Abstract: Process for confinement of waste containing at least one chemical species to be confined, by in-can vitrification in a hot metal can into which waste and a vitrification additive are added, the waste and the vitrification additive are melted to obtain a glass melt which is then cooled, characterised in that at least one oxidising agent is also added into the metal can and in that the concentration of oxidising agent(s) expressed as oxide(s) in the glass melt is between 0.1 and 20% by mass, preferably 4 and 20% by mass, even more preferably 5 and 15% by mass, and even more preferably 10 and 13% by mass of the glass melt mass.

Abstract: The method according to the invention enables a facility having a rather reduced dimension, for incinerating to be used, melting and vitrifying mixed waste (30) introduced into a reactor (10), by means of a basket (18) in turn passing through an air lock (12). Plasma torches (14) burn all waste (30) contained in the basket (18). The waste is then lowered in a melting bath of a furnace (20) with an inductor (24) including a crucible-forming container (23). A combustion gas treatment train completes the facility. The furnace (20) can be dismantled, after a series of treatments of several baskets (18) of waste (30) for disassembling the crucible-forming container (23) from the furnace (20). Application in treating different radiologically contaminated and/or toxic mixed waste.

Abstract: A basket for incinerating waste inside an incinerator for a duration longer than fifteen minutes with no need for waste to be molten earlier, particularly when waste is introduced inside the incinerator. The basket includes mainly of a glass fiber envelope: it is preferably stiffened by a lightweight metal structure located inside or outside the envelope or built into it. A gripping handle is installed on top of the assembly that is stiffened at the top by a metal tube to which a lightweight metal structure is fixed and by a base formed from a drip pan fixed to the base of the lightweight metal structure.

Abstract: The melting induction furnace comprises, together with a casing (7) to which a lower sole plate (11) is added to form the central part of the structure, a removable inner crucible (1) composed of an internal layer (4) resisting heat and aggressiveness of the molten bath (20), an external layer (6) delimiting the crucible and an insulating intermediate layer (5). The crucible (1) is a disposable crucible and can be stored with its charge in an appropriate container. Heat losses are low, even when the casing (7) is cooled. Stresses due to differential thermal expansions are also very much reduced.

Abstract: The method according to the invention enables a facility having a rather reduced dimension, for incinerating to be used, melting and vitrifying mixed waste (30) introduced into a reactor (10), by means of a basket (18) in turn passing through an air lock (12). Plasma torches (14) burn all waste (30) contained in the basket (18). The waste is then lowered in a melting bath of a furnace (20) with an inductor (24) including a crucible-forming container (23). A combustion gas treatment train completes the facility. The furnace (20) can be dismantled, after a series of treatments of several baskets (18) of waste (30) for disassembling the crucible-forming container (23) from the furnace (20). Application in treating different radiologically contaminated and/or toxic mixed waste.

Abstract: The basket according to the invention can be used to incinerate waste inside an incinerator for a duration longer than fifteen minutes with no need for waste to be molten earlier, particularly when waste is introduced inside the incinerator. The basket is composed mainly of a glass fibre envelope (10): it is preferably stiffened by a lightweight metal structure (12) located inside or outside the envelope or built into it. A gripping handle (14) is installed on top of the assembly that is stiffened at the top by a metal tube (16) to which a lightweight metal structure (12) is fixed and by a base formed from a drip pan (18) fixed to the base of the lightweight metal structure (12). Application for incineration of toxic waste.

Abstract: The melting induction furnace comprises, together with a casing (7) to which a lower sole plate (11) is added to form the central part of the structure, a removable inner crucible (1) composed of an internal layer (4) resisting heat and aggressiveness of the molten bath (20), an external layer (6) delimiting the crucible and an insulating intermediate layer (5). The crucible (1) is a disposable crucible and can be stored with its charge in an appropriate container. Heat losses are low, even when the casing (7) is cooled. Stresses due to differential thermal expansions are also very much reduced.

Abstract: The invention relates to equipment for refining a load of silicon(s) that comprises a crucible (5) including at least one sole (20) made of a first refractory material having good heat conductivity, means (26, 28) for cooling the sole, a protection member (30) made of at least a second refractory material having low heat conductivity and to be provided between the crucible and the load, and induction heating means (23, 24) of the load including a winding (23) provided in or under the sole.

Abstract: Process for confinement of waste containing at least one chemical species to be confined, by in-can vitrification in a hot metal can into which waste and a vitrification additive are added, the waste and the vitrification additive are melted to obtain a glass melt which is then cooled, characterised in that at least one oxidising agent is also added into the metal can and in that the concentration of oxidising agent(s) expressed as oxide(s) in the glass melt is between 0.1 and 20% by mass, preferably 4 and 20% by mass, even more preferably 5 and 15% by mass, and even more preferably 10 and 13% by mass of the glass melt mass.

