Patents by Inventor Rolf Mülhaupt
Rolf Mülhaupt has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 9120909Abstract: Process for producing a polymer-graphite nanocomposite, which comprises the steps a) oxidation of graphite to graphite oxide, b) conversion of the graphite oxide into an aqueous dispersion, c) mixing of the aqueous dispersion comprising graphite oxide or, if appropriate, reduced graphite oxide which is obtained from b) with an aqueous polymer dispersion comprising at least one polymer and d) separating off the polymer-graphite mixture from the aqueous phase, wherein the graphite oxide which has been oxidized in step a) is reduced to graphite between step b) and c) or between step c) and d).Type: GrantFiled: September 13, 2010Date of Patent: September 1, 2015Assignee: Styrolution Europe GmbHInventors: Hans-Helmut Görtz, Rolf Minkwitz, Rolf Mülhaupt, Rainer Wissert, Peter Steurer
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Patent number: 9040649Abstract: The present invention relates to coating compositions repairable by introduction of energy and comprising defined fatty acid esters, to coatings obtained therewith and repairable by introduction of energy, to methods of producing them, and to their use.Type: GrantFiled: October 3, 2013Date of Patent: May 26, 2015Assignee: BASF SEInventors: Oihana Elizalde, Frederic Lucas, Angelika Maria Steinbrecher, Lydie Tuchbreiter, Axel Pfahler, Rolf Muelhaupt
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Patent number: 8946377Abstract: The present invention relates to a process for preparing high-functionality polyetherols by reacting at least one trifunctional or higher-functionality alcohol and if appropriate further di- and/or monofunctional alcohols and/or modifying reagents, with the aid of acidic catalysts, where the trifunctional or higher-functionality alcohol is not glycerol. The present invention further relates to high-functionality polyetherols obtainable by such a process and to the use of these high-functionality polyetherols as adhesion promoters, thixotropic agents, rheology modifiers of polymers, phase transfer reagents, micro- or nanocontainers for biologically active compounds, for example for active medical ingredients, biocides, herbicides or fungicides, as pigment dispersants, an additive in printing inks or as structural units for preparing polyaddition or polycondensation polymers or for treatment of seed.Type: GrantFiled: February 12, 2009Date of Patent: February 3, 2015Assignee: BASF SEInventors: Rolf Muelhaupt, Anne Fiedler, Fabian Schueler, Bernd Bruchmann, Markus Schuette, Daniel Schoenfelder
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Publication number: 20140225026Abstract: The present invention relates to polyamide composites containing graphene, a method for producing them and to their use as or for producing a material with gas barrier and/or electroconductive and/or thermally conductive properties and/or a mechanically reinforced material.Type: ApplicationFiled: February 12, 2014Publication date: August 14, 2014Applicant: BASF SEInventors: Hye Jin Park, Qi Xia, Cecile Schneider, Philippe Desbois, Bernd Bruchmann, Rolf Mülhaupt
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Publication number: 20140112973Abstract: The present invention is directed to a biocompatible and preferably biodegradable gradient layer system comprising at least one set of layers comprising a biocompatible and preferably biodegradable cross-linked polymer and at least one biocompatible and preferably biodegradable support layer, wherein a gradient is preferably formed with respect to the mechanical and/or physical properties of one or more layers of the at least one set of layers comprising a biocompatible and biodegradable cross-linked polymer and/or the at least one biocompatible and preferably biodegradable support layer. The at least one support layer preferably comprises a biocompatible and preferably biodegradable meltable polymer and/or a biocompatible and incorporable material. This biocompatible and preferably biodegradable gradient layer system may be used as a biomaterial for regenerative medicine, particularly as a wound dressing or for tissue support.Type: ApplicationFiled: April 4, 2012Publication date: April 24, 2014Applicants: ALBERT-LUDWIGS-UNIVERSITAET FREIBURG, UNIVERSITAETSKLINIKUM FREIBURGInventors: Thorsten Steinberg, Pascal Tomakidi, Simon Schulz, Marco Angarano, Rolf Muelhaupt, Martin Fabritius
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Publication number: 20140031483Abstract: The present invention relates to coating compositions repairable by introduction of energy and comprising defined fatty acid esters, to coatings obtained therewith and repairable by introduction of energy, to methods of producing them, and to their use.Type: ApplicationFiled: October 3, 2013Publication date: January 30, 2014Applicant: BASF SEInventors: Oihana ELIZALDE, Frederic Lucas, Angelika Maria Steinbrecher, Lydie Tuchbreiter, Axel Pfahler, Rolf Muelhaupt
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Patent number: 8609789Abstract: The present invention relates to halogen-free, oligomeric or polymeric phosphonic acids made up of units of the general formula (I) —[(O)m—{R1(X)n(Y)o}pR1(X)q]r—[(O)s—R5(X)t]v—??(I), where: X is —P?O(OH)2, Y is carbonyl or sulfonyl, R1, R5 are, independently of one another, divalent or polyvalent, substituted or unsubstituted, heteroatom-free or heteroatom- comprising aromatic radicals, m, o, s are each, independently of one another, 0 or 1, n, q, t are each, independently of one another, 0 or an integer from 1 to 8, with n and s not simultaneously being 0, r, v are each, independently of one another, from 0 to 1, with the sum of r and v being from 0.95 to 1.Type: GrantFiled: February 12, 2007Date of Patent: December 17, 2013Assignee: BASF SEInventors: Helmut Moehwald, Thorsten Bock, Rolf Muelhaupt
