured by parallel plate rheometer. The polyaryletherketones are in a pseudo-amorphous state in the thermoformable sheets.

Abstract: The invention concerns a composite article, such as a mold part or an extrusion die, made of a composition comprising at least one polyarylether ketone and at least one thermally conductive filler, wherein the composite article has a thermal conductivity of at least 0.5 W/mK. The invention also concerns a composition and uses thereof.

Abstract: A method for making a high temperature composite, which is a carbon carbon composite, carbon fiber reinforced ceramic matrix composite, ceramic fiber reinforced ceramic matrix composite, or a carbon silica composite, including: a) providing a precursor part including a resin comprising a poly(aryl ether ketone) (PAEK) and at least one reinforcing material, wherein the resin has a degree of crystallinity of 10% or more; b) pyrolyzing the precursor part to a pyrolyzed part; c) infusing a liquid second resin into the pyrolyzed part to make an infused part; and d) pyrolyzing the infused part to make the carbon carbon composite carbon fiber reinforced ceramic matrix composite, ceramic fiber reinforced ceramic matrix composite, or the carbon silica composite, optionally repeating steps c. through d. Also, a carbon carbon composite, carbon fiber reinforced ceramic matrix composite, ceramic fiber reinforced ceramic matrix composite, or carbon silica composite made by the method.

Abstract: A method for making a carbon carbon, carbon ceramic matrix, or carbon silica composite, comprising melt processing a resin comprising a polyaryletherketone (PAEK) and at least one reinforcing additive to make a precursor part, pyrolyzing the precursor part to make a pyrolyzed part, infusing a liquid second resin into the pyrolyzed part to make an infused part, and pyrolyzing the infused part. Other methods comprise processing aligned reinforcing additives and a resin comprising a PAEK to make an aligned reinforcing additives PAEK, aligned 1-2 dimensional flake material, or aligned 1-2 dimensional platelet material, to create a fabric, prepreg or tape comprising the aligned reinforcing additives and impregnated PAEK. Other methods comprise impregnating continuous fiber tape or fabric with a resin comprising PAEK and at least one reinforcing additive or co-weaving a continuous fiber or fabric with a PAEK fiber comprising PAEK and at least one reinforcing additive.

Abstract: The invention relates to an additive manufacturing process by extrusion for forming a three-dimensional part in an additive manufacturing machine having a build environment, the process comprising: i) providing a composition comprising at least one poly-aryl-ether-ketone (PAEK) having a melt viscosity from about 200 Pa·s to about 1500 Pa·s, according to ASTM D3835-16, measured at a temperature of 320° C. and at a shear rate of 100 s?1, by capillary rheology using a 1 mm diameter, 15 mm long die; ii) extruding the composition in the build environment at an extrusion temperature equal to 330° C. or less, to form an extruded part section; and, iii) cooling the extruded part section in the build environment. The invention also relates to a filament and its use in said additive manufacturing process and the corresponding object obtainable from said additive manufacturing process.

Abstract: The present disclosure is directed to a gas phase adsorption device comprising a large annulus and a small annulus block wherein the small annulus block is concentrically positioned inside the large annulus block. The present disclosure is also directed to a method for the storage of gas.

Abstract: The invention relates to membranes formed from long chain branched fluoropolymers, and especially long chain branched homopolymers and copolymers of polyvinylidene fluoride such as KYNAR resins. The novel membranes retain all the advantages of a fluoropolymer membrane (excellent chemical resistance especially to strong acids and oxidizing agents, and good mechanical strength), and additionally offer improved permeability, improved strain hardening, and even better resistance to caustic attacks. The improvements are believed to be related to an improvement to the microstructure of the membranes, producing a more open structure due to the long chain branched fluoropolymers. Further improvements in the mechanical properties of the membranes can be induced by strain hardening.

Abstract: The present disclosure is directed to an immobilized media device and methods for making an immobilized media device. The present disclosure is also directed to methods for the separation of components of a media comprising filtering the media through an immobilized media device.

Abstract: Hollow fiber membranes having improved toughness and durability are prepared using a vinylidene fluoride polymer-containing component, such as Kynaro resins, having relatively low crystallinity. One aspect of the invention provides a membrane in the form of a fiber, wherein i) the fiber has a porous wall of a polymeric component enclosing a central hollow space extending the length of the fiber, ii) the polymeric component has a crystallinity as determined by wide angle x-ray diffraction of less than about 35%, iii) the polymeric component is comprised of at least one homopolymer or copolymer of vinylidene fluoride and iv) the membrane has an energy to break of at least about 0.5 J per square mm of membrane cross section.

Abstract: The invention relates to the use of a high performance thermoplastic polymer binder material for immobilizing adsorptive materials, such as activated carbon, in gas storage devices. The use of these binders, especially polyamide binders or polyvinylidene fluoride such as Kyblock™ resin, provides for high adsorbent packing density, low fouling solid structure that maximizes the volume of gas to the volume of the storage space.

Abstract: Hollow fiber membranes having improved toughness and durability are prepared using a vinylidene fluoride polymer-containing component, such as Kynaro resins, having relatively low crystallinity. One aspect of the invention provides a membrane in the form of a fiber, wherein i) the fiber has a porous wall of a polymeric component enclosing a central hollow space extending the length of the fiber, ii) the polymeric component has a crystallinity as determined by wide angle x-ray diffraction of less than about 35%, iii) the polymeric component is comprised of at least one homopolymer or copolymer of vinylidene fluoride and iv) the membrane has an energy to break of at least about 0.5 J per square mm of membrane cross section.

Abstract: The invention relates to membranes formed from long chain branched fluoropolymers, and especially long chain branched homopolymers and copolymers of polyvinylidene fluoride such as KYNAR resins. The novel membranes retain all the advantages of a fluoropolymer membrane (excellent chemical resistance especially to strong acids and oxidizing agents, and good mechanical strength), and additionally offer improved permeability, improved strain hardening, and even better resistance to caustic attacks. The improvements are believed to be related to an improvement to the microstructure of the membranes, producing a more open structure due to the long chain branched fluoropolymers. Further improvements in the mechanical properties of the membranes can be induced by strain hardening.