Abstract: Electromagnetic device for fusion and interfacial agitation of diphase systems, particularly for the acceleration of metallurgic or pyrochemical processes, which includes for example a crucible to contain a diphase system, an inductor surrounding this crucible, and a circuit for the supply of the inductor by a current with two components, namely a high frequency component which melts the phases of the system and a low frequency component which agitates the interface of the phases.

Abstract: Process for combustion and vitrification of waste in which at least one oxygen plasma jet is associated with a continuous melting device by high frequency direct induction. The crucible is composed of a continuous external shell and a sole plate, both cooled by a liquid circulating in internal channels. The inductor is placed below the sole plate. There is a gravity drain valve at the bottom or on the side.

Abstract: Process for the production of hydrogen by the thermochemical route from water, based on the chlorine/cerium cycle, in which, according to a first reaction scheme, the following reactions are carried out: H2O+Cl2=2HCl+½O2;??(A) 8HCl+2CeO2=2CeCl3+Cl2+4H2O;??(B) 2CeCl3+4H2O=2CeO2+6HCl+H2;??(C) or in which, according to a second reaction scheme, the following reactions are carried out: H2O+Cl2=2HCl+½O2;??(A) 8HCl+2CeO2=2CeCl3+Cl2+4H2O;??(B) 2CeCl3+2H2O=2CeOCl+4HCl;??(B?) 2CeOCl+2H2O=2CeO2+2HCl+H2;??(C?) and in which the reaction (B) for the chlorination of cerium oxide is carried out in the liquid phase, the cerium chloride passing into solution.

Abstract: The mass to be vitrified undergoes a reduction operation in order to have the ruthenium pass from an oxidized state to a metal state in order to reduce the viscosity, the electric conductivity and to obtain good chemical kinetics.

Abstract: Process for combustion and vitrification of waste in which at least one oxygen plasma jet is associated with a continuous melting device by high frequency direct induction. The crucible is composed of a continuous external shell and a sole plate, both cooled by a liquid circulating in internal channels. The inductor is placed below the sole plate. There is a gravity drain valve at the bottom or on the side.

Abstract: Process for combustion and vitrification of waste in which at least one oxygen plasma jet is associated with a continuous melting device by high frequency direct induction. The crucible is composed of a continuous external shell and a sole plate, both cooled by a liquid circulating in internal channels. The inductor is placed below the sole plate. There is a gravity drain valve at the bottom or on the side.

Abstract: Process for the production of hydrogen by the thermochemical route from water, based on the chlorine/cerium cycle, in which, according to a first reaction scheme, the following reactions are carried out: H2O+Cl2=2HCl+½O2; ??(A) 8HCl+2CeO2=2CeCl3+Cl2+4H2O; ??(B) 2CeCl3+4H2O=2CeO2+6HCl+H2; ??(C) or in which, according to a second reaction scheme, the following reactions are carried out: H2O+Cl2=2HCl+½O2; ??(A) 8HCl+2CeO2=2CeCl3+Cl2+4H2O; ??(B) 2CeCl3+2H2O=2CeOCl+4HCl; ??(B?) 2CeOCl+2H2O=2CeO2+2HCl+H2; ??(C?) and in which the reaction (B) for the chlorination of cerium oxide is carried out in the liquid phase, the cerium chloride passing into solution.

Abstract: Electromagnetic device for fusion and interfacial agitation of diphase systems, particularly for the acceleration of metallurgic or pyrochemical processes. This device comprises for example a crucible (2, 28), to contain a diphase system, an inductor (4) surrounding this crucible and means (18) for the supply of the inductor by a current with two components, namely a high frequency component which melts the phases of the system and a low frequency component which agitates the interface (12) of the phases.

Abstract: Process for combustion and vitrification of waste in which at least one oxygen plasma jet is associated with a continuous melting device by high frequency direct induction (4). The crucible is composed of a continuous external shell (1) and a sole plate (2), both cooled by a liquid circulating in internal channels. The inductor is placed below the sole plate. There is a gravity drain valve at the bottom or on the side.

Abstract: A melting furnace for insulating materials is provided with a cooled crucible (10) having continuous metal side malls, a partitioned and cooled bottom (12) and at least one induction coil (28) placed under the bottom which serves as the sole heating means. The depth of the melting bath contained in the crucible and the excitation frequency of the induction coil are selected so that the depth and half of the inside radius of the crucible are less than the skin thickness of the bath.

Abstract: This invention relates to a process for treating fly ash produced by a waste incinerator and containing chlorides of toxic metals, which includes a step consisting of subjecting said fly ash to a phosphating reaction, at high temperature, to convert the chlorides of toxic metals into phosphates, the phosphating reaction being obtained by the addition of a reactant comprising a phosphorus compound, characterised in that said phosphorus compound is a non-metallic compound and in that the chlorinated products obtained are discharged in a gaseous form. It also relates to an installation for implementing this process.