Patents by Inventor Rodolfo Iezzi

Rodolfo Iezzi has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 10646854
    Abstract: The present invention relates to a catalytic composition which comprises microspheroidal alumina and an active component containing a mixture comprising Gallium and/or Gallium oxides, Tin and/or Tin oxides, a quantity ranging from 1 ppm to 500 ppm with respect to the total weight of the catalytic composition of platinum and/or platinum oxides, and oxides of alkaline and/or alkaline earth metals.
    Type: Grant
    Filed: December 24, 2012
    Date of Patent: May 12, 2020
    Assignee: versalis S.p.A.
    Inventors: Rodolfo Iezzi, Giulio Manzini, Paolo Pollesel, Alessandro Del Seppia
  • Patent number: 10486140
    Abstract: The present invention relates to a dehydrogenation process starting from reagents selected from single butenes, or mixtures thereof, or mixtures of butenes with butanes, to give 1-3 butadiene using catalytic composition of microspheroidal alumina and an active component containing a mixture comprising Gallium and/or Gallium oxides, Tin and/or Tin oxides, a quantity ranging from 1 ppm to 500 ppm with respect to the total weight of the catalytic composition of platinum and/or platinum oxides, and oxides of alkaline and/or alkaline earth metals.
    Type: Grant
    Filed: October 13, 2017
    Date of Patent: November 26, 2019
    Assignee: versalis S.p.A.
    Inventors: Rodolfo Iezzi, Giulio Manzini, Paolo Pollesel, Alessandro Del Seppia
  • Publication number: 20180043338
    Abstract: The present invention relates to a dehydrogenation process starting from reagents selected from single butenes, or mixtures thereof, or mixtures of butenes with butanes, to give 1-3 butadiene using catalytic composition of microspheroidal alumina and an active component containing a mixture comprising Gallium and/or Gallium oxides, Tin and/or Tin oxides, a quantity ranging from 1 ppm to 500 ppm with respect to the total weight of the catalytic composition of platinum and/or platinum oxides, and oxides of alkaline and/or alkaline earth metals.
    Type: Application
    Filed: October 13, 2017
    Publication date: February 15, 2018
    Applicant: versalis S.p.A.
    Inventors: Rodolfo IEZZI, Giulio MANZINI, Paolo POLLESEL, Alessandro DEL SEPPIA
  • Publication number: 20140378731
    Abstract: The present invention relates to a catalytic composition which comprises microspheroidal alumina and an active component containing a mixture comprising Gallium and/or Gallium oxides, Tin and/or Tin oxides, a quantity ranging from 1 ppm to 500 ppm with respect to the total weight of the catalytic composition of platinum and/or platinum oxides, and oxides of alkaline and/or alkaline earth metals.
    Type: Application
    Filed: December 24, 2012
    Publication date: December 25, 2014
    Applicant: versalis S.p.A.
    Inventors: Rodolfo Iezzi, Giulio Manzini, Paolo Pollesel, Alessandro Del Seppia
  • Patent number: 7473668
    Abstract: Process for the catalytic dehydrogenation of alkylaromatic hydrocarbons optionally mixed with ethane which comprises: A) dehydrogenating the hydrocarbon stream, optionally mixed with an inert gas, in a fluid bed reactor in the presence of a catalytic composition based on gallium and manganese supported on alumina modified with silica, at a temperature ranging from 400 to 700° C., at a total pressure ranging from 0.1 to 3 ata and with a GHSV (Gas Hourly Space Velocity) ranging from 50 to 10,000 h?1; and B) regenerating and heating the catalyst, by means of the catalytic oxidation of a fuel, in a fluid bed regenerator at a temperature higher than 400° C.
    Type: Grant
    Filed: December 18, 2002
    Date of Patent: January 6, 2009
    Assignee: Snamprogetti S.p.A.
    Inventors: Andrea Bartolini, Domenico Sanfilippo, Rodolfo Iezzi
  • Patent number: 7235706
    Abstract: A process for preparing light olefins from corresponding paraffins consists of reacting said paraffins in a reactor, operating at a temperature of between 450 and 800° C., a pressure of between 0.1 and 3 atm absolute and a GHSV of between 100 and 10000 h?1, with a catalytic system containing gallium, platinum, possibly one or more alkaline or alkaline-earth metals, and a support consisting of alumina in delta or theta phase or in delta+theta or theta+alpha or delta+theta+alpha mixed phase, modified with silica, the gallium, expressed as Ga2O3, being in a quantity of between 0.1 and 33.6 wt %, the platinum being in a quantity of between 1 and 99 ppm, the alkaline or alkaline-earth metals, expressed as oxide, being in a quantity of between 0 and 5 wt %, and the silica being in a quantity of between 0.08 and 3 wt %, the rest to 100% being alumina, and regenerating said catalytic system in a regenerator by burning off the coke which has deposited on its surface, without subsequently reducing it.
