Patents by Inventor Rolf Drewes

Rolf Drewes has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20060138391
    Abstract: Flame retardants are described, comprising (A) at least one metal or metalloid salt of a phosphonic acid of formula (I) wherein R is hydrogen, C1-C18alkyl, C5-C6cycloalkyl, C2-C6alkenyl, C6-C10aryl or C7-C11aralkyl and R? is hydrogen, C1-C8alkyl, C6-C10aryl or C7-C11aralkyl, the substituents R and R? that are other than hydrogen being unsubstituted or substituted by halogen, hydroxyl, amino, C1-C4alkylamino, di-C1-C4alkoxy, carboxy or C2-C5alkoxycarbonyl; and the metal or metalloid is one from Group IA, IB, IIA, IIB, IA, IVA, VA or VII of the Periodic Table; and (B) at least one flame retardant component based on a nitrogen compound, and also the use thereof in synthetic polymers.
    Type: Application
    Filed: November 12, 2003
    Publication date: June 29, 2006
    Inventors: Rolf Drewes, Nicolaas Aelmans
  • Patent number: 6531533
    Abstract: Halogen-containing polymers or the recyclates thereof are stabilized by the addition of (a) a halogen-containing polymer or a recyclate thereof; (b) at least one zeolite in the form of sodium, potasssium and/or lithium, in particular at least one zeolite of formula M2O.Al2O3.x SiO2.y H2O  (I), wherein M is Na, K or Li, x is 2 to 12, and y is 1 to 15, with the exception of zeolite A, Na12Al12Si12O48.27 H2O and clinoptilolite Na6Al6Si30O72.2 H2O, (c) at least one organic zinc, aluminium or rare earth compound, and/or (d) at least one organotin compound, as described in more detail in claim 1.
    Type: Grant
    Filed: February 12, 1997
    Date of Patent: March 11, 2003
    Assignee: Crompton Vinyl Additives GmbH
    Inventors: Karl Josef Kuhn, Wolfgang Wehner, Rolf Drewes
  • Patent number: 6310128
    Abstract: A polyoxyalkylene compound and an inorganic salt are used to reduce the tendency of halogen-containing polymers to build up electrostatic charge and at the same time to achieve good stability.
    Type: Grant
    Filed: June 24, 1996
    Date of Patent: October 30, 2001
    Assignee: Witco Vinyl Additives GmbH
    Inventors: Bruno Hilti, Ernst Minder, Jürgen Pfeiffer, Rolf Drewes
  • Patent number: 6194494
    Abstract: A stabiliser combination, mainly for PVC, is described, comprising A) at least one compound of formula I  wherein R*1 and R*2 are each independently of the other C1-C12alkyl, C3-C6lkenyl, C5-C8cycloalkyl that is unsubstituted or substituted by from 1 to 3 C1-C4alkyl, C1-C4alkoxy, C5-C8cycloalkyl or by hydroxy groups or by chlorine atoms, or C7-C9phenylalkyl that is unsubstituted or substituted at the phenyl ring by from 1 to 3 C1-C4alkyl, C1-C4alkoxy, C5-C8cycloalkyl or by hydroxy groups or chlorine atoms, and R*1 and R*2 may additionally be hydrogen and C1-C12alkyl, and Y is S or O, and B) at least one compound from the following groups: B1) perchlorate compounds, B2) glycidyl compounds, B3) beta-diketones and beta-keto esters, B4) dihydropyridines and polydihydropyridines, B5) polyols and disaccharide alcohols, B6) sterically hindered amines (tetraalkylpiperidine compounds), B7) alkali aluminosilicates (zeolites), B8) hydrotalcites, B9) alkali aluminocarbonates (dawsonite
    Type: Grant
    Filed: June 30, 1998
    Date of Patent: February 27, 2001
    Assignee: Witco Vinyl Additives GmbH
    Inventors: Wolfgang Wehner, Hans-Helmut Friedrich, Kornelia Malzacher, Hans-Ludwig Mehner, Rolf Drewes
  • Patent number: 6174941
