Abstract: An optical adhesive product and a process for manufacturing an optical adhesive product, laminated film ensembles, and laminated lenses. The optical adhesive product includes a glyoxal water solution that is pH adjusted for use as an optical adhesive that demonstrates a wet peel force strength above about 6 Newtons. A water based polymer, such as PVOH, may be added to the adhesive system. According to the process, the glyoxal adhesive system is manufactured and utilized to laminate TAC-PVA-TAC films together to form a polar film ensemble. The polar film ensemble is laminated to an optical substrate and in the case of an ophthalmic lens, surfaced, coated and edged. The optical adhesive product avoids film separation in the polar TAC-PAV-TAC film ensemble during edging.

Abstract: A method and coating used to prepare a photochromically-enabled bifocal ophthalmic lens. The coating is a high adhesive strength acrylate-based coating that contains a small quantity of a polycarbonate-based TPU. The coating is applied to produce an intermediate imbibable bifocal surface. A photochromic solution is subsequently imbibed by contact with the bifocal surface.

Abstract: An optical adhesive product and a process for manufacturing an optical adhesive product, laminated film ensembles, and laminated lenses. The optical adhesive product includes a glyoxal water solution that is pH adjusted for use as an optical adhesive that demonstrates a wet peel three strength above about 6 Newtons. A water based polymer, such as PVOH, may be added to the adhesive system. According to the process, the glyoxal adhesive system is manufactured and utilized to laminate TAC-PVA-TAC films together to form a polar film ensemble. The polar film ensemble is laminated to an optical substrate and in the case of an ophthalmic lens, surfaced, coated and edged.

Abstract: An acrylate-based optical coating composition containing a blend of monomers, a metal salt, a Hindered Amine Light Stabilizer (HALS), an antioxidant (AO), an initiator and a photochromic dye. The initiator has a range of free radical energy that is below a predetermined level. The cure process is controlled by the catalyst and initiator in combination with the HALS and AO to avoid deleterious reactions that can increase yellowness. The composition is well suited to be applied to a lens and cured in the mold to form a coating with reduced yellowness having high adhesion and abrasion-resistant properties. A photochromic segmented bifocal lens is produced with low photochromic fatigue and favorable % T values.

Abstract: A photochromic coating exhibiting improved performance and photochromic lenses made using the coating. The coating has excellent photochromic darkening and fatigue properties. The coating formulation is made from a monomer blend having at least two different types of monomers. A metal salt catalyst is used along with an initiator. An antioxidant is used in combination with a hindered amine light stabilizer. The coating is suitable for use in an in-mold coating process.

Abstract: The invention relates to a acrylated-based optical coating composition containing an organic peroxide initiator which presents a low yellowness level. The initiator has a range of free radical energy that is below a predetermined level. The cure process is controlled by the use a catalyst and a low energy initiator to avoid deleterious reactions that can increase yellowness. The composition is well suited to be applied to a lens and cured in the mold to form a coating with reduced yellowness having high adhesion and abrasion-resistant properties. A dye can be introduced into the composition to form a tinted lens.

Abstract: A system and method for providing photochromic segmented multifocal optical lenses. A latex primer formulation is provided for effectuating adhesion of a surface casting composition onto a lens having a photochromic coating. The method provides efficient, cost effective production of durable photochromic segmented lenses, via secure adhesion of a surface casting layer onto a photochromic substrate while maintaining desirable optical characteristics. A composite optical lens is advantageously formed having a photochromic base lens, a primer composition bonded to a convex surface of said base lens, and a cured casting composition bonded to said primer composition layer. The cured casting formulation includes a segment region to impart multifocal qualities onto the resultant composite optical lens.

Abstract: An acrylate-based optical coating composition containing a blend of monomers, a metal salt, a Hindered Amine Light Stabilizer (HALS), an antioxidant (AO), an initiator and a photochromic dye. The initiator has a range of free radical energy that is below a predetermined level. The cure process is controlled by the catalyst and initiator in combination with the HALS and AO to avoid deleterious reactions that can increase yellowness. The composition is well suited to be applied to a lens and cured in the mold to form a coating with reduced yellowness having high adhesion and abrasion-resistant properties. A photochromic segmented bifocal lens is produced with low photochromic fatigue and favorable % T values.

Abstract: A method and coating used to prepare a photochromically-enabled bifocal ophthalmic lens. The method and equipment includes injection molding a single vision lens, for example, from polycarbonate. The clamp opens vertically and the top insert is exchanged for a bifocal mold having a base curve similar to the single vision lens. The thermoset coating includes compounds from several acrylate classes, and is applied to the single vision lens. The coating may include a photochromic dye. The coating is also formulated to receive a photochromic solution through an imbibition process.

