Patents by Inventor Rodney S. Ruoff
Rodney S. Ruoff has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 11879183Abstract: The present invention relates to a manufacturing method for single crystalline metal foil including: thermally treating poly-crystalline metal foil positioned to be spaced apart from a base to manufacture single crystalline metal foil, and a single crystalline metal foil manufactured thereby. According to the present invention, single crystalline metal foil having a large area may be obtained by thermally treating the poly-crystalline metal foil under a condition at which stress applied to the poly-crystalline metal foil is minimized.Type: GrantFiled: June 22, 2021Date of Patent: January 23, 2024Assignees: INSTITUTE FOR BASIC SCIENCE, UNIST (ULSAN NATIONAL INSTITUTE OF SCIENCE AND TECHNOLOGY)Inventors: Rodney S. Ruoff, Sunghwan Jin
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Publication number: 20210310149Abstract: The present invention relates to a manufacturing method for single crystalline metal foil including: thermally treating poly-crystalline metal foil positioned to be spaced apart from a base to manufacture single crystalline metal foil, and a single crystalline metal foil manufactured thereby. According to the present invention, single crystalline metal foil having a large area may be obtained by thermally treating the poly-crystalline metal foil under a condition at which stress applied to the poly-crystalline metal foil is minimized.Type: ApplicationFiled: June 22, 2021Publication date: October 7, 2021Inventors: Rodney S. RUOFF, Sunghwan JIN
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Patent number: 11078594Abstract: The present invention relates to a manufacturing method for single crystalline metal foil including: thermally treating poly-crystalline metal foil positioned to be spaced apart from a base to manufacture single crystalline metal foil, and a single crystalline metal foil manufactured thereby. According to the present invention, single crystalline metal foil having a large area may be obtained by thermally treating the poly-crystalline metal foil under a condition at which stress applied to the poly-crystalline metal foil is minimized.Type: GrantFiled: July 12, 2017Date of Patent: August 3, 2021Assignees: INSTITUTE FOR BASIC SCIENCE, UNIST(ULSAN NATIONAL INSTITUTE OF SCIENCE AND TECHNOLOGY)Inventors: Rodney S. Ruoff, Sunghwan Jin
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Publication number: 20190242028Abstract: The present invention relates to a manufacturing method for single crystalline metal foil including: thermally treating poly-crystalline metal foil positioned to be spaced apart from a base to manufacture single crystalline metal foil, and a single crystalline metal foil manufactured thereby. According to the present invention, single crystalline metal foil having a large area may be obtained by thermally treating the poly-crystalline metal foil under a condition at which stress applied to the poly-crystalline metal foil is minimized.Type: ApplicationFiled: July 12, 2017Publication date: August 8, 2019Inventors: Rodney S. RUOFF, Sunghwan JIN
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Publication number: 20180320987Abstract: Sugar alcohol blends of galactitol and mannitol and compositions comprising such blends are disclosed as phase change materials (PCMs). A method of forming carbon nanotubes on a carbon substrate is described. Carbon substrates with carbon nanotubes, in particular, conformal layers of carbon nanotubes on carbon substrates, are also disclosed, as are methods of making and using these materials. Thermal storage units are also provided. The thermal storage units can comprise a heat exchange path through which a heat exchange medium flows, and a thermal storage medium in thermal contact with the heat exchange path.Type: ApplicationFiled: July 9, 2018Publication date: November 8, 2018Inventors: Alexandre K. Da Silva, Evan Fleming, Li Shi, Christopher W. Bielawski, Rodney S. Ruoff, Shaoyi Wen, Hengxing Ji, Michael Pettes, Abhijit Paul, Eunsu Paek, Alexander J. Pak, Daniel P. Sellan
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Patent number: 10072355Abstract: A method of forming graphene single crystal domains on a carbon substrate is described.Type: GrantFiled: April 15, 2014Date of Patent: September 11, 2018Assignee: Board of Regents, The University of Texas SystemInventors: Luigi Colombo, Rodney S. Ruoff, Yufeng Hao
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Patent number: 10037855Abstract: Doped activated microwave expanded graphite oxide materials and doped monolayer graphene materials, and methods of making these materials. The materials exhibit increased capacitance relative to undoped activated microwave expanded graphite oxide and monolayer graphene. The materials are suitable for use in, for example, ultracapacitors.Type: GrantFiled: February 23, 2016Date of Patent: July 31, 2018Assignee: BOARD OF REGENTS, THE UNIVERSITY OF TEXAS SYSTEMInventors: Rodney S. Ruoff, Li Li Zhang, Meryl D. Stoller