    Abstract: A description is given of compounds of the general formula I where Y is oxygen or sulfur, and R1 and R2 independently of one another are C1-C18-alkyl, C3-C6-alkenyl, unsubstituted or C1-C4-alkoxy-, C5-C8-cycloalkyl-, —OH— and/or Cl-substituted C1-C18-alkyl, C5-C8-cycloalkyl, phenyl or C7-C9-phenylalkyl which is unsubstituted or substituted on the phenyl ring by C1-C4-alkyl, C1-C4-alkoxy, C5-C8-cycloalkyl, —OH and/or Cl, and R3 is unsubstituted C9-C18-alkyl or is C1-C18-alkyl substituted by —OH, C1-C12-alkoxy, phenoxy, C6-C8-alkylphenoxy, C7-C9-alkoxyphenyl, —C═O(OR4) and/or —O—COR4, or is C3-C6-alkenyl, C5-C8-cycloalkyl, or mono- to tri-OH—, —C1-C4-alkyl-, —C1-C4-alkoxy-, —C═O(OR4)— and/or —O—COR4-substituted phenyl or naphthyl, and where R4 is C1-C12-alkyl, which are suitable for stabilizing chlorine-containing polymers, especially PVC.
    Type: Grant
    Filed: June 18, 1999
    Date of Patent: January 16, 2001
    Assignee: Witco Vinyl Additives GmbH
    Inventors: Wolfgang Wehner, Hans-Helmut Friedrich, Rolf Drewes
  • Patent number: 6002004
    Abstract: The invention relates to compositions comprisinga) a chlorine-containing polymer andb) at least one compound containing at least one radical of the formula I ##STR1## in which A is the additional groups or atoms necessary to form an unsubstituted or substituted six-membered heterocyclic ring containing two nitrogen ring atoms.
    Type: Grant
    Filed: January 14, 1998
    Date of Patent: December 14, 1999
    Assignee: Witco Vinyl Additives GmbH
    Inventors: Wolfgang Wehner, Hans-Helmut Friedrich, Rolf Drewes
  • Patent number: 5985964
    Abstract: High stabilization of PVC containing recycled material is achieved by using at least one lubricant and a stabilizer containing no lead or cadmium compounds.
    Type: Grant
    Filed: December 18, 1997
    Date of Patent: November 16, 1999
    Assignee: Witco Vinyl Additives GmbH
    Inventors: Heinz Herbst, Kurt Hoffmann, Rudolf Pfaendner, Rolf Drewes
  • Patent number: 5925696
    Abstract: A stabilizer combination, mainly for PVC, is described, comprisingA) at least one compound of formula I ##STR1## wherein R*.sub.1 and R*.sub.2 are each independently of the other C.sub.1 -C.sub.12 alkyl, C.sub.3 -C.sub.6 lkenyl, C.sub.5 -C.sub.8 cycloalkyl that is unsubstituted or substituted by from 1 to 3 C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.5 -C.sub.8 cycloalkyl or by hydroxy groups or by chlorine atoms, or C.sub.7 -C.sub.9 phenylalkyl that is unsubstituted or substituted at the phenyl ring by from 1 to 3 C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.5 -C.sub.8 cycloalkyl or by hydroxy groups or chlorine atoms,and R*.sub.1 and R*.sub.2 may additionally be hydrogen and C.sub.1 -C.sub.
    Type: Grant
    Filed: October 10, 1996
    Date of Patent: July 20, 1999
    Assignee: Ciba Speciality Chemicals Corporation
    Inventors: Wolfgang Wehner, Hans-Helmut Friedrich, Kornelia Malzacher, Hans-Ludwig Mehner, Rolf Drewes
  • Patent number: 5859100
    Abstract: Compositions are described, comprisingA) rigid or semi-rigid PVC having a plasticiser content of up to 20%, andB) at least one compound of formula 1, ##STR1## wherein X is O or S, and R is H or phenyl, with the proviso that compounds from the groups of the perchlorate compounds, glycidyl compounds, beta-diketones, beta-keto esters, dihydropyridines, polydihydro-pyridines, polyols, disaccharide alcohols, sterically hindered amines (tetraalkylpiperidine compounds), alkali alumosilicates (zeolites), hydrotalcites, alkali alumocarbonates (dawsonites) are not present.
