Patents by Inventor Rolf Drewes
Rolf Drewes has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Publication number: 20060138391Abstract: Flame retardants are described, comprising (A) at least one metal or metalloid salt of a phosphonic acid of formula (I) wherein R is hydrogen, C1-C18alkyl, C5-C6cycloalkyl, C2-C6alkenyl, C6-C10aryl or C7-C11aralkyl and R? is hydrogen, C1-C8alkyl, C6-C10aryl or C7-C11aralkyl, the substituents R and R? that are other than hydrogen being unsubstituted or substituted by halogen, hydroxyl, amino, C1-C4alkylamino, di-C1-C4alkoxy, carboxy or C2-C5alkoxycarbonyl; and the metal or metalloid is one from Group IA, IB, IIA, IIB, IA, IVA, VA or VII of the Periodic Table; and (B) at least one flame retardant component based on a nitrogen compound, and also the use thereof in synthetic polymers.Type: ApplicationFiled: November 12, 2003Publication date: June 29, 2006Inventors: Rolf Drewes, Nicolaas Aelmans
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Patent number: 6531533Abstract: Halogen-containing polymers or the recyclates thereof are stabilized by the addition of (a) a halogen-containing polymer or a recyclate thereof; (b) at least one zeolite in the form of sodium, potasssium and/or lithium, in particular at least one zeolite of formula M2O.Al2O3.x SiO2.y H2O (I), wherein M is Na, K or Li, x is 2 to 12, and y is 1 to 15, with the exception of zeolite A, Na12Al12Si12O48.27 H2O and clinoptilolite Na6Al6Si30O72.2 H2O, (c) at least one organic zinc, aluminium or rare earth compound, and/or (d) at least one organotin compound, as described in more detail in claim 1.Type: GrantFiled: February 12, 1997Date of Patent: March 11, 2003Assignee: Crompton Vinyl Additives GmbHInventors: Karl Josef Kuhn, Wolfgang Wehner, Rolf Drewes
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Patent number: 6310128Abstract: A polyoxyalkylene compound and an inorganic salt are used to reduce the tendency of halogen-containing polymers to build up electrostatic charge and at the same time to achieve good stability.Type: GrantFiled: June 24, 1996Date of Patent: October 30, 2001Assignee: Witco Vinyl Additives GmbHInventors: Bruno Hilti, Ernst Minder, Jürgen Pfeiffer, Rolf Drewes
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Patent number: 6194494Abstract: A stabiliser combination, mainly for PVC, is described, comprising A) at least one compound of formula I wherein R*1 and R*2 are each independently of the other C1-C12alkyl, C3-C6lkenyl, C5-C8cycloalkyl that is unsubstituted or substituted by from 1 to 3 C1-C4alkyl, C1-C4alkoxy, C5-C8cycloalkyl or by hydroxy groups or by chlorine atoms, or C7-C9phenylalkyl that is unsubstituted or substituted at the phenyl ring by from 1 to 3 C1-C4alkyl, C1-C4alkoxy, C5-C8cycloalkyl or by hydroxy groups or chlorine atoms, and R*1 and R*2 may additionally be hydrogen and C1-C12alkyl, and Y is S or O, and B) at least one compound from the following groups: B1) perchlorate compounds, B2) glycidyl compounds, B3) beta-diketones and beta-keto esters, B4) dihydropyridines and polydihydropyridines, B5) polyols and disaccharide alcohols, B6) sterically hindered amines (tetraalkylpiperidine compounds), B7) alkali aluminosilicates (zeolites), B8) hydrotalcites, B9) alkali aluminocarbonates (dawsoniteType: GrantFiled: June 30, 1998Date of Patent: February 27, 2001Assignee: Witco Vinyl Additives GmbHInventors: Wolfgang Wehner, Hans-Helmut Friedrich, Kornelia Malzacher, Hans-Ludwig Mehner, Rolf Drewes
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Patent number: 6174941Abstract: A description is given of compounds of the general formula I where Y is oxygen or sulfur, and R1 and R2 independently of one another are C1-C18-alkyl, C3-C6-alkenyl, unsubstituted or C1-C4-alkoxy-, C5-C8-cycloalkyl-, —OH— and/or Cl-substituted C1-C18-alkyl, C5-C8-cycloalkyl, phenyl or C7-C9-phenylalkyl which is unsubstituted or substituted on the phenyl ring by C1-C4-alkyl, C1-C4-alkoxy, C5-C8-cycloalkyl, —OH and/or Cl, and R3 is unsubstituted C9-C18-alkyl or is C1-C18-alkyl substituted by —OH, C1-C12-alkoxy, phenoxy, C6-C8-alkylphenoxy, C7-C9-alkoxyphenyl, —C═O(OR4) and/or —O—COR4, or is C3-C6-alkenyl, C5-C8-cycloalkyl, or mono- to tri-OH—, —C1-C4-alkyl-, —C1-C4-alkoxy-, —C═O(OR4)— and/or —O—COR4-substituted phenyl or naphthyl, and where R4 is C1-C12-alkyl, which are suitable for stabilizing chlorine-containing polymers, especially PVC.Type: GrantFiled: June 18, 1999Date of Patent: January 16, 2001Assignee: Witco Vinyl Additives GmbHInventors: Wolfgang Wehner, Hans-Helmut Friedrich, Rolf Drewes
