Abstract: The use of gelatin-based copolymers containing at least one grafted side chain formed from ethylenically unsaturated compounds as an anti-accretion additive is proposed for water-based drilling fluids in the development, exploitation and completion of underground mineral oil and natural gas deposits and in deep wells. These copolymers are water-soluble and have good biodegradability.

Abstract: A process for producing mineral oil from underground mineral oil deposits, in which an aqueous formulation comprising at least one water-soluble, hydrophobically associating copolymer is injected through at least one injection well into a mineral oil deposit having a deposit temperature of 20° C. to 120° C. and crude oil is withdrawn from the deposit through at least one production well, wherein the water-soluble copolymer comprises at least acrylamide or derivatives thereof and a mixture comprising at least two amphiphilic macromonomers.

Abstract: The present invention relates to water-soluble hydrophobically associating copolymers which are obtained in the presence of a nonpolymerizable surface-active compound and which comprise novel hydrophobically associating monomers. The monomers comprise an ethylenically unsaturated group and a polyether block, the polyether block comprising a hydrophilic polyethyleneoxy block and a hydrophobic polyalkyleneoxy block consisting of alkyleneoxy units having at least 4 carbon atoms. The monomers may optionally have a terminal polyethyleneoxy block. The invention further relates to processes for preparing the copolymers and to the use thereof.

Abstract: Process for tertiary mineral oil production in which an aqueous injection fluid comprising at least a water soluble polyacrylamide-(co)polymer dissolved in the aqueous fluid is injected into a mineral oil deposit and the aqueous injection fluid is prepared by mixing a liquid dispersion polymer composition comprising particles of polyacrylamide-(co)polymers dispersed in an organic, hydrophobic liquid with an aqueous fluid. Preferably, the process is carried out on an off-shore production site.

Abstract: The present invention relates to a process for preparing hydrophobically associating macromonomers M and to the novel macromonomers prepared by means of the process according to the invention. The macromonomers M comprise a copolymerizable, ethylenically unsaturated group and a polyether structure in block form, the latter consisting of a polyethyleneoxy block and a hydrophobic polyalkyleneoxy block consisting of alkyleneoxy units having at least 4 carbon atoms. Optionally, the macromonomers M may have a terminal polyethyleneoxy block. The macromonomers prepared by the process according to the invention are suitable for reaction with further monomers, especially with acrylamide, to give a water-soluble, hydrophobically associating copolymer.

Abstract: A process for producing mineral oil from underground mineral oil deposits, in which an aqueous formulation comprising at least one water-soluble, hydrophobically associating copolymer is injected through at least one injection well into a mineral oil deposit having a deposit temperature of 20° C. to 120° C. and crude oil is withdrawn from the deposit through at least one production well, wherein the water-soluble copolymer comprises at least acrylamide or derivatives thereof and a mixture comprising at least two amphiphilic macromonomers.

Abstract: Methods of a setting accelerator composition for inorganic binders which comprises at least one water-soluble comb polymer suitable as a superplasticizer for hydraulic binders and calcium silicate hydrate particles in the development, exploitation and completion of underground mineral oil and natural gas deposits and in deep wells which not only accelerates the setting and hardening of the cement slurries but also shortens the time in which the static gel strength of the hardening cement slurries increases from 100 lb/100 ft2 (4.88 kg/m2) to 500 lb/100 ft2 (24.4 kg/m2).

Abstract: The present application relates to compositions comprising at least one acrylamide polymer P and at least one stabilizer S selected from sterically hindered amines; more particularly, the composition may be an aqueous solution comprising at least one acrylamide polymer P and at least one stabilizer S. In addition, the present invention relates to a process for producing the composition and to the use thereof in mineral oil production.

Abstract: Water-soluble, hydrophobically associating copolymer comprising a monoethylenically unsaturated, water-soluble, surface-active monomer (a), and a monoethylenically unsaturated, hydrophilic monomer (b) different from monomer (a). The copolymer is prepared in the presence of a nonpolymerizable surfactant and has marked thickening properties in aqueous systems.

Abstract: The present invention relates to water-soluble hydrophobically associating copolymers which are obtained in the presence of a nonpolymerizable surface-active compound and which comprise novel hydrophobically associating monomers. The monomers comprise an ethylenically unsaturated group and a polyether block, the polyether block comprising a hydrophilic polyethyleneoxy block and a hydrophobic polyalkyleneoxy block consisting of alkyleneoxy units having at least 4 carbon atoms. The monomers may optionally have a terminal polyethyleneoxy block. The invention further relates to processes for preparing the copolymers and to the use thereof.

Abstract: The present invention relates to a process for preparing hydrophobically associating macromonomers M and to the novel macromonomers prepared by means of the process according to the invention. The macromonomers M comprise a copolymerizable, ethylenically unsaturated group and a polyether structure in block form, the latter consisting of a polyethyleneoxy block and a hydrophobic polyalkyleneoxy block consisting of alkyleneoxy units having at least 4 carbon atoms. Optionally, the macromonomers M may have a terminal polyethyleneoxy block. The macromonomers prepared by the process according to the invention are suitable for reaction with further monomers, especially with acrylamide, to give a water-soluble, hydrophobically associating copolymer.