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Publication number: 20170010512Abstract: A hybrid transparent conductive film, and methods for fabricating such hybrid transparent conductive films, involving the assembly of two-dimensional graphene-based materials with one-dimensional silver and/or copper nanowires with high optical transmittance and good electrical conductivity. The hybrid films are characterized by a good degree of control of the architecture at the nanoscale level, where the weakness(es) of each component are offset by the strengths of the other components. By rational design of the structure and using simple and locate-cost fabrication methods, hybrid films with sheet resistance of 26 ohm/sq and optical transmittance (at ?=550 nm) of 83% for reduced graphene oxide/silver nanowire films, and 64 ohm/sq and optical transmittance of 93.6% for monolayer graphene/silver nanowire films have been fabricated. These values are comparable to transparent conductive films based on indium tin oxide but are now able to be used in flexible electronics due to their good mechanical properties.Type: ApplicationFiled: September 21, 2016Publication date: January 12, 2017Inventors: Rodney S. Ruoff, Iskandar Kholmanov
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Patent number: 9477128Abstract: A hybrid transparent conductive film, and methods for fabricating such hybrid transparent conductive films, involving the assembly of two-dimensional graphene-based materials with one-dimensional silver and/or copper nanowires with high optical transmittance and good electrical conductivity. The hybrid films are characterized by a good degree of control of the architecture at the nanoscale level, where the weakness(es) of each component are offset by the strengths of the other components. By rational design of the structure and using simple and locate-cost fabrication methods, hybrid films with sheet resistance of 26 ohm/sq and optical transmittance (at ?=550 nm) of 83% for reduced graphene oxide/silver nanowire films, and 64 ohm/sq and optical transmittance of 93.6% for monolayer graphene/silver nanowire films have been fabricated. These values are comparable to transparent conductive films based on indium tin oxide but are now able to be used in flexible electronics due to their good mechanical properties.Type: GrantFiled: April 10, 2014Date of Patent: October 25, 2016Assignee: Board of Regents, The University of Texas SystemInventors: Rodney S. Ruoff, Iskandar Kholmanov
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Publication number: 20160254102Abstract: Doped activated microwave expanded graphite oxide materials and doped monolayer graphene materials, and methods of making these materials. The materials exhibit increased capacitance relative to undoped activated microwave expanded graphite oxide and monolayer graphene. The materials are suitable for use in, for example, ultracapacitors.Type: ApplicationFiled: February 23, 2016Publication date: September 1, 2016Inventors: Rodney S. Ruoff, Li Li Zhang, Meryl D. Stoller
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Patent number: 9412484Abstract: Disclosed is a carbon material that can be useful, for example, in ultracapacitors. Also disclosed are applications and devices containing the carbon material.Type: GrantFiled: March 1, 2013Date of Patent: August 9, 2016Assignee: BOARD OF REGENTS, THE UNIVERSITY OF TEXAS SYSTEMInventors: Rodney S. Ruoff, Yanwu Zhu, Meryl D. Stoller, Shanthi Murali
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Publication number: 20160209124Abstract: Sugar alcohol blends of galactitol and mannitol and compositions comprising such blends are disclosed as phase change materials (PCMs). A method of forming carbon nanotubes on a carbon substrate is described. Carbon substrates with carbon nanotubes, in particular, conformal layers of carbon nanotubes on carbon substrates, are also disclosed, as are methods of making and using these materials. Thermal storage units are also provided. The thermal storage units can comprise a heat exchange path through which a heat exchange medium flows, and a thermal storage medium in thermal contact with the heat exchange path.Type: ApplicationFiled: August 29, 2014Publication date: July 21, 2016Inventors: Alexandre K. DA SILVAa, Evan FLEMING, Li SHI, Christopher W. BIELAWSKI, Rodney S. RUOFF, Shaoyi WEN, Hengxing JI, Michael PETTES, Abhijit PAUL, Eunsu PAEK, Alexander J. PAK, Daniel P. SELLAN
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Publication number: 20160137507Abstract: A graphene transfer method using water vapor-assisted determination of CVD-grown graphene film on the Cu foil. By using the polymer film as a supporting layer, we found that graphene can be directly detached from the Cu foil as a consequence of water intercalated at the graphene-Cu interface(s), by a ‘dry transfer’ method. The delaminated graphene films are continuous over large area. This nondestructive method also worked for the transfer of graphene grown on a Cu single crystal without sacrificing the expensive crystal, thus affording the possibility of producing high-quality graphene and reusing the substrate. The Cu foil and single crystal can both be repeatedly used for many times, which may reduce the cost of graphene synthesis and is environmentally more benign. Our method affords the advantages of high efficiency, likely industrial scalability, minimal use of chemicals, and the reusability of the Cu foil in multiple growth and delamination cycles.Type: ApplicationFiled: November 19, 2014Publication date: May 19, 2016Applicants: INSTITUTE FOR BASIC SCIENCE, UNIST ACADEMY-INDUSTRY RESEARCH CORPORATIONInventors: Xuequi YOU, Da Luo, Rodney S. Ruoff
