Abstract: In some aspects, a method for incremental hydrogen production includes separating in a first Pressure Swing Absorption (PSA) system an existing reformer synthesis gas product stream into a first hydrogen stream and a first waste stream. The first waste stream is compressed to at least 40 bar to produce a compressed waste stream. Water is removed from the compressed waste stream to produce a dried waste stream. Carbon dioxide is removed from the dried waste stream to produce a remaining waste stream, and the removed carbon dioxide is at least 85% of carbon dioxide in the existing reformer synthesis gas product stream. A second PSA system separates the remaining waste stream into a second hydrogen stream and a second waste stream, and the second hydrogen stream comprises at least 11% of hydrogen from the existing reformer synthesis gas product stream.

Abstract: The GTLpetrol Process for Maximum H2 Production. The GTLpetrol process uses a proprietary combination of two stage pressure swing adsorption hydrogen purification plus a C02 condensation removal step to give H2 recoveries in the range of 95% to 98% based on H2+CO from synthesis gas generation.

Abstract: An integrated plant for the conversion of a hydrocarbon gas such as natural gas to useful hydrocarbon liquid fuels and feed-stocks comprises an H2+CO syn-gas generation system which provides feed gas to a Fischer-Tropsch catalytic hydrocarbon synthesis system with an associated power and heat energy system.

Abstract: In some aspects, a method for incremental hydrogen production includes separating in a first Pressure Swing Absorption (PSA) system an existing reformer synthesis gas product stream into a first hydrogen stream and a first waste stream. The first waste stream is compressed to at least 40 bar to produce a compressed waste stream. Water is removed from the compressed waste stream to produce a dried waste stream. Carbon dioxide is removed from the dried waste stream to produce a remaining waste stream, and the removed carbon dioxide is at least 85% of carbon dioxide in the existing reformer synthesis gas product stream. A second PSA system separates the remaining waste stream into a second hydrogen stream and a second waste stream, and the second hydrogen stream comprises at least 11% of hydrogen from the existing reformer synthesis gas product stream.

Abstract: In various implementations, feed streams that include methane are reacted to produce synthesis gas. The synthesis gas may be further processed to produce ultrapure, high-pressure hydrogen streams.

Abstract: In some implementations, a system may include a compressor, a heat exchanger and an ITM. The compressor is configured to receive an air stream and compress the air stream to generate a pressurized stream. The heat exchanger is configured to receive the pressured stream and indirectly heat the pressurized stream using heat from an oxygen stream from an Ion Transport Membrane (ITM). The ITM is configured to receive the heated pressurized stream and generate an oxygen stream and the non-permeate stream, wherein the non-permeate stream is passed to a gas turbine burner and the oxygen stream is passed to the heat exchanger.

Abstract: In various implementations, feed streams that include methane are reacted to produce synthesis gas. The synthesis gas may be further processed to produce ultrapure, high-pressure hydrogen streams.

Abstract: In some implementations, one or more methods can include producing a hydrogen rich fuel gas for a gas turbine ballasted with nitrogen and steam and superheated to a temperature above its dew point. The fuel gas may have a minimal or reduced content of CO2 or fuel components CO and CH4 which contain carbon so that when combusted in a suitable gas turbine there may be minimal or reduced emissions of CO2 to the atmosphere. These example methods may result in a capture of the bulk of the carbon present in the total natural gas feed as CO2 compressed to pipeline delivery pressure for sequestration.

Abstract: In various implementations, methanol is produced using a (CO+H2) containing synthesis gas produced from a combined POX plus EHTR or a combined ATR plus EHTR at a pressure of 70 bar to 100 bar at the correct stoichiometric composition for methanol synthesis so that no feed gas compressor is required for the feed to the methanol synthesis reactor loop.

Abstract: A system may include a compressor, a heat exchanger and an ITM. The compressor is configured to receive an air stream and compress the air stream to generate a pressurized stream. The heat exchanger is configured to receive the pressured stream and indirectly heat the pressurized stream using heat from an oxygen stream from an Ion Transport Membrane (ITM). The ITM is configured to receive the heated pressurized stream and generate an oxygen stream and the non-permeate stream, wherein the non-permeate stream is passed to a gas turbine burner and the oxygen stream is passed to the heat exchanger.

