Abstract: The present invention relates to a semi-conductive polymer composition, the present invention provides a semi-conductive polymer composition comprising an ethylene copolymer comprising polar co-monomer units; an olefin homo- or copolymer; and a conductive filler; wherein the olefin homo- or copolymer has a degree of crystallinity below 20%. The invention also relates to a wire or cable comprising said semi-conductive polymer composition, and to the use of said composition for the production of a layer, preferably a semi-conducting shield layer of a wire or cable.

Abstract: A copolymer of ethylene with silane groups containing comonomer that is produced in a high pressure radical polymerisation process comprising the steps of: (a) compressing ethylene together with the silane groups containing comonomer under pressure in a compressor, wherein a compressor lubricant is used for lubrication, (b) polymerising ethylene together with the silane groups containing comonomer in a polymerisation zone, (c) separating the obtained ethylene from the unreacted products and recovering the separated ethylene copolymer in a recovery zone, wherein in step a) the compressor lubricant comprises a mineral oil and ethylene copolymer has a silane groups containing comonomer content of 0.5 to 3 wt % and an MFR2 of 0.3 to 10 g/10 min. The copolymer of ethylene with silane groups containing comonomer can be used.

Abstract: The present invention relates to a polymer composition comprising a surfactant interacting additive, and wherein the polymer composition further comprises at least one silanol condensation catalyst, wherein each catalyst is selected from: i) a compound of formula I ArSO3H (I) or a precursor thereof, wherein Ar is an 1 to 4 alkyl groups substituted aryl, wherein the aryl is phenyl or naphthyl, and wherein each alkyl group, independently, is a linear or branched alkyl with 10 to 30 carbons, wherein the total number of carbons in the alkyl groups is in the range of 20 to 80 carbons; ii) a derivative of i) selected from the group consisting of an anhydride, an ester, an acetylate, an epoxy blocked ester and an amine salt thereof which is hydrolysable to the corresponding compound of formula I; and iii) a metal salt of i) wherein the metal ion is selected from the group consisting of copper, aluminum, tin and zinc; an article, for example, a coating, a wire or a cable, comprising the polymer composition, a process

Abstract: A copolymer of ethylene with silane groups containing comonomer that is produced in a high pressure radical polymerization process comprising the steps of: (a) compressing ethylene together with the silane groups containing comonomer under pressure in a compressor, wherein a compressor lubricant is used for lubrication, (b) polymerizing ethylene together with the silane groups containing comonomer in a polymerization zone, (c) separating the obtained ethylene from the unreacted products and recovering the separated ethylene copolymer in a recovery zone, wherein in step a) the compressor lubricant comprises a mineral oil and ethylene copolymer has a silane groups containing comonomer content of 0.5 to 3 wt % and an MFR2 of 0.3 to 10 g/10 min. The co-polymer of ethylene with silane groups containing comonomer can be used.

Abstract: A copolymer of ethylene with silane groups containing comonomer that is produced in a high pressure radical polymerisation process comprising the steps of: (a) compressing ethylene together with the silane groups containing comonomer under pressure in a compressor, wherein a compressor lubricant is used for lubrication, (b) polymerising ethylene together with the silane groups containing comonomer in a polymerisation zone, (c) separating the obtained ethylene from the unreacted products and recovering the separated ethylene copolymer in a recovery zone, wherein in step a) the compressor lubricant comprises a mineral oil and ethylene copolymer has a silane groups containing comonomer content of 0.5 to 3 wt % and an MFR2 of 0.3 to 10 g/10 min. The co polymer of ethylene with silane groups containing comonomer can be used.

Abstract: The present invention relates to a polymer composition comprising a surfactant interacting additive, and wherein the polymer composition further comprises at least one silanol condensation catalyst, wherein each catalyst is selected from: i) a compound of formula I ArSO3H (I) or a precursor thereof, wherein Ar is an 1 to 4 alkyl groups substituted aryl, wherein the aryl is phenyl or naphthyl, and wherein each alkyl group, independently, is a linear or branched alkyl with 10 to 30 carbons, wherein the total number of carbons in the alkyl groups is in the range of 20 to 80 carbons; ii) a derivative of i) selected from the group consisting of an anhydride, an ester, an acetylate, an epoxy blocked ester and an amine salt thereof which is hydrolysable to the corresponding compound of formula I; and iii) a metal salt of i) wherein the metal ion is selected from the group consisting of copper, aluminum, tin and zinc; an article, for example, a coating, a wire or a cable, comprising the polymer composition, a process