    Type: Grant
    Filed: September 22, 1997
    Date of Patent: January 12, 1999
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Wolfgang Wehner, Hans-Helmut Friedrich, Rolf Drewes, Kornelia Malzacher
  • Patent number: 5770643
    Abstract: The invention relates to compositions comprisinga) a chlorine-containing polymer andb) at least one compound containing at least one radical of the formula I ##STR1## in which A is the additional groups or atoms necessary to form an unsubstituted or substituted six-membered heterocyclic ring containing two nitrogen ring atoms.
    Type: Grant
    Filed: March 20, 1996
    Date of Patent: June 23, 1998
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Wolfgang Wehner, Hans-Helmut Friedrich, Rolf Drewes
  • Patent number: 5543449
    Abstract: A high degree of stabilization of flexible PVC is achieved by using a perchlorate and a terminal epoxide compound.
    Type: Grant
    Filed: April 10, 1995
    Date of Patent: August 6, 1996
    Assignee: Ciba-Geigy Corporation
    Inventors: Rolf Drewes, Markus Kolb, Karl J. Kuhn, Hans-J urgen Sander, Wolfgang Wehner
  • Patent number: 5534566
    Abstract: Use of a di- or polysaccharide alcohol and an inorganic or organic zinc, aluminum or rare-earth compound allows a high degree of stabilization of a halogen-containing polymer or polymer recyclate.
    Type: Grant
    Filed: April 10, 1995
    Date of Patent: July 9, 1996
    Assignee: Ciba-Geigy Corporation
    Inventors: Wolfgang Wehner, Rolf Drewes, Karl J. Kuhn, Hans-Jurgen Sander, Markus Kolb
  • Patent number: 5519077
    Abstract: A high degree of stabilization of polyvinyl chloride is achieved by using a perchlorate, a terminal epoxide compound and an antioxidant.
    Type: Grant
    Filed: April 10, 1995
    Date of Patent: May 21, 1996
    Assignee: Ciba-Geigy Corporation
    Inventors: Rolf Drewes, Markus Kolb, Karl J. Kuhn, Hans-Jurgen Sander, Wolfgang Wehner
  • Patent number: 5492949
    Abstract: Use of an inorganic or organic zinc compound and a terminal epoxide compound, optionally with chalk, gives a high level of stabilization of PVC.
    Type: Grant
    Filed: April 12, 1994
    Date of Patent: February 20, 1996
    Assignee: Ciba-Geigy Corporation
    Inventors: Rolf Drewes, Markus Kolb, Karl Kuhn, Wolfgang Wehner
  • Patent number: 5344992
    Abstract: There is disclosed a process for the preparation of 1,3-diketones of formula I ##STR1## wherein R.sub.1 and R.sub.2 are each independently of the other C.sub.1 -C.sub.20 alkyl, phenyl or phenyl which is substituted by halogen, hydroxy, NO.sub.2, C.sub.1 -C.sub.4 alkyl and/or C.sub.1 -C.sub.4 alkoxy, C.sub.7 -C.sub.9 phenylalkyl or a radical of formula II--A--X--R.sub.4 (II)whereinA is C.sub.1 -C.sub.12 alkylene, phenylene or phenylene which is substituted by halogen, hydroxy, NO.sub.2, C.sub.1 -C.sub.4 alkyl and/or C.sub.1 -C.sub.4 alkoxy, or is C.sub.1 -C.sub.12 alkylene which is substituted by hydroxy, halogen and/or alkoxy,X is oxygen or sulfur, andR.sub.4 is hydrogen, C.sub.1 -C.sub.18 alkyl, phenyl or phenyl which is substituted by halogen, hydroxy,C.sub.1 -C.sub.4 alkyl, NO.sub.2 and/or C.sub.1 -C.sub.4 alkoxy, or is C.sub.7 -C.sub.9 phenylalkyl, andR.sub.3 is hydrogen, C.sub.1 -C.sub.20 alkyl, phenyl or phenyl which is substituted by halogen, hydroxy, C.sub.1 -C.sub.4 alkyl, NO.sub.2 and/or C.sub.1 -C.