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Publication number: 20150292112Abstract: A method of forming graphene single crystal domains on a carbon substrate is described.Type: ApplicationFiled: April 15, 2014Publication date: October 15, 2015Applicant: Board of Regents, The University of Texas SystemInventors: Luigi Colombo, Rodney S. Ruoff, Yufeng Hao
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Publication number: 20150050482Abstract: Method for synthesizing large single-crystal graphene films by suppressing evaporative substrate loss in chemical vapor deposition, and graphene films synthesized thereby. The substrate may be configured as a tube prior to exposure to an organic compound at high temperature. Low flow rate of the gaseous carbon source may be employed, and this flow rate may be increased after an initial nucleation period.Type: ApplicationFiled: August 14, 2013Publication date: February 19, 2015Inventors: Rodney S. Ruoff, Shanshan Chen
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Publication number: 20140313562Abstract: A hybrid transparent conductive film, and methods for fabricating such hybrid transparent conductive films, involving the assembly of two-dimensional graphene-based materials with one-dimensional silver and/or copper nanowires with high optical transmittance and good electrical conductivity. The hybrid films are characterized by a good degree of control of the architecture at the nanoscale level, where the weakness(es) of each component are offset by the strengths of the other components. By rational design of the structure and using simple and locate-cost fabrication methods, hybrid films with sheet resistance of 26 ohm/sq and optical transmittance (at ?=550 nm) of 83% for reduced graphene oxide/silver nanowire films, and 64 ohm/sq and optical transmittance of 93.6% for monolayer graphene/silver nanowire films have been fabricated. These values are comparable to transparent conductive films based on indium tin oxide but are now able to be used in flexible electronics due to their good mechanical properties.Type: ApplicationFiled: April 10, 2014Publication date: October 23, 2014Applicant: Board of Regents, The University of Texas SystemInventors: Rodney S. Ruoff, Iskandar Kholmanov
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Publication number: 20130295367Abstract: Composite polymer films or layers have graphene-based nanosheets dispersed in the polymer for the reduction of gas permeability and light transmittance.Type: ApplicationFiled: March 22, 2013Publication date: November 7, 2013Applicant: Northwestern UniversityInventors: Owen C. Compton, SonBinh T. Nguyen, Sasha Stankovich, Rodney S. Ruoff
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Patent number: 8574681Abstract: A ceramic composite thin film or layer includes individual graphene oxide and/or electrically conductive graphene sheets dispersed in a ceramic (e.g. silica) matrix. The thin film or layer can be electrically conductive film or layer depending the amount of graphene sheets present. The composite films or layers are transparent, chemically inert and compatible with both glass and hydrophilic SiOx/silicon substrates. The composite film or layer can be produced by making a suspension of graphene oxide sheet fragments, introducing a silica-precursor or silica to the suspension to form a sol, depositing the sol on a substrate as thin film or layer, at least partially reducing the graphene oxide sheets to conductive graphene sheets, and thermally consolidating the thin film or layer to form a silica matrix in which the graphene oxide and/or graphene sheets are dispersed.Type: GrantFiled: May 13, 2008Date of Patent: November 5, 2013Assignee: Northwestern UniversityInventors: Rodney S. Ruoff, Sasha Stankovich, Dmitriy A. Dikin, SonBinh T. Nguyen
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Publication number: 20130235509Abstract: Disclosed is a carbon material that can be useful, for example, in ultracapacitors. Also disclosed are applications and devices containing the carbon material.Type: ApplicationFiled: March 1, 2013Publication date: September 12, 2013Inventors: Rodney S. Ruoff, Yanwu Zhu, Meryl D. Stoller, Shanthi Murali
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Patent number: 8470400Abstract: Processes for synthesizing graphene films. Graphene films may be synthesized by heating a metal or a dielectric on a substrate to a temperature between 400° C. and 1,400° C. The metal or dielectric is exposed to an organic compound thereby growing graphene from the organic compound on the metal or dielectric. The metal or dielectric is later cooled to room temperature. As a result of the above process, standalone graphene films may be synthesized with properties equivalent to exfoliated graphene from natural graphite that is scalable to size far greater than that available on silicon carbide, single crystal silicon substrates or from natural graphite.Type: GrantFiled: May 5, 2010Date of Patent: June 25, 2013Assignees: Board of Regents, The University of Texas System, Texas Instruments, Inc.Inventors: Luigi Colombo, Xuesong Li, Rodney S. Ruoff