Abstract: Water-soluble, hydrophobically associating copolymers which comprise new types of hydrophobically associating monomers. The monomers comprise an ethylenically unsaturated group and a polyether group with block structure comprising a hydrophilic polyalkylene oxide block which consists essentially of ethylene oxide groups, and a terminal, hydrophobic polyalkylene oxide block which consists of alkylene oxides with at least 4, preferably at least 5 carbon atoms.

Abstract: The use of gelatin-based copolymers containing at least one grafted side chain formed from ethylenically unsaturated compounds as an anti-accretion additive is proposed for water-based drilling fluids in the development, exploitation and completion of underground mineral oil and natural gas deposits and in deep wells. These copolymers are water-soluble and have good biodegradability.

Abstract: What is proposed is the use of a water-soluble hydrophobically associating copolymer as an additive in the development, exploitation and completion of underground mineral oil and natural gas deposits and in deep drillings, wherein the copolymer comprises (a) at least one monoethylenically unsaturated monomer (a) selected from H2C?C(R1)—R4—O—(—CH2—CH2—O—)k—(—CH2—CH(R3)—O—)l—R5??(I), and/or H2C?C(R1)—O—(—CH2—CH2—O—)k—R2??(II), and (b) at least one monoethylenically unsaturated, hydrophilic monomer (b) different from monomer (a), wherein the copolymer is obtainable through copolymerization of the monomers (a) and (b) in the presence of at least one surfactant (c).

Abstract: Graft copolymers based on a polyamide which was reacted with maleic anhydride and which has at least one vinylically unsaturated side chain are proposed, this grafted side chain containing at least one representative selected from a) N-vinylcaprolactam and/or b) N-vinylpyrrolidone. Inter alia, natural but also synthetic polyamides are provided as preferred polyamide components. Such graft copolymers, but also generally polyamide-based graft copolymers composed of at least one side chain containing ethylenically unsaturated compounds, are in general suitable in construction chemistry applications but also in the development, exploitation and completion of underground mineral oil and natural gas deposits and in deep wells and moreover in the extraction and the transport of oil or gas and here in particular as a gas hydrate inhibitor.

Abstract: A process for mineral oil production, in which an aqueous formulation comprising at least one water-soluble, hydrophobically associating copolymer is injected through at least one injection borehole into a mineral oil deposit, and crude oil is withdrawn from the deposit having a deposit temperature of 35° C. to 120° C., preferably 40° C. to 90° C., through at least one production borehole, wherein the water-soluble, hydrophobically associating copolymer comprises at least acrylamide or derivatives thereof, a monoethylenically unsaturated monomer having anionic groups and a monoethylenically unsaturated monomer which can bring about the association of the copolymer.

Abstract: What is proposed is the use of a terpolymer comprising 5-95 mol % of 2-acrylamido-2-methylpropanesulfonic acid, 5-95 mol % of N,N-dimethylacrylamide and 5-12 mol % of acrylic acid as a fluid loss additive in well cementing.

Abstract: Water-soluble, hydrophobically associating copolymers which comprise new types of hydrophobically associating monomers. The monomers comprise an ethylenically unsaturated group and a polyether group with block structure comprising a hydrophilic polyalkylene oxide block which consists essentially of ethylene oxide groups, and a terminal, hydrophobic polyalkylene oxide block which consists of alkylene oxides with at least 4, preferably at least 5 carbon atoms.

Abstract: A graft polymer mixture comprising a grafting base based on brown coal and/or polyphenol is proposed, which has, as a graft component, a copolymer consisting of one or more ethylenically unsaturated monomers different from one another and one or more polyamides different from one another. Typical grafting bases are brown coal, brown coal coke, lignite and brown coal derivatives and tannins. Suitable graft components are in particular vinyl-containing components and styrenes, which may also be present in sulphonated form. Natural polyamides, such as, for example, casein, gelatin and collagen, are suitable polyamide components. These graft polymers having a preferred molar mass Mn>5000 g/mol are suitable as a mixture, in particular in construction chemistry applications, and in the development, exploitation and completion of underground mineral oil and natural gas deposits, and in deep wells, since they have excellent salt and temperature stabilities and are simultaneously water-soluble and/or biodegradable.

Abstract: Water-soluble, hydrophobically associating copolymers which comprise new types of hydrophobically associating monomers. The monomers comprise an ethylenically unsaturated group and a polyether group with block structure comprising a hydrophilic polyalkylene oxide block which consists essentially of ethylene oxide groups, and a terminal, hydrophobic polyalkylene oxide block which consists of alkylene oxides with at least 4, preferably at least 5 carbon atoms.