    Type: Grant
    Filed: May 11, 1993
    Date of Patent: September 6, 1994
    Assignee: Ciba-Geigy Corporation
    Inventors: Rolf Drewes, Hans-Helmut Friedrich, Hans-Ludwig Mehner, Bernd Braun, Walter Wecht
  • Patent number: 5322964
    Abstract: There is disclosed a process for the preparation of an alpha-aminoketone salt of formula I ##STR1## which comprises reacting a nitrosated keto ester of formula II ##STR2## with a carboxylic anhydride of formula IV ##STR3## under the conditions of catalytic hydrogenation, to a compound of formula III ##STR4## which compound of formula III is then hydrolysed with an acid H.sub.n A to the salt I, in which formulae above R.sub.1 is C.sub.1 -C.sub.6 alkyl, phenoxy-C.sub.1 -C.sub.4 alkyl, phenyl, C.sub.7 -C.sub.9 phenylalkyl, or phenyl or C.sub.7 -C.sub.9 phenylalkyl which are substituted by halogen, C.sub.1 -C.sub.6 alkyl or C.sub.1 -C.sub.6 alkoxy, hydroxy or cyano, R.sub.2 is C.sub.1 -C.sub.4 alkyl or cyclohexyl, n is 1 to 3, R.sub.3 is C.sub.1 -C.sub.4 alkyl and A is the radical of an organic or mineral protic acid.Pyrroles suitable as co-stabilisers for PVC can be prepared from alpha-aminoketone salts of formula I.
    Type: Grant
    Filed: September 8, 1993
    Date of Patent: June 21, 1994
    Assignee: Ciba-Geigy Corporation
    Inventors: Rolf Drewes, Hans-Helmut Friedrich
  • Patent number: 5288776
    Abstract: A composition comprisinga) a chlorinated polymer, andb) at least one compound of formula I ##STR1## wherein X is a group ##STR2## R.sub.1 and R.sub.2 are each independently of the other C.sub.1 -C.sub.20 alkyl, hydroxy- and/or halogen-substituted C.sub.1 -C.sub.10 alkyl, C.sub.3 -C.sub.20 alkenyl, C.sub.5 -C.sub.12 cycloalkyl, C.sub.1 -C.sub.4 alkyl-substituted C.sub.5 -C.sub.8 cycloalkyl, phenyl or phenyl which is substituted by 1 to 3 radicals A.sub.1, which radicals A.sub.1 are each independently of one another selected from the group consisting of C.sub.1 -C.sub.10 alkyl, halogen, hydroxy, methoxy and ethoxy,R.sub.1 and R.sub.2 are further C.sub.7 -C.sub.10 phenylalkyl or C.sub.7 -C.sub.10 phenylalkyl which is substituted in the phenyl moiety by 1 to 3 radicals A.sub.2, which radicals A.sub.2 are each independently of one another selected from the group consisting of C.sub.1 -C.sub.20 alkyl, halogen, hydroxy, methoxy and ethoxy, andR.sub.3 is phenyl or phenyl which is substituted by 1 to 3 radicals A.sub.
    Type: Grant
    Filed: June 3, 1991
    Date of Patent: February 22, 1994
    Assignee: Ciba-Geigy Corporation
    Inventors: Rolf Drewes, Hans-Helmut Friedrich