Patents by Inventor Roger L. Klaus

Roger L. Klaus has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 5858640
    Abstract: This invention provides a thermally processable imaging element comprising a support and a thermographic or photothermographic imaging layer, said imaging layer comprising a sulfenimide compound represented by the formula: ##STR1## wherein M represents the atoms necessary to form, with R.sup.1 and R.sup.2, a five or six-membered ring or a multiple ring system; w is 1 or 0, wherein when w is 0, R.sup.1 and R.sup.2 are independently substituted or unsubstituted aliphatic, aromatic or heterocyclic groups, and when w is 1, R.sup.1 and R.sup.2 are independently carbonyl or sulfonyl groups; R.sup.3 is independently a substituted or unsubstituted aliphatic, aromatic or heterocyclic group and x is 0 or 1.In one embodiment the thermally processable imaging element comprises:(a) photographic silver halide, and(b) an image-forming combination comprising(i) an organic silver salt oxidizing agent, with(ii) a reducing agent for the organic silver salt oxidizing agent.
    Type: Grant
    Filed: May 16, 1997
    Date of Patent: January 12, 1999
    Assignee: Eastman Kodak Company
    Inventors: Peter J. Cowdery-Corvan, Roger L. Klaus, Franklin D. Saeva
  • Patent number: 5849470
    Abstract: The invention relates to a photographic element comprising at least two photographic emulsions wherein the grains of said at least two emulsions are the same and wherein at least one of said at least two emulsions is treated with a speed decreasing compound.
    Type: Grant
    Filed: April 23, 1997
    Date of Patent: December 15, 1998
    Assignee: Eastman Kodak Company
    Inventors: Jerzy Z. Mydlarz, Frederick C. Derks, Roger L. Klaus
  • Patent number: 5840473
    Abstract: The invention relates to a photographic element comprising at least two photographic emulsions wherein the grains of said at least two emulsions are the same and wherein at least one of said at least two emulsions is treated with a speed decreasing compound of Formula I:Z.sup.1 --X.sup.1 O.sub.2 S--M.sup.1 (I)and a compound of Formula II:Z.sup.2 --X.sup.2 O.sub.x --M.sup.2 (II)wherein X.sup.1 is sulfur and X.sup.2 is selected from the group consisting of sulfur and selenium, M.sup.1 and M.sup.2 are independently selected from group consisting of a metal ion and ##STR1## wherein R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are independently selected from the group consisting of hydrogen and an alkyl of 1-3 carbon atoms, and Z.sup.1 and Z.sup.
    Type: Grant
    Filed: April 23, 1997
    Date of Patent: November 24, 1998
    Assignee: Eastman Kodak Company
    Inventors: Jerzy Z. Mydlarz, Roger L. Klaus, Frederick C. Derks
  • Patent number: 5750324
    Abstract: This invention relates to a silver halide photographic element for digital exposure comprising a cubical silver chloride emulsion precipitated and/or chemically sensitized in the presence of an aryliodonium compound represented by the formula: ##STR1## wherein R.sup.1 and R.sup.2 and R.sup.3 are independently H, or aliphatic, aromatic or heterocyclic groups, alkoxy groups, hydroxy groups, halogen atoms, aryloxy groups, alkylthio groups, arylthio groups, acyl groups, sulfonyl groups, acyloxy groups, carboxyl groups, cyano groups, nitro groups, sulfo groups, alkylsulfoxide or trifluoralkyl groups, or any two of R.sup.1, R.sup.2 and R.sup.3 together represent the atoms necessary to form a five or six-membered ring or a multiple ring system;R.sup.4 is a carboxylate salt or 0.sup.- ; w is 0 or 1; and X.sup.- is an anionic counter ion; with the proviso that when R.sup.3 is a carboxyl or sulfo group, w is 0 and R.sup.4 is 0.sup.-.
    Type: Grant
    Filed: January 8, 1997
    Date of Patent: May 12, 1998
    Assignee: Eastman Kodak Company
    Inventors: Jerzy Z. Mydlarz, Roger L. Klaus, Franklin D. Saeva
  • Patent number: 5733717
    Abstract: This invention relates to a silver halide photographic element comprising a silver halide emulsion precipitated and/or chemically sensitized in the presence of an aryliodonium compound represented by the formula: ##STR1## wherein R.sup.1 and R.sup.2 and R.sup.3 are independently H, or aliphatic, aromatic or heterocyclic groups, alkoxy groups, hydroxy groups, halogen atoms, aryloxy groups, alkylthio groups, arylthio groups, acyl groups, sulfonyl groups, acyloxy groups, carboxyl groups, cyano groups, nitro groups, sulfo groups, alkylsulfoxide or trifluoralkyl groups, or any two of R.sup.1, R.sup.2 and R.sup.3 together represent the atoms necessary to form a five or six-membered ring or a multiple ring system;R.sup.4 is a carboxylate salt or 0.sup.- ; w is 0 or 1; and X.sup.- is an anionic counter ion; with the proviso that when R.sup.3 is a carboxyl or sulfo group, w is 0 and R.sup.4 is 0.sup.-.