    Type: Grant
    Filed: July 1, 2002
    Date of Patent: June 26, 2007
    Assignees: Snamprogetti S.p.A., Enitecnologie S.p.A.
    Inventors: Rodolfo Iezzi, Andrea Bartolini, Franco Buonomo
  • Patent number: 6841712
    Abstract: A process is described for the dehydrogenation of ethylbenzene to styrene in a fluid-bed reactor-regenerator system, which uses a catalyst based on iron oxide supported on a modified alumina and promoted with further metal oxides.
    Type: Grant
    Filed: September 19, 2000
    Date of Patent: January 11, 2005
    Assignee: Snamprogetti S.p.A.
    Inventors: Rodolfo Iezzi, Domenico Sanfilippo
  • Publication number: 20040259727
    Abstract: Process for the catalytic dehydrogenation of alkylaromatic hydrocarbons optionally mixed with ethane which comprises: A) dehydrogenating the hydrocarbon stream, optionally mixed with an inert gas, in a fluid bed reactor in the presence of a catalytic composition based on gallium and manganese supported on alumina modified with silica, at a temperature ranging from 400 to 700° C., at a total pressure ranging from 0.1 to 3 ata and with a GHSV (Gas Hourly Space Velocity) ranging from 50 to 10,000 h−1; and B) regenerating and heating the catalyst, by means of the catalytic oxidation of a fuel, in a fluid bed regenerator at a temperature higher than 400° C.
    Type: Application
    Filed: May 14, 2004
    Publication date: December 23, 2004
    Inventors: Andrea Bartolini, Domenico Sanfilippo, Rodolfo Iezzi
  • Publication number: 20020198428
    Abstract: A process for preparing light olefins from corresponding paraffins consists of reacting said paraffins in a reactor, operating at a temperature of between 450 and 800° C., a pressure of between 0.1 and 3 atm absolute and a GHSV of between 100 and 10000 h−1, with a catalytic system containing gallium, platinum, possibly one or more alkaline or alkaline-earth metals, and a support consisting of alumina in delta or theta phase or in delta+theta or theta+alpha or delta+theta+alpha mixed phase, modified with silica, the gallium, expressed as Ga2O3, being in a quantity of between 0.1 and 33.6 wt %, the platinum being in a quantity of between 1 and 99 ppm, the alkaline or alkaline-earth metals, expressed as oxide, being in a quantity of between 0 and 5 wt %, and the silica being in a quantity of between 0.
    Type: Application
    Filed: July 1, 2002
    Publication date: December 26, 2002
    Applicant: SNAMPROGETTI S.p.A.
    Inventors: Rodolfo Iezzi, Andrea Bartolini, Franco Buonomo
  • Patent number: 6362385
    Abstract: A process for obtaining light olefins by the dehydrogenation of corresponding paraffins, by reacting the paraffins with a catalytic system containing chromium oxide, tin oxide, at least one alkali metal oxide, and an alumina-silica carrier, and then regenerating the catalytic system in a regenerator by burning coke deposited on its surface at a temperature higher than the average temperature of the reactor.
    Type: Grant
    Filed: July 23, 1998
    Date of Patent: March 26, 2002
    Assignees: Siamprogetti S.p.A., Oao Nil Yarsintez
    Inventors: Rodolfo Iezzi, Andrea Bartolini, Franco Buonomo, Gueorgui Kotelnikov, Vladimir Bespalov
  • Patent number: 6242660
    Abstract: Catalytic system for dehydrogenating ethylbenzene to styrene, containing chromium oxide, tin oxide, at least one oxide of an alkaline metal (M) and an alumina carrier, in delta or theta phase or in a mixture of delta+theta or theta+alpha or delta+theta+alpha phases, modified with silica, and characterized in that: the chromium, expressed as Cr2O3, is in a quantity of between 6 and 30% by weight; the tin, expressed as SnO, is in a quantity of between 0.1 and 3.5% by weight; the alkaline metal, expressed as M2O, is in a quantity of between 0.4 and 3% by weight; the silica is in a quantity of between 0.08 and 3% by weight, the complement to 100 being alumina.
    Type: Grant
    Filed: August 12, 1999
    Date of Patent: June 5, 2001
    Assignee: Snamprogetti S.p.A.
