Abstract: The titanium (IV) and iron (III) MOF solid MUV-17 (TiFe2), has general formula (1): [TiIVFeIII2(O)(L)2(X)3]S, where X is each equal or different selected from: O2?, OH?, H2O, F?, Cl?, Br?, I?, NO3?, ClO4?, BF4?, SCN?, OH?, CH3COO?, C5H7O2?, SO42? and CO32?, L is a tricarboxylic ligand and S is at least one molecule of a polar solvent selected from the group consisting of N,N?-dimethylformamide,N,N?-diethylformamide,N,N?-dimethylacetamide, N-methyl-2-pyrrolidone, methanol, ethanol, isopropanol, n-propanol, water and mixtures thereof. The titanium (IV) and iron (III) MOF solid has long-term catalytic activity for the degradation of toxic compounds. The method for obtaining them comprises dissolving the components under anaerobic conditions. The invention also relates to the use of the titanium (IV) and iron (III) MOF solid as an additive with detoxifying properties of toxic compounds.

Abstract: Related are a chemical warfare agent (CWA) decontaminant, a method of decontaminating a CWA using the CWA decontaminant, and a product including the CWA decontaminant. The CWA decontaminant may include a metal-organic framework (MOF) including at least one metallic compound among metal hydroxide, metal hydride, metal acetate, metal methoxide, and metal oxide, and the at least one metallic compound may be dispersed either on a surface of the MOF or in pores of the MOF, or both.