    Type: Grant
    Filed: January 8, 1997
    Date of Patent: March 31, 1998
    Assignee: Eastman Kodak Company
    Inventors: Franklin D. Saeva, Roger L. Klaus, Jerzy Z. Mydlarz
  • Patent number: 5714311
    Abstract: This invention provides a thermally processable imaging element comprising a support and a thermographic or photothermographic imaging layer, said imaging layer comprising an aryliodonium compound represented by the formula: ##STR1## wherein R.sup.1 and R.sup.2 and R.sup.3 are independently H, or aliphatic, aromatic or heterocyclic groups, alkoxy groups, hydroxy groups, halogen atoms, aryloxy groups, alkylthio groups, arylthio groups, acyl groups, sulfonyl groups, acyloxy groups, carboxyl groups, cyano groups, nitro groups, sulfo groups, alkylsulfoxide or trifluoralkyl groups, or any two of R.sup.1, R.sup.2 and R.sup.3 together represent the atoms necessary to form a five or six-membered ring or a multiple ring system;R.sup.4 is a carboxylate salt or 0.sup.- ; w is 0 or 1; and X.sup.- is an anionic counter ion; with the proviso that when R.sup.3 is a carboxyl or sulfo group, w is 0 and R.sup.4 is 0.sup.-.
    Type: Grant
    Filed: January 8, 1997
    Date of Patent: February 3, 1998
    Assignee: Eastman Kodak Company
    Inventors: Peter J. Cowdery-Corvan, Roger L. Klaus, Franklin D. Saeva
  • Patent number: 5418127
    Abstract: A disulfide compound represented by the following formula: ##STR1## wherein X is independently --O--, --NH-- or --NR--, where R is a substituent;m and r are independently 0, 1 or 2;M is --H or a cationic species;Ar is an aromatic group; andL is a linking group, where p is 0 or 1.A silver halide emulsion comprising said disulfide compounds and a photographic element comprising a silver halide emulsion in reactive association with said disulfide compounds and a method of making same.
    Type: Grant
    Filed: March 18, 1994
    Date of Patent: May 23, 1995
    Assignee: Eastman Kodak Company
    Inventors: Jerzy A. Budz, George J. Burgmaier, Roger L. Klaus, Xin Wen
  • Patent number: 5328820
    Abstract: This invention provides a method of preparing a silver halide photographic emulsion which comprises adding to the silver halide emulsion after precipitation and before or during sensitization a disulfide compound and a sulfinate compound, wherein the disulfide compound and the sulfinate compound are added simultaneously. It further provides a silver halide photographic emulsion prepared by the above method.
    Type: Grant
    Filed: November 19, 1992
    Date of Patent: July 12, 1994
    Assignee: Eastman Kodak Company
    Inventors: Roger L. Klaus, Patricia A. Leonard
  • Patent number: 5246825
    Abstract: Photosensitive silver halide emulsions are prepared by providing an emulsion containing an anionic acid-substituted organic ripening agent and a salt of an element in Group IIA of the Periodic Table and then growing silver halide grains in the emulsion. This combination of an acid-substituted organic ripener and a salt of a Group IIA element produces a superadditive effect on the growth of silver halide crystals.
    Type: Grant
    Filed: May 8, 1992
    Date of Patent: September 21, 1993
    Assignee: Eastman Kodak Company
    Inventors: Arthur H. Herz, Roger L. Klaus
  • Patent number: 5246827
    Abstract: A photosensitive silver halide emulsion is prepared by providing an emulsion containing an anionic acid-substituted and a neutral organic ripening agent and then growing silver halide grains in the emulsion. This combination of organic ripening agents of differing charge types produces a superadditive effect on the growth of silver halide crystals.
    Type: Grant
    Filed: May 8, 1992
    Date of Patent: September 21, 1993
    Assignee: Eastman Kodak Company
    Inventors: Arthur H. Herz, Roger L. Klaus, Dale E. Hamilton
  • Patent number: 5246826
    Abstract: The present invention relates to a process of preparing a photosensitive silver halide emulsion. In this process, an emulsion comprising an acid substituted organic ripening agent and a dispersing medium is prepared. Silver halide grains are then permitted to grow in the emulsion at a pH of from about 2 to about 4.6 to accelerate the growth of the silver halide grains. Subsequently, the pH of the emulsion is adjusted to a value of about 5.3 to about 7 to repress grain growth, to prevent interference with dye sensitization, and to limit fog formation, particularly during storage of the coated emulsion.
    Type: Grant
    Filed: May 8, 1992
    Date of Patent: September 21, 1993
    Assignee: Eastman Kodak Company
    Inventors: Arthur H. Herz, Roger L. Klaus, George J. Burgmaier
  • Patent number: 5219721
    Abstract: This invention provides a method of preparing a silver halide photographic emulsion which comprises adding to the silver halide emulsion before or during sensitization a non-labile chalcogen compound represented by Formula I:R.sup.1 --X.sup.1 --X.sup.2 --R.sup.2 (Formula I)It further provides a silver halide photographic emulsion prepared by the above method.
    Type: Grant
    Filed: April 16, 1992
    Date of Patent: June 15, 1993
    Assignee: Eastman Kodak Company
    Inventors: Roger L. Klaus, Ingo H. Leubner, Michael E. Ryan
  • Patent number: 5217859
    Abstract: This invention provides a method of preparing a silver halide photographic emulsion which comprises adding to the silver halide emulsion a solid particle dispersion of a non-labile chalcogen compound represented by Formula I:R.sup.1 --X.sup.1 --X.sup.2 --R.sup.2 (Formula I)It further provides a silver halide photographic emulsion prepared by the above method.
    Type: Grant
    Filed: April 16, 1992
    Date of Patent: June 8, 1993
    Assignee: Eastman Kodak Company
    Inventors: John W. Boettcher, Roger L. Klaus, Joseph W. Manthey
  • Patent number: 4782013
    Abstract: This invention is directed to a photographic element containing a radiation-sensitive silver halide emulsion layer and a macrocyclic thia or selena ether compound which also comprises oxygen atoms. These macrocyclic compounds are improved silver halide ripening agents.
    Type: Grant
    Filed: July 23, 1987
    Date of Patent: November 1, 1988
    Assignee: Eastman Kodak Company
    Inventors: Arthur H. Herz, Roger L. Klaus