Abstract: A method used to prepare a photochromically-enabled bifocal ophthalmic lens. A lens substrate is injection molded and then a coating is applied to the substrate to form a bifocal surface. The coating is a high adhesive strength acrylate-based coating that contains a small quantity of a polycarbonate-based TPU. The thermoset coating produces an intermediate imbibable bifocal surface. A photochromic solution is subsequently imbibed by contact with the bifocal surface. The TPU acts as an adhesion enhancer so that the coating to substrate integrity is maintained following the imbibing step.

Abstract: Processes suitable for creating polarized articles using polyvinyl alcohol films, and articles produced by those processes.

Abstract: A method and coating used to prepare a photochromically-enabled bifocal ophthalmic lens. The coating is a high adhesive strength acrylate-based coating that contains a small quantity of a polycarbonate-based TPU. The coating is applied to produce an intermediate imbibable bifocal surface. A photochromic solution is subsequently imbibed by contact with the bifocal surface.

Abstract: A method and coating used to prepare a photochromically-enabled bifocal ophthalmic lens. The coating is a high adhesive strength acrylate-based coating that contains a small quantity of a polycarbonate-based TPU. The coating is applied to produce an intermediate imbibable bifocal surface. A photochromic solution is subsequently imbibed by contact with the bifocal surface.

Abstract: The invention relates to a acrylated-based optical coating composition containing an organic peroxide initiator which presents a low yellowness level. The initiator has a range of free radical energy that is below a predetermined level. The cure process is controlled by the use a catalyst and a low energy initiator to avoid deleterious reactions that can increase yellowness. The composition is well suited to be applied to a lens and cured in the mold to form a coating with reduced yellowness having high adhesion and abrasion-resistant properties. A dye can be introduced into the composition to form a tinted lens.

Abstract: A photochromic coating exhibiting improved performance and photochromic lenses made using the coating. The coating has excellent photochromic darkening and fatigue properties. The coating formulation is made from a monomer blend having at least two different types of monomers. A metal salt catalyst is used along with an initiator. An antioxidant is used in combination with a hindered amine light stabilizer. The coating is suitable for use in an in-mold coating process.

Abstract: A system and method for providing photochromic segmented multifocal optical lenses. A latex primer formulation is provided for effectuating adhesion of a surface casting composition onto a lens having a photochromic coating. The method provides efficient, cost effective production of durable photochromic segmented lenses, via secure adhesion of a surface casting layer onto a photochromic substrate while maintaining desirable optical characteristics. A composite optical lens is advantageously formed having a photochromic base lens, a primer composition bonded to a convex surface of said base lens, and a cured casting composition bonded to said primer composition layer. The cured casting formulation includes a segment region to impart multifocal qualities onto the resultant composite optical lens.

Abstract: A method and coating used to prepare a photochromically-enabled bifocal ophthalmic lens. The coating is a high adhesive strength acrylate-based coating that contains a small quantity of a polycarbonate-based TPU. The coating is applied to produce an intermediate imbibable bifocal surface. A photochromic solution is subsequently imbibed by contact with the bifocal surface.

Abstract: A method and coating used to prepare a photochromically-enabled bifocal ophthalmic lens. The method and equipment includes injection molding a single vision lens, for example, from polycarbonate. The clamp opens vertically and the top insert is exchanged for a bifocal mold having a base curve similar to the single vision lens. The thermoset coating includes compounds from several acrylate classes, and is applied to the single vision lens. The coating may include a photochromic dye. The coating is also formulated to receive a photochromic solution through an imbibition process.

Abstract: The invention relates to a process for manufacturing a polarized poly(thio)urethane-based optical article comprising the steps of disposing a polarizing film or wafer in a molding cavity of a two part mold assembly; pouring a polymerizable composition comprising at least one polyiso(thio)cyanate monomer and at least one polyol and/or polythiol; or a mixture of at least one liquid NCO and/or NCS terminated poly(thio)urethane prepolymer and at least one liquid OH and/or SH terminated poly(thio)urethane prepolymer; with the proviso that the polymerizable composition has a ratio of NH2 functionalities to the NCO or NCS functionalities of less than 0.9; polymerizing the composition under such conditions that a hard gel is obtained in less than 30 minutes; completing the polymerization; and opening the two part mold so as to recover the bubble free optical article.

Abstract: Processes suitable for creating polarized articles using polyvinyl alcohol films, and articles produced by those processes.