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Patent number: 8586697Abstract: The present invention relates to coating compositions repairable by introduction of energy and comprising defined fatty acid esters, to coatings obtained therewith and repairable by introduction of energy, to methods of producing them, and to their use.Type: GrantFiled: April 7, 2011Date of Patent: November 19, 2013Assignee: BASF SEInventors: Oihana Elizalde, Frederic Lucas, Angelika Maria Steinbrecher, Lydie Tuchbreiter, Axel Pfahler, Rolf Muelhaupt
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Publication number: 20120328502Abstract: The present invention relates to a preparation process for metal oxide nanotubes, the SiO2 nanotubes prepared by this process and the use of these nanotubes as catalyst supports. The invention especially concerns a supported catalyst system for polymerization of olefins, comprising a support made of fibers or a fleece of fibers.Type: ApplicationFiled: December 16, 2010Publication date: December 27, 2012Applicant: BASELL POLYOLEFINE GMBHInventors: Georg Müller, Rolf Mülhaupt, Marc Oliver Kristen
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Publication number: 20120187348Abstract: Process for producing a polymer-graphite nanocomposite, which comprises the steps a) oxidation of graphite to graphite oxide, b) conversion of the graphite oxide into an aqueous dispersion, c) mixing of the aqueous dispersion comprising graphite oxide or, if appropriate, reduced graphite oxide which is obtained from b) with an aqueous polymer dispersion comprising at least one polymer and d) separating off the polymer-graphite mixture from the aqueous phase, wherein the graphite oxide which has been oxidized in step a) is reduced to graphite between step b) and c) or between step c) and d).Type: ApplicationFiled: September 13, 2010Publication date: July 26, 2012Applicant: BASF SEInventors: Hans-Helmut Görtz, Rolf Minkwitz, Rolf Mülhaupt, Rainer Wissert, Peter Steurer
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Patent number: 8133832Abstract: The present invention relates to new catalyst supports comprising nanofibers, a catalyst system comprising these supports as well as a process for preparing nanocomposites and the nanocomposites prepared. The invention especially concerns a supported catalyst system for polymerization of olefins, comprising a support made of fibers or a fleece of fibers, wherein the mean fiber diameter is less than 1000 nm, preferably less than 500 nm and the mean fiber length is more than 200,000 nm, preferably more than 500,000 nm and especially preferred more than 1,000,000 nm as well as a process for polymerizing olefinic systems in the presence of these catalyst systems and the resulting nanocomposites.Type: GrantFiled: July 22, 2008Date of Patent: March 13, 2012Assignee: Basell Polyolefine GmbHInventors: Marc Oliver Kristen, Rolf Mülhaupt, Georg Müller
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Publication number: 20110251335Abstract: The present invention relates to coating compositions repairable by introduction of energy and comprising defined fatty acid esters, to coatings obtained therewith and repairable by introduction of energy, to methods of producing them, and to their use.Type: ApplicationFiled: April 7, 2011Publication date: October 13, 2011Applicant: BASF SEInventors: Oihana Elizalde, Frederic Lucas, Angelika Maria Steinbrecher, Lydie Tuchbreiter, Axel Pfahler, Rolf Mülhaupt
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Patent number: 8022165Abstract: Process for preparing polymeric aromatic phosphonates and also polymeric aromatic phosphonates which can be prepared by the process of the invention and blends comprising these polymeric aromatic phosphonates and at least one further polymer and also films, composites and membranes comprising these polymers or blends, the use of the membranes of the invention in fuel cells or in separation technology and also fuel cells comprising the membranes of the invention.Type: GrantFiled: February 13, 2007Date of Patent: September 20, 2011Assignee: BASF SEInventors: Helmut Moehwald, Thorsten Bock, Rolf Muelhaupt
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Publication number: 20100324261Abstract: The present invention relates to a process for preparing high-functionality polyetherols by reacting at least one trifunctional or higher-functionality alcohol and if appropriate further di- and/or monofunctional alcohols and/or modifying reagents, with the aid of acidic catalysts, where the trifunctional or higher-functionality alcohol is not glycerol. The present invention further relates to high-functionality polyetherols obtainable by such a process and to the use of these high-functionality polyetherols as adhesion promoters, thixotropic agents, rheology modifiers of polymers, phase transfer reagents, micro- or nanocontainers for biologically active compounds, for example for active medical ingredients, biocides, herbicides or fungicides, as pigment dispersants, an additive in printing inks or as structural units for preparing polyaddition or polycondensation polymers or for treatment of seed.Type: ApplicationFiled: February 12, 2009Publication date: December 23, 2010Applicant: BASE SEInventors: Rolf Muelhaupt, Anne Fiedler, Fabian Schueler, Bernd Bruchmann, Markus Schuette, Daniel Schoenfelder