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Patent number: 6002004Abstract: The invention relates to compositions comprisinga) a chlorine-containing polymer andb) at least one compound containing at least one radical of the formula I ##STR1## in which A is the additional groups or atoms necessary to form an unsubstituted or substituted six-membered heterocyclic ring containing two nitrogen ring atoms.Type: GrantFiled: January 14, 1998Date of Patent: December 14, 1999Assignee: Witco Vinyl Additives GmbHInventors: Wolfgang Wehner, Hans-Helmut Friedrich, Rolf Drewes
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Patent number: 5985964Abstract: High stabilization of PVC containing recycled material is achieved by using at least one lubricant and a stabilizer containing no lead or cadmium compounds.Type: GrantFiled: December 18, 1997Date of Patent: November 16, 1999Assignee: Witco Vinyl Additives GmbHInventors: Heinz Herbst, Kurt Hoffmann, Rudolf Pfaendner, Rolf Drewes
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Patent number: 5925696Abstract: A stabilizer combination, mainly for PVC, is described, comprisingA) at least one compound of formula I ##STR1## wherein R*.sub.1 and R*.sub.2 are each independently of the other C.sub.1 -C.sub.12 alkyl, C.sub.3 -C.sub.6 lkenyl, C.sub.5 -C.sub.8 cycloalkyl that is unsubstituted or substituted by from 1 to 3 C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.5 -C.sub.8 cycloalkyl or by hydroxy groups or by chlorine atoms, or C.sub.7 -C.sub.9 phenylalkyl that is unsubstituted or substituted at the phenyl ring by from 1 to 3 C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.5 -C.sub.8 cycloalkyl or by hydroxy groups or chlorine atoms,and R*.sub.1 and R*.sub.2 may additionally be hydrogen and C.sub.1 -C.sub.Type: GrantFiled: October 10, 1996Date of Patent: July 20, 1999Assignee: Ciba Speciality Chemicals CorporationInventors: Wolfgang Wehner, Hans-Helmut Friedrich, Kornelia Malzacher, Hans-Ludwig Mehner, Rolf Drewes
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Patent number: 5859100Abstract: Compositions are described, comprisingA) rigid or semi-rigid PVC having a plasticiser content of up to 20%, andB) at least one compound of formula 1, ##STR1## wherein X is O or S, and R is H or phenyl, with the proviso that compounds from the groups of the perchlorate compounds, glycidyl compounds, beta-diketones, beta-keto esters, dihydropyridines, polydihydro-pyridines, polyols, disaccharide alcohols, sterically hindered amines (tetraalkylpiperidine compounds), alkali alumosilicates (zeolites), hydrotalcites, alkali alumocarbonates (dawsonites) are not present.Type: GrantFiled: September 22, 1997Date of Patent: January 12, 1999Assignee: Ciba Specialty Chemicals CorporationInventors: Wolfgang Wehner, Hans-Helmut Friedrich, Rolf Drewes, Kornelia Malzacher
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Patent number: 5770643Abstract: The invention relates to compositions comprisinga) a chlorine-containing polymer andb) at least one compound containing at least one radical of the formula I ##STR1## in which A is the additional groups or atoms necessary to form an unsubstituted or substituted six-membered heterocyclic ring containing two nitrogen ring atoms.Type: GrantFiled: March 20, 1996Date of Patent: June 23, 1998Assignee: Ciba Specialty Chemicals CorporationInventors: Wolfgang Wehner, Hans-Helmut Friedrich, Rolf Drewes
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Patent number: 5543449Abstract: A high degree of stabilization of flexible PVC is achieved by using a perchlorate and a terminal epoxide compound.Type: GrantFiled: April 10, 1995Date of Patent: August 6, 1996Assignee: Ciba-Geigy CorporationInventors: Rolf Drewes, Markus Kolb, Karl J. Kuhn, Hans-J urgen Sander, Wolfgang Wehner
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Patent number: 5534566Abstract: Use of a di- or polysaccharide alcohol and an inorganic or organic zinc, aluminum or rare-earth compound allows a high degree of stabilization of a halogen-containing polymer or polymer recyclate.Type: GrantFiled: April 10, 1995Date of Patent: July 9, 1996Assignee: Ciba-Geigy CorporationInventors: Wolfgang Wehner, Rolf Drewes, Karl J. Kuhn, Hans-Jurgen Sander, Markus Kolb