Abstract: The present invention relates to a polymer composition comprising a surfactant interacting additive, and wherein the polymer composition further comprises at least one silanol condensation catalyst, wherein each catalyst is selected from: i) a compound of formula I ArSO3H (I) or a precursor thereof, wherein Ar is an 1 to 4 alkyl groups substituted aryl, wherein the aryl is phenyl or naphthyl, and wherein each alkyl group, independently, is a linear or branched alkyl with 10 to 30 carbons, wherein the total number of carbons in the alkyl groups is in the range of 20 to 80 carbons; ii) a derivative of i) selected from the group consisting of an anhydride, an ester, an acetylate, an epoxy blocked ester and an amine salt thereof which is hydrolysable to the corresponding compound of formula I; and iii) a metal salt of i) wherein the metal ion is selected from the group consisting of copper, aluminum, tin and zinc; an article, for example, a coating, a wire or a cable, comprising the polymer composition, a process

Abstract: The present invention relates to a process for manufacturing polyethylene-silane-copolymer conducted in a plant including at least one compressor unit and at least one reactor downstream of the compressor unit. The process includes the steps of (a) feeding a first feed stream including ethylene into the at least one compressor unit and subsequently to the at least one reactor, and (b1) feeding a second feed stream including at least one silane comonomer to the at least one reactor as front feed and/or (b2) feeding a second feed stream including at least one silane comonomer to the at least one reactor at at least one location along the reactor.

Abstract: The present invention relates to the use of a silicon containing compound for reducing the retention time of a polyolefin composition comprising a crosslinkable polyolefin with hydrolysable silane groups. A master batch is compounded with the polyolefin composition to form a compounding composition. The master batch comprises a matrix polymer, a Bronsted acid that is a silanol condensation catalyst and is present in the amount of 0.7 to 3.5 wt %, and a silicon containing compound with a structure according to the formula (I): (R1)x[Si(R2)y(R3)z]m wherein R1 is C6-22 alkyl, R2 is C1-10 alkoxy, R3 is —R4SiR1R2 , R4 is —(CH2)rYs(CH2)t— where Y is a difunctional heteroatomic group, x+y+z=4, and m=1. The silicon containing compound is 2 to 10 wt % of the master batch, and 0.01 to 1.5 wt % of the compounding composition.

Abstract: The present invention relates to a process for manufacturing polyethylene-silane-copolymer conducted in a plant including at least one compressor unit and at least one reactor downstream of the compressor unit. The process includes the steps of (a) feeding a first feed stream including ethylene into the at least one compressor unit and subsequently to the at least one reactor, and (b1) feeding a second feed stream including at least one silane comonomer to the at least one reactor as front feed and/or (b2) feeding a second feed stream including at least one silane comonomer to the at least one reactor at at least one location along the reactor.

Abstract: The present invention relates to a semi-conductive polymer composition, the present invention provides a semi-conductive polymer composition comprising an ethylene copolymer comprising polar co-monomer units; an olefin homo- or copolymer; and a conductive filler; wherein the olefin homo- or copolymer has a degree of crystallinity below 20%. The invention also relates to a wire or cable comprising said semi-conductive polymer composition, and to the use of said composition for the production of a layer, preferably a semi-conducting shield layer of a wire or cable.

Abstract: The present invention relates to a polyolefin composition comprising (A) a crosslinkable polyolefin with hydrolysable silane groups which upon hydrolysation form an acid or a base, characterised in that the acid or base generates a gel content of at least 40% after 40 hours in the 90° C. cross-linking test, wherein the acid or base is added in an amount of 4.5 mmol/kg to an ethylene/vinyltrimethoxysilane copolymer with a MFR2=2 g/10 min, a density of 923 g/cm3, and 2 wt. % of vinyltrimethoxysilane and then is cross-linked in a waterbath at 90° C., and to a polyolefin composition comprising (i) a crosslinkable polyolefin with hydrolysable silane groups, and (ii) a non-polymeric compound with hydrolysable silane groups which upon hydrolysation form an acid or a base, characterised in that the acid or base generates a gel content of at least 40% after 40 hours in the 90° C. cross-linking test, wherein the acid or base is added in an amount of 4.

Abstract: The present invention relates to a polyolefin composition comprising a cross-linkable polyolefin with (A) hydrolysable silane groups which upon hydrolysation form an acid or a base, (B) hydrolysable silane groups different from silane groups (A).