    Inventors: Franco Buonomo, Domenico Sanfilippo, Rodolfo Iezzi, Emilio Micheli
  • Patent number: 5994258
    Abstract: Catalytic system for dehydrogenating ethylbenzene to styrene, containing chromium oxide, tin oxide, at least one oxide of an alkaline metal (M) and an alumina carrier, in delta or theta phase or in a mixture of delta+theta or theta+alpha or delta+theta+alpha phases, modified with silica, and characterized in that:the chromium, expressed as Cr.sub.2 O.sub.3, is in a quantity of between 6 and 30% by weight;the tin, expressed as SnO, is in a quantity of between 0.1 and 3.5% by weight;the alkaline metal, expressed as M.sub.2 O, is in a quantity of between 0.4 and 3% by weight,the silica is in a quantity of between 0.08 and 3% by weight, the complement to 100 being alumina.
    Type: Grant
    Filed: June 19, 1998
    Date of Patent: November 30, 1999
    Assignee: Snamprogetti S.p.A.
    Inventors: Franco Buonomo, Domenico Sanfilippo, Rodolfo Iezzi, Emilio Micheli
  • Patent number: 5633421
    Abstract: A process for dehydrogenating light paraffins, in particular C.sub.2 -C.sub.5, to obtain the corresponding light olefins, comprising reacting said paraffins with a catalytic system containing platinum, tin and an alumina support and possibly an element of the lanthanide group in a fluidized bed reactor, where the heat required for the reaction is provided by said catalytic system as sensible heat, operating at a temperature of between 500.degree. and 700.degree. C. and at a pressure of between 1 and 2 kg/cm.sup.2, and regenerating said catalytic system by burning the coke which has deposited on the surface of the catalytic system, said regeneration being conducted in air and/or oxygen, if necessary by increasing the temperature of the catalytic system to a suitable level, followed by reduction of said catalytic system with a reducing agent.
    Type: Grant
    Filed: February 22, 1995
    Date of Patent: May 27, 1997
    Assignees: Eniricerche S.p.A., Snamprogetti S.p.A.
    Inventors: Rodolfo Iezzi, Andrea Bartolini
  • Patent number: 5414182
    Abstract: The process for activating a catalytic composition for paraffin dehydrogenation containing gallium, alumina, possibly silica and/or one or more alkaline or alkaline-earth metals, comprises thermal activation in air followed by post-activation effected by the following stages:oxidation with air and/or oxygen or a mixture containing oxygen and inert gas;purging with inert gas;reduction with hydrogen or a mixture of hydrogen and an inert or reducing gas.The catalytic composition activated by said process contains gallium, alumina, silica and possibly one or more alkaline or alkaline-earth metals, the alumina being in .delta. or .theta. phase or in .delta.+.theta. or .delta.+.theta.+.alpha. phase mixture.
    Type: Grant
    Filed: February 10, 1994
    Date of Patent: May 9, 1995
    Assignees: Snamprogetti S.p.A., Eniricerche S.p.A.
    Inventors: Rodolfo Iezzi, Andrea Bartolini, Franco Buonomo
  • Patent number: 5308822
    Abstract: The process for activating a catalytic composition for paraffin dehydrogenation containing gallium, alumina, possibly silica and/or one or more alkaline or alkaline-earth metals, comprises thermal activation in air followed by post-activation effected by the following stages:oxidation with air and/or oxygen or a mixture containing oxygen and inert gas;purging with inert gas;reduction with hydrogen or a mixture of hydrogen and an inert or reducing gas.The catalytic composition activated by said process contains gallium, alumina, silica and possibly one or more alkaline or alkaline-earth metals, the alumina being in .delta. or .theta. phase or in .delta.+.theta. or .delta.+.theta.+.alpha. phase mixture.
    Type: Grant
    Filed: March 8, 1993
    Date of Patent: May 3, 1994
    Assignees: Snamprogetti S.p.A, Eniricerche S.p.A.
    Inventors: Rodolfo Iezzi, Andrea Bartolini, Franco Buonomo
  • Patent number: 5143886
    Abstract: A catalytic composition for the dehydrogenation of C.sub.2 -C.sub.5 paraffins, constituted by:platinum, in an amount comprised within the range of from 0.01 to 3% by weight,optionally tin, in an amount comprised within the range of from 0 to 1.5% by weight,a support selected from:titanated alumina,titanated silica and/ortitanium silicalitein which the titanium amount in the same support is comprised within the range of from 0.05 to 3% by weightis disclosed.
    Type: Grant
    Filed: February 5, 1991
    Date of Patent: September 1, 1992
    Assignee: Snamprogetti S.p.A.
    Inventors: Rodolfo Iezzi, Franco Buonomo, Domenico Sanfilippo