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Publication number: 20100190931Abstract: The present invention relates to new catalyst supports comprising nanofibers, a catalyst system comprising these supports as well as a process for preparing nanocomposites and the nanocomposites prepared. The invention especially concerns a supported catalyst system for polymerization of olefins, comprising a support made of fibers or a fleece of fibers, wherein the mean fiber diameter is less than 1000 nm, preferably less than 500 nm and the mean fiber length is more than 200,000 nm, preferably more than 500,000 nm and especially preferred more than 1,000,000 nm as well as a process for polymerizing olefinic systems in the presence of these catalyst systems and the resulting nanocomposites.Type: ApplicationFiled: July 22, 2008Publication date: July 29, 2010Inventors: Marc Oliver Kristen, Rolf Mülhaupt, Georg Müller
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Publication number: 20100152387Abstract: The present invention relates to a process for preparing functionalized isotactic polystyrene, functionalized isotactic polystyrene which can be prepared by the process of the invention, the use of the functionalized isotactic polystyrene of the invention as macromonomer, a process for preparing a macroinitiator, a macroinitiator which can be prepared by the abovementioned process, the use of the macroinitiator for controlled free-radical polymerization, the use of the functionalized isotactic polystyrene of the invention as macromonomer, preferably in copolymerization with olefins, ROMP with cycloolefins or for coupling with silicone segments, a process for epoxidizing the functionalized isotactic polystyrene of the invention, epoxidized isotactic polystyrene which can be prepared by the abovementioned process and a process for preparing soft thermoplastic elastomers (TPEs) by metathesis polymerization of the functionalized isotactic polystyrene of the invention with suitable polymers which have terminal douType: ApplicationFiled: May 7, 2008Publication date: June 17, 2010Applicant: BASF SEInventors: Helmut Steininger, Konrad Knoll, Rolf Mülhaupt, Barbara Gall, Frédéric Pelascini
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Publication number: 20100121009Abstract: The invention relates to a catalyst system comprising a support in which transition metal cations or uncharged transition metal atoms are distributed. The system further comprises one or more separately added ligands which are capable of forming a coordinate or covalent bond with the transition metals. The catalyst system is produced by replacing metal ions present in a support by transition metal ions. The transition metal ions can optionally be reduced. One or more ligands which are capable of forming a coordinate or covalent bond with the transition metal or metals are subsequently added. The catalyst is used for the polymerization of olefins.Type: ApplicationFiled: May 5, 2008Publication date: May 13, 2010Applicant: BASELL POLYOLEGINE GMBHInventors: Marc Oliver Kristen, Rolf Mülhaupt, Gil Scheuermann, Alexander Kurek
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Publication number: 20090253840Abstract: Process for preparing polymeric aromatic phosphonates and also polymeric aromatic phosphonates which can be prepared by the process of the invention and blends comprising these polymeric aromatic phosphonates and at least one further polymer and also films, composites and membranes comprising these polymers or blends, the use of the membranes of the invention in fuel cells or in separation technology and also fuel cells comprising the membranes of the invention.Type: ApplicationFiled: February 13, 2007Publication date: October 8, 2009Applicant: BASF SEInventors: Helmut Möhwald, Thorsten Bock, Rolf Mülhaupt
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Patent number: 7495037Abstract: Polymerizable materials which contain (1) 1 to 80 wt.-% of at least one polysiloxane, (2) 0.1 to 5 wt.-% of one or more initiators for radical polymerization, (3) 0 to 60 wt.-% of radically polymerizable monomer and (4) 1 to 50 wt.-% of one or more radically polymerizable monomers which carry at least phosphonic acid group, sulphonic acid group and/or mono- or dihydrogen phosphoric acid ester group, the polysiloxane (1), the monomer (3) or both being substituted by fluorine. The materials are suitable in particular for the coating of natural or artificial teeth.Type: GrantFiled: August 27, 2004Date of Patent: February 24, 2009Assignee: Ivoclar Vivadent AGInventors: Norbert Moszner, Simone Klapdohr, Ulrich Salz, Jörg Zimmermann, Volker M. Rheinberger, Rolf Mülhaupt
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Patent number: 7129292Abstract: A process for emulsion polymerizing one or more olefins involves reacting it/them with at least one complex compound of the formula Ia or b where M is a transition metal from groups 7 to 10 of the Periodic Table of the Elements and is preferably Ni in aqueous dispersion and at least one radical R1 to R3 and optionally one radical R4 to R9 contains a hydrophilic group X, selection being made from —SO3?, —O—PO32?, NH(R15)2+, N(R15)3+ or —(OCH2CH2)nOH, where n is an integer between 1 and 15. For the process of the invention it is optional to use an activator such as, for example, olefin complexes of rhodium or of nickel.Type: GrantFiled: October 18, 2000Date of Patent: October 31, 2006Assignee: BASF AktiengesellschaftInventors: Marc Oliver Kristen, Lambertus Manders, Stefan Mecking, Florian M. Bauers, Rolf Mülhaupt