Abstract: A Vacuum Diode is constructed in which the electrodes of the Vacuum Diode are coated with a thin film of diamond-like carbonaceous material. The cathode and anode are separated by spacers and a rinse-able material, the rinse-able material which is later removed. Carbonaceous films and the related process for producing a thin film of ablated diamond are not previously known in connection with Vacuum Thermionic Converters, and provide a practical and improved means of constructing such devices.A Vacuum Thermionic Converter is optimized for the most efficient generation of electricity by utilizing a cathode and anode of very low work function. The relationship of the work functions of cathode and anode are shown to be optimized when the cathode work function is the minimum value required to maintain current density saturation at the desired temperature, while the anode's work function is as low as possible, and in any case lower than the cathode's work function.