Abstract: The present invention relates to a composition comprising (i) a crosslinkable polyolefin with hydrolysable silane groups (A), (ii) a silanol condensation catalyst (B) of the formula Ar(SO3H)x as defined herein, and (iii) a silicon containing compound (C) selected from the group consisting of 3-ureidopropyltrimethoxysilane, N-trimethoxysilylmethyl-O-methylcarbamate, and mixtures thereof; to an article, in particular a wire or cable, comprising such a composition, and to the use of such a composition for producing the article. The present invention further relates to the use of silicon containing compound (C) as a processing aid in the compounding of polyolefin compositions and as a surface smoothening agent in polyolefin compositions.

Abstract: The present invention relates to a composition comprising (i) a crosslinkable polyolefin with hydrolysable silane groups (A), (ii) a silanol condensation catalyst (B), and (iii) a silicon containing compound (C) according to the formula (R1)x[Si(R2)yR3)z]m (I) wherein R1, which may be the same or different if more than one such group is present, is a monofunctional, or, if m=2, is a bifunctional, hydrocarbyl residue comprising from 1 to 100 carbon atoms and at least one heteroatom; R2, which may be the same or different if more than one such group is present, is a hydrocarbyloxy residue comprising from 1 to 100 carbon atoms; R3, is —R4SiR1pR2q, wherein p is 0 to 3, q is 0 to 3, with the proviso that p+q is 3, and R4 is —(CH2)rYs(CH2)t— where r and t independently are 1 to 3, s is 0 or 1 and Y is a difunctional heteroatomic group selected from —O—, —O—(CO)—, —NH—, —NH2, —NH—(CO)—NH2, —NH—(CO)—OCH3, an epoxy group, a carbamate group, —S—, —SO—, —SO2—, —NR—, —PR—, where R is a hydrocarbon or a hydrogen and where

Abstract: Hence, according to the present invention, an energy monitoring apparatus (100) is provided. The energy monitoring apparatus comprises a detector (111) configured to detect light from a flashing lamp (11) on an energy meter (10) and provide a detector signal based on the detected light. The flashing frequency of the lamp indicates energy consumption metered by the energy meter. The energy monitoring apparatus further comprises a signal adjusting component (112) configured to process the detector signal and output a rescaled signal (based on the processed detector signal), and a controller (121) configured to adaptively control the signal adjusting component such that, responsive to detection of light from the flashing lamp, the rescaled signal pulsates (or oscillates) around a predetermined threshold level. The present invention is advantageous in that it can be used for a wide range of energy meter lamps.

Abstract: The present invention relates to a composition comprising (i) a crosslinkable polyolefin with hydrolysable silane groups (A), and (ii) a silanol condensation catalyst comprising an organic sulphonic acid (B) which comprises the structural element Ar—R1 (I) wherein Ar is an aromatic group, which may e.g. be a benzene, naphthalene, phenantrene or anthracene group, and R1 is an organic residue comprising at least 21 C-atoms, the organic sulphonic acid (B) further comprising one, two or more sulphonic acid groups, to an article, in particular a wire or cable, comprising such a composition, and to the use of such a composition for the production of an article.

Abstract: The present invention is directed to particular titanium dioxide containing compositions which allow the retention of a high crosslinking performance of a polyolefin composition comprising a crosslinkable polyolefin with hydrolysable silane groups, a Brönstedt acid silanol condensation catalyst and said titanium dioxide containing composition. The retention of the high crosslinking performance is shown by a difference in torque measured at 120° C. of 40 Nm or higher.

Abstract: The present invention relates to a polyolefin composition comprising (A) a crosslinkable polyolefin with hydrolysable silane groups which upon hydrolysation form an acid or a base, characterised in that the acid or base generates a gel content of at least 40% after 40 hours in the 90° C. cross-linking test, wherein the acid or base is added in an amount of 4.5 mmol/kg to an ethylene/vinyltrimethoxysilane copolymer with a MFR2=2 g/10 min, a density of 923 g/cm3, and 2 wt. % of vinyltrimethoxysilane and then is cross-linked in a waterbath at 90° C., and to a polyolefin composition comprising (i) a crosslinkable polyolefin with hydrolysable silane groups, and (ii) a non-polymeric compound with hydrolysable silane groups which upon hydrolysation form an acid or a base, characterised in that the acid or base generates a gel content of at least 40% after 40 hours in the 90° C. cross-linking test, wherein the acid or base is added in an amount of 4.

Abstract: The present invention relates to a polyolefin composition comprising a cross-linkable polyolefin with (A) hydrolysable silane groups which upon hydrolysation form an acid or a base, (B) hydrolysable silane groups different from silane groups (A).