Abstract: A hydrogen rich fuel gas for a gas turbine ballasted with nitrogen and steam can be produced and superheated to a temperature above its dew point. The fuel gas may have a minimal or reduced content of CO2 or fuel components CO and CH4 which contain carbon so that when combusted in a suitable gas turbine there may be minimal or reduced emissions of CO2 to the atmosphere. These example methods may result in a capture of the bulk of the carbon present in the total natural gas feed as CO2 compressed to pipeline delivery pressure for sequestration.

Abstract: In various implementations, methanol is produced using a (CO+H2) containing synthesis gas produced from a combined POX plus EHTR or a combined ATR plus EHTR at a pressure of 70 bar to 100 bar at the correct stoichiometric composition for methanol synthesis so that no feed gas compressor is required for the feed to the methanol synthesis reactor loop.

Abstract: An integrated plant for the conversion of a hydrocarbon gas such as natural gas to useful hydrocarbon liquid fuels and feed-stocks comprises an H2+CO syngas generation system which provides feed gas to a Fischer-Tropsch catalytic hydrocarbon synthesis system with an associated power and heat energy system.

Abstract: A system may include a compressor, a heat exchanger and an ITM. The compressor is configured to receive an air stream and compress the air stream to generate a pressurized stream. The heat exchanger is configured to receive the pressured stream and indirectly heat the pressurized stream using heat from an oxygen stream from an Ion Transport Membrane (ITM). The ITM is configured to receive the heated pressurized stream and generate an oxygen stream and the non-permeate stream, wherein the non-permeate stream is passed to a gas turbine burner and the oxygen stream is passed to the heat exchanger.

Abstract: In some implementations, one or more methods can include producing a hydrogen rich fuel gas for a gas turbine ballasted with nitrogen and steam and superheated to a temperature above its dew point. The fuel gas may have a minimal or reduced content of CO2 or fuel components CO and CH4 which contain carbon so that when combusted in a suitable gas turbine there may be minimal or reduced emissions of CO2 to the atmosphere. These example methods may result in a capture of the bulk of the carbon present in the total natural gas feed as CO2 compressed to pipeline delivery pressure for sequestration.

Abstract: In various implementations, feed streams that include ultrapure, high-pressure hydrogen streams and ultrapure, high-pressure nitrogen streams are reacted to produce ultrapure, high-pressure feed gas in a stoichiometric ratio to an ammonia synthesis reactor loop without or independent of including a methanol loop purge gas.

Abstract: Methods include producing a hydrogen rich fuel gas for a gas turbine ballasted with nitrogen and steam and superheated to a temperature above its dew point. The fuel gas may have a minimal or reduced content of CO2 or fuel components CO and CH4 which contain carbon so that when combusted in a suitable gas turbine there may be minimal or reduced emissions of CO2 to the atmosphere. These methods may result in a capture of the bulk of the carbon present in the total natural gas feed as CO2 compressed to pipeline delivery pressure for sequestration.

Abstract: In various implementations, methanol is produced using a (CO+H2) containing synthesis gas produced from a combined PDX plus EHTR or a combined ATR plus EHTR at a pressure of 70 bar to 100 bar at the correct stoichiometric composition for methanol synthesis so that no feed gas compressor is required for the feed to the methanol synthesis reactor loop.

Abstract: In various systems and processes, synthesis gas generation may be combined. A partial oxidation reactor (POX) and a gas convectively heated steam/hydrocarbon catalytic reformer (GHR) may be combined to produce synthesis gas. In some implementations, a partial oxidation reactor, a gas convectively heated steam/catalytic reformer, and a waste hat boiler may be combined to produce synthesis gas.

Abstract: In various implementations, various feed gas streams which include hydrogen and carbon monoxide may be processed for conversion to product streams. For example, the feed gas stream may be processed using the Fischer-Tropsch process or a methanol synthesis process. Unconverted hydrogen and carbon monoxide can be recycled at high recovery and/or inert components removed to prevent build-up in the recycle system by using an arrangement of pressure swing adsorption systems designed to recover impure product gas streams.