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Patent number: 5519077Abstract: A high degree of stabilization of polyvinyl chloride is achieved by using a perchlorate, a terminal epoxide compound and an antioxidant.Type: GrantFiled: April 10, 1995Date of Patent: May 21, 1996Assignee: Ciba-Geigy CorporationInventors: Rolf Drewes, Markus Kolb, Karl J. Kuhn, Hans-Jurgen Sander, Wolfgang Wehner
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Patent number: 5492949Abstract: Use of an inorganic or organic zinc compound and a terminal epoxide compound, optionally with chalk, gives a high level of stabilization of PVC.Type: GrantFiled: April 12, 1994Date of Patent: February 20, 1996Assignee: Ciba-Geigy CorporationInventors: Rolf Drewes, Markus Kolb, Karl Kuhn, Wolfgang Wehner
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Patent number: 5344992Abstract: There is disclosed a process for the preparation of 1,3-diketones of formula I ##STR1## wherein R.sub.1 and R.sub.2 are each independently of the other C.sub.1 -C.sub.20 alkyl, phenyl or phenyl which is substituted by halogen, hydroxy, NO.sub.2, C.sub.1 -C.sub.4 alkyl and/or C.sub.1 -C.sub.4 alkoxy, C.sub.7 -C.sub.9 phenylalkyl or a radical of formula II--A--X--R.sub.4 (II)whereinA is C.sub.1 -C.sub.12 alkylene, phenylene or phenylene which is substituted by halogen, hydroxy, NO.sub.2, C.sub.1 -C.sub.4 alkyl and/or C.sub.1 -C.sub.4 alkoxy, or is C.sub.1 -C.sub.12 alkylene which is substituted by hydroxy, halogen and/or alkoxy,X is oxygen or sulfur, andR.sub.4 is hydrogen, C.sub.1 -C.sub.18 alkyl, phenyl or phenyl which is substituted by halogen, hydroxy,C.sub.1 -C.sub.4 alkyl, NO.sub.2 and/or C.sub.1 -C.sub.4 alkoxy, or is C.sub.7 -C.sub.9 phenylalkyl, andR.sub.3 is hydrogen, C.sub.1 -C.sub.20 alkyl, phenyl or phenyl which is substituted by halogen, hydroxy, C.sub.1 -C.sub.4 alkyl, NO.sub.2 and/or C.sub.1 -C.Type: GrantFiled: May 11, 1993Date of Patent: September 6, 1994Assignee: Ciba-Geigy CorporationInventors: Rolf Drewes, Hans-Helmut Friedrich, Hans-Ludwig Mehner, Bernd Braun, Walter Wecht
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Patent number: 5322964Abstract: There is disclosed a process for the preparation of an alpha-aminoketone salt of formula I ##STR1## which comprises reacting a nitrosated keto ester of formula II ##STR2## with a carboxylic anhydride of formula IV ##STR3## under the conditions of catalytic hydrogenation, to a compound of formula III ##STR4## which compound of formula III is then hydrolysed with an acid H.sub.n A to the salt I, in which formulae above R.sub.1 is C.sub.1 -C.sub.6 alkyl, phenoxy-C.sub.1 -C.sub.4 alkyl, phenyl, C.sub.7 -C.sub.9 phenylalkyl, or phenyl or C.sub.7 -C.sub.9 phenylalkyl which are substituted by halogen, C.sub.1 -C.sub.6 alkyl or C.sub.1 -C.sub.6 alkoxy, hydroxy or cyano, R.sub.2 is C.sub.1 -C.sub.4 alkyl or cyclohexyl, n is 1 to 3, R.sub.3 is C.sub.1 -C.sub.4 alkyl and A is the radical of an organic or mineral protic acid.Pyrroles suitable as co-stabilisers for PVC can be prepared from alpha-aminoketone salts of formula I.Type: GrantFiled: September 8, 1993Date of Patent: June 21, 1994Assignee: Ciba-Geigy CorporationInventors: Rolf Drewes, Hans-Helmut Friedrich
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Patent number: 5288776Abstract: A composition comprisinga) a chlorinated polymer, andb) at least one compound of formula I ##STR1## wherein X is a group ##STR2## R.sub.1 and R.sub.2 are each independently of the other C.sub.1 -C.sub.20 alkyl, hydroxy- and/or halogen-substituted C.sub.1 -C.sub.10 alkyl, C.sub.3 -C.sub.20 alkenyl, C.sub.5 -C.sub.12 cycloalkyl, C.sub.1 -C.sub.4 alkyl-substituted C.sub.5 -C.sub.8 cycloalkyl, phenyl or phenyl which is substituted by 1 to 3 radicals A.sub.1, which radicals A.sub.1 are each independently of one another selected from the group consisting of C.sub.1 -C.sub.10 alkyl, halogen, hydroxy, methoxy and ethoxy,R.sub.1 and R.sub.2 are further C.sub.7 -C.sub.10 phenylalkyl or C.sub.7 -C.sub.10 phenylalkyl which is substituted in the phenyl moiety by 1 to 3 radicals A.sub.2, which radicals A.sub.2 are each independently of one another selected from the group consisting of C.sub.1 -C.sub.20 alkyl, halogen, hydroxy, methoxy and ethoxy, andR.sub.3 is phenyl or phenyl which is substituted by 1 to 3 radicals A.sub.Type: GrantFiled: June 3, 1991Date of Patent: February 22, 1994Assignee: Ciba-Geigy CorporationInventors: Rolf Drewes, Hans-Helmut Friedrich